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At least 163 records · Page 9

Flow structure in continuous flow electrophoresis chambers

There are at least two ways that hydrodynamic processes can limit continiuous flow electrophoresis. One arises from the sensitivity of the flow to small temerature gradients, especially at low flow rates and power levels. This sensitivity can be suppressed, at least in principle, by providing a carefully tailored, stabilizing temperature gradient in the cooling system that surrounds the flow channel. At higher power levels another limitation arises due to a restructuring of the main flow. This restructuring is caused by buoyancy, which is in turn affected by the electro-osmotic crossflow. Approximate solutions to appropriate partial differential equations have been computed by finite difference methods. One set of results is described here to illustrate the strong coupling between the structure of the main (axial) flow and the electro-osmotic flow.

Deiber, J. A.

Stellar occultation spikes as probes of atmospheric structure and composition

The characteristics of spikes observed in occultation light curves of Beta Scorpii by Jupiter are discussed in terms of the gravity-gradient model. The occultation of Beta Sco by Jupiter on May 13, 1971, is reviewed, and the gravity-gradient model is defined as an isothermal atmosphere of constant composition in which the refractivity is a function only of the radial coordinate from the center of refraction, which is assumed to lie parallel to the local gravity gradient. The derivation of the occultation light curve in terms of the atmosphere, the angular diameter of the occulted star, and the occultation geometry is outlined. It is shown that analysis of the light-curve spikes can yield the He/H2 concentration ratio in a well-mixed atmosphere, information on fine-scale atmospheric structure, high-resolution images of the occulted star, and information on ray crossing. Observational limits are placed on the magnitude of horizontal refractivity gradients, and it is concluded that the spikes are the result of local atmospheric density variations: atmospheric layers, density waves, or turbulence.

Elliot, J. L.

Structure development in silicon sheet by shaped crystallization

Models are presented for the development of a parallel twinned structure of the 110 plane type and the 112 line type in silicon ribbons. The models are believed to be mutually compatible and operable. The first model relates the requirements for super-cooling during crystallization. The existence of reentrant angles associated with the twin structure is proposed to provide a rough interface to reduce super-cooling. The spacing of the twins is proposed to be limited by the geometrical relationship between the thermal gradient in the liquid and the dimensions of the twinned crystallization front. The second model relates the thermal stress configuration to detail dislocation reactions which would be expected to develop twins. While a specific dislocation mechanism cannot yet be defined, a number of alternatives are presented. All of these various dislocation mechanisms would result in the observed crystalline configuration and the choice among them is not critical.

Leipold, M. H.

Theoretical analysis of heat flow in horizontal ribbon growth from a melt

A theoretical heat flow analysis for horizontalribbon growth is presented. Equations are derived relating pull speed, ribbon thickness, thermal gradient in the melt, and melt temperature for limiting cases of heat removal by radiation only and isothermal heat removal from the solid surface over the melt. Geometrical cross sections of the growth zone are shown to be triangular and nearly parabolic for the two respective cases. Theoretical pull speed for silicon ribbon 0.01 cm thick, where the loss of latent heat of fusion is by radiation to ambient temperature (300 K) only, is shown to be 1 cm/sec for horizontal growth extending 2 cm over the melt and with no heat conduction either to or from the melt. Further enhancement of ribbon growth rate by placing cooling blocks adjacent to the top surface is shown to be theoretically possible.

Zoutendyk, J. A.

Interaction effects in thermocapillary bubble migration

Two bubbles migrating along their line of centers under the influence of an imposed thermal gradient are considered in the quasi-static limit. Results are reported for representative values of the governing parameters.

Meyyappan, M.

Parabolic Dish Concentrator (PDC-1)

The design, construction, and installation of the Parabolic Dish Concentrator, Type 1 (PDC-1) has been one of the most significant JPL concentrator projects because of the knowledge gained about this type of concentrator and the development of design, testing, and analysis procedures which are applicable to all solar concentrator projects. The need for these procedures was more clearly understood during the testing period which started with the prototype panel evaluation and ended with the performance characterization of the completed concentrator. For each phase of the test program, practical test procedures were required and these procedures defined the mathematical analysis which was essential for successful concentrator development. The concentrator performance appears to be limited only by the distortions resulting from thermal gradients through the reflecting panels. Simple optical testing can be extremely effective, but comprehensive mechanical and optical analysis is essential for cost effective solar concentrator development.

