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At least 163 records · Page 9

Fundamental Needs for Dynamic and Interactive Thermal Storage Solutions for Buildings (2019 Workshop)

The 2019 Workshop on Fundamental Needs for Dynamic and Interactive Thermal Storage Solutions for Buildings was held at Lawrence Berkeley National Laboratory (LBNL) in Berkeley, California, on November 19–20, 2019. The workshop convened 47 individuals involved in thermal, building, and materials science to present and discuss the use of thermal energy storage (TES) associated with buildings. The goals of the event were to revisit recent breakthroughs and identify future research opportunities in scientific areas.

25 ENERGY STORAGE↗

Fundamental Studies of Oxidation Reactions on Model Catalysts. Final report

This report covers the reporting period from 08/15/2003 to 08/31/2019. The research activities were focused on the oxidation of methane, nitric oxide, and propylene in addition to contributions on the kinetics, synthesis, theory and characterization of various catalytic systems. As described in the report, we were able to formulate hypotheses, construct specialized equipment and carry out experimental and theoretical work to test the hypotheses. Major advances were accomplished in the fundamental understanding of these systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fundamental Understanding of Methane-Carbon Dioxide-Water (CH 4 -CO 2 - H 2 O) Interactions in Shale Nanopores under Reservoir Conditions (Quarterly Report)

Shale is characterized by the predominant presence of nanometer-scale (1-100 nm) pores. The behavior of fluids in those pores directly controls shale gas storage and release in shale matrix and ultimately the wellbore production in unconventional reservoirs. Recently, it has been recognized that a fluid confined in nanopores can behave dramatically differently from the corresponding bulk phase due to nanopore confinement. CO 2 and H 2 O, either preexisting or introduced, are two major components that coexist with shale gas (predominately CH 4 ) during hydrofracturing and gas extraction. Note that liquid or supercritical CO 2 has been suggested as an alternative fluid for subsurface fracturing such that CO 2 enhanced gas recovery can also serve as a CO 2 sequestration process. Limited data indicate that CO 2 may preferentially adsorb in nanopores (particularly those in kerogen) and therefore displace CH 4 in shale. Similarly, the presence of water moisture seems able to displace or trap CH 4 in shale matrix. Therefore, fundamental understanding of CH 4 -CO 2 -H 2 O behavior and their interactions in shale nanopores is of great importance for gas production and the related CO 2 sequestration. This project focuses on the systematic study of CH 4 -CO 2 -H 2 O interactions in shale nanopores under high-pressure and high temperature reservoir conditions. The proposed work will help develop new stimulation strategies to enable efficient resource recovery from fewer and less environmentally impactful wells.

04 OIL SHALES AND TAR SANDS↗

The Fundamental Creep Behavior Model of Gr.91 Alloy by ICME Approach (Final Report)

The current project mainly focused on the fundamental creep cracking mechanism of the Grade 91 system during the operation conditions in the advanced technologies FE power plants and build the link among Composition-Processing Parameters-Phase Stability-Microstructure-Creep Resistance. A model based on computational thermodynamics and diffusion kinetics will be developed to provide guidance on how to improve the creep resistance of the alloy system. The PI mainly investigate the Gr.91 base alloy and weldment with the Integrated Computational Materials Engineering (ICME) approach. The long-term goal of the proposed program is to develop a model for creep and fatigue resistant alloys with different elemental systems, compositions, and processing parameters of weldment and heat-treatment. In addition, new creep and fatigue resistant alloys are to be designed based on the predictions from the model. The computational as well as experimental results include three sections: 1) The compositional optimization and secondary phases evaluation regarding the creep resistance in Grade 91 steel through the CALPHAD approach. In this section, the formation of the critical secondary phases, M23C6, MX and Z-phase were well predicted based on many conditions like the temperature as well as compositions. Meanwhile, the role of different alloying elements was also considered as they will directly affect the formation of the secondary phases mentioned above based on the compositional evolution of the alloying elements. 2) An investigation of Creep Resistance in Grade 91 Steel through Computational Thermodynamics. We systematically considered the evolution of the four critical temperatures, Ac3, Ac1, the threshold of M23C6 and Z-phase, on basis of the computational approach. Meanwhile, the equilibrium cooling as well as Scheil simulations were also considered to perform further predictions based on the different cooling rates. 3) Creep lifetime and microstructural evolution of the Grade 91 steel. In this part, mainly experimental approach was performed on the real creep test from the beginning of the commercial Gr.91 alloys. The alloys were normalized, tempered, welded (Gleeble) and PWHT and finally subjected to the creep lifetime analyses. Finally, all the samples after each process were further characterized based on the OM, XRD and SEM technique to draw final conclusions.

