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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

New Theoretical Technique Developed for Predicting the Stability of Alloys

When alloys are being designed for aeronautical and other applications, a substantial experimental effort is necessary to make incremental changes in the desired alloy properties. A scheme to narrow the field to the most promising candidates would substantially reduce the high cost of this experimental screening. Such a method for determining alloy properties, called the BFS (Bozzolo, Ferrante, and Smith) method, has been developed at the NASA Lewis Research Center. This method was used to calculate the thermal stability and mechanical strength of 200 alloys of Ni3Al, with Cu and Au impurities forming ternary and quaternary compounds. With recent advances in the method, almost any metallic impurity and crystal structure can be addressed. In addition, thermal effects can be addressed with Monte Carlo techniques. At present, an experimental program is in progress to verify these results. The method identified a small number of the most promising candidates from the 200 alloys with the largest negative heat of formation and the highest bulk modulus. This calculation required only 5 min of CPU time on a VAX computer. It is clear that semi-empirical methods have achieved the level of development and reliability to warrant examining this new approach to the problem of alloy design. The present work was meant to demonstrate, perhaps in a rather simple way, this power. This type of application of atomistic simulation methods can narrow the gap and improve the feedback between theoretical predictions and laboratory experimentation.

Source record↗

Tailoring of Boehmite-Derived Aluminosilicate Aerogel Structure and Properties: Influence of Ti Addition

Aluminosilicate aerogels offer potential for extremely low thermal conductivities at temperatures greater than 900 C, beyond where silica aerogels reach their upper temperature limits. Aerogels have been synthesized at various Al:Si ratios, including mullite compositions, using Boehmite (AlOOH) as the Al source, and tetraethoxy orthosilicate as the Si precursor. The Boehmite-derived aerogels are found to form by a self-assembly process of AlOOH crystallites, with Si-O groups on the surface of an alumina skeleton. Morphology, surface area and pore size varies with the crystallite size of the starting Boehmite powder, as well as with synthesis parameters. Ternary systems, including Al-Si-Ti aerogels incorporating a soluble Ti precursor, are possible with careful control of pH. The addition of Ti influences sol viscosity, gelation time pore structure and pore size distribution, as well as phase formation on heat treatment.

Hurwitz, Frances I.↗

Water Based Phase Change Material Heat Exchanger Development

In a cyclical heat load environment such as low Lunar orbit, a spacecraft’s radiators are not sized to reject the full heat load requirement. Traditionally, a supplemental heat rejection device (SHReD) such as an evaporator or sublimator is used to act as a “topper” to meet the additional heat rejection demands. Utilizing a Phase Change Material (PCM) heat exchanger (HX) as a SHReD provides an attractive alternative to evaporators and sublimators as PCM HXs do not use a consumable, thereby leading to reduced launch mass and volume requirements. Studies conducted in this paper investigate utilizing water’s high latent heat of formation as a PCM, as opposed to traditional waxes, and corresponding complications surrounding freezing water in an enclosed volume. Work highlighted in this study is primarily visual and includes understanding ice formation, freeze front propagation, and the solidification process of water/ice. Various test coupons were constructed of copper to emulate the interstitial pin configuration (to aid in conduction) of the proposed water PCM HX design. Construction of a prototypic HX was also completed in which a flexible bladder material and interstitial pin configurations were tested. Additionally, a microgravity flight was conducted where three copper test articles were frozen continuously during microgravity and 2-g periods and individual water droplets were frozen during microgravity.

Hansen, Scott W.↗

Highly Thermal Conductive Nanocomposites

Disclosed are methods for forming carbon-based fillers as may be utilized in forming highly thermal conductive nanocomposite materials. Formation methods include treatment of an expanded graphite with an alcohol/water mixture followed by further exfoliation of the graphite to form extremely thin carbon nanosheets that are on the order of between about 2 and about 10 nanometers in thickness. Disclosed carbon nanosheets can be functionalized and/or can be incorporated in nanocomposites with extremely high thermal conductivities. Disclosed methods and materials can prove highly valuable in many technological applications including, for instance, in formation of heat management materials for protective clothing and as may be useful in space exploration or in others that require efficient yet light-weight and flexible thermal management solutions.