Dennison, E. W.

Thermostructural Analysis of Carbon Cloth Phenolic Material Tested at the Laser Hardened Material Evaluation Laboratory

RSRM nozzle liner components have been analyzed and tested to explore the occurrence of anomalous material performance known as pocketing erosion. Primary physical factors that contribute to pocketing seem to include the geometric permeability, which governs pore pressure magnitudes and hence load, and carbon fiber high temperature tensile strength, which defines a material limiting capability. The study reports on the results of a coupled thermostructural finite element analysis of Carbon Cloth Phenolic (CCP) material tested at the Laser Hardened Material Evaluation Laboratory (the LHMEL facility). Modeled test configurations will be limited to the special case of where temperature gradients are oriented perpendicular to the composite material ply angle. Analyses were conducted using a transient, one-dimensional flow/thermal finite element code that models pore pressure and temperature distributions and in an explicitly coupled formulation, passes this information to a 2-dimensional finite element structural model for determination of the stress/deformation behavior of the orthotropic fiber/matrix CCP. Pore pressures are generated by thermal decomposition of the phenolic resin which evolve as a multi-component gas phase which is partially trapped in the porous microstructure of the composite. The nature of resultant pressures are described by using the Darcy relationships which have been modified to permit a multi-specie mass and momentum balance including water vapor condensation. Solution to the conjugate flow/thermal equations were performed using the SINDA code. Of particular importance to this problem was the implementation of a char and deformation state dependent (geometric) permeability as describing a first order interaction between the flow/thermal and structural models. Material property models are used to characterize the solid phase mechanical stiffness and failure. Structural calculations were performed using the ABAQUS code. Iterations were made between the two codes involving the dependent variables temperature, pressure and across-ply strain level. Model results comparisons are made for three different surface heat rates and dependent variable sensitivities discussed for the various cases.

Clayton, J. Louie

Pioneer-10 measurements of the differential and integral cosmic-ray gradient between 1 and 3 AU

The cosmic-ray experiment on Pioneer has provided measurements of the differential radial gradient of cosmic-ray helium nuclei between 1 and 3 AU. Upper limits are quoted between 10 and 500 MeV/nuc which are everywhere 25%/AU and in some cases substantially smaller. The integral proton gradient ( 56 MeV) was also measured and found to have the following values: 2.4 + or - 0.3%/AU (1-2 AU), 7.6 + or - 0.7%/AU (2-3 AU).

Teegarden, B. J.

Kinetics of boron deposition by the hydrogen reduction of boron trichloride

The chemical vapor deposition of boron filament is generally considered to be limited by the diffusion of the reactive species to the hot substrate. From concentration gradient considerations and from experimental measurements it is concluded that the product species (HCl) is more likely to be involved in limiting the deposition rate. Comparison of theoretically calculated and experimentally measured deposition rates show that the rate is generally partially limited by diffusion and partially by the surface reaction rate (desorption) of HCl. The relative amounts of surface reaction or diffusion rate impedance were determined as a function of temperature and gas velocity. The temperature coefficient for the desorption of HCl was found to be 52 Kcal/mole.

Mehalso, R. M.

An experimental study of three-dimensional turbulent boundary layer and turbulence characteristics inside a turbomachinery rotor passage

Three-dimensional boundary layer and turbulence measurements of flow inside a rotating helical channel of a turbomachinery rotor are described. The rotor is a four-bladed axial flow inducer operated at large axial pressure gradient. The mean velocity profiles, turbulence intensities and shear stresses, and limiting stream-line angles are measured at various radial and chordwise locations, using rotating triaxial hot-wire and conventional probes. The radial flows in the rotor channel are found to be higher compared to those at zero or small axial pressure gradient. The radial component of turbulence intensity is found to be higher than the streamwise component due to the effect of rotation. Flow near the annulus wall is found to be highly complex due to the interaction of the blade boundary layers and the annulus wall resulting in an appreciable radial inward flow, and a large defect in the mainstream velocity. Increased level of turbulence intensity and shear stresses near the midpassage are also observed near this radial location.

Anand, A. K.

