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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Determining orbital particle parameters of impacts into germanium using morphology analysis and calibration data from hypervelocity impact experiments in the laboratory

This paper describes the work that is done at the Lehrstuhl fur Raumfahrttechnik (lrt) at the Technische Universitat Munchen to examine particle impacts into germanium surfaces which were flown on board the LDEF satellite. Besides the description of the processing of the samples, a brief overview of the particle launchers at our institute is given together with descriptions of impact morphology of high- and hypervelocity particles into germanium. Since germanium is a brittle, almost glass-like material, the impact morphology may also be interesting for anyone dealing with materials such as optics and solar cells. The main focus of our investigations is to learn about the impacting particle's properties, for example mass, velocity and direction. This is done by examining the morphology, various geometry parameters, crater obliqueness and crater volume.

Paul, Klaus G.↗

Structural Damage Prediction and Analysis for Hypervelocity Impact: Properties of Largest Fragment Produced by Hypervelocity Impact of Aluminum Spheres with Thin Aluminum Sheets

Results of a series of hypervelocity impact tests are presented. In these tests, 1.275-g, 9.53-mm-diameter, 2017-T4 aluminum spheres were fired at normal incidence at eight thicknesses of 6061-T6 aluminum sheet. Bumper thickness to projectile diameter (t/D) ratio ranged from 0.026 to 0.424. Nominal impact velocity was 6.7 km/s. Results of five tests using 6.35, 9.53, and 12.70-mm-diameter aluminum spheres and other aluminum alloy bumpers are also given. A large chunky fragment of projectile was observed at the center of the debris clouds produced by the impacts. The equivalent diameter of this large fragment ranged from 5.5 mm for the lowest t/D ratio to a minimum of 0.6 mm for the case where maximum breakup of the projectile occurred (t/D approximately 0.2 to 0.3). When the t/D ratio was 0.42, numerous large flaky fragments were evenly distributed in the external bubble of bumper debris. Velocity of the large central fragments decreased continuously with increasing t/D ratio, ranging from about 99 percent to less than 80 percent of the impact velocity. The change in the velocity of small fragments spalling from the rear of the projectile was used to obtain a relationship showing a linear increase in the size of the central projectile fragment with decrease in the shock-induced stress in the projectile.

Piekutowski, Andrew J.↗

Chicxulub Impact Melts: Geochemical Signatures of Target Lithology Mixing and Post-Impact Hydrothermal Fluid Processes

Impact melts within complex impact craters are generally homogeneous, unless they differentiated, contain immiscible melt components, or were hydrothermally altered while cooling. The details of these processes, however, and their chemical consequences, are poorly understood. The best opportunity to unravel them may lie with the Chicxulub impact structure, because it is the world s most pristine (albeit buried) large impact crater. The Chicxulub Scientific Drilling Project recovered approx. 100 meters of impactites in a continuous core from the Yaxcopoil-1 (YAX-1) borehole. This dramatically increased the amount of melt available for analyses, which was previously limited to two small samples N17 and N19) recovered from the Yucatan-6 (Y-6) borehole and one sample (N10) recovered from the Chicxulub-1 (C-1) borehole. In this study, we describe the chemical compositions of six melt samples over an approx. 40 m section of the core and compare them to previous melt samples from the Y-6 and C-1 boreholes.

Kring, David A.↗

Effect of High Impact or Non-impact Loading Activity on Bone Bending Stiffness and Mineral Density

