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At least 163 records · Page 9

Williston Basin Carbon Ore, Rare Earths, and Critical Minerals (CORE-CM) Program

The U.S. Department of Energy’s Office of Fossil Energy awarded 13 CORE-CM programs as part of the CORE-CM Initiative, designed to develop the technology and upstream and midstream supply chains to extract rare-earth elements (REEs) and critical minerals (CMs) from the nation’s coal supplies. The intent is to catalyze regional economic growth and job creation while strengthening the use of domestic resources. The Williston Basin CORE-CM Program aims to drive the expansion and transformation of coal and coal-based resource usage within the Williston Basin to produce REEs, CMs, and nonfuel carbon-based products (CBPs). A coalition team of nearly 30 private industry, university, and state, local, and federal government partners was formed for this task. Partners include the University of North Dakota’s Energy & Environmental Research Center, College of Engineering and Mines Research Institute, and Nistler College; North Dakota State University; Montana Tech University; Pacific Northwest National Laboratory; Critical Materials Institute; North Dakota Geological Survey; South Dakota Geological Survey; U.S. Geological Survey; North American Coal Corporation; BNI Energy; Basin Electric Power Cooperative; Minnkota Power Cooperative; and many more. This presentation will focus on the current status and results to date of the Williston Basin CORE-CM Program, with a focus on core sample characterization for REE and CM content.

Folkedahl, Bruce C.↗

Heavy-lift vehicle-launched Space Station method and apparatus

Methods and apparatus are provided for a single heavylift launch to place a complete, operational space station on-orbit. A payload including the space station takes the place of a Shuttle Orbiter using the launch vehicle of the Shuttle Orbiter. The payload includes a forward shroud, a core module, a propulsion module, and a transition module between the core module and the propulsion module. The essential subsystems are pre-integrated and verified on Earth. The core module provides means for attaching international modules with minimum impact to the overall design. The space station includes six control moment gyros for selectably operating in either LVLH (local-vertical local-horizontal) or SI (solar inertial) flight modes.

Wade, Donald C.↗

Illinois Basin Carbon Ore, Rare Earth, and Critical Minerals (IB-CORE-CM) Initiative (Final Report (Redacted)(Public))

Final Report; Illinois Basin - Carbon Ore, Rare Earth and Critical Mineral (IB-CORE-CM) project team has conducted a comprehensive basin-wide assessment of CORE-CM presence in coal, coal-based, and waste stream resources, as well as a thorough examination of mining practices, separation technologies, and the local infrastructure necessary for producing and providing the needed CORE-CM resources for U.S. industry. This final report details the research, methods, and results of the project.

01 COAL, LIGNITE, AND PEAT↗

Chemical evolution of the Earth: Equilibrium or disequilibrium process?

To explain the apparent chemical incompatibility of the Earth's core and mantle or the disequilibrium process, various core forming mechanisms have been proposed, i.e., rapid disequilibrium sinking of molten iron, an oxidized core or protocore materials, and meteorite contamination of the upper mantle after separation from the core. Adopting concepts used in steady state thermodynamics, a method is devised for evaluating how elements should distribute stable in the Earth's interior for the present gradients of temperature, pressure, and gravitational acceleration. Thermochemical modeling gives useful insights into the nature of chemical evolution of the Earth without overly speculative assumptions. Further work must be done to reconcile siderophile elements, rare gases, and possible light elements in the outer core.

Sato, M.↗

Energetics of core formation - A correction.

An error has recently been discovered in the calculation of the temperature rise conducted by Birch (1965) in connection with a determination of the release of gravitational energy accompanying a rapid formation of the earth's core from an initially undifferentiated state. A revised calculation of the energetic relations involved in the core formation is, therefore, presented. The radii of the initial undifferentiated cold earth and of the fictitious undifferentiated warm earth are both found to be slightly smaller than that of the present differentiated warm earth.

Flasar, F. M.↗

No Nd-142 Excess in the Early Archean Isua Gneiss IE 715-28

There is abundant evidence for the existence of 146Sm in the early solar system and for preservation of effects in the 146Sm-142Nd system in differentiated meteorites ([1]; see recent discussion in Stewart et al. 1994). Information from the 182Hf-182W system, as revised by new careful work [2-3] also indicates that the Earth s core formed relatively early. It is in principle possible for early-formed crust and mantle reservoirs on Earth to have preserved evidence for 146Sm if such reservoirs were produced with high Sm/Nd fractionation and if they have remained isolated and closed since ~4.3 Ga. The mean life of 146Sm of 149 Ma is sufficiently long to make this an intriguing possibility.