Sun, Ya-Ping↗

Highly Thermal Conductive Nanocomposites

Disclosed are methods for forming carbon-based fillers as may be utilized in forming highly thermal conductive nanocomposite materials. Formation methods include treatment of an expanded graphite with an alcohol/water mixture followed by further exfoliation of the graphite to form extremely thin carbon nanosheets that are on the order of between about 2 and about 10 nanometers in thickness. Disclosed carbon nanosheets can be functionalized and/or can be incorporated in nanocomposites with extremely high thermal conductivities. Disclosed methods and materials can prove highly valuable in many technological applications including, for instance, in formation of heat management materials for protective clothing and as may be useful in space exploration or in others that require efficient yet light-weight and flexible thermal management solutions.

Sun, Ya-Ping↗

Fabrication of Lenses by Droplet Formation on a Pre-Heated Surface

A lithography-free, mold-free, single-step method of fabricating high quality optical lenses by curing polydimethylsiloxane (PDMS) droplets on a pre-heated smooth surface allows lenses with different focal lengths to be made by varying the droplet volume and surface temperature.

Shih, Wei-Chuan↗

Delamination Depth Imaging for Quasi-Static and Fatigue Load Testing Using Passive Thermography

Passive thermography is used to monitor small increases in temperature resulting from delamination damage formation in composite hat-stiffened panels during both quasi-static and fatigue loading. It has been observed that rapid damage formation produces heating. This is composed of two heat generation components. The first component is an instantaneous response due to an irreversible thermoelastic strain release. The second component is mechanical heating, at the interface of failure, due to fracture damage. This produces a transient rise in temperature as the heat diffuses to the surface. The first component defines the thermal start time for the transient response. A one-dimensional thermal model is fitted to the data pixel by pixel, to produce imagery of the damage depth. The results are compared to ultrasonic and X-ray CT data.

Passive thermography↗

Bubble Departure from Metal-Graphite Composite Surfaces and Its Effects on Pool Boiling Heat Transfer

The formation and growth processes of a bubble in the vicinity of graphite micro-fiber tips on metal-graphite composite boiling surfaces and their effects on boiling behavior are investigated. It is discovered that a large number of micro bubbles are formed first at the micro scratches and cavities on the metal matrix in pool boiling. By virtue of the non-wetting property of graphite, once the growing micro bubbles touch the graphite tips, the micro bubbles are sucked by the tips and merged into larger micro bubbles sitting on the end of the tips. The micro bubbles grow rapidly and coalesce to form macro bubbles, each spanning several tips. The necking process of a detaching macro bubble is analyzed. It is revealed that a liquid jet is produced by sudden break-off of the bubble throat. The composite surfaces not only have higher temperatures in micro- and macrolayers but also make higher frequency of the bubble departure, which increase the average heat fluxes in both the bubble growth stage and in the bubble departure period. Based on these analyses, the enhancement mechanism of pool boiling heat transfer on composite surfaces is clearly revealed.

Chao, David F.↗

STS-121: Discovery Pre-Launch Mission Management Team Press Briefing

The briefing began with Allard Buetel (NASA Public Affairs) introducing Bill Gerstenmaier (Associate Administrator for Space Operations) who provided an update of the Mission Management team meeting. The 3 criteria reviewed by the team were: a) ascent heating; b) ice formation and c) remaining foam still intact. The ascent heating had a safety factor of 5 and posed no concern. Ice formation was not a concern. In order to insure there was no damage to the remaining foam, an 8ft. pipe with a camera attached was used to provide pictures. The boroscope pictures showed there was no damage to the brackets or foam. The inspection went very well and the foam was acceptable and ready to fly. Then the floor was open to questions from the press.