Material properties of conical bone, including mineral density (BMD) and its geometry is closely related to its load-carrying capacity. These two primary components determine the strength of conical bone. High impact loading involving acceleration and deceleration movements used in gymnastics induce higher BMD of the affected bone compared to the non-impact acceleration and deceleration movements used in swimming. Study of these two groups of athletes on bone bending stiffness has not been reported. The purpose of this study was to compare differences in bone bending stiffness and BMD between competitive female synchronized swimmers and female gymnasts. Thirteen world class female synchronized swimmers (SYN) and 8 female gymnasts (GYM), mean age 21 +/- 2.9 yr. were recruited for this study. We used a mechanical response tissue analyzer (Gaitscan, NJ) to calculate EI, where E is Young's modulus of elasticity and I is the cross-sectional moment of inertia. EI was obtained from tissue response to a vibration probe placed directly on the skin of the mid-region of tibia and ulna. BMD of the heel and wrist were measured with a probe densitometer (PIXI, Lunor, WI). The SYN were taller than (p < 0.05) the GYM but weighed the same as the GYM. EI obtained from tibia and ulna of the SYN (291 +/- 159 and 41 +/- 19.4, respectively) were not significantly different from thc GYM (285 +/- 140 and 44 +/- 18.3, respectively). BMD of the heel and wrist in GYM were higher than in SYN (p < 0.001). High impact weight-bearing activities promote similar bone strength but greater BMD response than non-impact activities performed in a buoyant environment.

Liang, Michael T. C.↗

Osmium-Isotope and Platinum-Group-Element Systematics of Impact-Melt Rocks, Chesapeake Bay Impact Structure, Virginia, USA

Osmium (Os) isotopes and platinum-group elements (PGEs) are useful for geochemically identifying a meteoritic component within impact structures, because meteorites are typically characterized by low (187)Os/(188)Os ratios and high PGE concentrations. In contrast, most types of crustal target rocks have high radiogenic Os and very low PGE concentrations. We have examined Os isotope and PGE systematics of impact-melt rocks and pre-impact target rocks from a 2004 test hole in the late Eocene Chesapeake Bay impact structure and from nearby coreholes. Our goal is to determine the proportion of the projectile component in the melt rock Additional information is included in the original extended abstract.

Lee, Seung Ryeol↗

The Interaction of Impact Melt, Impact-Derived Sediment, and Volatiles at Crater Tooting, Mars

We are producing a 1:200K geologic map of Tooting crater, Mars. This work has shown that an incredible amount of information can be gleaned from mapping at even larger scales (1:10K 1:25K) using CTX and HiRISE data. We have produced two new science papers (Morris et al., 2010; Mouginis-Mark and Boyce, 2010) from this mapping, and additional science questions continue to arise from our on-going analysis of Tooting crater: 1) What was the interplay of impact melt and volatile-rich sediments that, presumably, were created during the impact? Kieffer and Simonds [1980] predicted that melt would have been destroyed during impacts on Mars because of the volatiles present within the target we seek to understand if this is indeed the case at Tooting crater. We have identified pitted and fractured terrain that formed during crater modification, but the timing of the formation of these materials in different parts of the crater remains to be resolved. Stratigraphic relationships between these units and the central peak may reveal deformation features as well as overlapping relationships. 2) Morris et al. [2010] identified several lobate flows on the inner and outer walls of Tooting crater. It is not yet clear what the physical characteristics of the source areas of these flows really are; e.g., what are the sizes of the source areas, what elevations are they located at relative to the floor of the crater, are they interconnected, and are they on horizontal or tilted surfaces? 3) What were the details of dewatering of the inner wall of Tooting crater (Fig. 1)? We find evidence within Tooting crater of channels carved by water release, and the remobilization of sediment (which is inferred to have formed during the impact event). Sapping can be identified along the crest of unit 8 near the floor of the crater (Fig. 2a, 2b). This unit displays amphitheater-headed canyons that elsewhere on Mars are typically attributed to water leaking from the substrate [Laity and Malin, 1985; Malin and Edgett, 2000].

Mouginis-Mark, P.↗

Lunar Impact Basins: Stratigraphy, Sequence and Ages from Superposed Impact Crater Populations Measured from Lunar Orbiter Laser Altimeter (LOLA) Data