Simulation and Modeling of Hypersonic Turbulent Boundary Layers Subject to Favorable Pressure Gradients due to Streamline Curvature

Direct numerical simulations (DNS) of favorable-pressure-gradient turbulent boundary layers are presented for a nominal freestream Mach number of 5, with the objective of assessing the limitations of the currently available Reynolds-averaged Navier-Stokes (RANS) models. The favorable pressure gradient is induced by the streamwise curvature of the two-dimensional, planar, convex measurement surface used during experiments at the Texas A&M University. The DNS data shows good comparison with the measured velocity profiles, strain rates, and some, but not all, of the Reynolds-stress components. The discrepancies between the predicted and the measured wall-normal as well as shear stress components are primarily attributed to the lower than actual values inferred from typical PIV measurements of turbulent boundary layers. The DNS data shows a zero or slightly negative Reynolds shear stress in the outer part of the boundary-layer, which is indicative of the decaying turbulent motion under a strong favorable pressure gradient. The DNS data is also compared with the results of RANS computations based on commonly used zero, one, and two equation eddy-viscosity models. The RANS models yield reasonable comparisons with the DNS-based skin friction under zero and weak pressure gradients, but significant discrepancies under a strong pressure gradient. The k-w SST model provided the best overall predictions of skin friction, except in the region where the flow transitions from a favorable to an adverse pressure gradient. While the RANS models examined herein also give good predictions of the Reynolds shear stress under a sufficiently weak pressure gradient, none of those models are able to appropriately capture the reduction in the Reynolds stresses when the flow was subjected to a strong pressure gradient. An a priori assessment of the turbulent heat-flux prediction based on the assumption of a constant turbulent Prandtl number with the DNS data shows that while the constant turbulent Prandtl number model is effective in predicting the wall-normal component of turbulent heat flux, it does not capture the turbulent heat transfer in the streamwise direction for all the pressure gradient cases. The failure of the constant turbulent Prandtl number model highlights a requirement for more advanced models of the turbulent heat flux.

turbulent boundary layers

Twentieth Century Redistribution in Climatic Drivers of Global Tree Growth

Energy and water limitations of tree growth remain insufficiently understood at large spatiotemporal scales, hindering model representation of interannual or longer-term ecosystem processes. By assessing and statistically scaling the climatic drivers from 2710 tree-ring sites, we identified the boreal and temperate land areas where tree growth during 1930–1960 CE responded positively to temperature (20.8 ± 3.7 Mio km2; 25.9 ± 4.6%), precipitation (77.5 ± 3.3 Mio km2; 96.4 ± 4.1%), and other parameters. The spatial manifestation of this climate response is determined by latitudinal and altitudinal temperature gradients, indicating that warming leads to geographic shifts in growth limitations. We observed a significant (P < 0.001) decrease in temperature response at cold-dry sites between 1930–1960 and 1960–1990 CE, and the total temperature-limited area shrunk by −8.7 ± 0.6 Mio km2. Simultaneously, trees became more limited by atmospheric water demand almost worldwide. These changes occurred under mild warming, and we expect that continued climate change will trigger a major redistribution in growth responses to climate.

Babst, Flurin

Moist Energy Constraints on Surface Temperature Variance Under Climate Warming

Understanding the factors controlling surface temperature variance is crucial for predicting temperature extremes. Previous investigations have examined individual impacts of temperature advection and surface turbulent fluxes on temperature fluctuations. Here, we explore the constraints on temperature variance from the moist static energy (MSE) balance and introduce a new scaling relation that connects the generation of temperature variance through moist energy transport with its dissipation due to the net energetic forcing of the atmosphere. This theory is evaluated in an idealized aquaplanet model. We find that surface temperature variance is influenced by eddy (sensible) heat flux, MSE gradient, and the Clausius‐Clapeyron relation for evaporative cooling. Under global warming, the reduced temperature variance in the aquaplanet model is dominated by the weakening in eddy heat flux, but it is also affected by changes in evaporative cooling and MSE gradient, which may be more important in realistic, moisture‐limited regions over land.

