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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Thermal Remote Sensing and the Thermodynamics of Ecosystem Development

Thermal remote sensing can provide environmental measuring tools with capabilities for measuring ecosystem development and integrity. Recent advances in applying principles of nonequilibrium thermodynamics to ecology provide fundamental insights into energy partitioning in ecosystems. Ecosystems are nonequilibrium systems, open to material and energy flows, which grow and develop structures and processes to increase energy degradation. More developed terrestrial ecosystems will be more effective at dissipating the solar gradient (degrading its exergy content) and can be measured by the effective surface temperature of the ecosystem on a landscape scale. Ecosystems are viewed as open thermodynamic systems with a large gradient impressed on them by the exergy flux from the sun. Ecosystems, according to the restated second law, develop in ways that systematically increases their ability to degrade the incoming solar exergy, hence negating it's ability to set up even larger gradients. Thus it should be expected that more mature ecosystems degrade the exergy they capture more completely than a less developed ecosystem. The degree to which incoming solar exergy is degraded is a function of the surface temperature of the ecosystem. If a group of ecosystems receives the same amount of incoming radiation, we would expect that the most mature ecosystem would reradiate its energy at the lowest quality level and thus would have the lowest surface temperature (coldest black body temperature). Initial development work was done using NASA's airborne Thermal Infrared Multispectral Scanner (TIMS) followed by the use of a multispectral visible and thermal scanner- Airborne Thermal and Land Applications Sensor (ATLAS). Luvall and his coworkers have documented ecosystem energy budgets, including tropical forests, midlatitude varied ecosystems, and semiarid ecosystems. These data show that under similar environmental conditions (air temperature, relative humidity, winds, and solar irradiance) and within a given biome type, the more developed the ecosystem, the cooler it's surface temperature and the more degraded the quality of it's reradiated energy. HyspIRI is a hyperspectral visible/Near IR and multispectral thermal future global satellite mission that will collect data to study the world's ecosystems and will provide a benchmark on the state of the worlds ecosystems against which future changes can be assessed. HyspIRI will provide global data sets that will provide a means for measuring ecosystem development and integrity.

Luvall, Jeffrey C.↗

Validation and Sensitivity Analyses of Arc-Jet Performance of Woven Thermal Protection Entry Systems

A material response model is developed for the determination of erosion rates and thermal response of woven materials to enable accurate thermal protection material sizing and future missions to Venus and giant planets. The stagnation-point thermal response is further evaluated using a Monte Carlo global sensitivity analysis to determine the interactions between key parameters in the material surface energy balance, such as, convective blowing correction parameter and weave material properties including isotropic and orthotropic thermal conductivites. The time-accurate material response for the dual layer weave erosion and surface temperatures show excellent agreement with stagnation flat face arc-jet tests involving time-varying aeroheating-cooling cycles. The high-fidelity Monte Carlo sensitivity analysis technique was used to address challenges in thermal protection sizing for the Adaptive Deployable Entry and Placement Technology (ADEPT) system, a low ballistic coefficient hypersonic decelerator. The results represent new correlations for such weaves involving Carbon-air oxidation equilibrium chemistry. Through the multi-variate regression analyses and uncertainty rankings performed, only three properties were found to contribute to the transient thermal response of the gore, with emissivity contributing to nearly 95% of the total output uncertainty.

Pratibha Raghunandan↗

Validation and Sensitivity Analyses of Arc-Jet Performance of Woven Thermal Protection Entry Systems

A material response model is developed for the determination of erosion rates and thermal response of woven materials to enable accurate thermal protection material sizing and future missions to Venus and giant planets. The stagnation-point thermal response is further evaluated using a Monte Carlo global sensitivity analysis to determine the interactions between key parameters in the material surface energy balance, such as, convective blowing correction parameter and weave material properties including isotropic and orthotropic thermal conductivites. The time-accurate material response for the dual layer weave erosion and surface temperatures show excellent agreement with stagnation flat face arc-jet tests involving time-varying aeroheating-cooling cycles. The high-fidelity Monte Carlo sensitivity analysis technique was used to address challenges in thermal protection sizing for the Adaptive Deployable Entry and Placement Technology (ADEPT) system, a low ballistic coefficient hypersonic decelerator. The results represent new correlations for such weaves involving Carbon-air oxidation equilibrium chemistry. Through the multi-variate regression analyses and uncertainty rankings performed, only three properties were found to contribute to the transient thermal response of the gore, with emissivity contributing to nearly 95% of the total output uncertainty.