Impact basin formation is a fundamental process in the evolution of the Moon and records the history of impactors in the early solar system. In order to assess the stratigraphy, sequence, and ages of impact basins and the impactor population as a function of time, we have used topography from the Lunar Orbiter Laser Altimeter (LOLA) on the Lunar Reconnaissance Orbiter (LRO) to measure the superposed impact crater size-frequency distributions for 30 lunar basins (D ≥ 300 km). These data generally support the widely used Wilhelms sequence of lunar basins, although we find significantly higher densities of superposed craters on many lunar basins than derived by Wilhelms (50% higher densities). Our data also provide new insight into the timing of the transition between distinct crater populations characteristic of ancient and young lunar terrains. The transition from a lunar impact flux dominated by Population 1 to Population 2 occurred before the mid-Nectarian. This is before the end of the period of rapid cratering, and potentially before the end of the hypothesized Late Heavy Bombardment. LOLA-derived crater densities also suggest that many Pre-Nectarian basins, such as South Pole-Aitken, have been cratered to saturation equilibrium. Finally, both crater counts and stratigraphic observations based on LOLA data are applicable to specific basin stratigraphic problems of interest; for example, using these data, we suggest that Serenitatis is older than Nectaris, and Humboldtianum is younger than Crisium. Sample return missions to specific basins can anchor these measurements to a Pre-Imbrian absolute chronology.

Fassett, C. I.↗

Orion Ground Test Article Water Impact Tests: Photogrammetric Evaluation of Impact Conditions

The Ground Test Article (GTA) is an early production version of the Orion Crew Module (CM). The structural design of the Orion CM is being developed based on LS-DYNA water landing simulations. As part of the process of confirming the accuracy of LS-DYNA water landing simulations, the GTA water impact test series was conducted at NASA Langley Research Center (LaRC) to gather data for comparison with simulations. The simulation of the GTA water impact tests requires the accurate determination of the impact conditions. To accomplish this, the GTA was outfitted with an array of photogrammetry targets. The photogrammetry system utilizes images from two cameras with a specialized tracking software to determine time histories for the 3-D coordinates of each target. The impact conditions can then be determined from the target location data.

Vassilakos, Gregory J.↗

IMPACTing Medical System Design with a Risk Analysis Tool [“IMPACT” sur la Conception du Système Médical avec un Outil d'Analyse des Risques]

Background: Following the success of Artemis I, NASA is preparing for human extended duration missions. Ongoing efforts are focused on mitigating mission-related risks, including those affecting crew health and performance. Communication latency, logistics of resupply and time frame of medical evacuation are barriers to provision of healthcare for these missions, especially with respect to constraints in mass, volume, and crew training. An in-depth assessment of medical risks, capabilities and resources for a specific mission design is necessary to determine an optimal balance that maximizes likelihood of mission success. Overview: IMPACT (Informed Mission Planning via Analysis of Complex Tradespaces) is a dynamic tool designed to estimate medical risk and outcomes for a specific mission design. In its current iteration, a list of medical conditions selected based on likelihood of occurrence and/or consequence was linked to a set of clinical capabilities and resources necessary for diagnosis and management. A probabilistic risk analysis tool was then used to identify and estimate the likelihood and consequence of risks through the following outcome metrics: loss of crew life (inflight mortality due to medical conditions), need for medical evacuation (return to definitive care), and crew disability (task time affected based on how medical conditions influence the ability to perform specific exploration mission crew tasks). Finally, the model’s optimization algorithm provides recommendations for medical capabilities that maximize risk mitigation relative to mass and volume constraints. In the Spring of 2023, IMPACT was utilized to estimate outcome metrics for a design reference mission that would be representative of an extended duration Artemis mission. Notional data generated were then used to determine a recommended set of medical capabilities and resources relative to user-defined mass and volume constraints. A multidisciplinary team has also been updating IMPACT to strengthen the model’s fidelity. Figure 1 shows how updates to outcome metric inputs for the conditions resulted in different capability and resource allocation recommendations. Discussion: This presentation will discuss the IMPACT tool and share the latest data generated for a representative extended duration Artemis mission. Efforts to improve the fidelity of data generated by the model’s algorithm will also be discussed.

