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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Effects of Heat Treatment on Microstructure, Thermal Transport and Stability in SRF Niobium

Efficient heat transfer and thermal stability are critical for preventing thermal quench and ensuring the high performance and reliability of superconducting radiofrequency (SRF) cavities, especially under high RF fields. In this article, we investigate thermal conductivity and heat capacity of high-purity cold-worked niobium used in SRF applications, with a particular focus on the effects of high-temperature heat treatments. Our measurements reveal a pronounced sensitivity of thermal transport and thermodynamic properties to the underlying microstructure such as grain size and dislocation density. The results show the critical role of controlled heat treatment processes in optimizing the thermal performance of SRF niobium, providing valuable insights for improving cavity fabrication and processing.

36 MATERIALS SCIENCE↗

A three-D circulation model study of the radiative-dynamic coupling within the stratosphere

The role of radiative transfer processes in the general circulation of the stratosphere was studied by comparing the thermal and dynamical structure of the stratosphere as simulated by two controlled numerical experiments performed with the aid of a spectral 3-dimensional quasi-geostrophic circulation model. In the first experiment, a detailed radiative transfer model is employed to treat the longwave radiative transfer in the stratosphere. In the second experiment, longwave radiative transfer is accounted for by employing the Newtonian cooling approximation. It is found that the exchange of longwave radiation between the troposphere and lower stratosphere has a net heating effect on the lower stratosphere. It is shown that this heating effect contributes partly to the maintenance of the warm high-latitude belt in the lower stratosphere during winter and spring seasons. The strong temperature dependence of the Newtonian cooling coefficient plays an important role in determining the zonal temperatures and has a significant influence on the transmissivity of stratosphere to propagating planetary scale waves.

Ramanathan, V.↗

Radiative aspects of Antarctic ozone hole in 1985

In order to investigate the radiative heating effects of aerosols during September - October, 1985, at Antarctica, researchers solved the radiative transfer equation using a one-dimensional model, which includes the absorption of solar energy by water vapor, carbon dioxide, ozone and aerosols, the thermal emission and absorption by the above species and in addition, Rayleigh and Mie scattering, and the surface scattering effects. In this calculation, they used data of ozone density, water vapor density and aerosol extinction at 0.385, 0.453, 0.525 and 1.02 mu m in the stratosphere obtained by SAGE II satellite and meteorological data from NOAA. Results show that the Antarctic stratosphere is nearly in radiative equilibrium during that period, if the effects of aerosols are excluded. It is also shown that the heating effects of aerosols are too small to cause effective upward motions, in spite of some ambiguous parameters such as aerosol composition. The parameter dependences of results are also discussed.

Akiyoshi, H.↗

Structural characterization and gas reactions of small metal particles by high-resolution TEM and TED

The interaction of 100 and 200 keV electron beams with amorphous alumina, titania, and aluminum nitride substrates and nanometer-size palladium particulate deposits was investigated for the two extreme cases of (1) large-area electron-beam flash-heating and (2) small-area high-intensity electron-beam irradiation. The former simulates a short-term heating effect with minimum electron irradiation exposure, the latter simulates high-dosage irradiation with minimum heating effect. All alumina and titania samples responded to the flash-heating treatment with significant recrystallization. However, the size, crystal structure, shape, and orientation of the grains depended on the type and thickness of the films and the thickness of the Pd deposit. High-dosage electron irradiation also readily crystallized the alumina substrate films but did not affect the titania films. The alumina recrystallization products were usually either all in the alpha phase, or they were a mixture of small grains in a number of low-temperature phases including gamma, delta, kappa, beta, theta-alumina. Palladium deposits reacted heavily with the alumina substrates during either treatment, but they were very little effected when supported on titania. Both treatments had the same, less prominent localized crystallization effect on aluminum nitride films.

Heinemann, K.↗

Exploring Catalyst Compositions for Microwave-Assisted Methane Dehydroaromatization

The flaring of natural gas in U.S. shale regions remains a challenge for producers. One alternative to flaring is converting the wasted gas into valuable chemicals. Microwave-based processes offer a promising solution, potentially enabling the development of compact, modular systems for on-site production of chemicals, such as aromatics, from natural gas. This is due to the advantages of microwave heating, including efficient heating of compact volumes, accelerated reaction rates, and electrification of heating. However, developing effective catalysts for microwave-based processes is challenging, as conventional materials often require modification to be effectively heated by microwaves. This study provides an overview of a catalyst development project focused on a molybdenum-supported zeolite catalyst, optimized for the direct conversion of methane into aromatics under microwave irradiation. It details the synthesis, characterization, and the effects of promoters, as well as computational efforts undertaken to understand and enhance the catalyst's performance.

flare gas↗

Smaller and faster: a review of conventional and nanocalorimetry techniques for determining thermophysical properties of nuclear materials

