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At least 163 records · Page 9

Collisional pumping of water masers by species of particles at different temperatures

It has been reported that the extreme power of astrophysical water masers can be obtained from purely collisional pumping in environments with two kinetic temepratures. It is found that this pumping vanishes when the latest rates are utilized for the collisional excitation of H2O molecules by neutrals. Energetic ions must also be present under the conditions that have been proposed for such 'two-temperature' pumping, but they have been ignored in the past due to lack of information about the relevant cross sections. Quantal, multichannel calculations in the impact parameter approximation are performed to provide a basis for estimating these rates for the collisional excitation of H2O molecules by ions. Including the effects of these ions does not restore the inversion, but rather reduces the pumping for H2O masers in the proposed 'two-temperature' environments.

Anderson, Nels↗

Electric propulsion system technology

The work performed in fiscal year (FY) 1991 under the Propulsion Technology Program RTOP (Research and Technology Objectives and Plans) No. (55) 506-42-31 for Low-Thrust Primary and Auxiliary Propulsion technology development is described. The objectives of this work fall under two broad categories. The first of these deals with the development of ion engines for primary propulsion in support of solar system exploration. The second with the advancement of steady-state magnetoplasmadynamic (MPD) thruster technology at 100 kW to multimegawatt input power levels. The major technology issues for ion propulsion are demonstration of adequate engine life at the 5 to 10 kW power level and scaling ion engines to power levels of tens to hundreds of kilowatts. Tests of a new technique in which the decelerator grid of a three-grid ion accelerator system is biased negative of neutralizer common potential in order to collect facility induced charge-exchange ions are described. These tests indicate that this SAND (Screen, Accelerator, Negative Decelerator) configuration may enable long duration ion engine endurance tests to be performed at vacuum chamber pressures an order of magnitude higher than previously possible. The corresponding reduction in pumping speed requirements enables endurance tests of 10 kW class ion engines to be performed within the resources of existing technology programs. The results of a successful 5,000-hr endurance of a xenon hollow cathode operating at an emission current of 25 A are described, as well as the initial tests of hollow cathodes operating on a mixture of argon and 3 percent nitrogen. Work performed on the development of carbon/carbon grids, a multi-orifice hollow cathode, and discharge chamber erosion reduction through the addition of nitrogen are also described. Critical applied-field MPD thruster technical issues remain to be resolved, including demonstration of reliable steady-state operation at input powers of hundreds to thousands of kilowatts, achievement of thruster efficiency and specific impulse levels required for missions of interest, and demonstration of adequate engine life at these input power, efficiency, and specific impulse levels. To address these issues we have designed, built, and tested a 100 kW class, radiation-cooled applied-field MPD thruster and a unique dual-beam thrust stand that enables separate measurements of the applied- and self-field thrust components. We have also initiated the development of cathode thermal and plasma sheath models that will eventually be used to guide the experimental program. In conjunction with the cathode modeling, a new cathode test facility is being constructed. This facility will support the study of cathode thermal behavior and erosion mechanisms, the diagnosis of the near-cathode plasma and the development and endurance testing of new, high-current cathode designs. To facilitate understanding of electrode surface phenomenon, we have implemented a telephoto technique to obtain photographs of the electrodes during engine operation. In order to reduce the background vacuum tank pressure during steady-state engine operation in order to obtain high fidelity anode thermal data, we have developed and are evaluating a gas-dynamic diffuser. A review of experience with alkali metal propellants for MPD thrusters led to the conclusion that alkali metals, particularly lithium, offer the potential for significant engine performance and lifetime improvements. These propellants are also condensible at room temperature, substantially reducing test facility pumping requirements. The most significant systems-level issue is the potential for spacecraft contamination. Subsequent experimental and theoretical efforts should be directed toward verifying the performance and lifetime gains and characterizing the thruster flow field to assess its impact on spacecraft surfaces. Consequently, we have begun the design and development of a new facility to study engine operation with alkali metal propellants.

Brophy, John R.↗

Time and frequency technology at NIST

The state of development of advanced timing systems at NIST is described. The work on cesium and rubidium frequency standards, stored-ion frequency standards, diode lasers used to pump such standards, time transfer, and methods for characterizing clocks, oscillators, and time distribution systems is presented. The emphasis is on NIST-developed technology rather than the general state of the art in this field.