01 COAL, LIGNITE, AND PEAT↗

Some Physics Fundamentals of High Energy Density Welding

The purpose of this section of this document is to provide a brief summary of the physics aspects of high energy density welding (HEDW). One reason for this is to help elucidate some of the differences between EBW and LBW. A fundamental understanding of these differences can help guide an appropriate choice of process for a particular application.

42 ENGINEERING↗

Molten Salt Reactor Fundamental Safety Function PIRT

The phenomenon identification and ranking table (PIRT) process was employed to evaluate the current capability to assess the ability of liquid-salt–fueled molten salt reactors to achieve their fundamental safety functions (FSFs). The PIRT process provides a structured mechanism to elicit and document expert opinions on the most important phenomena and the corresponding level of knowledge with regard to achieving the FSFs. The PIRT panel included reactor developers, accident progression evaluation tool developers, US Department of Energy (DOE) national laboratory technical staff, university researchers, and US Nuclear Regulatory Commission (NRC) staff. The information-gathering process concentrated on phenomena related to accidents in which the fuel salt—including any in the cover gas—has been released from the first barrier layer. This information-gathering process included identifying all potential accidents that could result in the release of a substantial amount of radionuclides that could breach or bypass the first barrier. The PIRT did not identify any previously unrecognized systemic vulnerabilities. However, the elicitation process identified several areas with low levels of knowledge and significant potential impact on accident progression. These areas either require additional research to improve the state of knowledge or additional design conservatism to accommodate the remaining unknowns.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Fundamental Studies of Complex Oxides and Their Interfaces

This is a final close-out report for DOE contract DE-FG02-00ER45818 entitled “Fundamental Studies of Complex Oxides and their Interfaces” at the University of Missouri, Columbia, Missouri. It funded research in Condensed Matter Physics Basic Energy Science from July 1, 2000 through Nov 30, 2022. Presented below are: (i) An overview of the research accomplishments during the entire grant period with highlights of research results from the last funding period, (ii) A list of postdocs and graduate students that received support from this grant, and (iii) A list of original papers published through the duration of the grant with impact factor metrics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Fundamental U235 Nuclear Resonance Spectroscopy (FY2022 LDRD End of Year Report)

Enriched uranium (U-235) is ubiquitous in the nuclear industry yet many of its fundamental properties have never been studied using magnetic resonance. To remedy this we built a high frequency nuclear quadrupole resonance spectrometer that is capable of measuring the very high quadruple resonance signals of U-235.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Fundamentals of Wind Energy [Slides]

This slide deck was developed for and presented at an Energy Fundamentals Course hosted by the Bangladesh University of Engineering and Technology (BUET) in October 2022. The National Renewable Energy Laboratory (NREL) helped organize this course in partnership with the United States Agency for International Development (USAID). The students in this four-day course were postgraduates and working professionals in the energy sector or related industries in Bangladesh. While some of the content in the slide deck is tailored to Bangladesh specifically, this presentation is intended to be a general primer on wind energy that can be utilized for similar purposes by other universities or organizations throughout the world. The content of this slide deck is not intended to be fully comprehensive of all wind energy concepts.