Papanastassiou, D. A.↗

The source of the Earth's long wavelength geoid anomalies: Implications for mantle and core dynamics

The long wavelength components of the Earth's gravity field result mainly from density contrasts associated with convection in the mantle. Direct interpretation of the geoid for mantle convection is complicated by the fact that convective flow results in dynamically maintained deformation of the surface of the Earth, the core mantle boundary (CMB), and any interior chemical boundaries which might exist. These boundary deformations effect the geoid opposite in sign and are comparable in magnitude to those of the interior density contrasts driving the flow. The total difference of two relatively large quantities.

Hager, B. H.↗

Decadal Polar Motion of the Earth Excited by the Convective Outer Core From Geodynamo Simulations

Long time geodetic observation records show that the orientation of the Earth's rotation axis with respect to the terrestrial reference frame, or polar motion, changes on a broad range of timescales. Apart from external torques from the luni-solar tides, these changes are excited by interactions among different components of the Earth system. The convective fluid outer core has long been conjectured a likely contributor to the observed polar motion on timescales upward of decades, such as the 30 year Markowitz wobble. We investigated the electromagnetic coupling scenario across the core-mantle boundary via numerical geodynamo simulation for different geodynamo parameters (Rayleigh numbers and magnetic Rossby numbers). Our simulated polar motion varies strongly with the dynamo parameters, while its excitation on decadal timescales appear to converge asymptotically within the adopted range of numerical Rossby numbers. Three strongest asymptotic modes emerge from numerical results, with periods around 30, 40, and 60 years for the prograde excitation and around 24, 30, and 60 years for the retrograde excitation. Their amplitudes are all larger than 5 times 10 (sup minus 8), or approximately 10 milliseconds of arc.The results suggest that the electromagnetic core-mantle coupling could explain a substantial portion, if not all, of the observed decadal polar motion. In particular, the predicted 60 year polar motion deserves special attention for future observations and studies.

Kuang, W.↗

Core-Mantle Partitioning of Volatile Siderophile Elements and the Origin of Volatile Elements in the Earth

There are currently several hypotheses on the origin of volatile siderophile elements in the Earth. One hypothesis is that they were added during Earth s accretion and core formation and mobilized into the metallic core [1], others claim multiple stage origin [2], while some hypothesize that volatiles were added after the core already formed [3]. Several volatile siderophile elements are depleted in Earth s mantle relative to the chondrites, something which continues to puzzle many scientists. This depletion is likely due to a combination of volatility and core formation. The Earth s core is composed of Fe and some lighter constituents, although the abundances of these lighter elements are unknown [4]. Si is one of these potential light elements [5] although few studies have analyzed the effect of Si on metal-silicate partitioning, in particular the volatile elements. As, In, Ge, and Sb are trace volatile siderophile elements which are depleted in the mantle but have yet to be extensively studied. The metal-silicate partition coefficients of these elements will be measured to determine the effect of Si. Partition coefficients depend on temperature, pressure, oxygen fugacity, and metal and silicate composition and can constrain the concentrations of volatile, siderophile elements found in the mantle. Reported here are the results from 13 experiments examining the partitioning of As, In, Ge, and Sb between metallic and silicate liquid. These experiments will examine the effect of temperature, and metal-composition (i.e., Si content) on these elements in or-der to gain a greater understanding of the core-mantle separation which occurred during the Earth s early stages. The data can then be applied to the origin of volatile elements in the Earth.

Nickodem, K.↗

Core and Crustal Geomagnetic Field Modeling Using Oersted and Magsat Data

This grant supplied funding to use Magsat and Oersted magnetic field data to model the magnetic field due to Earth's core and crust. Since the launch of Oersted was significantly delayed and no data were yet available by 5/31/99, the end of the funding period, it is perhaps fortunate that our primary goals were to develop and exploit innovative schemes for modeling the geomagnetic field, including new techniques for minimizing the influence of crustal magnetic fields in core field modelling. We were able to proceed with these efforts independently despite the lack of new observations. The work carried out under this grant has resulted in four peer-reviewed publications, with ongoing work contributing to a fifth in press paper. The research also provided significant contributions to education in PhD theses. Details of the results from this work can be found in the attached copies of the published work.

