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NASA NTRSDate not supplied

Characterization of Fluorescence Signals in Synthetic Anorthite

In-situ resource utilization (ISRU) is a key capability to enable a long term presence on the Moon and other planetary bodies. For example, efforts have been underway to develop processes to utilize the lunar regolith to produce building materials and extract useful resources. In processes that utilize the regolith directly to produce construction materials, such as in various sintering methods, characterizing the composition of the regolith is important as the composition can affect the optimal process parame-ters. In processes that involve extracting resources such as iron, oxygen, hydrogen, etc., identifying areas with higher abundance of a particular resource will be critical since different regions of the Moon exhibit differing regolith composition. To this end, Ra-man is one technique that can rapidly characterize the mineralogy of rock samples. This technique has al-ready been deployed on Mars to detect various miner-als including olivine, carbonates, phosphates, etc. Besides characterizing the mineralogy, Raman spectra often contain unwanted fluorescence signals that can mask Raman peaks. In some cases, the fluorescence signals are narrow enough to aid in the identification of specific elements in soils. In this work, we explore fluorescence peaks in a synthetic anorthite sample, which are at the same position as Ruby fluorescence peaks attributed to chromium. These fluorescence peaks, as well as similar fluorescence peaks attributed to other elements, could have important implications for ISRU and the mining of critical resources as has been previously described.

Raman Spectroscopy↗

NASA NTRS1999

Deformation Behaviors of HIPped Foil Compared with Those of Sheet Titanium Alloys

Micromechanics-based modeling of composite material behaviors requires an accurate assessment of the constituent properties and behaviors. For the specific case of continuous-fiber-reinforced metal matrix composites (MMC's) manufactured from a foil/fiber/foil process, much emphasis has been placed on characterizing foil-based matrix materials that have been fabricated in the same way as the composite. Such materials are believed to yield mechanical properties and behaviors that are representative of the matrix constituent within the composite (in situ matrix). Therefore, these materials are desired for micromechanics modeling input. Unfortunately, such foils are extremely expensive to fabricate and procure because of the labor-intensive rolling process needed to produce them. As a potential solution to this problem that would maintain appropriately representative in situ properties, the matrix constituent could be characterized with sheet-based materials, which are considerably less expensive to manufacture than foils, are more readily procured, and result in fewer plies to obtain a desired panel thickness. The critical question is, however, does the consolidated sheet material exhibit the same properties and behaviors as do the consolidated foils? Researchers at NASA Lewis Research Center's Life Prediction Branch completed a detailed experimental investigation to answer this question for three titanium alloys commonly used in metal matrix composite form.

Castelli, Michael G.↗

NASA NTRS1973

Experimental and theoretical investigation of HT-S/PMR-PI composites for application to advanced aircraft engines

Investigations were performed in order to: (1) demonstrate that high quality angleplied laminates can be made from HT-S/PMR-PI (PMR in situ polymerization of monomeric reactants), (2) characterize the PMR-PI material and to determine the HT-S unidirectional composite properties required for composite micro and macromechanics and laminate analyses, and (3) select HT-S/PMR laminate configurations to meet the general design requirements for high-tip-speed compressor blades. The results of the investigation show that HT-S/PMR laminate configurations can be fabricated which satisfy the high-tip-speed compressor blade design requirements when operating within the temperature capability of the polyimide matrix.

Hanson, M. P.↗

NASA NTRS1974

Graphite-polyimide composite for application to aircraft engines

A combined experimental and theoretical investigation was performed in order to (1) demonstrate that high quality angleplied laminates can be made from HT-S/PMR-RI (PMR in situ polymerization of monomeric reactants), (2) characterize the PMR-PI material and to determine the HT-S unidirectional composite properties required for composite micro and macromechanics and laminate analyses, and (3) select HT-S/PMR-PI laminate configurations to meet the general design requirements for high-tip-speed compressor blades. The results of the investigation showed that HT-S/PMR laminate configurations can be fabricated which satisfy the high-tip-speed compressor blade design requirements when operating within the temperature capability of the polymide matrix.