Sullivan, D. B.↗

Industrial ion source technology

Plasma probe surveys were conducted in a 30-cm source to verify that the uniformity in the ion beam is the result of a corresponding uniformity in the discharge-chamber plasma. A 15 cm permanent magnet multipole ion source was designed, fabricated, and demonstrated. Procedures were investigated for texturing a variety of seed and surface materials for controlling secondary electron emission, increasing electron absorption of light, and improved attachment of biological tissue for medical implants using argon and tetrafluoromethane as the working gases. The cross section for argon-argon elastic collisions in the ion-beam energy range was calculated from interaction potentials and permits calculation of beam interaction effects that can determine system pumping requirements. The data also indicate that different optimizations of ion-beam machines will be advantageous for long and short runs, with 1 mA-hr/cm being the rough dividing line for run length. The capacity to simultaneously optimize components in an ion-beam machine for a single application, a capacity that is not evident in competitive approaches such as diode sputtering is emphasized.

Kaufman, H. R.↗

Excitation of parametric instabilities by radio waves in the ionosphere.

The excitation of parametric instabilities by radio waves in a magnetoplasma is discussed. A uniform medium is assumed and linear approximations are used. Excitation by a pump wave of ordinary polarization is hardly affected by the magnetic field. Low or zero frequency ion waves and high frequency Langmuir waves are excited simultaneously. For an extraordinary pump wave, the excited high frequency electrostatic waves are in the Bernstein mode. The threshold is slightly higher and excitation can occur only within certain 'allowed' frequency bands. A new type of parametric instability in which the excited waves are electromagnetic in nature and which is more strongly affected by the inhomogeneous nature of the medium is discussed qualitatively.

Fejer, J. A.↗

The location of the Ca II ions in the beta Pictoris disk

Echelle spectra of beta Pictoris have been obtained in the region of the Ca II 8542A line which arises from the metastable 3d 2D5/2 level. A narrow, weak, circumstellar absorption line is seen at the stellar radial velocity. A simple theory is developed of the radiative pumping of the metastable levels of the Ca II ions by the radiation from the star at the H and K lines. The relatively large fractional population, N3(Ca II)/N1(Ca II) of roughly 0.05, observed for the metastable level then requires that the calcium absorbers be largely concentrated within about 1 AU of the star. This result confirms two previous, independent estimates of the location of this gas. A time-variable circumstellar component of the 8542A line also is found at an infall velocity of about 15 km/s.

Hobbs, L. M.↗

Development of mid-infrared solid state lasers for spaceborne lidar

The laser performance of a Ho(3+):Tm(3+):Cr(3+):YAG crystal was measured under flashlamp pumping at various operating temperatures. The normal mode laser thresholds of a Ho(3+)(0.45 at. percent):Tm(3+)(2.5 at. percent):Cr(3+)(1.5 at. percent ):YAG crystal were found to range from 26 to 50 J between 120 and 200 K with slope efficiencies up to 0.36 percent with a 60 percent reflective output mirror. From the Q-switched operations a slope efficiency corresponding to 90 percent of the normal mode operation was observed. Laser wavelengths were measured for various operating conditions and fluorescence spectra were obtained at various temperatures in order to help understand the dynamic energy processes among the Ho(3+), Tm(3+), and Cr(3+) ions. A pulse forming network for a flashlamp pumped Cr:GSAG laser, which is to be used as a high power laser diode simulator in rare earth laser pumping, was completed and tested. The network provided critically damped, 1 ms FWHM, square pulses with a rise time of about 160 micrometers at an input electrical energy of 300 J.

Whitney, Donald A.↗

Ion engine endurance testing at high background pressures

Ion engine endurance testing at vacuum chamber pressures in the low 10 exp -3 Pa range is enabled through the use of a three-grid accelerator system with the decelerator grid biased 50 to 100 volts negative of neutralizer cathode potential. The negative decelerator grid serves to collect the facility induced charge exchange ion current which normally results in rapid erosion of the accelerator grid during testing at elevated vacuum chamber pressures. This screen, accelerator, negative decelerator (SAND) grid configuration enables an order of magnitude reduction in vacuum chamber pumping speeds relative to that required for endurance testing of ion engines with conventional two-grid accelerator systems. A 900-hr test of a 30-cm diameter engine at 6.5 kW and a tank pressure of 3.7 x 10 exp -3 Pa was performed to test the feasibility of the three-grid SAND accelerator system technology. Grid erosion rates from this test are compared to those from a 200-hr test performed with the same discharge chamber, in the same test facility, and at the same background pressure with a conventional two grid accelerator system. The SAND optics resulted in greater than a factor of 100 reduction in accelerator grid erosion rate relative to the two-grid system.