Constable, Catherine↗

Data use investigation for the magnetic field satellite (MAGSAT) mission: Geomagnetic field forecasting and fluid dynamics of the core

MAGSAT data were used to construct a variety of spherical harmonic models of the main geomagnetic field emanating from Earth's liquid core at poch 1980. These models were used to: (1) accurately determine the radius of Earth's core by a magnetic method, (2) calculate estimates, of the long-term ange of variation of geomagnetic Gauss coefficients; (3) establish a preferred truncation level for current spherical harmonic models of the main geomagnetic field from the core; (4) evaluate a method for taking account of electrical conduction in the mantle when the magnetic field is downward continued to the core-mantle boundary; and (5) establish that upwelling and downwelling of fluid motion at the top of the core is probably detectable, observationally. A fluid dynamics forecast model was not produced because of insufficient data.

Benton, E. R.↗

Nickel-cobalt systematics and their bearing on lunar origin

The earliest metal phases to crystallize from the least-fabricated low Ti mare basalts contain about 30% Ni and 2 to 7% of Co. Experimental investigations of partitioning of Ni and Co between primitive lunar basaltic magmas and metal phases are currently in progress. Preliminary results show that the metal phase crystallizing near the liquidus of Green Glass (185 ppm Ni, 70 ppm Co) would contain about 40% Ni and 2.3% Co. It seems, therefore, that if a lunar core does exist, as suggested by the results of (2), it is relatively rich in Ni (30-40%) and Co (2-7%). This composition presents a remarkable contrast to that of the Earth's core which is estimated to contain about 6% Ni and 0.3% Co. Explanations for the differing densities of Earth and Moon are imvestigated.

Ringwood, A. E.↗

Expectations for the Martian core magnetic field

In the traditional view of planetary magnetism, a planet either has a core dynamo (Earth, Jupiter, Saturn, Uranus, Neptune, maybe Mercury) or does not (Mars, Venus, Moon...) I argue that this view is simplistic in two respects. First, mantle convection in terrestrial planets is invariably ata high enough Rayleigh number that it is time variable; this leads to the intermittent arrival of mantle 'cold fingers' at the core-mantle boundary promoting at least local core convection and dynamo action even when the planetary core is stably stratified on average. Thus, I predict an intermittent dynamo regime in addition to the simple dynamo-on (Earth) and dynamo-off regimes. Second, the mantle convection-driven horizontal temperature gradients just below the core-mantle boundary can lead to unstable flows that will convert thermoelectric or electrochemical toroidal fields into externally detectable poloidal fields, even when a dynamo is not possible. It is likely that Mars possesses an interesting core magnetic field of the latter kind, complex but with a dipole that might be approximately aligned with the rotation axis and a surface field of a few to tens of gammas.

Stevenson, D. J.↗

A problem in representing the core magnetic field of the earth using spherical harmonics

Although there are computational advantages to the representation of the earth's magnetic field by spherical harmonic coefficients of the magnetic potential, up to the thirteenth degree and order, the following disadvantages emerge: (1) the use of spherical harmonics of up to a certain degree does not remove wavelengths greater than a certain value from the surface fields, and (2) the total field magnitudes represented by spherical harmonics up to a certain degree have minimum wavelengths equal to the circumference of the earth divided by twice the maximum degree of the harmonic used. The implications of the ways in which surface fields are separated into core and crustal components are discussed, and it is concluded that since field signals are generated in the core, the representation of the core field by spherical harmonics of potential does not adequately represent all core field components.

Carle, H. M.↗

Application of shock wave data to earth and planetary science

It is pointed out that shock wave data for: (1) low temperature condensable gases H2 and He, (2) H2O, CH4, NH3, CO, CO2, and N2 ices, and (3) silicates, metals, oxides and sulfides have many applications in geophysics and planetary science. The present paper is concerned with such applications. The composition of planetary interiors is discussed, taking into account the division of the major constituent of the planets in three groups on the basis of 'cosmic abundance' arguments, the H-He mixtures in the case of Jupiter and Saturn, shock wave data for hydrogen, and constraints on the internal structure of Uranus and Neptune. Attention is also given to the earth's mantle, shock wave data for mantle materials, the earth's core, impacts on planetary surfaces, elastic wave velocities as a function of pressure along the Hugoniot of iron, and reactions which yield the CO2 bearing atmospheres for Venus, earth, and Mars.

