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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Numerical solution of a coupled pair of elliptic equations from solid state electronics

Iterative methods are considered for the solution of a coupled pair of second order elliptic partial differential equations which arise in the field of solid state electronics. A finite difference scheme is used which retains the conservative form of the differential equations. Numerical solutions are obtained in two ways, by multigrid and dynamic alternating direction implicit methods. Numerical results are presented which show the multigrid method to be an efficient way of solving this problem.

Phillips, T. N.↗

Numerical solution of a coupled pair of elliptic equations from solid state electronics

Iterative methods are considered for the solution of a coupled pair of second order elliptic partial differential equations which arise in the field of solid state electronics. A finite difference scheme is used which retains the conservative form of the differential equations. Numerical solutions are obtained in two ways, by multigrid and dynamic alternating direction implicit methods. Numerical results are presented which show the multigrid method to be an efficient way of solving this problem. Previously announced in STAR as N83-30109

Phillips, T. N.↗

Rotational-vibrational coupling in the theory of electron-molecule scattering

The adiabatic-nuclei approximation of vibrational-rotational excitation of homonuclear diatomic molecules can be simply augmented to describe the vibrational-rotational coupling by including the dependence of the vibrational wave function on j. Appropriate formulas are given, and the theory, is applied to e-H2 excitation, whereby it is shown that deviations from the simple Born-Oppenheimer approximation measured by Wong and Schultz can be explained. More important, it can be seen that the inclusion of the j-dependent centrifugal term is essential for transitions involving high-rotational quantum numbers.

Temkin, A.↗

The Martian ionosphere in light of the Viking observations

A theoretical model has been constructed in which the ion density and the ion and electron temperature distributions are calculated by solving the coupled continuity-momentum equations and the coupled energy equations. The latest experimental results from the Viking 1 and 2 landers are used to vary some of the parameters in the model in order to obtain agreement between the theoretical and experimental results. It is found that solar EUV radiation alone is not able to maintain the observed high ion temperatures. It was also established that the energy coupling between the electron and ion gas is insufficient to account for the measured ion temperatures even in the presence of very large electron temperatures. Direct heat input to the ion gas, probably due to solar wind-ionosphere interactions, can result in ion temperature values in reasonable agreement with the observations. The ion densities calculated with the present model agree well with the Viking observations in the chemically controlled region, but at higher altitudes, dynamic transport processes need to be invoked to achieve consistency among the observed and calculated temperature and density values.

Chen, R. H.↗

Novel High Efficient Organic Photovoltaic Materials: Final Summary of Research

The objectives and goals of this project were to investigate and develop high efficient, lightweight, and cost effective materials for potential photovoltaic applications, such as solar energy conversion or photo detector devices. Specifically, as described in the original project proposal, the target material to be developed was a block copolymer system containing an electron donating (or p-type) conjugated polymer block coupled to an electron withdrawing (or n-type) conjugated polymer block through a non-conjugated bridge unit. Due to several special requirements of the targeted block copolymer systems, such as electron donating and withdrawing substituents, conjugated block structures, processing requirement, stability requirement, size controllability, phase separation and self ordering requirement, etc., many traditional or commonly used block copolymer synthetic schemes are not suitable for this system. Therefore, the investigation and development of applicable and effective synthetic protocols became the most critical and challenging part of this project. During the entire project period, and despite the lack of a proposed synthetic polymer postdoctoral research associate due to severe shortage of qualified personnel in the field, several important accomplishments were achieved in this project and are briefly listed and elaborated. A more detailed research and experimental data is listed in the Appendix.

Sun, Sam↗

Analysis of vibronic transitions in titanium doped sapphire using the temperature of the fluorescence spectra

An analysis of the fluorescence spectra of titanium-doped sapphire crystals for temperatures ranging from 13 to 578 K is made. Zero- and multiphoton assisted electronic transitions are observed at temperatures below 125 K. Zero-phonon transition energies agree with previously reported measured and predicted values. Photon-assisted transitions suggest that two principle modes of lattice vibrations with energies of 220 and 260/cm are coupled to the electronic 2T2g state. A single phonon energy of 173/cm is observed to couple to the 2Eg electronic state. Crossover energy is estimated to be about 11,800/cm using a simple harmonic approximation. Lineshape analysis is performed. The fluorescence lifetime as measured to be a constant 3.9 microsec below 150 k decreasing to 2.9 microsec at 300 K.

Byvik, C. E.↗

Kinetic Temperature and Electron Density Measurement in an Inductively Coupled Plasma Torch using Degenerate Four-Wave Mixing

Laser wave mixing is presented as an effective technique for spatially resolved kinetic temperature measurements in an atmospheric-pressure radio-frequency inductively-coupled plasma. Measurements are performed in a 1 kW, 27 MHz RF plasma using a continuous-wave, tunable 811.5-nm diode laser to excite the 4s(sup 3)P2 approaches 4p(sup 3)D3 argon transition. Kinetic temperature measurements are made at five radial steps from the center of the torch and at four different torch heights. The kinetic temperature is determined by measuring simultaneously the line shape of the sub-Doppler backward phase-conjugate degenerate four-wave mixing and the Doppler-broadened forward-scattering degenerate four-wave mixing. The temperature measurements result in a range of 3,500 to 14,000 K+/-150 K. Electron densities measured range from 6.1 (+/-0.3) x 10(exp 15)/cu cm to 10.1 (+/-0.3) x 10(exp 15)/cu cm. The experimental spectra are analyzed using a perturbative treatment of the backward phase-conjugate and forward-geometry wave-mixing theory. Stark width is determined from the collisional broadening measured in the phase-conjugate geometry. Electron density measurements are made based on the Stark width. The kinetic temperature of the plasma was found to be more than halved by adding deionized water through the nebulizer.

