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NASA NTRS2010

Active Dust Control and Mitigation Technology for Lunar and Martian Exploration

Mars is covered with a layer of dust that has been homogenized by global dust storms. Dust, levitated by these storms as well as by the frequent dust devils, is the dominant weather phenomenon on Mars. NASA's Mars exploration rovers have shown that atmospheric dust falling on solar panels can decrease their efficiency to the point of rendering the rover unusable. Dust covering the surface of the moon is expected to be electrostatically charged due to the solar wind, cosmic rays, and the solar radiation itself through the photoelectric effect. Electrostatically charged dust has a large tendency to adhere to surfaces. The Apollo missions to the moon showed that lunar dust adhesion can hinder manned and unmanned exploration activities. In this paper, we report on our efforts to develop and electrodynamic dust shield to prevent the accumulation of dust on surfaces and to remove dust already adhering to those surfaces. The technology uses electrostatic and dielectrophoretic forces to carry dust particles off surfaces and to generate an electrodynamic shield that prevents further accumulation of dust. The concept of the electrodynamic dust shield was introduced by NASA in the late 1960s and later reduced to practice during the 1970s for terrestrial applications. In 2003, our laboratory, in collaboration with several universities, applied this technology to space applications, specifically to remove dust from solar panels on Mars. We show how, with an appropriate design, we can prevent the electrostatic breakdown at the low Martian atmospheric pressures. We are also able to show that uncharged dust can be lifted and removed from surfaces under simulated Martian environmental conditions. We have also been able to develop a version of the electrodynamic dust shield working under hard vacuum conditions that simulate the lunar environment. We have implemented the electrodynamic dust shield on solar arrays, optical systems, spectrometers, viewports, thermal radiators, batteries, and power systems, as well as on fabrics for spacesuits. We present data on the design and optimization of the electrodynamic dust shields and provide data on the performance of the different implementations of the technology for lunar and Martian exploration activities.

Calle, C. I.↗

NASA NTRS2019

How Well Does NASA GEOS Model Perform in Simulating Dust Deposition into the Tropical Atlantic Ocean?

Massive dust emitted from North Africa can transport long distances across the tropical Atlantic Ocean, reaching the Americas. Dust deposition along the transit adds microorganisms and essential nutrients to marine ecosystem, which has important implications for biogeochemical cycle and climate. However, assessing the dust-ecosystemclimate interactions has been hindered in part by the paucity of dust deposition measurements and large uncertainties associated with oversimplified representations of dust processes in current models. We have recently produced a unique dataset of seasonal dust deposition flux and dust loss frequency into the tropical Atlantic Ocean at a nominal resolution of 200 km x 500 km by using the decade-long (2007-2016) record of aerosol three-dimensional distribution from four satellite sensors, namely CALIOP, MODIS, MISR, and IASI. On the basis of the ten-year average, the yearly dust deposition into the tropical Atlantic Ocean is estimated at 98-153 Tg. The dust deposition shows large spatial and temporal (on seasonal and interannual scale) variability. The satellite observations also yield an estimate of annual mean dust loss frequency of 0.052 ~ 0.078 d-1, a useful diagnostic that makes it possible to disentangle the dust transport and removal processes from the dust emissions when identifying the major factors contributing to the uncertainties and biases in the model simulated dust deposition. In this study, we use the dataset along with in situ and remote sensing observations to assess how well NASA GEOS model performs in simulating trans-Atlantic dust transport and deposition. We found that the GEOS modeling of dust deposition falls within the range of satellite-based estimates. However, this reasonable agreement in dust deposition is a compensation of the model's underestimate of dust emissions and overestimate of dust removal efficiency. Further, the overestimate of dust removal efficiency results largely from the model's overestimate of rainfall rate. Our results provide insights into the model's deficiencies at process level, which could better guide model improvements.

Yu, Hongbin↗

NASA NTRS2023

Dust Lifting Observations with the Mars Science Laboratory Navigation Cameras

Martian dust lifting is believed to occur through two primary mechanisms: dust devils and wind stress forced dust lifting. Gale Crater's varied terrain and meteorology provide a unique in situ perspective on Martian dust lifting, with the Mars Science Laboratory Curiosity rover passing through both conditions and locations detrimental to dust lifting (e.g., the crater floor) and those with active sand motion and frequent dust lifting (e.g., the Bagnold Dunes). Between L s = 248° in Mars Year 33 and L s = 51° in Mars Year 37, over ∼3.5 Mars years and 2,300 sols, the rover's Navigation Cameras took 1,260 dedicated image sequences to search for dust lifting. Approximately 42.7% of all sequences, and 9.5% of the total images have shown active dust lifting, both dust devils and linear/straight-line wind stress dust lifting. 79% of dust lifting events are classified as dust devils, while ∼16% are linear wind stress dust lifting and the remainder are of an indeterminate type. We analyze this large catalog of dust lifting events to provide ground truth on theoretical and model expectations of dust lifting and show that dust lifting in Gale Crater occurs throughout the Martian year, is strongly peaked in frequency near solar noon (even after accounting for observational biases), and that dust lifting shows an affinity for sand-covered surfaces which highlights the importance of saltating sand grains for Martian dust lifting in both dust devils and wind stress forced lifting.

