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Results for “Effective thermal conductivity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

A review of thermal physics and management inside lithium-ion batteries for high energy density and fast charging

Traditionally it has been assumed that battery thermal management systems should be designed to maintain the battery temperature around room temperature. That is not always true as lithium-ion battery (LIB) R&D is pivoting towards the development of high energy density and fast charging batteries. Therefore, it is necessary to have a comprehensive review of thermal considerations for LIBs targeted for high energy density and fast charging, i.e., the optimal thermal condition, thermal physics (heat transport and generation) inside the battery, and thermal management strategies. As the energy density and charge rate increases, the optimal battery temperature can shift to be higher than room temperature. In the first part of the review various sources of heat generation inside LIBs and various approaches to minimizing battery heat generation are summarized. The importance of heat of mixing due to ion diffusion during fast charging is also highlighted. To improve the temperature uniformity and avoid excessive internal temperature rise, heat transfer inside the battery needs to be enhanced, and reducing the thermal contact resistance between the electrodes and separator can significantly increase the effective thermal conductivity of batteries. In the second part of the review various challenges and latest developments related to thermal transport and properties of LIBs are discussed. Finally, a summary of latest advancement on smart control of internal temperature of LIBs is discussed as depending on the ambient temperature and the optimal temperature; the battery heat needs to be retained or dissipated to elevate or avoid temperature rise.

25 ENERGY STORAGE↗

Site specific porosity-thermal performance correlations in neutron irradiated U-10Zr fuel

In this work, we present a site-specific three-dimensional analysis of porosity evolution in neutron-irradiated U–10Zr metallic fuel using high-resolution synchrotron X-ray tomography. Focused ion beam cubic lift-outs from four radial positions—fuel center, middle, edge, and fuel-cladding interaction (FCCI) zones—were imaged, reconstructed, and segmented to quantify pore volume, density, morphology, and pore connectivity. Porosity increased modestly from 5.5% at the center to 10.5% at the edge, yet pore number density increased by over two orders of magnitude in the fuel portion near the FCCI interface (from 4.8 x 10 4 to 6.0 x 10 6 pores/mm 3 ). Morphological classification revealed a progression from small spherical pores at the center to equiaxed and tortuous networks at the periphery, with enhanced orientation along the radial direction. Connectivity and permeability analysis reveal that the FCCI region maintains dense, highly interconnected pores despite a moderate volume fraction, enabling rapid fission gas transport and lanthanide migration. Effective thermal conductivity models incorporating sodium logging confirm that these site-specific pore features critically influenced heat transport during reactor irradiation. These findings demonstrate that pore topology—not just porosity fraction—controls thermal performance and thermal pathways in U–10Zr fuels, impacting fuel thermal performance in a reactor.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A non-volatile thermal switch for building energy savings

Compared with traditional static insulation, a thermally switchable building envelope could reduce annual heating and cooling loads by intermittently coupling to the outside environment when beneficial. Here, we demonstrate a voltage-actuated, contact/non-contact thermal switch that meets the unique challenges of this application. The switch is non-volatile, consuming electricity only briefly while switching and none to hold steady state. The switch ratio is 12, the off state has a low effective thermal conductivity of 0.045 W m -1 K -1 , comparable to fiberglass insulation, and the performance is stable over 1,000 switching cycles. Numerical simulations using real-world climate data show that combining this thermal switch with a thermal storage layer in a building envelope can yield annual energy savings of 9%-55% (heating) and 17%-76% (air conditioning), depending on the climate zone. The greatest benefits are realized when the exterior temperature crosses well above and below the desired interior temperature within a single 24 h period.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Simulation of the High Temperature Test Facility (HTTF) Core Using the 2D Ring Model with SAM

