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NASA NTRS1995

Hydrogen Molecules in SN 1987A

The observations of CO and SiO in the infrared spectrum of SN 1987A clearly indicate that molecules can form in the debris of a supernova explosion. Since H2 is not easily observable we compute its abundance theoretically. For conditions typical of the inner (v less than 2500 km/s) envelope of SN 1987A, the fraction of H that is in molecular form rises to approx. 1% by t approx. 800 days. For t less than 500 days the formation is dominated by the gas-phase reactions H + H(+) yields H2(+) + hv; H2(+) + H yields H2 + H(+). Thereafter, the formation is dominated by the reactions H + e yields H(-) + hv; H(-) + H yields H2 + e. At early times the H(-) may absorb approx. 10%-30% of visible photons, contributing to the apparent paucity of H alpha emission. For t greater than 1000 days the abundance of H2 'freezes out' due to the slowing of all reactions. The opacity of the supernova envelope in the range 912 less than lambda less than or approx. equal to 1400 A (the upper limit depending on temperature) is dominated by resonance scattering in the Lyman and Werner bands of H2. The resulting fluorescence emission bands of H2 in the range 1150 less than lambda less than 1650 A may be observable in the UV spectra of supernovae at late times.

Culhane, Michael↗

NASA NTRS2018

Solar Irradiance Variability, Influenced by r Modes

A spectrum of the four-decade solar irradiance record has a prominent cluster of power for periodicities near 1 yr. Correlating irradiance with a bandpass filter showed that periodicity values were not constant, but varied sinusoidally with each cycle lasting 14 ± 1 yr. The large modulation amplitude makes solar frequencies ≥1 yr(exp −1) hard to detect at the solar surface. After removing the modulation, a Lomb–Scargle spectrum exposed two true periodicities: 1.006 and 0.920 yr. They are interpreted as the synodic rotation periods of r modes of lowest angular degree (ℓ = 1). The first propagates in the stable interior and the second in the convective envelope perturbed by its several flow fields. The rotational beat period of the two modes is about 10.9 yr. This is close to the average length of a solar cycle and possibly controls this average. The 1.006 yr periodicity dominates most of the filtered irradiance record but an abrupt change to about 0.8 yr occurs in mid-2010. Also found was evidence for higher-degree r modes (ℓ = 2 to 8) and a curious sawtooth modulation with a recurrence period of 2.6 yr.

Wolff, Charles L.↗

NASA NTRS1992

Hydrogen recombination at high optical depth and the spectrum of SN 1987A

A general theory is presented for hydrogen recombination line formation in an expanding medium in which some of the lines are optically thick. This theory is used to calculate the time evolution of the hydrogen lines of SN 1987A at t equal to or greater than 150 days, assuming that the supernova envelope is a homologously expanding uniform sphere. The theoretical luminosities and ratios of the recombination lines agree remarkably well with the observations. For the first 2 yr, the supernova envelope is optically thick to Balmer continuum. For t equal to or less than 400 days, hydrogen is ionized primarily from the n = 2 level by Balmer continuum photons, which are provided partly by the two-photon decay of the 2s state and partly by emission lines of heavy elements.

Xu, Yueming↗

NASA NTRS1987

Inside supernova 1987A

The future evolution of the electromagnetic spectrum of the supernova 1987A is considered. It is shown that conventional models for supernova explosions predict that within several months a spectacular display of X-rays and UV emission lines will be seen from SN 1987A as the envelope expands to reveal the inner debris of the explosion. Two likely scenarios are considered: first, that the debris produces strong gamma rays from radioactive Co-56, and second, that an X-ray-emitting pulsar exists at the center. It is also predicted that a bright infrared echo will soon appear as a result of reprocessing of the optical/ultraviolet light by circumstellar grains; the luminosity of this echo can provide a sensitive test of the mass-loss history of the supernova progenitor.