Scott D. Guzewich↗

NASA NTRS2022

Importance of Different Parameterization Changes for the Updated Dust Cycle Modeling in the Community Atmosphere Model (Version 6.1)

The Community Atmosphere Model (CAM6.1), the atmospheric component of the Community Earth System Model (CESM; version 2.1), simulates the life cycle (emission, transport, and deposition) of mineral dust and its interactions with physio-chemical components to quantify the impacts of dust on climate and the Earth system. The accuracy of such quantifications relies on how well dust-related processes are represented in the model. Here we update the parameterizations for the dust module, including those on the dust emission scheme, the aerosol dry deposition scheme, the size distribution of transported dust, and the treatment of dust particle shape. Multiple simulations were undertaken to evaluate the model performance against diverse observations, and to understand how each update alters the modeled dust cycle and the simulated dust direct radiative effect. The model–observation comparisons suggest that substantially improved model representations of the dust cycle are achieved primarily through the new more physically-based dust emission scheme. In comparison, the other modifications induced small changes to the modeled dust cycle and model–observation comparisons, except the size distribution of dust in the coarse mode, which can be even more influential than that of replacing the dust emission scheme. We highlight which changes introduced here are important for which regions, shedding light on further dust model developments required for more accurately estimating interactions between dust and climate.

mineral dust parameterizations↗

NASA NTRS2007

The Lunar Environment: Determining the Health Effects of Exposure to Moon Dusts

The Earth s moon presents a hostile environment in which to live and work. There is no atmosphere to protect its surface from the ravages of solar wind and micrometeorite impacts. As a result, the moon s surface is covered with a thin layer of fine, charged, reactive dust capable of entering habitats and vehicle compartments, where it can result in crewmember health problems. During the Apollo missions, lunar dusts were introduced into the crew vehicle, resulting in direct exposure and occasional reports of respiratory, dermal and ocular irritation. In order to study the toxicological effects of lunar dust, NASA formed the Lunar Airborne Dust Toxicity Advisory Group (LADTAG). This interdisciplinary group is comprised of leading experts in space toxicology, lunar geology, space medicine and biomedical research. LADTAG has demonstrated that lunar soil contains several types of reactive dusts, including an extremely fine respirable component. These dusts have highly reactive surfaces in the lunar environment; the grains contain surface coatings which are generated by vapor phases formed by hypervelocity impact of micrometeorites. This unique class of dusts has surface properties that are unlike any Earth based analog. These distinctive properties are why lunar dusts are of great toxicological interest. Understanding how these reactive components behave "biochemically" in a moisture-rich pulmonary environment will aid in determining how toxic these particles are to humans. The data obtained from toxicological examination of lunar dusts will determine the human risk criteria for lunar dust exposure and produce a lunar health standard. LADTAG s analysis of lunar dusts and lunar dust simulants will include detailed lunar particle characterizations, determining the properties of particle activation, reactivation of lunar dust, the process of dust passivation and discerning the pathology of lunar dust exposure via inhalation, intratracheal instillation, cell culture exposure, dermal exposure and ocular exposure. The resulting health standard will be time-based and will vary by the duration and type of exposure. It may also be necessary to set multiple standards for different types of lunar dust, as well as for dust in its activated form vs. aged & passivated dust. This standard, set to protect the health of our robust astronaut crews, will not only impact NASA medical operations, but engineering designs as well. The data from our multidisciplinary research are vital in developing remediation devices and environmental monitors. Ultimately, the engineering and safety groups will design and develop countermeasures for space vehicles, suits, rovers and habitats that will be sustained within the limits of the health standard.