Eddy heat flux

Weighted active space protocol for multireference machine-learned potentials

Multireference methods such as multiconfiguration pair-density functional theory accurately capture electronic correlation in systems with strong multiconfigurational character, but their cost precludes direct use in molecular dynamics. Combining these methods with machine-learned interatomic potentials (MLPs) can extend their reach. However, the sensitivity of multireference calculations to the choice of the active space complicates the consistent evaluation of energies and gradients across structurally diverse nuclear configurations. To overcome this limitation, we introduce the weighted active space protocol (WASP), a systematic approach to assign a consistent active space for a given system across uncorrelated configurations. By integrating WASP with MLPs and enhanced sampling techniques, we propose a data-efficient active learning cycle that enables the training of an MLP on multireference data. We demonstrated the approach on the TiC + -catalyzed C–H activation of methane, a reaction that poses challenges for Kohn–Sham density functional theory due to its significant multireference character. This framework enables accurate and efficient modeling of catalytic dynamics, establishing a paradigm for simulating complex reactive processes beyond the limits of conventional electronic-structure methods.

enhanced sampling

Climate-Driven Divergence in Biophysical and Economic Impacts of Agrivoltaics

Increasing global demands for food and energy necessitate innovative land-use solutions. Agrivoltaics, colocating solar photovoltaics with agriculture, shows promise, but its widespread adoption faces complex biophysical and economic trade-offs in a changing climate. Here, we develop an integrated biophysical-economic modeling framework to quantify how agrivoltaics affect biophysical and economic impacts across the Midwestern United States under both current and project climate conditions. We find strong regional divergences driven by climate gradients. In the humid eastern Midwest, solar panel shading limits photosynthesis, leading to reduced yields (maize -24%; soybean -16%) and lower farmers' profitability (maize -16%; soybean -2%) compared to conventional agriculture. Conversely, in the semiarid western region, shading alleviates heat and water stress, moderating yield reductions for maize (-12%) and even boosting soybean yields (+6%), resulting in improved economic returns (-6% for maize; +9% for soybean), for a scenario with 33% photovoltaic ground coverage ratio. Although agrivoltaics generate substantial electrical energy across all regions, high upfront installation costs challenge solar developers compared to standalone solar photovoltaics. However, our analysis identifies “win-win” opportunities where soybean-based agrivoltaics in the semiarid region produce economic benefits for both farmers and solar developers, highlighting the necessity for region-specific designs tailored to local climate conditions. Critically, future climate projections indicate eastward expansion of semiarid conditions, broadening areas where agrivoltaics can mitigate crop yield penalties (even boosting yield) and improve overall profitability, especially under high-emission scenarios. The results provide a mechanistic and economically integrated understanding essential for developing evidence-based and region-specific strategies to scale agrivoltaics in a changing climate.

14 SOLAR ENERGY

Infrared limb scanning in the presence of horizontal temperature gradients - An operational approach

Simulation and analysis of IR limb radiance obtained by a satellite-borne IR limb scanner have demonstrated that horizontal temperature gradients in the atmosphere play an important role in limiting the accuracy of retrieved temperature and constituents below approximately 25 km. A simple operational approach to converting these observed radiances to equivalent spherical radiances is developed which preserves the advantages of the sphericity assumption in the inversion process.

Roewe, D. A.

Nonlinear evolution of the lower-hybrid drift instability

The results of simulations of the lower-hybrid drift instability in a neutral sheet configuration are described. The simulations use an implict formulation to relax the usual time step limitations and thus extend previous explicit calculations to weaker gradients, larger mass ratios, and long times compared with the linear growth time. The numerical results give the scaling of the saturation level, heating rates, resistivity, and cross-field diffusion and a demonstration by comparison with a fluid electron model that dissipation in the lower-hybrid drift instability is caused by electron kinetic effects.

Brackbill, J. U.

Determination of shuttle orbiter center of gravity from flight measurements

Flight measurements of pitch, yaw, and roll rates and the resultant rotationally induced linear accelerations during three orbital maneuvers on Shuttle mission space transportation system (STS) 61-C were used to calculate the actual orbiter center-of-gravity location. The calculation technique reduces error due to lack of absolute calibration of the accelerometer measurements and compensates for accelerometer temperature bias and for the effects of gravity gradient. Accuracy of the technique was found to be limited by the nonrandom and asymmetrical distribution of orbiter structural vibration at the accelerometer mounting location. Fourier analysis of the vibration was performed to obtain the power spectral density profiles which show magnitudes in excess of 10(exp 4) ug (sup 2)/Hz for the actual vibration and over 500 ug (sup 2)/Hz for the filtered accelerometer measurements. The data from this analysis provide a characterization of the Shuttle acceleration environment which may be useful in future studies related to accelerometer system application and zero-g investigations or processes.

Hinson, E. W.