Source record↗

Formation of chondrules by electrical discharge heating

A possible mechanism for making chondrules in the solar nebula is electrical discharge ('lightning') heating, which can create high-temperature (greater than 1600 K), short-duration (approximately 10 s) thermal events as indicated by the chondritic record. Lightning occurs in many diverse terrestrial and planetary settings, and may have occurred in the solar nebula; it is thus worthwhile to investigate its implications for chondrule formation. Nebular discharges do not appear a viable source of heat for melting chondrule precursors, regardless of the uncertainty in the details of the mode. Nonetheless, we believe nebular lightning worthy of further investigation than what is presented here. Experiments analogous to those currently underway to investigate terrestrial thunderstorm lightning could be fruitful in refining nebular lightning models, and would be double interesting in application to nonthunderstorm and planetary lightnings.

Love, S. G.↗

Development of Ceramic Fibers for Reinforcement in Composite Materials

Refinements of the vertical arc fiberizing apparatus resulted in its ability to fiberize very different refractory glasses having wide ranges of properties. Although the apparatus, was originally designed as a laboratory research tool for the evaluation of many compositions daily, up to one quarter pound of fibers of a single composition could be produced in an 8-hour day. Fibers up to six and a half feet long were produced with the apparatus. Studies were conducted of two methods of fiberizing refractory glasses requiring rapid freezing from the melt. The first method consisted of fiberizing droplets of molten glass passing through an annular nozzle. The second method consisted of reconstructing the annular nozzle in. the shape of a horseshoe to achieve a shorter delay in blasting a molten droplet from the tip of a rod. Both methods were judged feasible for producing fibers of glasses requiring rapid freezing. The first method would be more amenable to volume fiber production. Studies of induction heating for fiber formation did not lead to its designation as a very efficient heating method. Problems. remain to be solved, in the design of a suitable susceptor for a higher heating rate, in protecting the susceptor from oxidation with an inert gas, in contamination of the melt from a refractory crucible, and in the protective radiation shielding of the induction concentrator coil. It is not considered practical to continue studies of this heating method. In the course of this program 151 refractory glass compositions were evaluated for fiber, forming characteristics. Of the various types of materials studied, the following showed promise in producing acceptable refractory fibers: sIlica- spinel (magnesium aluminate), silica- spinel-zirconia, silica-zirconia, silica-zinc spinel, aluminum phosphate glasses, and fluoride glasses. Compositions which did not produce acceptable fibers were high zirconia materials, barium spinels, and calcium aluminates. Improvements in the. testing apparatus for single fiber tensile strength increased the precision. of tests conducted on nine fibers. The highest mean tensile strength, a value of 295,000 pounds per square inch, was obtained with R-141 fibers. Treatment of R-74 fibers with anhydrous Linde A-1100 silane finish improved its mean fiber tensile strength by 25 percent. The lapse of time after fiber formation had no measurable effect on tensile strength. A static heating test conducted with various high melting fibers indicated that Fiberfrax and R-108 underwent no significant changes in bulk volume or resiliency on exposure to 2750 degrees Fahrenheit (1510 degrees Centigrade) in an oxidizing atmosphere. For fiber-resin composition fabrication, ten fiber materials were selected on the bases of high fiber yield, fusion temperature, and type of composition. Fiberfrax, a commercial ceramic fiber, was included for comparison. A new, more effective method of removing pellets from blown fibers was developed. The de-pelletized fibers were treated with a silane finish and felted into ten-inch diameter felts prior to resin impregnation. Composites containing 30 percent by weight of CTL 91-LD phenolic resin were molded under high pressure from the impregnated felts and post-cured to achieve optimum properties. Flexural strength, flexural modules of elasticity, and punch shear strength tests were conducted on the composite specimens. The highest average flexural strength obtained was 19,958 pounds per square inch with the R-74-fiber-resin composite. This compares very favorably with the military specification of 13,000 pounds per square inch flexural strength for randomly oriented fiber reinforced composites. The highest punch shear strength (11,509 pounds per square inch) was obtained with the R-89 fiber-resin composite. The effects of anhydrous fiber finishes on composite strength were not clearly indicated. Plasma arc tests at a heat flux of 550 British Thermal Units per square foot per second on eight composite materials indicated ablation rates generally equivalent to Fiberglas-Micarta No. 259-2. The composite reinforced with R-99 fibers had an average ablation rate of 0.008 inch per second and appears quite promising on the basis of these tests. Preliminary studies for processing fibers into yarn and fabric were conducted with R-99 fibers. The use of certain organic gums aided in 2 fabricating by hand several relatively strong yarns and a crude fabric swatch. This indicated the practicality of developing techniques for processing these fibers into yarn and fabric without significant damage to the fibers.