Hanson, M. P.↗

NASA NTRS1974

Experimental and theoretical investigation of HT-S/PMR-PI composites for application to advanced aircraft engines

A combined experimental and theoretical investigation was performed in order to: (1) demonstrate that high quality angleplied laminates can be made from HT-S/PMR-PI (PMR in situ polymerization of monomeric reactants), (2) characterize the PMR-PI material and to determine the HT-S unidirectional composite properties required for composite micro and macromechanics and laminate analyses, (3) select HT-S/PMR laminate configurations to meet the general design requirements for high-tip-speed compressor blades. The results of the investigation showed that: HT-S/PMR laminate configurations can be fabricated which satisfy the high-tip-speed compressor blade design requirements when operating within the temperature capability of the polymide matrix.

Hanson, M. P.↗

NASA NTRS1984

Characteristics of solar and heliospheric ion populations observed near earth

The composition and spectra of ions in solar-energetic-particle and energetic-storm-particle events, of diffuse ions upstream of the earth bow shock, and of ions in deep-geomagnetic-tail plasmoids are characterized in a summary of in situ observations. Data are presented in graphs and tables, and remarkable similarities are noted in the distribution functions of the heliospheric ion populations. The solar wind, acting through acceleration mechanisms associated with shocks and turbulence, is identified as the major plasma source of suprathermal and energetic particles.

Gloeckler, G.↗

NASA NTRS1993

The red edge in arid region vegetation: 340-1060 nm spectra

The remote sensing study of vegetated regions of the world has typically been focused on the use of broad-band vegetation indices such as NDVI. Various modifications of these indices have been developed in attempts to minimize the effect of soil background, e.g., SAVI, or to reduce the effect of the atmosphere, e.g., ARVI. Most of these indices depend on the so-called 'red edge,' the sharp transition between the strong absorption of chlorophyll pigment in visible wavelengths and the strong scattering in the near-infrared from the cellular structure of leaves. These broadband indices tend to become highly inaccurate as the green canopy cover becomes sparse. The advent of high spectral resolution remote sensing instrument such as the Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) has allowed the detection of narrow spectral features in vegetation and there are reports of detection of the red edge even for pixels with very low levels of green vegetation cover by Vane et al. and Elvidge et al., and to characterize algal biomass in coastal areas. Spectral mixing approaches similar to those of Smith et al. can be extended into the high spectral resolution domain allowing for the analysis of more endmembers, and potentially, discrimination between material with narrow spectral differences. Vegetation in arid regions tends to be sparse, often with small leaves such as the creosote bush. Many types of arid region vegetation spend much of the year with their leaves in a senescent state, i.e., yellow, with lowered chlorophyll pigmentation. The sparseness of the leaves of many arid region plants has the dual effect of lowering the green leaf area which can be observed and of allowing more of the sub-shrub soil to be visible which further complicates the spectrum of a region covered with arid region vegetation. Elvidge examined the spectral characteristics of dry plant materials showing significant differences in the region of the red edge and the diagnostic ligno-cellulose absorptions at 2090 nm and 2300 nm. Ray et al. detected absorption at 2100 nm in AVIRIS spectra of an abandoned field known to be covered by a great deal of dead plant litter. In order to better study arid region vegetation remote sensing data, it is necessary to better characterize the reflectance spectra of in situ, living, arid region plants.

Ray, Terrill W.↗

NASA NTRS2003

Evolutionary Origin of Body Axis Segmentation in Annelids and Arthropods

During the period of this report, we have made a number of important discoveries. To date this work has led to 4 peer-reviewed publications in primary research journals plus 1 minireview and 1 chapter in the proceedings of a meeting. Publications resulting from this grant support are enumerated at the end of the report. Two additional, on-going studies also described. 1. Using laser cell ablation, we have obtained evidence that an annelid - the leech Helobdella robusta - patterns the anteroposterior (AP) polarity of its nascent segment primordia independent of cell interactions oriented along the AP axis. 2. We cloned a Helobdella homologue (hro-hh) of the Drosophila segment polarity gene hedgehog, and used in situ hybridization and northern blots to characterize its expression in the embryo. 3. We have used laser cell ablations to examine the possible role of cell interactions during the developmental patterning of the 4 rostralmost "head" segments of the leech Helobdella robusta.