K A Shair↗

Health impact assessment in environmental impact assessment in China: Status, practice and problems

In China, the environmental impact assessment (EIA) system has gradually developed into an integrated evaluation system, owing to continuous improvement on institutional framework, system infrastructure, technical methods and professionals training, since EIA was first introduced in 1979. Though health impact assessment (HIA) is a part of the EIA system, the development of HIA is so slow as to remain at the early developing stage. This research aims to understand the extent and main issues concerning “health considerations” under the context of EIA, in China. Through case study on 42 environmental impact statements, the results demonstrate that HIA was not implemented in most of the cases, and health issues were not even mentioned in more than half of these cases. Where HIA was implemented, various problems were revealed through this study, including lacks of systematic approaching tools, insufficient supporting data on health effects, ineffective public participation, limited health considerations on biophysics, and so forth. Nevertheless, these problems can be attributed to lacks of legal supports, systematic evaluation methods, knowledge on evaluation technologies, and professional training institutions for HIA in China. In order to improve HIA methodologies, technologies, and management, to perfect HIA evaluation system, and to enhance public participation system within HIA, some recommendations from institutional, technical, administrative, and managerial aspects were then proposed in this study. - Highlights: •The status and deficiencies of HIA in EIA in China were identified and evaluated. •There were great industrial differences for the implementation of HIA in EIA. •Public participation was not well executed within HIA in EIA.

54 ENVIRONMENTAL SCIENCES↗

Impacts of feedstock properties on the process economics of fast-pyrolysis biorefineries

Feedstock properties are an important factor affecting process yields and economics of fast pyrolysis biorefineries. Here, this study develops a fast pyrolysis process model sensitive to feedstock properties based on the experimental results. 64 simulations are run to evaluate the impacts of carbon, ash and moisture content in biomass feedstocks on process yields and energy consumptions. An economic analysis is conducted for each run to quantify process economics under different feedstock properties. With biomass feedstocks of 48% carbon and 15% moisture, Minimum Fuel Selling Price (MFSP) increases from 0.97/L to 1.06/L when ash content increases from 1% to 7%, due to reduced hydrocarbon yields. With biomass feedstocks of 48% carbon and 3% ash content, MFSP increases from 1.03/L to 1.08/L when feedstock moisture increases from 15% to 45% as a consequence of increased energy demand for feedstock drying. Finally, the impact of feedstock ash content decreases gradually as ash content increases. Feedstock carbon content has less significant impacts on process economics in this study.

09 BIOMASS FUELS↗

Impact of numerics on the predictive capabilities of reacting flow LES

Combustors in modern aerospace propulsion systems are highly optimized devices and further enhancements to their performance will require advanced predictive modeling techniques. The LES approach has potential to be such a technique, but demonstration of its true predictive capability remains a challenge. In this paper, a methodical study is performed to assess the impact of numerical error on the predictive capabilities of LES and to distinguish it from error arising from physical modeling. Four codes are employed to simulate the bluff body stabilized flame experiment of Volvo Flygmotor AB. The physical models (governing equations and sub-grid models) are kept identical between the codes so that the physical modeling error is the same. For the same reason, computational grids are also kept identical since the sub-grid models are grid dependent. Results indicate that all codes produce a very similar solution for the non-reacting flow in terms of large scale unsteady vortex shedding behavior, mean profiles and second order turbulence statistics, on a suitably refined grid. This solution is also very close to the experimentally observed behavior of the flow. In contrast, for the reacting case, solutions from the various codes exhibit significant differences when analyzed under the same metrics and with similar or even finer grid resolution than that used for the non-reacting case. These differences are large enough to change the macroscopic behavior of the flow, e.g. some codes predict symmetric vortex shedding while others predict asymmetric shedding and some codes show strong recirculation zones while others show stagnant regions behind the bluff body. It is also shown that none of the solutions truly predicts the experimentally observed flow. Given that the physical sub-grid models and computational grids are the same in all the simulations, the inconsistency between results points to a significant impact of numerical methods and, hence, numerical error. The need for mitigation of this impact is highlighted, along with the need for metrics detailing how LES should be applied to reacting flows. It is suggested that both of these issues should be the focus of future work.