Khan-Mayberry, Noreen↗

NASA NTRS2012

Pulmonary Toxicity Studies of Lunar Dust in Rodents

NASA has been contemplating returning astronauts to the moon for long-duration habitation and research and using it as a stepping-stone to Mars. Other spacefaring nations are planning to send humans to the moon for the first time. The surface of the moon is covered by a layer of fine dust. Fine terrestrial dusts, if inhaled, are known to pose a health risk to humans. Some Apollo crews briefly exposed to moon dust that adhered to spacesuits and became airborne in the Lunar Module reported eye and throat irritation. The habitable area of any lunar landing vehicle or outpost would inevitably become contaminated with lunar dust. To assess the health risks of exposure of humans to airborne lunar dust, we evaluated the toxicity of Apollo 14 moon dust in animal lungs. Studies of the pulmonary toxicity of a dust are generally first done by intratracheal instillation (ITI) of aqueous suspensions of the test dust into the lungs of rodents. If a test dust is irritating or cytotoxic to the lungs, the alveolar macrophages, after phagocytizing the dust particles, will release cellular messengers to recruit white blood cells (WBCs) and to induce dilation of blood capillary walls to make them porous, allowing the WBCs to gain access to the alveolar space. The dilation of capillary walls also allows serum proteins and water entering the lung. Besides altering capillary integrity, a toxic dust can also directly kill the cells that come into contact with it or ingest it, after which the dead cells would release their contents, including lactate dehydrogenase (a common enzyme marker of cell death or tissue damage). In the treated animals, we lavaged the lungs 1 and 4 weeks after the dust instillation and measured the concentrations of these biomarkers of toxicity in the bronchioalveolar lavage fluids to determine the toxicity of the dust. To assess whether the inflammation and cellular injury observed in the biomarker study would lead to persistent or progressive histopathological changes, a similar study was conducted to microscopically examine rat lung tissue and the associated lymph nodes for lesions, including fibrosis, 1 or 3 months after the instillation. The results from this ITI study led us to select two concentrations (20 and 60 mg/cu m) for an inhalation study, in which rats were exposed to lunar dust 6 h daily for 4 weeks (5d/wk). Similar biochemical and histopathological assessments were carried out in these rats 1 day or 1, 4, or 13 weeks after the dust exposure. Rats exposed to lunar dust by ITI or inhalation showed effects indicating that the dust is moderately toxic. The data will be useful to establish safe exposure limits for astronauts working in a lunar habitat and also help engineers designing dust mitigation systems for lunar vehicles and habitats.

Lam, Chiu-Wing↗

NASA NTRS2021

Mineral Dust Cycle in the Multiscale Online Nonhydrostatic AtmospheRe CHemistry Model (Monarch) Version 2.0

We present the dust module in the Multiscale Online Non-hydrostatic AtmospheRe CHemistry model (MONARCH) version 2.0, a chemical weather prediction system that can be used for regional and global modeling at a range of resolutions. The representations of dust processes in MONARCH were upgraded with a focus on dust emission (emission parameterizations, entrainment thresholds, considerations of soil moisture and surface cover), lower boundary conditions (roughness, potential dust sources), and dust–radiation interactions. MONARCH now allows modeling of global and regional mineral dust cycles using fundamentally different paradigms, ranging from strongly simplified to physics-based parameterizations. We present a detailed description of these updates along with four global benchmark simulations, which use conceptually different dust emission parameterizations, and we evaluate the simulations against observations of dust optical depth. We determine key dust parameters, such as global annual emission/deposition flux, dust loading, dust optical depth, mass-extinction efficiency, single-scattering albedo, and direct radiative effects. For dust-particle diameters up to 20 µm, the total annual dust emission and deposition fluxes obtained with our four experiments range between about 3500 and 6000 Tg, which largely depend upon differences in the emitted size distribution. Considering ellipsoidal particle shapes and dust refractive indices that account for size-resolved mineralogy, we estimate the global total (longwave and shortwave) dust direct radiative effect (DRE) at the surface to range between about −0.90 and −0.63 W m−2 and at the top of the atmosphere between −0.20 and −0.28 W m−2. Our evaluation demonstrates that MONARCH is able to reproduce key features of the spatiotemporal variability of the global dust cycle with important and insightful differences between the different configurations.

Dust cycle↗

NASA NTRS2013

Interstellar and Ejecta Dust in the Cas A Supernova Remnant

The ejecta of the Cas A supernova remnant has a complex morphology, consisting of dense fast-moving line emitting knots and diffuse X-ray emitting regions that have encountered the reverse shock, as well as more slowly expanding, unshocked regions of the ejecta. Using the Spitzer 5-35 micron IRS data cube, and Herschel 70, 100, and 160 micron PACS data, we decompose the infrared emission from the remnant into distinct spectral components associated with the different regions of the ejecta. Such decomposition allows the association of different dust species with ejecta layers that underwent distinct nuclear burning histories, and determination of the dust heating mechanisms. Our decomposition identified three characteristic dust spectra. The first, most luminous one, exhibits strong emission features at approx. 9 and 21 micron, and a weaker 12 micron feature, and is closely associated with the ejecta knots that have strong [Ar II] 6.99 micron and [Ar III] 8.99 micron emission lines. The dust features can be reproduced by magnesium silicate grains with relatively low MgO-to-SiO2 ratios. A second, very different dust spectrum that has no indication of any silicate features, is best fit by Al2O3 dust and is found in association with ejecta having strong [Ne II] 12.8 micron and [Ne III] 15.6 micron emission lines. A third characteristic dust spectrum shows features that best matched by magnesium silicates with relatively high MgO-to-SiO2 ratio. This dust is primarily associated with the X-ray emitting shocked ejecta and the shocked interstellar/circumstellar material. All three spectral components include an additional featureless cold dust component of unknown composition. Colder dust of indeterminate composition is associated with [Si II] 34.8 micron emission from the interior of the SNR, where the reverse shock has not yet swept up and heated the ejecta. The dust mass giving rise to the warm dust component is about approx. 0.1solar M. However, most of the dust mass is associated with the unidentified cold dust component. Its mass could be anywhere between 0.1 and 1 solar M, and is primarily limited by the mass of refractory elements in the ejecta. Given the large uncertainty in the dust mass, the question of whether supernovae can produce enough dust to account for ISM dust masses in the local and high-z universe remains largely unresolved.