Mccray, Richard↗

NASA NTRS1982

MAGELLAN: High resolution spectroscopy at FUV and EUV wavelengths

The aim of ESA's MAGELLAN mission is to provide high resolution spectra of celestial sources down to sixteenth magnitude over the extreme ultraviolet wavelength range (between 50 and 140 nm). This range extends from studies of interstellar matter in the disc and halo of this and other galaxies, to stellar envelopes, hot and evolved stars, clusters, intergalactic matter, nuclei of galaxies, quasars, and, finally, planets and satellites. The instrument has a nonconventional optical design using only one reflecting surface; a high groove density concave grating collects the star light, diffracts it and focuses its spectrum into a bidimensional windowless detector operated in a photon counting mode. The slitless configuration provides the spectra of all the sources (point like and extended) in the field of view of the grating. This field of view is limited by a grid collimator to reduce the diffuse background, the stray light and the probability of overlapping spectra in crowded fields.

Grewing, M.↗

DOE OSTI2015

Sub-additivity in combining infiltration with mechanical ventilation for single zone buildings

We report that in determining ventilation rates, it is often necessary to combine naturally-driven infiltration, with air flows from mechanical systems. When there are balanced mechanical systems, the solution is simple additivity, because a balanced system does not impact the internal pressure of the space or the air flows through the building envelope. Unbalanced systems, however, change internal pressures and therefore can impact natural ventilation non-linearly in such a way as to make it sub-additive. Several sub-additive approaches are found in the literature, but they are not robust across the full spectrum from tight to leaky buildings and ranges of mechanical ventilation air flow rates. There are two approaches for combining natural infiltration with mechanical ventilation that require different solutions. The forward problem is to find the total air flow when adding mechanical ventilation to natural infiltration, and this application has been investigated in previous studies. The inverse problem finds the required mechanical ventilation in order to meet a total ventilation rate given a known amount of natural infiltration. This article presents the results of millions of hours of simulations of the physically correct solution, which span a broad range of climates, air leakage and structural conditions. This large dataset allows for the comparison with three literature models and the development of new robust sub-additivity models. These improved models are for use with unbalanced systems appropriate for consensus standards and guidelines for both the forward and inverse problem. Finally, they reduce errors to 1% or less and work across the air tightness spectrum.

42 ENGINEERING↗

DOE OSTI2026

Peptoid-Based Nanosheets Exhibiting Broad Antiviral Activity Against Enveloped RNA Viruses

Enveloped RNA viruses, such as Influenza A (H1N1) and Sindbis virus, pose persistent global health threats due to their high mutation rates, efficient transmission, and frequent drug resistance. By mimicking host cell membrane receptors, multivalent virus inhibitors can block viral attachment, making them promising broad-spectrum antiviral agents. However, most of existing antivirals are often limited by strain specificity, short-lived efficacy, and toxicity. Here, we introduce a broad-spectrum antiviral platform based on highly tunable and biocompatible two-dimensional nanomembranes (2DNMs) self-assembled from amphiphilic peptoids, operating via a non-genomic, mutation-insensitive mechanism. By varying peptoid sequence, we design and synthesize over twenty different 2DNMs with various surface charge and high density of viral-attachment ligands (VALs). The self-assembled architecture of these stable 2DNMs provides cooperative noncovalent multivalent binding to virus particles that result in effective inhibition of viral infection. Screening of variants identified three leads that potently suppressed Influenza A (H1N1) and Sindbis virus infection across median tissue culture infectious dose (TCID50), plaque, RT–qPCR, and immunofluorescence assays, while maintaining >90% cell viability. These nanosheets significantly reduced infectious titers, viral RNA replication, and intracellular viral protein expression, indicating inhibition at early stages of viral entry and propagation. The sequence programmability, chemical robustness, and mutation-insensitive antiviral activity distinguish 2DNMs from traditional antivirals and positions them as a versatile materials platform for antiviral coatings, protective barriers, and prophylactic biomedical applications.