Thermal analysis of nuclear materials is critical for the advancement of nuclear technology. The heat effects associated with heat capacity, phase transformation, and radiation damage can be measured with conventional calorimeters. However, conventional calorimetric techniques are often restricted in terms of heating rate and sample mass, especially when studying the limited amounts of materials subject to extreme conditions. In this review, we summarize conventional calorimetric studies of critical thermophysical and thermochemical properties of pure actinide metals (U, Np, Am, Pu), fast reactor metallic fuel alloy systems (U–Zr, U–Pu–Zr, Pu–U, Pu–Zr), and actinide oxides that are primary constituents or transmutation products in light water reactor fuel rods (U–O, Np–O, Am–O, Pu–O, Pu–U–O). Adiabatic and drop calorimetry have been the primary techniques used for these studies, however the development of fast scanning calorimetry using micro-electro-mechanical-based systems allows determination of thermodynamic properties from smaller sample masses. We report recent investigations that leverage the fast heating rates of nanocalorimetry by itself or combined with other characterization techniques. Furthermore, we then discuss opportunities for nanocalorimetry to provide solutions to some of the technical challenges inherent in thermal analysis of nuclear materials, namely a reduction in sample activity, emulating heating transients, investigation of phase evolution in irradiated samples, and characterization of radiation damage evolution. Nanocalorimetry has the potential to significantly advance the understanding of thermophysical properties in nuclear materials and thus accelerate the development of nuclear technology.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Effect of surface tension anisotropy on cellular morphologies

A three-dimensional weakly nonlinear analysis for conditions near the onset of instability at the crystal-melt interface was carried out to second order, taking into account the effects of latent heat generation and surface-tension anisotropy of the crystal-melt interface; particular consideration was given to the growth of a cubic crystal in the 001-, 011-, and 111-line directions. Numerical calculations by McFadden et al. (1987), performed for an aluminum-chromium alloy with the assumption of a linear temperature field and an isotropic surface tension, showed that only hexagonal nodes (and not hexagonal cells) occurred near the onset of instability. The results of the present analysis indicate that the nonlinear temperature field (which occurs when thermal conductivities of the crystal and the melt are different and/or the latent heat effects are not negligible) can modify this result and, for certain alloys and processing conditions, can cause the occurrence of hexagonal cells near the onset of instability.

Mcfadden, G. B.↗

Nonequilibrium ionization effects in asymmetrically heated loops

The effects of nonequilibrium ionization on magnetic loop models with a steady siphon flow that is driven by a nonuniform heating rate are investigated. The model developed by Mariska (1988) to explain the observed redshifts of transition region emission lines is examined, and the number densities of the ions of carbon and oxygen along the loop are computed, with and without the approximation of ionization equilibrium. Considerable deviations from equilibrium were found. In order to determine the consequences of these nonequilibrium effects on the characteristics of the EUV emission from the loop plasma, the profiles and wavelength positions of all the important emission lines due to carbon and oxygen were calculated. The calculations are in broad agreement with Mariska's conclusions, although they show a significant diminution of the Doppler shifts, as well as modifications to the line widths. It is concluded that the inclusion of nonequilibrium effects make it more difficult to reproduce the observed characteristics of the solar transition region by means of the asymmetric-heating models.

Spadaro, D.↗

Trees halve urban heat island effect globally but unequal benefits only modestly mitigate climate-change warming

Although tree cover reduces the urban heat island, no global estimate quantifies air temperature reductions by contemporary or future tree cover, currently and with climate change. Here, we estimate these reductions for all 8,919 large urban areas. Current urban tree cover mitigates 41–49% of the maximum potential air-temperature urban heat island that would occur in the absence of tree canopy. Tree canopy reduces summer air temperature by a population-weighted mean of 0.15 ± 0.03 °C, with wide variation (0.0–2.7 °C), benefiting 914 (805–1040, 95% CI) million people by >0.25 °C. Cooling benefits are greater in already cooler areas: high-income countries and suburbs. Current and plausible future tree cover mitigate only ~10% (6.7–18% and 6.3–17%, respectively) of the median mid-century climate-change warming under a moderate emission scenario. Our results suggest tree canopy expansion in densely settled low-income urban areas is necessary for equitable urban heat island mitigation and climate adaptation.

McDonald, Robert I. [The Nature Conservancy (TNC),↗

Modeling and data analysis of the NASA-WSTF frictional heating apparatus - Effects of test parameters on friction coefficient

A theoretical model is being developed jointly by the NASA White Sands Test Facility (WSTF) and the University of California at Santa Barbara (UCSB) to analyze data generated from the WSTF frictional heating test facility. Analyses of the data generated in the first seconds of the frictional heating test are shown to be effective in determining the friction coefficient between the rubbing interfaces. Different friction coefficients for carobn steel and Monel K-500 are observed. The initial condition of the surface is shown to affect only the initial value of the friction coefficient but to have no significant influence on the average steady-state friction coefficient. Rotational speed and the formation of oxide film on the rotating surfaces are shown to have a significant effect on the friction coefficient.