Interstellar↗

NASA NTRSDate not supplied

Passive Dust Mitigation Technologies Being Developed for Demonstration Under Patch Plate Materials Compatibility Analysis Task

With the Artemis program, we are planning longer stays on the surface, with more activities that have the potential to put the astronauts and equipment in contact with greater quantities of lunar dust. The success of these missions will depend on our understanding of material interactions with lunar dust and the development of ways to mitigate dust effects in cases where exposure to dust will lead to failure of components, unacceptable loss of power or thermal control, unacceptable loss of visibility, or health issues. Passive dust mitigation by coating or surface alteration is one method that is being developed and demonstrated under the Space Technology Mission Directorate’s Game Changing Technology, Dust Mitigation Program as part of the Patch Plate Materials Compatibility Assessment Task. The goal of the task is to alter the surfaces of materials in order to passively reduce the adhesion of dust, demonstrate their performance in relevant ground-based tests using lunar simulants, and prepare them for demonstration through experiment on the lunar surface. Optically transparent, sputter deposited, work function matching coatings are being developed to reduce adhesion of dust to windows, lenses and display panels by matching the minimum energy to remove an electron from the surface to that of lunar dust in order to reduce adhesion due to charge transfer. Low surface energy coatings and surfaces for thermal control are also being developed to reduce the bonding of dust with the surface enabling it to be removed more easily. Conductive coatings with the ability to shed dust more easily are being developed for use with the active Electrodynamic Dust Shield technology to help reduce the power needed to remove dust from the surface. Passive dust mitigation surfaces for metals such as aluminum, stainless steel, and titanium are being developed that reduce the area of dust contact with the surfaces through topographical modification using laser ablation patterning to impart hierarchical topographies with nanometer to micrometer length scales in a single step. Topographically modified polymeric materials, both those with extensive space heritage and those with lower technology readiness levels, are also being evaluated. Space suit fabric surfaces that can reduce dust penetration into and through the fabric are also being investigated as well as pristine and topographically modified ceramic materials that exhibit high wear resilience. An overview of the passive dust mitigation surfaces and coatings being developed under this task, ground testing being conducted using lunar simulants, characterization techniques, and materials preparation for flight sample delivery for integration into the Alpha Space Regolith Adherence Characterization experiment going to the lunar surface on a Commercial Lunar Payload Services (CLPS) lander in 2023 will be discussed.

Lunar dust, passive mitigation, lunar simulant, co↗

NASA NTRS2021

Less Atmospheric Radiative Heating By Dust Due to the Synergy of Coarser Size and Aspherical Shape

Mineral dust aerosols cool and warm the atmosphere by scattering and absorbing solar (shortwave: SW) and thermal (longwave: LW) radiation. However, significant uncertainties remain in dust radiative effects, largely due to differences in the dust size distribution and spectral optical properties simulated in Earth system models. Dust models typically underestimate the coarse dust load (more than 2.5 µm in diameter) and assume a spherical shape, which leads to an overestimate of the fine dust load (less than 2.5 µm) after the dust emissions in the models are scaled to match observed dust aerosol optical depth at 550 nm (DAOD550). Here, we improve the simulated dust properties with data sets that leverage measurements of size-resolved dust concentration, asphericity factor, and refractive index in a coupled global chemical transport model with a radiative transfer module. After the adjustment of size-resolved dust concentration and spectral optical properties, the global and annual average of DAOD550 from the simulation increases from 0.023 to 0.029 and falls within the range of a semi-observationally based estimate (0.030 ± 0.005). The reduction of fine dust load after the adjustment leads to a reduction of the SW cooling at the top of the atmosphere (TOA). To improve agreement against a semi-observationally based estimate of the radiative effect efficiency at TOA, we find that a less absorptive SW dust refractive index is required for coarser aspherical dust. Thus, only a minor difference is estimated for the net global dust radiative effect at TOA (−0.08 vs. −0.00 W m−2 on a global scale). Conversely, our sensitivity simulations reveal that the surface warming is substantially enhanced near the strong dust source regions (less cooling to −0.23 from −0.60 W m−2 on a global scale). Thus, less atmospheric radiative heating is estimated near the major source regions (less heating to 0.15 from 0.59 W m−2 on a global scale), because of enhanced LW warming at the surface by the synergy of coarser size and aspherical shape.