Pratibha Raghunandan↗

Improved Methods for Hyperelastic Material Characterizations Based on Uniaxial, Radial-Biaxial, and Strip-Biaxial Test Data

This report concerns the different analytical methods used for material characterizations of hyperelastic silicone rubber, a potential candidate elastomer for aerospace applications. To establish the constitutive equations for the silicon rubber, strain-energy gradients (material constants) must be determined from experiments. Earlier experiments by Blatz-Ko showed that the material constants of natural rubber determined from different stress fields were different. Therefore, in the current material characterization, uniaxial, equalbiaxial, and strip-biaxial tensile tests were conducted. Based on the resulting stress-stretch data, the material constants were determined by using a trendline on the stress-difference plots and energy plots, and also the MSC-Marc ® curve-fitting method. The results confirm that the material constants determined from uniaxial and biaxial stress fields are indeed different. The material constants determined from the equal-biaxial energy plots and from the MSC-Marc ® combined-curve-fitting method were found to be extremely close, and can be considered as universal material constants for establishing the constitutive equations for the silicone rubber under any stress field. The results of this report show that a uniaxially stretched specimen became slightly anisotropic due to crystallization of polymer molecular chains, and that equal-biaxial and strip-biaxial testing must be conducted to fully understand the material properties of hyperelastic materials.

William L Ko↗

Graphene Based Ultra-Capacitors for Safer, More Efficient Energy Storage

Current power storage methods must be continuously improved in order to keep up with the increasingly competitive electronics industry. This technological advancement is also essential for the continuation of deep space exploration. Today's energy storage industry relies heavily on the use of dangerous and corrosive chemicals such as lithium and phosphoric acid. These chemicals can prove hazardous to the user if the device is ruptured. Similarly they can damage the environment if they are disposed of improperly. A safer, more efficient alternative is needed across a wide range of NASA missions. One solution would a solid-state carbon based energy storage device. Carbon is a safer, less environmentally hazardous alternative to current energy storage materials. Using the amorphous carbon nanostructure, graphene, this idea of a safer portable energy is possible. Graphene was electrochemically produced in the lab and several coin cell devices were built this summer to create a working prototype of a solid-state graphene battery.

Composite battery↗

Exobiochemistry

Exobiochemistry is the putative biochemistry of extraterrestrial life. It suggests the possible energy and material bases of extraterrestrial life and could help detect it. The diverse biochemistry of Earth indicates that a wide range of exobiochemistry is possible on other planets. An exobiochemistry will probably use the same energy sources as Earths ecology, light, biological organic material, and more rarely abiotic chemicals. Extraterrestrial life will be based on familiar chemical principles and probably capture, store, and release energy using oxidation-reduction reactions. Extraterrestrial life will give chemical indications of its existence. Key elements will be concentrated, stored, and recycled, altering their availability and isotopic composition. Any significant departure from chemical equilibrium would be good evidence for exobiochemistry, but an integrated system of departures from the expected equilibrium would be better. Exobiochemistry can be expected to include closed biogeochemical cycles of the major life supporting elements and may well show the complex dynamic close-coupled interactions that characterize the terrestrial biosphere. Terrestrial biochemistry provides a basis for generalization and extrapolation but it does not set bounds on exobiochemistry. In exobiochemistry we can expect: 1. closed chemical cycles that recycle materials, nutrients, and catalysts, 2. organisms with complementary metabolisms that cooperate to close the chemical cycles, 3. a high probability of a carbon and water chemistry, but some possibility of a non-carbon or non-water chemistry in extreme environments, and, 4. life similar to bacteria more prevalent than higher plants and animals.

Jones, Harry↗

Energy released by the interaction of coronal magnetic fields

Comparisons between coronal spectroheliograms and photospheric magnetograms are presented to support the idea that as coronal magnetic fields interact, a process of field-line reconnection usually takes place as a natural way of preventing magnetic stresses from building up in the lower corona. This suggests that the energy which would have been stored in stressed fields is continuously released as kinetic energy of material being driven aside to make way for the reconnecting fields. However, this kinetic energy is negligible compared with the thermal energy of the coronal plasma. Therefore, it appears that these slow adjustments of coronal magnetic fields cannot account for even the normal heating of the corona, much less the energetic events associated with solar flares.

Sheeley, N. R., Jr.↗

Coal conversion systems design and process modeling. Volume 1: Application of MPPR and Aspen computer models

The development of a coal gasification system design and mass and energy balance simulation program for the TVA and other similar facilities is described. The materials-process-product model (MPPM) and the advanced system for process engineering (ASPEN) computer program were selected from available steady state and dynamic models. The MPPM was selected to serve as the basis for development of system level design model structure because it provided the capability for process block material and energy balance and high-level systems sizing and costing. The ASPEN simulation serves as the basis for assessing detailed component models for the system design modeling program. The ASPEN components were analyzed to identify particular process blocks and data packages (physical properties) which could be extracted and used in the system design modeling program. While ASPEN physical properties calculation routines are capable of generating physical properties required for process simulation, not all required physical property data are available, and must be user-entered.