Schafer, Julia↗

On the bonding in Mn2(+)

Qualitative calculations are presented on the Mn2(+) ion. These yield a 12Sigma(g)(+) ground state, in agreement with experiment, in which the 3d electrons are ferromagnetically coupled. The 2Sigma(u)(+) state of Mu2(+) is found to lie 0.44 eV higher in energy; the 3d electrons on each center are high-spin coupled, but the interatomic coupling is antiferromagnetic. The large splitting between the 12Sigma(g)(+) and 2Sigma(u)(+) states is shown to be due to the intraatomic 4s-3d exchange energy, which is an order of magnitude larger than the weak interatomic 3d-3d interaction. The Mn2(+) ion is compared and contrasted with the Mn2 neutral species, where the analogous 11Sigma(u)(+) and 1Sigma(g)(+) states are reversed in order, but almost degenerate.

Bauschlicher, Charles W., Jr.↗

Photoionization cross-sections for atoms and ions of aluminum, silicon, and argon.

Photoionization cross sections for all levels belonging to the configurations of atoms and ions of aluminum, silicon, and argon have been calculated using Hartree-Fock bound-electron wave functions and close-coupling approximation free-electron wave functions. The results are presented in the form of a computationally convenient interpolation formula and should find wide astrophysical application.

Chapman, R. D.↗

The interaction of an artificial electron beam with the earth's upper atmosphere - Effects on spacecraft charging and the near-plasma evironment

The ionization created in the earth's upper atmosphere by an electron beam emitted from a low altitude spacecraft is described by two coupled nonlinear differential electron transport equations for the up-going and down-going differential energy flux. The equations are solved numerically, yielding estimates of the differential electron energy flux density at the spacecraft location. At altitudes below 200-250 km and for beam energies around 1 keV, it is shown that secondary electrons supply a significant contribution to the return current to the spacecraft and thereby reduce the spacecraft potential. The numerical results are in good agreement with observations from the Charge 2 sounding rocket experiment.

Neubert, T.↗

Inertia of Ionospheric Conductance During Electron Precipitation Events

Using the SuperThermal Electron Transport (STET) model coupled with the Super‐thermal Proton Electron Atomic Hydrogen—tRansport in the Ionosphere and Thermosphere (SPEAH‐RIT) codes, we demonstrate that temporal variability of ionospheric conductance is defined by several time scales: the temporal variations of the magnetospheric source, the start time of electron precipitation, and the termination of the corresponding source. In these cases, the time scales are defined by dissipation of energetic electrons and effective recombination processes. The results presented in this paper were applied in the regions of pulsating aurora and polararcs, demonstrating the fact that ionospheric conductance requires some time to form and decay. These time delays constitute an effective “inertia” in the conductance calculation which is- not accounted for in many global models which assume an instantaneous connection between precipitation and conductance. Ionospheric conductance inertia influences the temporal variation in ionospheric and magnetospheric electric fields, and as a result, impacts magnetosphere‐ionosphere (MI) dynamics on a global scale.

George V Khazanov↗

Measurement of the electron beam mode in earth's foreshock

High frequency electric field measurements from the AMPTE IRM plasma wave receiver are used to identify three simultaneously excited electrostatic wave modes in the earth's foreshock region: the electron beam mode, the Langmuir mode, and the ion acoustic mode. A technique is developed which allows the rest frame frequecy and wave number of the electron beam waves to be determined. It is shown that the experimentally determined rest frame frequency and wave number agree well with the most unstable frequency and wave number predicted by linear homogeneous Vlasov theory for a plasma with Maxwellian background electrons and a Lorentzian electron beam. From a comparison of the experimentally determined and theoretical values, approximate limits are put on the electron foreshock beam temperatures. A possible generation mechanism for ion acoustic waves involving mode coupling between the electron beam and Langmuir modes is also discussed.

Onsager, T. G.↗

Bipolar Electrode Sample Preparation Devices

An analyte selection device can include: a body defining a fluid channel having a channel inlet and channel outlet; a bipolar electrode (BPE) between the inlet and outlet; one of an anode or cathode electrically coupled with the BPE on a channel inlet side of the BPE and the other of the anode or cathode electrically coupled with the BPE on a channel outlet side of the BPE; and an electronic system operably coupled with the anode and cathode so as to polarize the BPE. The fluid channel can have any shape or dimension. The channel inlet and channel outlet can be longitudinal or lateral with respect to the longitudinal axis of the channel. The BPE can be any metallic member, such as a flat plate on a wall or mesh as a barrier BPE. The anode and cathode can be located at a position that polarizes the BPE.

Wang, Yi↗