A two-dimensional ring model is developed with SAM to model the core of the High Temperature Test Facility (HTTF) at the system level. The ring model simplifies the complex structure of the HTTF core by converting the hexagonal rows of heaters and flow channels into layers of concentric annular rings. The ring model is first compared against a 3D-1D model where the solid structures are fully resolved in three dimensions while the fluid structures are modeled as one-dimensional flows. Comparison between the 3D-1D and the ring models shows that the latter can predict major parameters reasonably well under steady-state normal operating condition, but the heater temperatures are underpredicted. Adjustment is made to the effective thermal conductivity of the ceramic core of the ring model to improve the heater temperature predictions. Furthermore, the ring model is also used to simulate a transient Pressurized Conduction Cooldown (PCC) condition and is benchmarked with the experimental data from the HTTF Test PG-27. Good agreement is obtained between the experimental data and the predictions by the ring model.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Hydride-based thermal energy storage

Abstract The potential and research surrounding metal hydride (MH) based thermal energy storage is discussed, focusing on next generation thermo-chemical energy storage (TCES) for concentrated solar power. The site availability model to represent the reaction mechanisms of both the forward and backward MH reaction is presented, where this model is extrapolated to a small pilot scale reactor, detailing how a TCES could function/operate in a real-world setting using a conventional shell & tube reactor approach. Further, the important parameter of effective thermal conductivity is explored using an innovative multi-scale model, to providing extensive and relevant experimental data useful for reactor and system design. Promising high temperature MH material configurations may be tuned by either destabilisation, such as using additions to Ca and Sr based hydrides, or by stabilisation, such as fluorine addition to NaH, MgH 2 , or NaMgH 3 . This versatile thermodynamic tuning is discussed, including the challenges in accurately measuring the material characteristics at elevated temperatures (500 –700 °C). Attention to scale up is explored, including generic design and prototype considerations, and an example of a novel pilot-scale pillow-plate reactor currently in development; where materials used are discussed, overall tank design scope and system integration.

25 ENERGY STORAGE↗

Granular Flow in Novel Octet Shape–Based Lattice Frame Material

Moving packed-bed heat exchangers in concentrated solar power (CSP) plants involves heat transfer between heated falling particles and supercritical carbon dioxide. The overall effective thermal conductivity of the moving packed bed and particle-side channel contact resistances are still the bottlenecks in achieving the desirable thermal transport levels. To this end, a novel moving packed bed heat exchanger consisting of an Octet lattice packed between the walls of the particle-side channel is proposed in this study. Granular flow analysis in Octet lattice moving packed bed heat exchanger (OLHX) was conducted through experiments and discrete element method (DEM)-based numerical simulations. The experimental images clearly demonstrated stagnation regions upstream of lattice fibers, void regions downstream of the fiber junctions, and wavy-type unobstructed flow on the lateral sides of the fibers. DEM simulations were successful in capturing all these critical flow phenomena. Larger flow velocities were observed on the lateral sides of the fibers in the simulations. Also, when the particles in the silo were emptied, the final images showed an accumulation of particles on the inter-fiber as well as fiber–channel wall junctions. Moreover, the fiber connections resulted in some regions devoid of particle contact on the channel endwall, which means that these regions would suffer from poor thermal exchange. Finally, the overall mass flowrate increased with increasing porosity for a fixed particle diameter.

14 SOLAR ENERGY↗

Microstructure, Thermal, and Mechanical Properties Relationships in U and UZr Alloys (Final Report)

Uranium-zirconium (U-Zr) alloys are candidate fuel systems for transmutation based reactors that can be used to burn long-lived minor actinides and fission products in fast spectrum reactors. Metallic fuels have also been gaining more recent attention for applications as accident tolerant fuels, as well as for use in small modular reactors. This research focused on a “science-based” approach to capture the connections between U and U-Zr alloys’ three-dimensional (3-D) microstructure, thermal properties, and mechanical properties through closely coordinated experiments and modeling efforts from the unirradiated to the irradiated fuels. Advanced characterization and modeling techniques were used to understand irradiation-induced microstructural evolution and its direct impact on the thermal and mechanical properties of U and U-Zr fuel. Closely coordinated experiments and modeling were performed to provide crucial data that does not currently exist. Overall, this research spanned multiple length and time scales within the models and experiments. The scope of the research encompassed the understanding of the irradiation effects in U and various U-Zr alloys with particular attention paid to three task areas: (1) microstructural evolution, (2) in-situ/ex-situ thermal and mechanical properties, and (3) multiscale modeling connections to microstructure, thermal, and mechanical properties. This research resulted in (1) the 3-D characterization of neutron irradiated U-Zr fuel in multiple phase regions to better understand fission gas swelling and constituent redistribution, (2) development of a microstructural model linking thermal and mechanical properties via in situ Raman and nanoindentation, (3) and mesoscale phase field modeling was coupled with the AEH method in the MOOSE framework was used to calculate the effective thermal conductivities of U-Zr fuels consisting of α-U and δ-UZr 2 heterogeneous microstructures.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Foam Degradation Model during Thermal Hypothetical Accident Conditions