17 WIND ENERGY↗

Fundamentals of Electric Vehicles (EVs) [Slides]

This slide deck was developed for and presented at an Energy Fundamentals Course hosted by the Bangladesh University of Engineering and Technology (BUET) in October 2022. The National Renewable Energy Laboratory (NREL) helped organize this course in partnership with the United States Agency for International Development (USAID). The students in this four-day course were postgraduates and working professionals in the energy sector or related industries in Bangladesh. While some of the content in the slide deck is tailored to Bangladesh specifically, this presentation is intended to be a general primer on electric vehicles that can be utilized for similar purposes by other universities or organizations throughout the world. The content of this slide deck is not intended to be fully comprehensive of all electric vehicle concepts.

33 ADVANCED PROPULSION SYSTEMS↗

Fundamentals of Energy Security and Resilience [Slides]

This slide deck was developed for and presented at an Energy Fundamentals Course hosted by the Bangladesh University of Engineering and Technology (BUET) in October 2022. The National Renewable Energy Laboratory (NREL) helped organize this course in partnership with the United States Agency for International Development (USAID). The students in this four-day course were postgraduates and working professionals in the energy sector or related industries in Bangladesh. While some of the content in the slide deck is tailored to Bangladesh specifically, this presentation is intended to be a general primer on energy security and resilience that can be utilized for similar purposes by other universities or organizations throughout the world. The content of this slide deck is not intended to be fully comprehensive of all energy security and resilience concepts.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Fundamentals of Energy Storage [Slides]

This slide deck was developed for and presented at an Energy Fundamentals Course hosted by the Bangladesh University of Engineering and Technology (BUET) in October 2022. The National Renewable Energy Laboratory (NREL) helped organize this course in partnership with the United States Agency for International Development (USAID). The students in this four-day course were postgraduates and working professionals in the energy sector or related industries in Bangladesh. While some of the content in the slide deck is tailored to Bangladesh specifically, this presentation is intended to be a general primer on energy storage that can be utilized for similar purposes by other universities or organizations throughout the world. The content of this slide deck is not intended to be fully comprehensive of all energy storage concepts.

25 ENERGY STORAGE↗

Cosmic Signatures of Fundamental Physics (Final Technical Report)

Cosmology is the study of the history of the Universe. Major topics of current cosmology research include the nature of the dark energy which today is causing the Universe to accelerate, and the nature of cosmic inflation which is our best theory of the very early evolution of the Universe. Each of these topics can be explored with modern cosmological data, and rely on our theories of fundamental physics to operate. Research supported by this grant has led to advances in all these areas. We developed specific models of cosmic inflation and explored potential observations signatures. We explored observational constraints on the number of dimensions of space, which in certain modern theories can take in different values, and developed the specific “brane theories” of dark energy. The possibility that novel quantum effects (“quantum entanglement”) during cosmic inflation could lead to interesting observable phenomena was also explored.

79 ASTRONOMY AND ASTROPHYSICS↗

IX Cell Wall Research Conference 2022 (IXCWRC): Cell wall research for new fundamental discoveries and applications in plant biology

This application is for securing funds to offset the registration fees and lodging costs for US-based early career investigators (ERCs) to participate to the IX Cell Wall Research Conference 2022 (IXCWRC 2022): Cell wall research for new fundamental discoveries and applications in plant biology. The conference will be held in East Lansing, Michigan on June 13-17, 2022. The conference will focus on the plant cell wall. Plant cells are encapsulated by the cell wall, a dynamic structure that protects them, enables them to interface with the external environment and supports the growth of the entire organism. There is a growing interest in understanding the complex processes necessary to build and deconstruct the plant cell wall. A better understanding of how the cell wall is synthesized during plant growth and in response to the environment, and how it is deconstructed for a broad variety of applications can inform and improve biotechnological processes for increasing biomass yield and improving industrial processes for the recovery of valuable, sustainable polymers. Acquiring such knowledge requires the exchange of new ideas and results as well as the development and application of new technologies. The IXCWRC 2022 aims to reach this goal by providing an opportunity for an open forum to discuss new ideas and theories and develop collaborations for scientists across the globe in a diverse and supportive environment. A distinction of the IXCWRC 2022 from all the preceding plant cell wall conferences will be its focus on the training and inclusion of the next generation of scientists, the ERCs. The overall goal of this application is to broaden the participation of ERCs with a focus on underrepresented communities. The specific goal of this application is to secure support for registration and lodging for US-based ERCs to attend the conference. Priority will be given to ERCs from underrepresented communities in science. We expect that support from DOE will allow the development of an exciting and innovative program to discuss the latest scientific advances in cell wall biology research, advance the next generation of plant cell wall researchers and foster the foundations of an inclusive community in science.