Brophy, John R.↗

Ionization by XFEL radiation produces distinct structure in liquid water

In the warm dense matter (WDM) regime, where condensed, gas, and plasma phases coexist, matter frequently exhibits unusual properties that cannot be described by contemporary theory. Experiments reporting phenomena in WDM are therefore of interest to advance our physical understanding of this regime, which is found in dwarf stars, giant planets, and fusion ignition experiments. Using 7.1 keV X-ray free electron laser radiation (nominally 5×10 5 J/cm 2 ), we produced and probed transient WDM in liquid water. Wide-angle X-ray scattering (WAXS) from the probe reveals a new ~9 Å structure that forms within 75 fs. By 100 fs, the WAXS peak corresponding to this new structure is of comparable magnitude to the ambient water peak, which is attenuated. Simulations suggest that the experiment probes a superposition of two regimes. In the first, fluences expected at the focus severely ionize the water, which becomes effectively transparent to the probe. In the second, out-of-focus pump radiation produces O 1+ and O 2+ ions, which rearrange due to Coulombic repulsion over 10 s of fs. Our simulations account for a decrease in ambient water signal and an increase in low-angle X-ray scattering but not the experimentally observed 9 Å feature, presenting a new challenge for theory.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Is Ba 3 In 2 O 6 a high- T c superconductor?

It has been suggested that Ba 3 In 2 O 6 might be a high-Tc superconductor. Experimental investigation of the properties of Ba 3 In 2 O 6 was long inhibited by its instability in air. Recently epitaxial Ba 3 In 2 O 6 with a protective capping layer was demonstrated, which finally allows its electronic characterization. The optical bandgap of Ba3In2O6 is determined to be 2.99 eV in-the (001) plane and 2.83 eV along the c-axis direction by spectroscopic ellipsometry. First-principles calculations were carried out, yielding a result in good agreement with the experimental value. Various dopants were explored to induce (super-)conductivity in this otherwise insulating material. Neither A- nor B-site doping proved successful. The underlying reason is predominately the formation of oxygen interstitials as revealed by scanning transmission electron microscopy and first-principles calculations. Additional efforts to induce superconductivity were investigated, including surface alkali doping, optical pumping, and hydrogen reduction. To probe liquid-ion gating, Ba 3 In 2 O 6 was successfully grown epitaxially on an epitaxial SrRuO 3 bottom electrode. So far none of these efforts induced superconductivity in Ba 3 In 2 O 6 , leaving the answer to the initial question of whether Ba 3 In 2 O 6 is a high-T c superconductor to be 'no' thus far.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The Addition of EI/CI Capability to the Mattauch-herzog Spectrograph with EOID

A modification was made to the Mattauch-Herzog Spectrograph with an electro-optical ion detector (EOID) previously designed and constructed, so that it would be capable of operating not only in the electron-impact (EI) mode of ionization, but also in the chemical ionization (CI) mode. This modification necessitated an effort in three specific design areas: (1) sample inlet; (2) ion source and analyzer regions; and (3) the pumping system. In addition, an appropriate electronics package had to be designed to control and operate the combined EI/CI source.

Fergusson, G. J.↗

MMS Observatory Thermal Vacuum Results Contamination Summary

The MMS mission is a constellation of 4 observatories designed to investigate the fundamental plasma physics of reconnection in the Earths magnetosphere. Each spacecraft has undergone extensive environmental testing to prepare it for its minimum 2 year mission. The various instrument suites measure electric and magnetic fields, energetic particles, and plasma composition. Thermal vacuum testing was conducted at the Naval Research Laboratory (NRL) in their Big Blue vacuum chamber. The individual spacecraft were tested and enclosed in a cryopanel enclosure called a Hamster cage. Specific contamination control validations were actively monitored by several QCMs, a facility RGA, and at times, with 16 Ion Gauges. Each spacecraft underwent a bakeout phase, followed by 4 thermal cycles. Unique aspects of the TV environment included slow pump downs with represses, thruster firings, Helium identification, and monitoring pressure spikes with Ion gauges. Various data from these TV tests will be shown along with lessons learned.

TV↗

Curious cross-field transport effects in multi-ion, magnetized plasma

In contrast to single-ion plasma, multiple-ion-species plasma exhibits new, curious, and large transport effects. On short timescales, where ions exchange momentum, magnetized multi-ion plasma behaves as a most unusual substance, compressible across field lines in number density but incompressible in charge density. It takes 40 times longer for electrons to participate. In this ion–ion cross-field transport regime, we identified the charge-incompressibility heat pump effect, transferring heat both spatially and between species. Curiously, the direction of impurity transport strongly depends on plasma magnetization, characterized by the ratio of light ion gyrofrequency to the collision frequency between light and heavy ion species. The expulsion of heavy ion impurities from a hotspot occurs sufficiently quickly to be observable on MagLIF, so long as plasma becomes sufficiently collisionally magnetized under implosion. Even more curious, multi-ion transport changes its nature in partially ionized plasma, where ions occupy different charge states. In this regime, we identify a partial-ionization deconfinement effect. The combination of cross-field transport, ionization, and recombination leads to a net ion charge moving across magnetic field lines on the ion–ion transport timescale as opposed to the electron–ion transport timescale. Cross-field transport effects in multi-ion plasma are important in a number of applications, including nuclear fusion and plasma mass filters.