Influenza A virus↗

NASA NTRS2013

The Aqua-Planet Experiment (APE): CONTROL SST Simulation

Climate simulations by 16 atmospheric general circulation models (AGCMs) are compared on an aqua-planet, a water-covered Earth with prescribed sea surface temperature varying only in latitude. The idealised configuration is designed to expose differences in the circulation simulated by different models. Basic features of the aqua-planet climate are characterised by comparison with Earth. The models display a wide range of behaviour. The balanced component of the tropospheric mean flow, and mid-latitude eddy covariances subject to budget constraints, vary relatively little among the models. In contrast, differences in damping in the dynamical core strongly influence transient eddy amplitudes. Historical uncertainty in modelled lower stratospheric temperatures persists in APE.Aspects of the circulation generated more directly by interactions between the resolved fluid dynamics and parameterized moist processes vary greatly. The tropical Hadley circulation forms either a single or double inter-tropical convergence zone (ITCZ) at the equator, with large variations in mean precipitation. The equatorial wave spectrum shows a wide range of precipitation intensity and propagation characteristics. Kelvin mode-like eastward propagation with remarkably constant phase speed dominates in most models. Westward propagation, less dispersive than the equatorial Rossby modes, dominates in a few models or occurs within an eastward propagating envelope in others. The mean structure of the ITCZ is related to precipitation variability, consistent with previous studies.The aqua-planet global energy balance is unknown but the models produce a surprisingly large range of top of atmosphere global net flux, dominated by differences in shortwave reflection by clouds. A number of newly developed models, not optimised for Earth climate, contribute to this. Possible reasons for differences in the optimised models are discussed.The aqua-planet configuration is intended as one component of an experimental hierarchy used to evaluate AGCMs. This comparison does suggest that the range of model behaviour could be better understood and reduced in conjunction with Earth climate simulations. Controlled experimentation is required to explore individual model behavior and investigate convergence of the aqua-planet climate with increasing resolution.

AGCM↗

NASA NTRS2024

Demonstration of GaN HEMT MMIC High-Power Amplifier for Lunar Proximity Communications

In this paper, we demonstrate a high efficiency, Ka-band (23.15 to 23.55 GHz) GaN HEMT MMIC based single-ended high power amplifier (HPA). The measured Pout, Gain, PAE, RMS EVM for Offset-QPSK, 8PSK, 16APSK, and 32APSK waveforms, 3rd-order IMD products, noise figure, and phase noise are presented. The results indicate that the saturated output power (P sat ) and the small signal Gain are on the order of 38.8 dBm (7.6 W) and 29.3 dB, respectively. The PAE at Psat is 20.0%. At the 1-dB compression point, the RMS EVM and the out-of-band spectral regrowth are less than 6% and –26 dBc respectively, for all four waveforms. Additionally, the spectrum is in compliance with the NTIA mask requirements for all four waveforms. The output 3rd-order intercept point (OIP3) is on the order of 42 dBm. The noise figure is less than 9.5 dB. The SSB phase noise spectral density is compliant with the envelope defined by the MIL-STD-188-164C. The HPA can enable proximity forward links between the orbiting Gateway/relay satellites and the lunar surface elements and cross links between relay satellites.

Ka-band↗

DOE OSTI2024

Electrically interfaced Brillouin-active waveguide for microwave photonic measurements

New strategies for converting signals between optical and microwave domains could play a pivotal role in advancing both classical and quantum technologies. Traditional approaches to optical-to-microwave transduction typically perturb or destroy the information encoded on intensity of the light field, eliminating the possibility for further processing or distribution of these signals. In this paper, we introduce an optical-to-microwave conversion method that allows for both detection and spectral analysis of microwave photonic signals without degradation of their information content. This functionality is demonstrated using an optomechanical waveguide integrated with a piezoelectric transducer. Efficient electromechanical and optomechanical coupling within this system permits bidirectional optical-to-microwave conversion with a quantum efficiency of up to -54.16 dB. Leveraging the preservation of the optical field envelope in intramodal Brillouin scattering, we demonstrate a multi-channel microwave photonic filter by transmitting an optical signal through a series of electro-optomechanical waveguide segments, each with distinct resonance frequencies. Such electro-optomechanical systems could offer flexible strategies for remote sensing, channelization, and spectrum analysis in microwave photonics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2023

Probabilistic Evaluation of Geomechanical Risks in CO2 Storage: An Exploration of Caprock Integrity Metrics Using a Multilaminate Model