Gates, L. E.↗

Heating of the corona by magnetic singularities

Theoretical models of current-sheet formation and magnetic heating in the solar corona are examined analytically. The role of photospheric connectivity in determining the topology of the coronal magnetic field and its equilibrium properties is explored; nonequilibrium models of current-sheet formation (assuming an initially well connected field) are described; and particular attention is given to models with discontinuous connectivity, where magnetic singularities arise from smooth footpoint motions. It is shown that current sheets arise from connectivities in which the photospheric flux structure is complex, with three or more polarity regions and a magnetic null point within the corona.

Antiochos, Spiro K.↗

Plasma perturbations created by transverse ion heating events in the magnetosphere

The nature of plasma perturbations created by transverse ion heating in the auroral and polar region of the magnetosphere is investigated. The creation of the perturbations by transverse ion heating and their evolution are studied by solving a set of plasma transport equations along open flux tubes for geocentric altitudes not less than 9371 km/s. Both localized and extended heating events in space are considered. Both short- and long-duration heating events are studied as well. For localized heating, the perturbation in the density consists of a density cavity topped by a density bump. During the early stage the plasma in the bump is that expelled from the cavity by the mirror force. The flow velocity is enhanced over the entire perturbation. The dominant feature of the density perturbation produced by extended ion heating is the formation of a cavity expanding ever upward as long as the heating lasts. Inside the cavity and above it the perpendicular temperature and flow velocity are enhanced.

Singh, Nagendra↗

Fragmentation of molecular clouds

Fragmentation is generally considered to be the initial process that a molecular cloud must undergo before stars can form. Yet its role in determining the final mass spectrum remains obscure. It appears that gravitational fragmentation, considered as a unique process, is unsatisfactory. Both fragmentation and complementary physical processes are, therefore, discussed. One of the principle aims of the discussion is to indicate how stars of solar mass (and more generally, how the initial mass spectrum of stars) can form. Attention is given to the evidence for fragmentation, opacity-limited fragmentation, magnetic flux-limited fragmentation, fragmentation induced by molecule formation and excitation, protostellar heat input, fragment coalescence, accretion, binary formation, and probabilistic theories.

Silk, J.↗

Chemical, thermal and impact processing of asteroids

The geological effects of impacts, heating, melting, core formation, and aqueous alteration on asteroids are reviewed. A review of possible heat sources appears to favor an important role for electrical induction heating. The effects of each geologic process acting individually and in combination with others, are considered; it is concluded that there is much evidence for impacts during alteration, metamorphism and melting. These interactions vastly increased the geologic diversity of the asteroid belt. Subsequent impacts of cool asteroids did not reduce this diversity. Instead new rock types were created by mixing, brecciation and minor melting.

Scott, E. R. D.↗

Generation of electron conical distributions by upper hybrid waves in the earth's polar region

The heating of electron populations through resonant wave-particle interaction with upper hybrid turbulence is examined. It is first demonstrated that upper hybrid waves are easily excited by a population of warm electrons with a loss cone type distribution in a background of cold electron plasma. Quasi-linear theory is then used to show that the upper hybrid turbulence can preferentially heat the warm electrons in the perpendicular direction. In analogy to ion conic formation, this perpendicular heating process is a viable mechanism of generating electron conical distributions observed in the Earth's midaltitude polar regions.

Wong, H. K.↗