Source record↗

Anitproton-matter interactions in antiproton applications

By virtue of the highly energetic particles released when they annihilate in matter, antiprotons have a variety of potentially important applications. Among others, these include remote 3-D density and composition imaging of the human body and also of thick, dense materials, cancer therapy, and spacecraft propulsion. Except for spacecraft propulsion, the required numbers of low energy antiprotons can be produced, stored, and transported through reliance on current or near term technology. Paramount to these applications and to fundamental research involving antiprotons is knowledge of how antiprotons interact with matter. The basic annihilation process is fairly well understood, but the antiproton annihilation and energy loss rates in matter depend in complex ways on a number of atomic processes. The rates, and the corresponding cross sections, were measured or are accurately predictable only for limited combinations of antiproton kinetic energy and material species.

Morgan, David L., Jr.↗

Energy Conversion and Storage Requirements for Hybrid Electric Aircraft

Among various options for reducing greenhouse gases in future large commercial aircraft, hybrid electric option holds significant promise. In the hybrid electric aircraft concept, gas turbine engine is used in combination with an energy storage system to drive the fan that propels the aircraft, with gas turbine engine being used for certain segments of the flight cycle and energy storage system being used for other segments. The paper will provide an overview of various energy conversion and storage options for hybrid electric aircraft. Such options may include fuel cells, batteries, super capacitors, multifunctional structures with energy storage capability, thermoelectric, thermionic or a combination of any of these options. The energy conversion and storage requirements for hybrid electric aircraft will be presented. The role of materials in energy conversion and storage systems for hybrid electric aircraft will be discussed.

Energy Conversion↗

Sample Return Systems for Extreme Environments (SaRSEE)

Sample return missions offer a greater science yield when compared to missions that only employ in situ experiments or remote sensing observations, since they allow the application of more complex technological and analytical methodologies in controlled terrestrial laboratories,that are both repeatable and can be independently verified. The successful return of extraterrestrial materials over the last four decades has contributed to our understanding of the solar system, but retrieval techniques have largely depended on the use of either soft-landing, or touch-and-go procedures that result in high V requirements, larger spacecraft mass ratios, and return yields typically limited to a few grams of surface materials that have experienced varying degrees of alteration from space weathering. Hard-landing methods using planetary penetrators offer an alternative for sample return that significantly reduce a mission's V and mass ratios,increase sample yields, and allow for the collection of subsurface materials, and lessons can be drawn from previous sample return missions. The following details progress in the design,development, and testing of penetrator/sampler technology capable of surviving subsonic and low, supersonic impact velocities (<700 m/s) that would enable the collection of geologic materials using tether technology to return the sample to a passing spacecraft. The testing of energy absorbing material for protecting the sample, design evolution and field testing of the penetrator, and dynamic modeling of tether behavior during sampling are discussed. It is shown through both modeling and field testing that penetrators at speeds between 300-600 m/s (~Mach 1-2) can penetrator into the ground to depths of 1-2 m with overall structural integrity attained.The first flight tests demonstrated the potential for survivability at these speeds. The second flight series demonstrated core sample collection with partial ejection of the sample return canister. The 3rd flight series demonstrated self-ejection of the sample return system fully intact and with the core retaining the full stratigraphy of the rock bed. The tether analysis shows that the forces on the tether during release and return of the sample to the main spacecraft are all at levels that can easily be handled by existing tether materials. The mass analysis of the requirements indicates that sample return form the asteroids could be handled with Discovery or New Frontier range of missions dependent on the number of samples to be returned to the Earth.

Winglee, R. M.↗

Aeolian Sand Transport in the Planetary Context: Respective Roles of Aerodynamic and Bed-Dilatancy Thresholds