simulated dust properties↗

NASA NTRS2008

Electrostatic Charging of Lunar Dust by UV Photoelectric Emissions and Solar Wind Electrons

The ubiquitous presence of dust in the lunar environment with its high adhesive characteristics has been recognized to be a major safety issue that must be addressed in view of its hazardous effects on robotic and human exploration of the Moon. The reported observations of a horizon glow and streamers at the lunar terminator during the Apollo missions are attributed to the sunlight scattered by the levitated lunar dust. The lunar surface and the dust grains are predominantly charged positively by the incident UV solar radiation on the dayside and negatively by the solar wind electrons on the night-side. The charged dust grains are levitated and transported over long distances by the established electric fields. A quantitative understanding of the lunar dust phenomena requires development of global dust distribution models, based on an accurate knowledge of lunar dust charging properties. Currently available data of lunar dust charging is based on bulk materials, although it is well recognized that measurements on individual dust grains are expected to be substantially different from the bulk measurements. In this paper we present laboratory measurements of charging properties of Apollo 11 & 17 dust grains by UV photoelectric emissions and by electron impact. These measurements indicate substantial differences of both qualitative and quantitative nature between dust charging properties of individual micron/submicron sized dust grains and of bulk materials. In addition, there are no viable theoretical models available as yet for calculation of dust charging properties of individual dust grains for both photoelectric emissions and electron impact. It is thus of paramount importance to conduct comprehensive measurements for charging properties of individual dust grains in order to develop realistic models of dust processes in the lunar atmosphere, and address the hazardous issues of dust on lunar robotic and human missions.

Abbas, Mian M.↗

NASA NTRS2019

The Mars Global Dust Storm of 2018

Mars is a dusty planet. Wind often lifts dust from the surface into the air forming clouds of dust at different locations across Mars. These dust storms typically last up to a couple days and grow to a few hundred km in size. However, once in a long while when conditions are just right, localized dust storms can interact in a way that optically thick suspended dust covers nearly the entire planet remaining aloft for weeks to months. These global-scale dust storms are the most dramatic of all weather phenomena on Mars, greatly altering the thermal structure and dynamics of the Martian atmosphere and significantly changing the global distribution of surface dust. Such a global-scale dust storm occurred during the summer of 2018, the first such event since 2007. The global dust storm was observed by an international fleet of spacecraft in Mars orbit and on the surface of Mars providing an unprecedented view of the initiation, growth, and decay of the storm as well as the physical properties of the dust during the storm's evolution. The 2018 global-scale dust storm was observed to grow from several localized dust-lifting centers with wind-blown dust suspended in the atmosphere encircling Mars after about two weeks of activity. Dust column optical depths recorded by the Opportunity and Curiosity rovers on the surface were the highest ever recorded on Mars. Peak global intensity of the dust storm was reached in early July 2018. Over the next couple months, the dust settled out and the atmosphere returned to its climatological average. Only a small number of global-scale dust storms have been observed on Mars, and so detailed analysis of the observations of this storm will provide important new insight into how these events occur and their effect on the current Mars climate.

Smith, Michael D.↗

NASA NTRS2024

Mineral Dust Optical Properties for Remote Sensing and Global Modeling: A Review

Dust plays a key role in many Earth system processes and is ubiquitous in the Martian atmosphere. Various intensive field campaigns, laboratory analyses, space-based remote sensing missions, and global modeling efforts aim to characterize dust optical properties. This is a bountiful time for dust scientists, and yet the interpretation of retrievals and comparison to models remains complicated by various conflicting assumptions that are part of each algorithm. For example, the conversion of satellite radiance measurements into products like aerosol optical depth for model evaluation depends upon aerosol properties like particle size and shape that are often prescribed and not part of the retrieval. Conversely, the model calculation of aerosol optical depth often uses different assumptions. The goal of this review is to first document algorithmic assumptions by various satellite retrieval products and models, and identify where there is consistency and where there are differences. In general, the differences documented in this paper reflect uncertainties resulting from incomplete observational characterization of dust aerosols and limitations in our understanding. Second, we note what observations might reduce uncertainties in our knowledge and bring greater consistency to retrievals and models, allowing for a more rigorous and harmonious comparison. The lack of comprehensive and realistic shape models for dust is an outstanding issue, such that closure between forward modeling from particle refractive index, shape, and size and observed optical properties cannot be achieved. Limitations in the computational methods that must be applied to model scattering from complex shapes also makes accurate optical modeling for dust challenging. Field observations indicate the persistence of coarse and giant dust particles at higher altitudes and farther downwind from their source than previously expected. Remote sensing retrieval algorithms based on observations at visible wavelengths have limited sensitivity to these particles and generally do not consider them, although a recent product based on longwave radiances is encouraging. Current measurements of the refractive index of bulk dust and fundamental dust minerology components such as hematite vary widely, inhibiting attempts to represent the variability in dust optical properties and forcing, as expected from different major dust source regions on Earth that have varying mineralogical composition. Some remote sensing retrieval algorithms allow for limited refractive index variability in their inversion solutions through mixing with other fine mode aerosol models, or optimizing the single scattering albedo, but Earth system models surveyed for this paper assume a globally uniform, size-invariant refractive index. Although no Martian dust samples have yet been returned to Earth, remote sensing observations indicate that Martian dust is globally homogenous in composition, and a single spectral refractive index assumption has been widely adopted to represent Martian dust. The lack of comprehensive, statistically representative measurements of dust particle microphysical properties (size distribution, morphology, complex index of refraction spectra, internal structure heterogeneity), and the resulting optical properties, limits our ability to verify the fidelity of these assumptions. A chain of measurements is needed, ranging from characterizing individual dust mineralogy components (e.g., pure hematite and goethite) to in situ sampling of complex atmospheric aerosol mixtures. Such results could be applied to both remote sensing retrievals that characterize the optical properties of the total aerosol burden in the atmosphere from total radiance measurements, and to global models that represent the total aerosol burden in the atmosphere by building it up from the balance of individual aerosol sources and sinks.

