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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Feasibility of supersonic diode pumped alkali lasers: Model calculations

The feasibility of supersonic operation of diode pumped alkali lasers (DPALs) is studied for Cs and K atoms applying model calculations, based on a semi-analytical model previously used for studying static and subsonic flow DPALs. The operation of supersonic lasers is compared with that measured and modeled in subsonic lasers. The maximum power of supersonic Cs and K lasers is found to be higher than that of subsonic lasers with the same resonator and alkali density at the laser inlet by 25% and 70%, respectively. These results indicate that for scaling-up the power of DPALs, supersonic expansion should be considered.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Integration of molecular-layer-deposited aluminum alkoxide interlayers into inorganic nanolaminate barriers for encapsulation of organic electronics with improved stress resistance

Diffusion barrier stacks for the encapsulation of organic electronics made from inorganic nanolaminates of Al{sub 2}O{sub 3} and TiO{sub 2} with aluminum alkoxide interlayers have been deposited by atomic layer deposition (ALD) and molecular layer deposition (MLD). As a part of the MLD process development, the deposition of aluminum alkoxide with low a density of about 1.7 g/cm{sup 3} was verified. The ALD/MLD diffusion barrier stack is meant to be deposited either on a polymer film, creating a flexible barrier substrate, or on top of a device on glass, creating a thin-film encapsulation. In order to measure the water vapor transmission rate (WVTR) through the barrier, the device is replaced by a calcium layer acting as a water sensor in an electrical calcium test. For the barrier stack applied as thin-film encapsulation on glass substrates, high resolution scanning electron microscopy investigations indicate that the inorganic nanolaminates without MLD interlayers are brittle as they crack easily upon the stress induced by the corroding calcium below. The introduction of up to three MLD interlayers of 12 nm each into the 48 nm barrier film laminate successfully mitigates stress issues and prevents the barrier from cracking. Using the three MLD interlayer configurations on glass, WVTRs of as low as 10{sup −5} g/m{sup 2}/d are measured at 38 °C and 32% relative humidity. On polymer barrier substrates, the calcium is evaporated onto the barrier stack and encapsulated with a cavity glass. In this configuration, the corroding calcium has space for expansion and gas release without affecting the underlying barrier film. In consequence, a WVTR of about 3 × 10{sup −3} g/m{sup 2}/d is measured for all samples independently of the number of MLD interlayers. In conclusion, a stabilization and preservation of the ALD barrier film against mechanical stress is achieved by the introduction of MLD interlayers into the inorganic nanolaminate.

36 MATERIALS SCIENCE↗

The influence of intake flow and coolant temperature on gasoline spray morphology during early-injection DISI engine operation

Multi-hole gasoline injectors operating at conditions spanning throttled early-intake stroke operation produce spray plumes that either remained separated or merge and collapse due to flash boiling. Flash boiling occurs due to the sudden expansion of gas bubbles in the liquid fuel at high fuel temperature and low ambient pressure. This study records high-speed images of spray-morphology changes due to in-cylinder flow, thereby revealing operating conditions that do and do not affect the self-induced morphology observed in quiescent vessels. Specifically, in a central-injection, four-valve, high-tumble engine, where the thermodynamic state and in-cylinder cross flow are dynamic. Motivated by cold start and hot restart operation, the fuel pressure, coolant temperature, in-cylinder air pressure, and engine rpm were systematically varied over relevant operating conditions, which bracketed the range from non- to flash-boiling sprays. The results reveal the operating conditions at which the in-cylinder cross flow disrupts the spray morphology as well as the extent of the disruption. At 650 rpm, the spray morphology was similar to that observed in quiescent vessels at nominally equivalent fuel temperature and in-cylinder pressure, indicating that the spray’s self-induced entrainment flow dominated the in-cylinder flow. However, for fuel temperature and ambient pressure near the transition between non- and flash-boiling, the intake cross flow at higher engine speed (1950 rpm) significantly disrupted the spray morphology. The high cross-flow velocity appears to induce plume merging and collapse, whereas none was evident at low rpm (650 rpm). This study led to the postulate that the spray merging and collapse are governed by the rate of atomization near the nozzle exit, presumed to be controlled by either or both aerodynamic atomization and flash-boiling intensity. It would then follow that spray modeling in CFD requires atomization models that blend the effects of both physical processes.

42 ENGINEERING↗

Effect of point defects on the thermal conductivity of UO 2 : molecular dynamics simulations

The thermal conductivity of uranium dioxide (UO 2 ) fuel is an important materials property that affects fuel performance since it is a key parameter determining the temperature distribution in the fuel, thus governing, e.g., dimensional changes due to thermal expansion, fission gas release rates, etc. The thermal conductivity of UO 2 nuclear fuel is also affected by fission gas, fission products, defects, and microstructural features such as grain boundaries. Here, molecular dynamics (MD) simulations are carried out to determine quantitatively, the effect of irradiation induced point defects on the thermal conductivity of UO 2 , as a function of defect concentrations, for a range of temperatures, 300 – 1500 K. The results will be used to develop enhanced continuum thermal conductivity models for MARMOT and BISON by INL. These models express the thermal conductivity as a function of microstructure state-variables, thus enabling thermal conductivity models with closer connection to the physical state of the fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

The thermal conductivity of mixed fuel U x Pu 1-x O 2 : molecular dynamics simulations

