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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

The multi-faceted inverted harmonic oscillator: Chaos and complexity

The harmonic oscillator is the paragon of physical models; conceptually and computationally simple, yet rich enough to teach us about physics on scales that span classical mechanics to quantum field theory. This multifaceted nature extends also to its inverted counterpart, in which the oscillator frequency is analytically continued to pure imaginary values. In this article we probe the inverted harmonic oscillator (IHO) with recently developed quantum chaos diagnostics such as the out-of-time-order correlator (OTOC) and the circuit complexity. In particular, we study the OTOC for the displacement operator of the IHO with and without a non-Gaussian cubic perturbation to explore genuine and quasi scrambling respectively. In addition, we compute the full quantum Lyapunov spectrum for the inverted oscillator, finding a paired structure among the Lyapunov exponents. We also use the Heisenberg group to compute the complexity for the time evolved displacement operator, which displays chaotic behaviour. Finally, we extended our analysis to N-inverted harmonic oscillators to study the behaviour of complexity at the different timescales encoded in dissipation, scrambling and asymptotic regimes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Self-alignment features for III-V ridge process and angled facet die

A method of forming a laser including device is provided that in one embodiment includes providing a laser chip including at least one ridge structure that provides an alignment features. The method further includes bonding a type IV photonics chip to the laser chip, wherein a vertical alignment feature from the type IV photonics chip is inserted in a recess relative to the at least one ridge structure that provides the alignment features of the laser structure.

Barwicz, Tymon↗

Three-dimensional atomic scale characterization of {11$\overline{2}$2} twin boundaries in titanium

The {11$\overline{2}$2}<11$\overline{23}$> compression twin can accommodate a considerable amount of strain under c-axis compression in Ti. However, unlike the tensile twin, the structure of the {10$\overline{1}$2}$\langle$$\overline{1}$011$\rangle$ compressive twins has not been completely characterized. In this study, we apply a combined technique of HR-TEM characterization, topological analysis, and atomistic simulations to explore the facets that bound the {11$\overline{2}$2}<11$\overline{23}$> twin in Ti. In addition to the currently known facets (CTB and B-Py), six new facets are observed and categorized for the first time from atomic-scale TEM observations along five crystallographic directions. The six new facets are (11$\overline{2}$0)//(11$\overline{2}$6), PrPr1, PyPy1, (2$\overline{11}$1)//($\overline{1}$2$\overline{1}$2), (1$\overline{1}$04)//(01$\overline{11}$), and (01$\overline{1}$0)//(2$\overline{11}$4). Results from the topological and computational analysis are in reasonable agreement with and support the HRTEM observations. Specifically, (1) the observed facets align with low-index interfaces in both twin and matrix domains, (2) the facets with lower surface energies are found to form extended interfaces, and (3) high-surface-energy facets are found at the twin tip region and explained by the fact that the energy of the combined facet and facet junction configuration is energetically preferred in the twin tip region. These results not only provide a comprehensive understanding of the 3D structure of the {11$\overline{2}$2}<11$\overline{23}$> compressive twins in Ti, but also validate the MD procedure and the Ti interatomic potential employed. This is extremely important for future study of the {11$\overline{2}$2} twin mobility and interactions with other defects, both features that remain extremely challenging to capture in experiments.

36 MATERIALS SCIENCE↗

Novel Lightweight, Low-Cost Heliostat for Concentrating Solar Power (SBIR Phase I Final Report)

The overall goal of this Department of Energy (DOE) SBIR Phase I project was to demonstrate the feasibility of the L.Garde, Inc. heliostat mirror facet for use in concentrated solar power applications. Prior to this Phase I project, L.Garde, Inc. developed a design for a lightweight and low cost mirror facet and successfully fabricated small scale (0.667 m 2 ) with a mirror surface flatness of 0.7 mrad. Therefore, the focus of the Phase I effort was to (1) demonstrate scalability by fabricating larger size mirrors while retaining the same mirror surface flatness, (2) demonstrate the design can withstand operating environment conditions through field testing, and (3) perform cost analysis to show the heliostat mirror facet design can meet DoE goals of < 12 kg/m2 and <$30/m 2 . During the Phase I project, L.Garde successfully fabricated large area (1.395 m 2 ) heliostat mirror facets, with a mass per unit area of 8 kg/m 2 and a cost of $29.80/m 2 . Surface flatness measurements (using contact probe technique) were performed on the mirror surface and results showed a flatness of 0.68 mrad, which were in agreement with previously fabricated small scale mirror facets. Slope error measurements was also performed on the mirror surface and results showed a slope error of 0.77 mrad which also was in agreement with previously fabricated small scale mirror facets. One large area mirror facet was subjected to a three (3) month field test. Surface flatness and slope error measurements were performed on the mirror surface after the field test and results were 0.663 mrad and 0.58 mrad respectively. The large scale heliostat mirror facets were also subjected to accelerated aging. However, during this exposure we observed failure due to the breaking of the mirror facets. Further investigation into the source of the failure showed that the mirror component alone showed signs of degradation during the same accelerated aging test. We believe that moisture ingress is occurring when subjected to high humidity, leading to buildup of water with the layers of protective paints and resulting in mirror breakage when water expands in freezing conditions. In order to mitigate or eliminate this issue, a new weatherproofing strategy may be implemented or a new mirror component may be used that is able to survive accelerated aging conditions.