Aeolian dust↗

NASA NTRS2014

Shaping the Dust Mass-Star-Formation Rate Relation

There is a remarkably tight relation between the observationally inferred dust masses and star-formation rates (SFRs) of Sloan Digital Sky Survey galaxies, M dust ∝ SFR 1.11(exp). Here we extend the M dust-SFR relation to the high end and show that it bends over at very large SFRs (i.e., dust masses are lower than predicted for a given SFR). We identify several distinct evolutionary processes in the diagram: (1) a star-bursting phase in which dust builds up rapidly at early times. The maximum attainable dust mass in this process is the cause of the bend-over of the relation. A high dust-formation efficiency, a bottom-light initial mass function, and negligible supernova shock dust destruction are required to produce sufficiently high dust masses. (2) A quiescent star-forming phase in which the subsequent parallel decline in dust mass and SFR gives rise to the M dust-SFR relation, through astration and dust destruction. The dust-to-gas ratio is approximately constant along the relation. We show that the power-law slope of the M dust-SFR relation is inversely proportional to the global Schmidt-Kennicutt law exponent (i.e., ~0.9) in simple chemical evolution models. (3) A quenching phase which causes star formation to drop while the dust mass stays roughly constant or drops proportionally. Combined with merging, these processes, as well as the range in total baryonic mass, give rise to a complex population of the diagram which adds significant scatter to the original M dust-SFR relation. (4) At very high redshifts, a population of galaxies located significantly below the local relation is predicted.