The traditional view of aeolian sand transport generally estimates flux from the perspective of aerodynamic forces creating the airborne grain population, although it has been recognized that "reptation" causes a significant part of the total airborne flux; reptation involves both ballistic injection of grains into the air stream by the impact of saltating grains as well as the "nudging" of surface grains into a creeping motion. Whilst aerodynamic forces may initiate sand motion, it is proposed here that within a fully-matured grain cloud, flux is actually governed by two thresholds: an aerodynamic threshold, and a bed-dilatancy threshold. It is the latter which controls the reptation population, and its significance increases proportionally with transport energy. Because we only have experience with terrestrial sand transport, extrapolations of aeolian theory to Mars and Venus have adjusted only the aerodynamic factor, taking gravitational forces and atmospheric density as the prime variables in the aerodynamic equations, but neglecting reptation. The basis for our perspective on the importance of reptation and bed dilatancy is a set of experiments that were designed to simulate sand transport across the surface of a martian dune. Using a modified sporting crossbow in which a sand-impelling sabot replaced the bolt-firing mechanism, individual grains of sand were fired at loose sand targets with glancing angles typical of saltation impact; grains were projected at about 80 m/s to simulate velocities commensurate with those predicted for extreme martian aeolian conditions. The sabot impelling method permitted study of individual impacts without the masking effect of bed mobilization encountered in wind-tunnel studies. At these martian impact velocities, grains produced small craters formed by the ejection of several hundred grains from the bed. Unexpectedly, the craters were not elongated, despite glancing impact; the craters were very close to circular in planform. High-speed photography showed them to grow in both diameter and depth after the impactor had ricochetted from the crater site. The delayed response of the bed was "explosive" in nature, and created a miniature ejecta curtain spreading upward and outward for many centimeters for impact of 100-300 micron-diameter grains into similar material. Elastic energy deposited in the bed by the impacting grain creates a subsurface stress regime or "quasi-Boussinesq" compression field. Elastic recovery of the bed occurs by dilatancy; shear stresses suddenly convert the grains from closed to open packing, and grains are consequently able to eject themselves forcefully from the impact site. Random jostling of the grains causes radial homogenization of stress vectors and a resulting circular crater. There is a great temptation to draw parallels with cratering produced by meteorite impacts, but a rigorous search for common modelling ground between the two phenomena has not been conducted at this time. For every impact of an aerodynamically energized grain, there are several hundred grains ejected into the wind for the high-energy transport that might occur on Mars. Many of these grains will themselves become subject to the boundary layer's aerodynamic lift forces (their motion will not immediately die and add to the creep population), and these grains will become indistinguishable from those lifted entirely by aerodynamic forces. As each grain impacts the bed, it will eject even more grains into the flow. A cascading effect will take place, but because it must be finite in its growth, damping will occur as the number of grains set in motion causes mid-air collisions that prevent much of the impact energy from reaching the surface of the bed -thus creating a dynamic equilibrium in a high-density saltation cloud. It is apparent that for a given impact energy, the stress field permits a smaller volume of grains to convert to open packing as the size of the bed grains increases, or as the energy of the "percussive" grain decreases (by decrease in velocity or mass). Thus, the mass of the "repercussive" grain population that is ejected from the impact site becomes a function of the scale of the stress field in relation to the scale of the bed material (self-similarity being applicable if both bed size and energy are simultaneously adjusted). In other words, in a very high energy aeolian system where an aerodynamically raised grain can ballistically raise many more grains, the amount of material lifted into the wind becomes largely a function of a dilatancy threshold. If this threshold is exceeded, grains are repercussively injected into the saltation cloud. The "dilatancy threshold" may be defined in terms of the saltation percussive force required to convert the bed, through elastic response, from a closed to an open packing system. If open packing cannot be created, the grains cannot escape from the impact site, even though the elastic deformation and percussive force may be able to reorganize the grains with respect to one another. As the crossbow experiments showed, for an ever-increasing bed grain size, a point is reached when no material can be moved because the energy of the percussive grain is insufficient to dilate the relatively coarse bed. Although this seems to be stating the obvious -- that too little energy will not cause the bed to splash -- the consequences of exceeding the "splash threshold" by dilatancy are not so obvious for high-energy aeolian transport. It is noted that the force required to elastically dilate the bed has to overcome Coulombic grain attractions such as dipole-dipole coupling, dielectric, monopole, contact-induced dipole attractions, van der Waals forces, molecular monolayer capillary forces, as well as the mechanical interlocking frictional resistance of the grains. On Mars, it is predicted that the dilatancy threshold may be the prime control of grain flux. Additional information is contained in the original.

Marshall, J. R.↗

Development of thermal energy storage units for spacecraft cryogenic coolers

Thermal Energy Storage Units were developed for storing thermal energy required for operating Vuilleumier cryogenic space coolers. In the course of the development work the thermal characteristics of thermal energy storage material was investigated. By three distinctly different methods it was established that ternary salts did not release fusion energy as determined by ideality at the melting point of the eutectic salt. Phase change energy was released over a relatively wide range of temperature with a large change in volume. This strongly affects the amount of thermal energy that is available to the Vuilleumier cryogenic cooler at its operating temperature range and the amount of thermal energy that can be stored and released during a single storage cycle.

Richter, R.↗

Relation of ultrasonic energy loss factors and constituent properties in unidirectional composites

A model is developed relating composite constituents properties with ultrasonic energy loss factors for longitudinal waves propagating in the principal directions of a unidirectional graphite/epoxy fiber composite. All the constituents are assumed to behave as linear viscoelastic materials with energy dissipation properties defined by loss factors. It is found that by introducing a new constituent called the interface material, the composite and constituent properties can be brought into consistency with simple series and parallel models. An expression relating the composite loss factors to the loss factors of the constituents is derived and its coefficients are evaluated.

Williams, J. H., Jr.↗