14 SOLAR ENERGY↗

Light Detecting and Ranging (LIDAR) for in-situ heliostat optical error assessment

A system and method for optical assessment of a heliostat includes obtaining a point cloud data representing an image of the heliostat; isolating the data; filtering and fitting the filtered heliostat data to a bounding box; translating the heliostat data to a plane to aid in segmentation; segmenting a plurality of facets of the heliostat fitting each of the segmented facets to a respective plane; generating normal vectors characterizing each of the plurality of facets; and calculating a canting angle associated with each respective facet of the plurality of facets. A heliostat with mirrored facets and a scanner are provided. The scanner captures point cloud data representing the heliostat, which is segmented for each facet. Normal vectors characterize the facets and a canting angle is calculated for the respective facet.

Small, Daniel E.↗

The impact of surface composition on the interfacial energetics and photoelectrochemical properties of BiVO{sub 4}.

The ability to engineer a photoelectrode surface is pivotal for optimizing the properties of any photoelectrode used for solar fuel production. Altering crystal facets exposed on the surface of photoelectrodes has been a major strategy to modify their surface structure. However, there exist numerous ways to terminate the surface even for the same facet, which can considerably alter the photoelectrode properties. Here we report tightly integrated experimental and computational investigations of epitaxial BiVO4 photoelectrodes with vanadium- and bismuth-rich (010) facets. Our study demonstrates that even for the same facet the surface Bi:V ratio has a remarkable impact on the interfacial energetics and photoelectrochemical properties. We also elucidate the microscopic origins of how the surface composition can affect the photoelectrochemical properties. This study opens an unexplored path for understanding and engineering surface energetics via tuning the surface termination/composition of multinary oxide photoelectrodes.

Lee, Dongho↗

From irregular to regular eutectic growth in the Al-Al 3 Ni system: In situ observations during directional solidification

Here we investigate the irregular eutectic growth dynamics of the Al-Al 3 Ni alloy, in which one of the solid phases (Al 3 Ni) grows faceted from the liquid. Leveraging in situ optical microscopy and synchrotron transmission x-ray microscopy, we address the question of the degree of coupling between Al and Al 3 Ni at the growth front and that of the shape of the microstructures left behind in the bulk solid during directional solidification. Real-time optical observations bring evidence for a morphological transition from a eutectic-grain dependent, irregular eutectic growth at low solidification velocity V (typically 1 μm s -1 ), to a weakly anisotropic, regular growth at higher V ( reaching 10 μm s -1 ). Unprecedented x-ray nano-imaging of the solid–liquid interface, and 3D characterization of the growth patterns, were made possible by a new DS setup at Brookhaven National Laboratory’s NSLS-II. At low V, the leading tips of partly faceted Al 3 Ni crystals are observed to grow not far ahead of the Al growth front. Correlating in situ images and postmortem 3D tomographic reconstructions reveals that the presence of faceted and non-faceted regions of Al 3 Ni crystals in the solid is a direct consequence of coupling and decoupling during DS, respectively. Upon increasing V, the lead distance of Al 3 Ni vanishes, and the shape of Al 3 Ni ceases to be governed by faceted growth. These observations cast light onto the basic mechanisms (faceted growth, diffusive coupling, and the dynamics of trijunctions) governing a faceted to rod-like transition upon increasing V in the Al 3 Ni system, with broad implications to a large class of irregular eutectics.

36 MATERIALS SCIENCE↗

Nanoscale morphological evolution of monocrystalline Pt surfaces during cathodic corrosion

This paper studies the cathodic corrosion of a spherical single crystal of platinum in an aqueous alkaline electrolyte, to map out the detailed facet dependence of the corrosion structures forming during this still largely unexplored electrochemical phenomenon. We find that anisotropic corrosion of the platinum electrode takes place in different stages. Initially, corrosion etch pits are formed, which reflect the local symmetry of the surface: square pits on (100) facets, triangular pits on (111) facets, and rectangular pits on (110) facets. We hypothesize that these etch pits are formed through a ternary metal hydride corrosion intermediate. In contrast to anodic corrosion, the (111) facet corrodes the fastest, and the (110) facet corrodes the slowest. For cathodic corrosion on the (100) facet and on higher-index surfaces close to the (100) plane, the etch pit destabilizes in a second growth stage, by etching faster in the (111) direction, leading to arms in the etch pit, yielding a concave octagon-shaped pit. In a third growth stage, these arms develop side arms, leading to a structure that strongly resembles a self-similar diffusion-limited growth pattern, with strongly preferred growth directions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