The probabilistic uncertainty assessment of geomechanical risk—specifically, caprock failure—attributable to CO2 injection, as presented in a simplified hypothetical geological model, was the focus of this study. Our approach amalgamates the implementation of a multilaminate model, the creation of a response surface model in conjunction with the Box–Behnken sampling design, the execution of associated numerical modeling experiments, and the utilization of Monte Carlo simulations. Probability distributions to encapsulate the inherent variability (elastic and mechanical properties of the caprock and reservoir) and uncertainty in prediction estimates (vertical displacement, total strain, and F value) were employed. Our findings reveal that the Young modulus of the caprock is a key factor controlling equivalent total strain but is insufficient as a stand-alone indicator of caprock integrity. It is confirmed that the caprock can accommodate significant deformation without failure, if it possesses a low Young’s modulus and high mechanical strength properties, such as the friction angle and uniaxial compressive strength. Similarly, vertical displacement was found to be an unreliable indicator for caprock integrity, as caprock failure can occur across a broad spectrum of vertical displacements, particularly when both the Young modulus and mechanical strength properties have wide ranges. This study introduces the F value as the most dependable indicator for caprock failure, although it is a theoretical attribute (the shortest distance between the Mohr circle and the nearest failure envelope used to measure the sensitivity to failure) and not physically measurable in the field. Deviatoric stress levels were found to vary based on stress regimes, with the maximum levels observed under extensive and compressive stress regimes. In conjunction with the use of the response surface method, this study demonstrates the efficacy of the multilaminate framework and the Mohr–Coulomb constitutive model in providing a simplified, yet effective, probabilistic model of the mechanical behavior of caprock failure, reducing mathematical and computational complexities.

Energy & Fuels↗

NASA NTRS1981

The ultraviolet variability of the T Tauri star RW Aurigae

Between 1978 and 1979 the visible brightness of RW Aurigae increased by 0.9 mag. During this time (1) CIV and SiIV increased by factors of 2 to 4 while the lower ionization lines remained unchanged; (2) the fluorescent OI line increased by a factor of 8; (3) the shell spectrum changed from emission to absorption; and (4) the ultraviolet continuum brightened by 2.3 mag. On a time scale of a week the continuum varied by as much as 0.8 mag., but the MgII emission lines showed no variability over 10 percent. An active chromosphere, transition region, and envelope cooled by mass loss are hypothesized in order to explain the ultraviolet observations of RW Aur.

Imhoff, C. L.↗

NASA NTRS1980

An absorption line in the ultraviolet spectrum of 40 Eridani B

Two excellent low-resolution spectra show an absorption line of equivalent width 3 A, near 1391 A, in the typical DA (hydrogen atmosphere) white dwarf 40 Eri B. The line is confirmed by a high-resolution spectrum and is the first seen in any DA star. Ultraviolet fluxes and the profile of Lyman-alpha confirm an effective temperature near 17,000 K. If the line is Si IV, it requires a temperature near 40,000 K. Unattractive possibilities are a hot circumstellar absorbing envelope dependent on accretion from companions, or formation at large optical depth in a transparent atmosphere with high Si/H. A suggestion that H2 should be considered leads to the possible interpretation as the (0, 5) transition of the Lyman band, formed at small optical depth. The band should be stronger in cooler DAs.

Greenstein, J. L.↗

NASA NTRS2004

A New Look at Stellar Outflows: Spitzer Observations of the HH 46/47 System

We present the Early Release Observations of the HH 46/47 system and HH 46 IRS 1 source, taken with the three instruments aboard the Spitzer Space Telescope. The optically invisible southwest lobe, driven by the HH 47C bow shock, is revealed in full detail by the Infrared Array Camera (IRAC) images and displays a 'loop'-like morphology. Both of the mid-infrared outflow lobes are narrower than those of CO flow. We believe that the combination of emission by H2 rotational lines [S(11)-S(4)] and some atomic lines, which fall within the IRAC passbands, are responsible for the bulk of the observed emission, although contributions from the 3.3, 6.2, and 7.7 micron polycyclic aromatic hydrocarbon emission bands cannot be ruled out. Weak spectral features corresponding to these emitters are present in the Infrared Spectrograph spectrum of the HH 47A bow shock. The spectrum of HH 46 IRS 1 shows remarkable similarities to those of high-mass protostars, which include the presence of H2O, CO2, CH4, and possibly NH3, CH3OH, and ices. The high ice abundances and the lack of signs of thermal processing indicate that these ices in the envelope are well shielded from the powerful outflow and its cavity. Emission from the Bok globule at 24 micron is detected and displays a similar structure to that observed at 8 micron.