Current practice in Safety Analysis Report for Packaging (SARP) thermal analysis for hypothetical accident conditions (HAC) of packages is to not explicitly model the consequence to the foam impact limiting material, but instead to make conservative estimates of those consequences and begin calculations from that point. This approach is typically used for the foam regression distance, which is the thickness of the degraded foam layer after the 30-minute fire event. Estimates for regression distance can come directly from package burn test results or from correlations based on one-dimensional testing by the foam manufacturer. In either case, this is a subjective process, and although it can be used to produce a conservative result, it is a significant approximation in the analysis. This paper describes testing and refinement of a simplified foam regression model. Comparisons are made against available data from laboratory experiments. Model refinements were tested until satisfactory agreement was achieved. The final modeling approach was then compared with post-test inspection results from HAC burn test data. A new model with an effective thermal conductivity based on foam to char density variation was shown successful in representing laboratory-scale foam thermal degradation experiments and full-scale burn tests of a current package. This model offers a technically defensible and predictive approach for modeling thermal degradation of rigid polyurethane insulation in transport packages.

36 MATERIALS SCIENCE↗

Precautions with classical absorption

Ultrasonic absorption in gaseous molecular relaxation processes, considering error due to neglecting thermal conductivity effect on frequency dependence

Bass, H. E.↗

Nonlinear least squares - An aid to thermal property determination

Nonlinear least squares techniques can be used to determine effective thermal conductivity values from experimental data. Comparisons between measured and predicted conductivity values indicate that the analytically determined values can be used with confidence in performing thermal protection system analyses. A study was performed to compare the relative efficiencies of different minimizing techniques; techniques; the method of Peckham was the most efficient.

Curry, D. M.↗

Electrohydrodynamic heat pipe research

Experimental and theoretical applications to electrohydrodynamic heat pipe (EHDHP) research are presented. Two problems in the research which are discussed are the prediction of the effective thermal conductance of an EHDHP with threaded grooves for fluid distribution to the evaporator of an EHDHP. Hydrodynamic equations are included along with a discussion of boundary conditions and burn-out conditions. A discussion of the theoretical and experimental results is presented.

Jones, T. B.↗

The thermal and mechanical properties of a low density elastomeric ablation material

Thermal and mechanical properties data were obtained for a low density elastomeric resin based ablation material with phenolic-glass honeycomb reinforcement. Data were obtained for the material in the charred and uncharred state. Ablation material specimens were charred in a laboratory furnace at temperatures in the range from 600 K to 1700 K to obtain char specimens representative of the ablation char layer formed during reentry. These specimens were then used to obtain effective thermal conductivity, heat capacity, porosity, and permeability data at the char formation temperature. This provided a boxing of the data which enables the prediction of the transient response of the material during ablation. Limited comparisons were made between the furnace charred specimens and specimens which had been exposed to simulated reentry conditions.

Engelke, W. T.↗

Nonlinear least squares - An aid to thermal property determination.

Nonlinear least squares techniques can be used to determine effective thermal conductivity values from experimental data. Comparisons between measured and predicted conductivity values indicate that the analytically determined values can be used with confidence in performing thermal protection system analyses. A study was performed to compare the relative efficiencies of different minimizing techniques; the method of Peckham was the most efficient.

Curry, D. M.↗