Ahrens, T. J.↗

Rationale for a GRAVSAT-MAGSAT mission: A perspective on the problem of external/internal transient field effects

The Earth's magnetic field at MAGSAT altitudes not only has contributions from the Earth's core and static magnetization in the lithosphere, but also from external electric current systems in the ionosphere and magnetosphere, along with induced electric currents flowing in the conducting earth. Hermance assessed these last two contributions; the external time-varying fields and their associated internal counter-parts which are electromagnetically induced. It is readily recognized that during periods of magnetic disturbance, external currents often contribute from 10's to 100's of nanoteslas (gammas) to observations of the Earth's field. Since static anomalies from lithospheric magnetization are of this same magnitude or less, these external source fields must be taken into account when attempting to delineate gross structural features in the crust.

Hermance, J. F.↗

Estimating the Libration of Mercury by Remote Sensing of Gravity and Altimetry

One of the most intriguing scientific questions about Mercury is whether the planet possesses a liquid core. One way that this can be ascertained is through the measurement of the longitudinal libration of Mercury about its rotation axis. The MESSENGER (Mercury Surface, Space, Environment, Geochemistry, and Ranging) mission to Mercury will attempt this measurement by deriving the rotation of the planet from remotely sensed observations of the Mercury gravity field and the planet's shape. For a fully fluid core the libration is expected to be an approximately 350-m-amplitude oscillation (at the equator) about the mean rotation of the planet. Thus, the shape of the planet undergoes a librational oscillation in the same way that features on the surface participate in the motion. In this sense altimetric topography can be considered analogous to imaging, with the important exception that for altimetry, the long wavelengths corresponding to low degrees and orders in a spherical harmonic expansion, can be precisely determined from orbital measurements. The rotation of the planet thus introduces a time dependence of the topographic image in an inertial (i.e. fixed) reference frame and the libration is a variation in the planetary rotation rate, manifest as an oscillation of the topographic image. Similarly, gravity measures the distribution of mass within a planet and as such can be viewed as providing a vertically integrated 'image' of the internal density structure. For a librating planet the gravitational field will also reveal a variation in the rotation rate, manifest as an oscillation of the field with respect to an inertial reference frame. While the long-wavelength gravity field contains contributions from the radial distribution of mass with depth, the long wavelength terms are most sensitive to the mass distribution of the deep interior. Thus, both the topography and the gravity independently can be used to determine the (irregular) rotation of a planet, although the topographical method measures the rotation of the crust while the gravity measures the rotation of the distributed mass, and these are not necessarily identical. For example, for a planet that contains a fluid outer core that is effectively decoupled from the mantle the gravity field will not librate in the manner of a solid body. The libration obtained from the variable rotation of the gravity field will represent a combination of contributions due to a librating mantle and a differentially rotating fluid core. Differential rotation of the Earth's inner core had been theoretically predicted from three dimensional geodynamical models and subsequently reported from seismic observations. A difference between the libration of the lithosphere as determined from altimetry and the deep interior as determined from gravity, if it could be detected, might provide further insight into the nature of core-mantle coupling. Additional information is contained in the original extended abstract.

Smith, D. E.↗

Time-Variable Gravity Signal due to Extratropic Pacific Water Mass Redistribution

Using the satellite-laser-ranging (SLR) data, Cox and Chao [2002] reported the detection of a large post-1998 anomaly (in the form of a positive jump) in the time series of Earth s lowest-degree gravity harmonic 52, or the dynamic oblateness. Among several groups now examining the mass redistribution in the global geophysical fluids in search of the cause(s), we report here a temporally coinciding anomalies found in the extratropic north + south Pacific basins. Clearly seen in the leading EOFPC mode for extratropic Pacific, these anomalies occurred in sea-surface height, sea-surface temperature, and temperature- and salinity-depth profiles. We based our analysis on two different data sources: TOPEX/Poseidon altimetry, and the ECCO ocean general circulation model output assimilating T/P data. The magnitude of these changes, when converted to equivalent J2 change, appears to be a few times too small to explain the observed J2 directly. These findings, and the fact that the anomalies occurred following the strong 1997-98 El Nino, suggest strong geophysical connection of the interannual-to-decadal variation of 52 with the Pacific Decadal Oscillation (PDO) and the ultimate global-change processes that cause PDO. More work is underway, and additional independent data sources are examined, paying close attention to the fact that the J2 anomaly has been reversing back to normal since 2001. These include: (1) cryospheric contributions (melting of glaciers and ice sheets); (2) land hydrological contributions; (3) polar sea influences ( e g , via deep flow); (4) fluid flow in Earth's core; (5) time-variable gravity signals from SLR in higher harmonic degree/order, including J3,J4, (2,1), and (2,2) coefficients, considering their lower signal-to-noise ratios; (6) Earth rotation data in terms of length-of-day and polar motion.

Chao, B. F.↗