Shaping↗

NASA NTRSDate not supplied

Chemical Reactivity of In-Situ Lunar Dust for Biotoxicity Assessment

Introduction: How does the chemical reactivity of in-situ lunar dust compare to Apollo samples currently stored in curation facilities here on Earth? Essential investigations of this question will help us to further mitigate exploration risks for future human explorers on the Moon and will also provide critical information for astrobiologists and space biologists using the Moon for scientific inquiry. Discussion: Apollo 14 dust biotoxicity studies, carried out by the NASA Lunar Airborne Dust Toxici-ty Assessment Group (LADTAG), included numerous physiochemical studies[1] and cellular and animal ex-periments. Intratracheal instillation [2] and inhalation studies [3] in rats both showed Apollo 14 dust to be intermediate in toxicity compared to low-tox titanium dusts and high-tox quartz dusts of similar particle siz-es. The collective results were used in models [4] to establish a safe exposure limit for astronauts [5]. Alt-hough LADTAG took extensive steps to preserve what chemical reactivity may still have existed in the sam-ples, it is simply unknown if they possessed true in-situ chemical reactivity or if that reactivity has de-cayed. Initial gas loss on collection and other altera-tions, and even intermittent exposure to Earth-normal conditions during subsequent decades of handling, obscure a forensic reconstruction of the initial state. Because a mineral dust’s chemical reactivity influ-ences its biotoxicity [6], researchers have developed methods to “activate” lunar dust and simulants [7][8]. Past studies that modeled impact processes and radia-tion [9] in the lunar environment suggest that in-situ lunar dust is likely to be more chemically reactive than Earth-exposed samples. Because of these results, in-situ measurements are warranted [10]. Other studies have examined the hydroxyl generating capability of iron bearing mineral phases [11][12] and further em-phasize the role iron plays in chemical reactivity of lunar material, as well as decay of chemical reactivity in mineral dusts [12]. Recent observations of the lunar surface reveal the presence of hematite [13], a finding that further supports the hypothesis that in-situ lunar dust is reactive. Since the lunar surface is heterogene-ous, dust biotoxicity is expected to vary from site to site [14] due to particle size, mineralogy, physical characteristics, degree of space weathering, and chemi-cal reactivity (Figure 1). This circumstance dictates dust assessments at a suite of lunar sites enabled by upcoming NASA and commercial lunar payload ser-vices (CLPS) opportunities. Dose, location, and dura-tion of particle exposure will also affect biological responses. In-situ chemical reactivity measurements can inform cross-cutting collaborative research cam-paigns such as astrobiology studies examining regolith interactions with organisms and its ability to preserve chemical and structural biomarkers, as well as space biology investigations that examine regolith-microbe interactions relating to life support systems, plant growth, biomining, and development of regolith bio-composites. Figure 1: Environment conditions on the lunar surface that may alter regolith reactivity. Summary A series of in-situ measurements of lu-nar dust free radical chemistry at future Artemis and CLPS landing sites, combined with LADTAG-like studies of freshly collected lunar dust specimens, will reveal the true chemical reactivity of in-situ lunar dust and generate scientific data that can be compared to the chemical reactivity and biotoxicity of samples from Apollo landing sites. Furthermore, results from in situ measurements and biotoxicity studies of freshly col-lected specimens can also be used to validate, or re-quire revision of, the current astronaut permissible exposure limit [15]. References: [1] McKay D et al (2015), Acta As-tronaut 107:163–176. [2] Rask J et al (2013), LPSC, p 3062. [3] Lam CW et al (2013), Inhal Toxicol 25:661–678. [4] James JT, et. al. (2013) , Inhal Toxicol 25:243–256. [5] Scully RR, et.al. (2013), Inhal Toxi-col 25:785–793. [6] Porter, D. W., et.al., (2002), Tox-icology 175, 63–71. [7] Wallace WT, et.al., (2009), Meteorit Planet Sci 44:961–970. [8] Wallace WT, et.al., (2010), Earth Planet Sci Lett 295:571–577. [9] Loftus D, Rask J, et.al., (2010), Earth Moon Planet 107:95–105. [10] Rask J, et.al., (2009) LEAG p 57. [11] Turci F, et.a., (2015), Astrobiology. 2015;15(5):371-380. [12] Hendrix DA, et.al., (2019), Geohealth. 2019;3(1):28-42. [13] Li, S., et.al., (2020), Science advances, 6(36), p.eaba1940. [14] Rask J. (2018), In: Cudnik B. (eds) Encyclopedia of Lunar Science. Springer, Cham. [15] Rask, J, (2020), LPI, Artemis III Sci. def. paper 2120.

chemical reactivity↗

NASA NTRS2022

Newly Identified Climatically and Environmentally Significant High-Latitude Dust Sources

Dust particles from high latitudes have a potentially large local, regional, and global significance to climate and the environment as short-lived climate forcers, air pollutants, and nutrient sources. Identifying the locations of local dust sources and their emission, transport, and deposition processes is important for understanding the multiple impacts of high-latitude dust (HLD) on the Earth’s systems. Here, we identify, describe, and quantify the source intensity (SI) values, which show the potential of soil surfaces for dust emission scaled to values 0 to 1 concerning globally best productive sources, using the Global Sand and Dust Storms Source Base Map (G-SDS-SBM). This includes 64 HLD sources in our collection for the northern (Alaska, Canada, Denmark, Greenland, Iceland, Svalbard, Sweden, and Russia) and southern (Antarctica and Patagonia) high latitudes. Activity from most of these HLD sources shows seasonal character. It is estimated that high-latitude land areas with higher (SI ≥ 0.5), very high (SI ≥ 0.7), and the highest potential (SI ≥ 0.9) for dust emission cover > 1 670 000 km 2 , > 560 000 km 2 , and > 240 000 km 2 , respectively. In the Arctic HLD region (≥ 60◦ N), land area with SI ≥ 0.5 is 5.5 % (1 035 059 km 2 ), area with SI ≥ 0.7 is 2.3 % (440 804 km 2 ), and area with SI ≥ 0.9 is 1.1 % (208 701 km 2 ). Minimum SI values in the northern HLD region are about 3 orders of magnitude smaller, indicating that the dust sources of this region greatly depend on weather conditions. Our spatial dust source distribution analysis modeling results showed evidence supporting a northern HLD belt, defined as the area north of 50◦ N, with a “transitional HLD-source area” extending at latitudes 50–58◦ N in Eurasia and 50–55◦ N in Canada and a “cold HLD-source area” including areas north of 60◦ N in Eurasia and north of 58◦ N in Canada, with currently “no dust source” area between the HLD and low-latitude dust (LLD) dust belt, except for British Columbia. Using the global atmospheric transport model SILAM, we estimated that 1.0 % of the global dust emission originated from the high-latitude regions. About 57 % of the dust deposition in snow- and ice-covered Arctic regions was from HLD sources. In the southern HLD region, soil surface conditions are favorable for dust emission during the whole year. Climate change can cause a decrease in the duration of snow cover, retreat of glaciers, and an increase in drought, heatwave intensity, and frequency, leading to the increasing frequency of topsoil conditions favorable for dust emission, which increases the probability of dust storms. Our study provides a step forward to improve the representation of HLD in models and to monitor, quantify, and assess the environmental and climate significance of HLD.