59 BASIC BIOLOGICAL SCIENCES↗

Fundamental Symmetries, Neutrons, and Neutrinos (FSNN): Whitepaper for the 2023 NSAC Long Range Plan

Through the exploration of fundamental symmetries, and by using nuclei, neutrons, and neutrinos, nuclear physics addresses some of the most profound questions in science. Why does the universe contain so much more matter than antimatter? Are neutrinos their own antiparticles and where do their masses come from? What objects make up the dark matter that is responsible for most of the universe’s mass? Does nature contain more forces than the four we know about? Our Standard Model of nature’s particles and forces is incomplete because it does not answer these questions; new physics, from beyond the Standard Model (BSM) is needed. With that physics not appearing at the high energy frontier, it has become imperative to realize the potential of the burgeoning program of precision nuclear-physics measurements.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Developing a Fundamental Knowledge Base for the Interaction of Ruthenium with Natural and Engineered Iron-Bearing Materials

The intent of this project is to build a fundamental knowledge base concerning the redox coupling between Ru and Fe in heterogeneous systems with predictive applications towards the fate, speciation, and transport of Ru in the environment and its capture using available technologies. RuNOCl 3 and Fe 3+ are redox active over a broad range of pH. Initial assessment of effect of redox coupling between Ru and Fe indicates that Fe(III) in ferrihydrite can oxidize Ru 2+ in RuNOCl3 to Ru(IV) during coprecipitation at ambient conditions and alkaline pH. Further, evidence suggests that Ru(IV) is incorporated in the structure of fh. Likewise, Fe 3+ (aq) also reduces Ru 2+ in RuNOCl 3 in the homogenous system at acidic pH although the kinetics of reaction appear to be slow. Rufh annealed to 500 0C transforms to Ru(III) doped hematite. AIMD informed EXAFS indicates that Ru substitutes for Fe(III) in regular octahedral sites of hematite but requires three distinct configurations involving edge-sharing protonated Fe vacancies and straight substitution with no local defects. Fe 2+ (aq) appears to oxidize at the surface of RuO 2 , but the amount is too low to reasonably expect detectable reduced Ru. Future experiments at higher pH are warranted to make Fe 2+ (aq) less stable (i.e., make more redox active). We also demonstrated that we can functionalize Si aerogels with Fe(II) and Fe(III) but likely need to go to higher T to make Feo nanoparticles.

36 MATERIALS SCIENCE↗

Fundamental Superconductivity of Nb films for Quantum Computing Application

Niobium is a widely accepted material for quantum computing device as well as superconducting radio frequency (SRF) technology. Superconducting niobium is a marginal type II superconductor which has a very narrow gap (~20-30 mT) of the mixed state at 2K, even showing the intermediate state (IMS) at the early stage of magnetic vortex penetration. Tremendous progress has been made in understanding the impact of the Nb surface and bulk superconductivities on SRF resonator performance. However, the effect of thin superconducting Nb films for quantum computing applications requires further examination. In this study, we explore the fundamental superconducting properties of various thin Nb films and compare them with respect to the energy relaxation time, T1, measured from superconducting qubit fabricated with these films. The Nb films are fabricated both with or without a surface protective layer that prevents the formation of lossy Nb2O5. Electromagnetic properties are characterized by means of bulk magnetization, electromagnetic transport, and dynamics of surface superconductivity. In addition, analytical electron microscopy is implemented to further connect the superconducting properties to microstructure.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