Mlodik, M. E. (ORCID:0000000343003941)↗

Development of a quadrupole-based Secondary-Ion Mass Spectrometry (SIMS) system at Lewis Research Center

The design, construction, and initial use of an ion microprobe to carry out secondary ion mass spectrometry (SIMS) of solid samples is reported. The system is composed of a differentially pumped custom-made UHV (Ultra High Vacuum) chamber, a quadrupole mass spectrometer and a telefocus A-DIDA ion gun with the capability of producing beams of Cesium, as well as inert and reactive gases. The computer control and acquisition of the data were designed and implemented using a personal computer with plug-in boards, and external circuitry built as required to suit the system needs. The software is being developed by using a FORTH-like language. Initial tests aimed at characterizing the system, as well as preliminary surface and depth-profiling studies are presently underway.

Vargas-Aburto, Carlos↗

Ion-molecule processes in lasers

Three classes of molecular electronic transition lasers produced by hybrid pumping of high pressure rate gas mixtures are discussed. These are (1) rare gas dimer lasers (such as excited Ar2, Kr2, and Xe2) lasing in the VUV, (2) rare gas halide lasers or excimer lasers (such as KrF, ArF, and XeCl excimers) lasing in the UV, and (3) the charge transfer molecular ion laser (such as N2/+/) lasing in the visible range. Laser excitation methods and kinetic sequences are examined for these lasers.

Laudenslager, J. B.↗

X-Ray Photoelectron Spectroscopy

The interaction of photon and the electron goes back to the early part of 19th century emanating from the photo-electric effect depicted by none other than Albert Einstein (Ref 1) described in 1905, and the redistribution of kinetic energy resulting from the interaction of x-ray and solids reported during early part of the century (Ref.2). The spectrum resolutions obtained at that time was not sufficient to observe distinct peaks in spectra for materials. Thus, these phenomena hardly attracted any attention for many years following these discoveries. The modern X-ray Photoelectron Spectroscopy (XPS) has been possible by the extensive and significant contribution from Kai Siegbahn and others (Ref.3, 4) of Uppsala University. Siegbahn developed and employed a high-resolution electron spectrometer that revealed electron peaks in a spectrum emerging from the interaction of x-rays and solids. Eventually, Kai Siegbahn received Nobel Prize in 1981 for his contributions to XPS. Around 1958, shifts in elemental peaks were realized in compounds when the same elements are bound to other but different elements. This discovery resulted in the chemical state identification in various chemicals as well as the oxidation states of atoms in compounds. Because of these useful physical effects, the Uppsala group named XPS with a synonymous name of ESCA (Electron Spectroscopy for Chemical Analysis) used widely today and will be used here alternatively. Therefore, XPS or ESCA not only identifies the element, but also the compound these elements form, from their chemical shifts. Compared to other micro-analytical techniques such as Energy Dispersive (EDS) or Wavelength Dispersive (WDS) techniques, XPS analyzes only few atomic layers present on the surface. This was discovered early in 1966 (Ref. 5). While this has awarded a merit to the analytical technique to analyze very thin layers such as films and coatings, it often analyzes the adsorbed superficial gases and contaminations on a sample introduced to its analytical chamber. This necessitates the surface is cleaned and the underlying material, material of interest, is exposed in a clean environment such that the material of interest is analyzed. The cleaning is accomplished by a scanning ion gun within the analytical chamber of the instrument. Ion gun uses an argon gas and is commonly attached in most modern machines. Reliable and efficient vacuum systems employed in modern machines does not allow adsorbed layers to rebuild after the surface is cleaned. Development of efficient and reliable vacuum pumps over these developmental years is yet another important step in the commercialization of XPS machines. Vacuum levels of better than 10-7 torr are essential to increase the mean free path of electrons released from the sample surface. Thus, modern machines are equipped with high capacity ion, turbo or cryogenic pumps in their analytical chambers. Today, XPS has advanced from an applied physics laboratory to industry for use in quality control as well as analysis of contaminants and has taken a dominant role in microanalysis. Its uniqueness arises from the fact that it is considered non-destructive compared to other common micro-analytical techniques using the electron and ion excitation sources. Polymers and plastics could be analyzed since the binding energies of saturated and unsaturated bonds in atoms could be separated. Extremely thin layers could be analyzed including materials with layered structures. The technique, though did not advance for many years, has now opened a new window for research as well as applications in industry due to its ability to separate and measure the chemical shifts in bound elements. Principles

Panda, Binayak↗