Herbig-Haro objects↗

DOE OSTI2016

Water accessibility in a membrane-inserting peptide comparing Overhauser DNP and pulse EPR methods

Water accessibility is a key parameter for the understanding of the structure of biomolecules, especially membrane proteins. Several experimental techniques based on the combination of electron paramagnetic resonance (EPR) spectroscopy with site-directed spin labeling are currently available. Among those, we compare relaxation time measurements and electron spin echo envelope modulation (ESEEM) experiments using pulse EPR with Overhauser dynamic nuclear polarization (DNP) at X-band frequency and a magnetic field of 0.33 T. Overhauser DNP transfers the electron spin polarization to nuclear spins via cross-relaxation. The change in the intensity of the {sup 1}H NMR spectrum of H{sub 2}O at a Larmor frequency of 14 MHz under a continuous-wave microwave irradiation of the nitroxide spin label contains information on the water accessibility of the labeled site. As a model system for a membrane protein, we use the hydrophobic α-helical peptide WALP23 in unilamellar liposomes of DOPC. Water accessibility measurements with all techniques are conducted for eight peptides with different spin label positions and low radical concentrations (10–20 μM). Consistently in all experiments, the water accessibility appears to be very low, even for labels positioned near the end of the helix. The best profile is obtained by Overhauser DNP, which is the only technique that succeeds in discriminating neighboring positions in WALP23. Since the concentration of the spin-labeled peptides varied, we normalized the DNP parameter ϵ, being the relative change of the NMR intensity, by the electron spin concentration, which was determined from a continuous-wave EPR spectrum.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1982

RF processing

The Loran-C radio frequency processing is discussed. A diagram which generally illustrates the automatic gain control is presented. The augmented differentiator for pulse envelopes adapts conventional communications receiver with wideband AM capability to detect pulse signals such as Loran-C. The circuit enhances reception for surveillance and observation of HF over-the-horizon radar signals or others where time difference estimates between pulse returns are of interest. The high resolution VLF spectrum which receives weak VLF signals by using an HP 3581A wave analyzer detecting signals with a very narrow bandwidth of only 3 Hz is also presented.

Burhans, R. W.↗

NASA NTRS1985

Submillimeter observations of evolved stars

Broadband submillimeter observations of thermal emission from several evolved stars have been obtained using the United Kingdom Infrared Telescope on Mauna Kea, Hawaii. The observations were carried out at an effective wavelength of 400 microns in order to estimate the mass loss rates in dust from the stars. Direct estimates of mass loss rates are in the range 10 to the -9th to 10 to the -6th solar mass/yr. Analysis of the spectrum of IRC + 10216 confirmed previous estimates of dust grain emissivity in the range 10-1000 microns. The infrared properties of IRC + 10216 are found to be similar to the carbon rich object CRL 3068. No systematic difference was found between the dust masses of carbon rich and oxygen rich envelopes. The largest mass loss rates in dust were obtained for the bipolar objects OH 231.8 + 4.2 CRL 2688, CRL 618, and NGC 7027. It is suggested that the ratios of gas to dust, and the slopes of the far infrared to submillimeter wavelength continua of these stars objects are probably representative of amorphous rather than crystalline grains.

Sopka, R. J.↗

NASA NTRS1985

An interpretation of the spectral variations of Theta Coronae Borealis

Measurements are presented of the strengths and displacements of sharp absorption components of the resonance lines of Si IV, C IV, and Al III in the spectrum of Theta CrB. No evidence is found for mass loss at a detectable rate. A qualitative model of a Be star is developed. It is suggested that the spectral variations of Theta CrB are the result of changes in the rate at which magnetic flux is generated in the envelope of the star and extruded through the photosphere of the star.

Underhill, A. B.↗