high latitude dust↗

NASA NTRS2024

Modeling Impacts of Dust Mineralogy on Fast Climate Response

Mineralogical composition drives dust impacts on Earth's climate systems. However, most climate models still use homogeneous dust, without accounting for the temporal and spatial variation in mineralogy. To quantify the radiative impact of resolving dust mineralogy on Earth's climate, we implement and simulate the distribution of dust minerals (i.e., illite, kaolinite, smectite, hematite, calcite, feldspar, quartz, and gypsum) from Claquin et al. (1999) (C1999) and activate their interaction with radiation in the GFDL AM4.0 model. Resolving mineralogy reduces dust absorption compared to the homogeneous dust used in the standard GFDL AM4.0 model that assumes a globally uniform hematite volume content of 2.7 % (HD27). The reduction in dust absorption results in improved agreement with observation-based single-scattering albedo (SSA), radiative fluxes from CERES (the Clouds and the Earth's Radiant Energy System), and land surface temperature from the CRU (Climatic Research Unit) compared to the baseline HD27 model version. It also results in distinct radiative impacts on Earth's climate over North Africa. Over the 19-year (from 2001 to 2019) modeled period during JJA (June–July–August), the reduction in dust absorption in AM4.0 leads to a reduction of over 50 % in net downward radiation across the Sahara and approximately 20 % over the Sahel at the top of the atmosphere (TOA) compared to the baseline HD27 model version. The reduced dust absorption weakens the atmospheric warming effect of dust aerosols and leads to an alteration in land surface temperature, resulting in a decrease of 0.66 K over the Sahara and an increase of 0.7 K over the Sahel. The less warming in the atmosphere suppresses ascent and weakens the monsoon inflow from the Gulf of Guinea. This brings less moisture to the Sahel, which combined with decreased ascent induces a reduction of precipitation. To isolate the effect of reduced absorption compared to resolving spatial and temporal mineralogy, we carry out a simulation where the hematite volume content of homogeneous dust is reduced from 2.7 % to 0.9 % (HD09). The dust absorption (e.g., single-scattering albedo) of HD09 is comparable to that of the mineralogically speciated model on a global mean scale, albeit with a lower spatial variation that arises solely from particle size. Comparison of the two models indicates that the spatial inhomogeneity in dust absorption resulting from resolving mineralogy does not have significant impacts on Earth's radiation and climate, provided there is a similar level of dust absorption on a global mean scale before and after resolving dust mineralogy. However, uncertainties related to emission and distribution of minerals may blur the advantages of resolving minerals to study their impact on radiation, cloud properties, ocean biogeochemistry, air quality, and photochemistry. On the other hand, lumping together clay minerals (i.e., illite, kaolinite, and smectite), but excluding externally mixed hematite and gypsum, appears to provide both computational efficiency and relative accuracy. Nevertheless, for specific research, it may be necessary to fully resolve mineralogy to achieve accuracy.

Soil dust↗

NASA NTRS2009

Pulmonary Toxicity Studies of Lunar Dusts in Rodents

NASA will build an outpost on the lunar surface for long-duration human habitation and research. The surface of the Moon is covered by a layer of fine, reactive dust, and the living quarters in the lunar outpost are expected to be contaminated by lunar dust. Because the toxicity of lunar dust is not known, NASA has tasked its toxicology laboratory to evaluate the risk of exposure to the dust and to establish safe exposure limits for astronauts working in the lunar habitat. Studies of the pulmonary toxicity of a dust are generally done first in rodents by intratracheal/intrapharyngeal instillation. This toxicity screening test is then followed by an inhalation study, which requires much more of the test dust and is labor intensive. Preliminary results obtained by examining lung lavage fluid from dust-treated mice show that lunar dust was somewhat toxic (more toxic than TiO2, but less than quartz dust). More extensive studies are in progress to further examine lung lavage fluid for biomarkers of toxicity and lung tissues for histopathological lesions in rodents exposed to aged and activated (ground) lunar dust samples. In these studies, reference dusts (TiO2 and quartz) of known toxicities and have industrial exposure limits will be studied in parallel so the relative toxicity of lunar dust can be determined. The results from the instillation studies will be useful for choosing exposure concentrations for the animal inhalation study. The animal inhalation exposure will be conducted with lunar dust simulant prior to the study with the lunar dust. The experiment with the simulate will ensure that the study techniques used with actual lunar dust will be successful. The results of instillation and inhalation studies will reveal the toxicological risk of exposures and are essential for setting exposure limits on lunar dust for astronauts living in the lunar habitat.

Lam, Chiu-wing↗