Energy & Fuels↗

Review of the impacts of leaking CO 2 gas and brine on groundwater quality

This review paper provides a synthetic view of the existing knowledge and summarizes data and findings of the recent literature on the subject of the potential leaking of CO2 from the deep subsurface storage reservoirs and the effects on aquifer quality. New ideas and concepts are developed and insights are also provided. The objectives of this paper are to: 1) present and discuss potential risks for groundwater degradation due to CO2 gas and brine exposure; 2) identify the set of geochemical data required to assess and predict aquifer responses to CO2 and brine leakage. Specifically, this paper will discuss the following issues: 1) Aquifer responses (such as changes in aqueous phase/groundwater chemical composition; changes in solid phase chemistry and mineralogy; changes in the extent and rate of reactions and processes and possible establishment of a new network of reactions and processes affecting or controlling overall mobility of major, minor, and trace elements; development of conceptual and reduced order models (ROMs) to describe and predict aquifer responses); 2) The degree of impact such as significant or insignificant changes in pH and major, minor, and trace element release that depend on the following controlling variables; the effect of leaking plume characteristics (gas composition, pure CO2 and/or CO2 -CH4 -H2S mixtures and brine concentration and composition (trace metals); aquifer properties [such as initial aqueous phase conditions and mineralogy: minerals controlling sediments’ response (e.g., calcite, Si bearing minerals, etc.)]; overview of relevant hydrogeological and geochemical processes related to the impact of CO2 gas and brine on groundwater quality; the fate of the elements released from sediments or transported with brine (such as precipitation/incorporation into minerals (calcite and other minerals), adsorption, electron transfer reactions, the role of natural attenuation; whether or not the release of metals following exposure to CO2 harmful (risk assessment).

Qafoku, Nikolla P.↗

Ni/Li Disordering in Layered Transition Metal Oxide: Electrochemical Impact, Origin, and Control

Lithium-ion batteries (LIBs) not only power most of today’s hybrid electric vehicles (HEV) and electric vehicles (EV) but also are considered as a very promising system for grid-level storage. Large-scale applications for LIBs require substantial improvement in energy density, cost, and lifetime. Layered Li(NixMnyCoz)O2 (NMC, x+y+z=1) materials from solid-solution approaches to LiMO2 (M = Ni, Mn, Co, etc) are the most promising candidates for their high reversible capacity, better environmental compatibility, and lower cost compared with the traditional LiCoO2. In order to further boost Li storage capacity, a great deal of attention has been directed toward developing Ni-rich NMCs. However, structural disorder as a result of Ni/Li exchange in octahedral sites becomes a critical issue when Ni content increases to high values, as it leads to a detrimental effect on Li diffusivity, cycling stability, first-cycle efficiency, and overall electrode performance. Increasing efforts have been dedicated to improving the electrochemical performance of NMC materials via reduction of cationic mixing. Therefore, it is important to summarize this research field and provide in-depth insight into impact of Ni/Li disorder on electrochemical characteristics in layered NMC materials and its origin to accelerate the future development of NMC materials with high performance. In this Account, we start by analyzing the impact of Ni/Li disorder on electrochemical characteristics in layered NMC materials. The antisite Ni in the Li layer can limit the rate performance by impeding the Li-ion transport. It will also degrade the cycling stability by inducing the anisotropic stress in the bulk structure. Nevertheless, the antisite Ni-ions don’t always bring drawbacks to the electrochemical performance, some studies including our works found that it can improve the thermal stability and the cycling structure stability of Ni-rich NMC materials. We next discussed the driving forces and the kinetic advantages accounting for the Ni/Li exchange and summarized that the steric effect of cation size and the magnetic interactions between TM cations are the two main driving forces to promote the Ni/Li exchange during synthesis procedure and the electrochemical cycling, and the low energy barrier of Ni2+ migration from the 3a site in TM layer to 3b site in Li layer further provides the kinetic advantage. Based on above understandings, we reviewed the progress made to control the Ni/Li disorder and summarized three main ways: (i) suppressing the driving force from the steric effect by ion exchange; (ii) tuning the magnetic interaction by cationic substitution; (iii) kinetic controlling of Ni migration. Finally, our brief outlooks on the future development of controlling the Ni/Li disorder in NMC materials are provided. It is believed that this Account will provide significant understanding and inspirations toward developing high-performance NMC materials with controlled Ni/Li disorder.

Zheng, Jiaxin↗