Mixed oxides (MOX), in the context of nuclear fuels, are a mixture of the oxides of heavy actinide elements such as uranium, plutonium and thorium. The interest in the UO 2 -PuO 2 system arises from the fact that these oxides are used both in fast breeder reactors (FBRs) as well as in pressurized water reactors (PWRs). The thermal conductivity of UO 2 fuel is an important material property that affects fuel performance since it is the key parameter determining the temperature distribution in the fuel, thus governing, e.g., dimensional changes due to thermal expansion, fission gas release rates, etc. For this reason it is important to understand the thermal conductivity of MOX fuel and how it differs from UO 2 . Here, molecular dynamics (MD) simulations are carried out to determine quantitatively, the effect of mixing on the thermal conductivity of U x Pu 1-x O 2 , as a function of PuO 2 concentrations, for a range of temperatures, 300 – 1500 K. The results will be used to develop enhanced continuum thermal conductivity models for MARMOT and BISON by INL. These models express the thermal conductivity as a function of microstructure state-variables, thus enabling thermal conductivity models with closer connection to the physical state of the fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Stress and tangent update equations for combined time-hardening creep and J 2 plasticity in an implicit hypo-elastic formulation

This work is motivated by the need to analyze the behavior of metallic nuclear fuels which under normal operating conditions build up stresses due to non-homogeneous thermal expansion, fission gas and solid product swelling among other phenomena that are simultaneously relaxed by creep and plastic flow. This report details the stress and tangent update equations for combined J 2 based rate independent plasticity and time-hardening creep effects in a fully implicit hypo-elastic formulation involving two cases: pure creep without plasticity where the yield criterion has not yet been met and the combined effect of both creep and plasticity beyond yield. Closed form expressions for the consistent material tangent to be used in both cases are derived which can be used in implicit codes and is expected to help in obtaining optimal convergence rates.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A general constitutive framework for the combined creep, plasticity and swelling behavior of nuclear fuels in an implicit hypoelastic formulation

This work is motivated by the need to analyze the behavior of nuclear fuels which under normal operating conditions build up stresses due to non-homogeneous thermal expansion, fission gas and solid product swelling among other phenomena that are simultaneously relaxed by creep and plastic flow. This report details the stress and tangent update equations for combined J2 based rate independent plasticity, timehardening creep and fission gas induced swelling e ects in a fully implicit hypo-elastic formulation involving two cases: pure creep without plasticity where the yield criterion has not yet been met and the combined e ect of both creep and plasticity beyond yield. Closed form expressions for the consistent material tangent to be used in both cases are derived which can be used in implicit codes and is expected to help in obtaining optimal convergence rates.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A numerical hydrodynamic study of coalescence in head-on collisions of identical stars.

The specific results reported refer to head-on collisions between identical polytropes of index 3 having solar mass and radius. If the polytropes were initially at rest at infinity, then about 5% of the combined mass is lost by ejection following collision. The volatilized mass fraction rises to about 18% for an initial relative collision velocity of 1000 km/sec at infinite separation, and to about 60% for the 2000 km/sec case. Since the initial kinetic and gravitational energies balance for a relative velocity of 1512 km/sec at infinity, it may be seen that net coalescence persists to velocities somewhat in excess of this figure. Mass ejection takes place in two ways simultaneously: (1) by a rapid sideward expulsion of fluid in a massive lateral sheet normal to the collision axis, and (2) as a result of two recoil shocks which lead momentum flows backward along this axis. The lateral effect has similarities to the expansion of gas into a vacuum i.e., shocks are not involved. However, the ejection of material from the rear colliding hemisphere due to the recoil shocks predominates at low collision velocities. As the velocity increases, both effects strengthen, but the lateral expulsion intensifies more rapidly than the recoil shocks.

Seidl, F. G. P.↗

Propulsion dynamics of lunar hoppers

A feasibility study was recently completed on a hopping transporter concept for locomotion on the moon. Termed a Lunar Pogo because it would operate similarly to a conventional pogo stick, this vehicle would accelerate up an inclined leg, pick up the leg, and then enter ballistic flight over the moon's surface. Upon recontacting the lunar surface, the Lunar Pogo would decelerate down the leg. Propulsion would be provided by expansion of gas against a piston. Operation would be partially conservative because much of the energy expended by the gas during takeoff would be recovered by compressing the gas during landing. Two models of the ballistics and propulsion have been set up to estimate performance. The simplified first-order model illuminates the thermodynamics of ideal operation. The second-order model, which includes realistic effects such as sliding, provides a better approximation to actual performance. In a one-man Lunar Pogo, an astronaut would typically make 15-m (50-ft) leaps at an average speed of 5-8 km (3-5 miles) per hour.

Meetin, R. J.↗

Shock-tube driver

Annular-arc accelerator consists of cold gas driver, expansion section, electrode sections, and shock tube section. Triggering improvement provides higher velocities and reduces contamination.

Leibowitz, L. P.↗

Homogeneous condensation of gaseous mixtures of Si, Fe, O, N, and C in relative cosmic abundance and implications for astronomical condensation

The pressure versus temperature curves for homogeneous nucleation and condensation of two gaseous mixtures with nearly relative solar abundance of Si, Fe, O, N, and C in an excess of H were determined experimentally. Mixtures of CO, Fe(CO)5, H2, SiH4, and N2O in Ar were heated behind reflected shocks in a shock tube. The nucleation and condensation, which took place in the subsequent gas-dynamic expansion (cooling phase), was monitored by light scattering and turbidity. Grain morphologies and crystalline phases present in the condensates were determined by electron microscopy. These data cast doubt on the validity of both equilibrium and classical nucleation theoretical approaches to predict homogeneous condensation in a solar nebula or stellar atmosphere.

Stephens, J. R.↗