Zhu, Sheng-Hu↗

Investigation of Effectiveness of Air-Heating a Hollow Steel Propeller for Protection Against Icing. 2: 50% Impartitioned Blades

The icing protection afforded an internal air-heated propeller blade by radial partitioning at 50-percent chord to confine the heated air to the forward half of the blade was determined in the NACA Cleveland icing research tunnel. A modified production-model hollow steel propeller, was used for the investigation. Temperatures of the blade surfaces for several heating rates were measured under various tunnel Icing' conditions. Photographic observations of ice formations on blade surfaces and blade heat-exchanger effectiveness were obtained. With 50-percent partitioning of the blades, adequate icing protection at 1050 rpm was obtained with a heating rate of 26,000 Btu per hour per blade at the blade shank using an air temperature of 400 F with a flow rate of 280 pounds per hour per blade, which is one-third less heat than was found necessary for similar Ice protection with unpartitioned blades. The chordwise distribution of the applied heat, as determined by surface temperature measurements, was considered unsatisfactory with much of the heat dissipated well back of the leading edge. Heat-exchanger effectiveness of approximately 56 percent also Indicated poor utilization of available heat. This effectiveness was, however, 9 percent greater than that obtained from unpartitioned blades.

Perkins, Porter J.↗

Thermal Barrier/Seal for Extreme Temperature Applications

Large solid rocket motors, as found on the Space Shuttle, are fabricated in segments for manufacturing considerations, bolted together, and sealed using conventional Viton O-ring seals. Similarly the nine large solid rocket motor nozzles are assembled from several different segments, bolted together, and sealed at six joint locations using conventional O-ring seals. The 5500 F combustion gases are generally kept a safe distance away from the seals by thick layers of phenolic or rubber insulation. Joint-fill compounds, including RTV (room temperature vulcanized compound) and polysulfide filler, are used to fill the joints in the insulation to prevent a direct flow-path to the O-rings. Normally these two stages of protection are enough to prevent a direct flow-path of the 900-psi hot gases from reaching the temperature-sensitive O-ring seals. However, in the current design 1 out of 15 Space Shuttle solid rocket motors experience hot gas effects on the Joint 6 wiper (sacrificial) O-rings. Also worrisome is the fact that joints have experienced heat effects on materials between the RTV and the O-rings, and in two cases O-rings have experienced heat effects. These conditions lead to extensive reviews of the post-flight conditions as part of the effort to monitor flight safety. We have developed a braided carbon fiber thermal barrier to replace the joint fill compounds in the Space Shuttle solid rocket motor nozzles to reduce the incoming 5500 F combustion gas temperature and permit only cool (approximately 100 F) gas to reach the temperature-sensitive O-ring seals. Implementation of this thermal barrier provides more robust, consistent operation with shorter turn around times between Shuttle launches.

Steinetz, Bruce M.↗

Thermal design for areas of interference heating on actively cooled hypersonic aircraft

Numerous actively cooled panel design alternatives for application in regions on high speed aircraft that are subject to interference heating effects were studied. Candidate design concepts were evaluated using mass, producibility, reliability and inspectability/maintainability as figures of merit. Three design approaches were identified as superior within certain regimes of the matrix of design heating conditions considered. Only minor modifications to basic actively cooled panel design are required to withstand minor interference heating effects. Designs incorporating internally finned coolant tubes to augment heat transfer are recommended for moderate design heating conditions. At severe heating conditions, an insulated panel concept is required.

Herring, R. L.↗

The effect of heat treatment on microfissuring in alloy 718

Changes in the microfissuring susceptibility of alloy 718 due to solution annealing and age hardening are studied. The effects of Ni3Nb (delta) precipitation during solution annealing and gamma-prime + gamma-double-prime precipitation during age hardening on microfissuring are investigated. It is observed that solution annealing reduces microfissuring and age hardening increases it, and the two precipitates do not affect microfissuring susceptibility. Potential causes for the detected intergranular segregation of the alloy are discussed.

Thompson, R. G.↗

Vortices induced in a stagnation region by wakes - Their incipient formation and effects on heat transfer from cylinders

Horseshoe-like vortices, induced by wakes in the stagnation region of bluff bodies, are proposed as an efficient mechanism for augmentation of convective heat transfer. The vortex 'flow module' induced by single or multiple wakes, which had not been observed previously, was first documented and the resulting flow field was studied using various visualization techniques and hot-wire anemometry. In an attempt to understand the driving force behind this flow module, the conditions at which incipient formation of the vortices occurs were investigated. Existence of such a threshold is essential and was hitherto an open question in analytical studies of stability of flow in stagnation region. Finally, effects of the flow module on heat transfer from a cylinder were measured.

Nagib, H. M.↗