Shankland, S. Martin↗

NASA NTRS2008

Improving Coastal Ocean Color Validation Capabilities through Application of Inherent Optical Properties (IOPs)

Understanding how the different components of seawater alter the path of incident sunlight through scattering and absorption is essential to using remotely sensed ocean color observations effectively. This is particularly apropos in coastal waters where the different optically significant components (phytoplankton, detrital material, inorganic minerals, etc.) vary widely in concentration, often independently from one another. Inherent Optical Properties (IOPs) form the link between these biogeochemical constituents and the Apparent Optical Properties (AOPs). understanding this interrelationship is at the heart of successfully carrying out inversions of satellite-measured radiance to biogeochemical properties. While sufficient covariation of seawater constituents in case I waters typically allows empirical algorithms connecting AOPs and biogeochemical parameters to behave well, these empirical algorithms normally do not hold for case I1 regimes (Carder et al. 2003). Validation in the context of ocean color remote sensing refers to in-situ measurements used to verify or characterize algorithm products or any assumption used as input to an algorithm. In this project, validation capabilities are considered those measurement capabilities, techniques, methods, models, etc. that allow effective validation. Enhancing current validation capabilities by incorporating state-of-the-art IOP measurements and optical models is the purpose of this work. Involved in this pursuit is improving core IOP measurement capabilities (spectral, angular, spatio-temporal resolutions), improving our understanding of the behavior of analytical AOP-IOP approximations in complex coastal waters, and improving the spatial and temporal resolution of biogeochemical data for validation by applying biogeochemical-IOP inversion models so that these parameters can be computed from real-time IOP sensors with high sampling rates. Research cruises supported by this project provides for collection and processing of seawater samples for biogeochemical (pigments, DOC and POC) and optical (CDOM and POM absorption coefficients) analyses to enhance our understanding of the linkages between in-water optical measurements (IOPs and AOPs) and biogeochemical constituents and to provide a more comprehensive suite of validation products.

Mannino, Antonio↗

NASA NTRS2007

Broadband Achromatic Telecentric Lens

A new type of lens design features broadband achromatic performance as well as telecentricity, using a minimum number of spherical elements. With appropriate modifications, the lens design form can be tailored to cover the range of response of the focal-plane array, from Si (400-1,000 nm) to InGaAs (400-1,700 or 2,100 nm) or InSb/HgCdTe reaching to 2,500 nm. For reference, lenses typically are achromatized over the visible wavelength range of 480-650 nm. In remote sensing applications, there is a need for broadband achromatic telescopes, normally satisfied with mirror-based systems. However, mirror systems are not always feasible due to size or geometry restrictions. They also require expensive aspheric surfaces. Non-obscured mirror systems can be difficult to align and have a limited (essentially one-dimensional) field of view. Centrally obscured types have a two-dimensional but very limited field in addition to the obscuration. Telecentricity is a highly desirable property for matching typical spectrometer types, as well as for reducing the variation of the angle of incidence and cross-talk on the detector for simple camera types. This rotationally symmetric telescope with no obscuration and using spherical surfaces and selected glass types fills a need in the range of short focal lengths. It can be used as a compact front unit for a matched spectrometer, as an ultra-broadband camera objective lens, or as the optics of an integrated camera/spectrometer in which the wavelength information is obtained by the use of strip or linear variable filters on the focal plane array. This kind of camera and spectrometer system can find applications in remote sensing, as well as in-situ applications for geological mapping and characterization of minerals, ecological studies, and target detection and identification through spectral signatures. Commercially, the lens can be used in quality-control applications via spectral analysis. The lens design is based on the rear landscape lens with the aperture stop in front of all elements. This allows sufficient room for telecentricity in addition to making the stop easily accessible. The crucial design features are the use of a doublet with an ultra-low dispersion glass (fluorite or S-FPL53), and the use of a strong negative element, which enables flat field and telecentricity in conjunction with the last (field lens) element. The field lens also can be designed to be in contact with the array, a feature that is desirable in some applications. The lens has a 20deg field of view, for a 50-mm focal length, and is corrected over the range of wavelengths of 450-2,300 nm. Transverse color, which is the most pernicious aberration for spectroscopic work, is controlled at the level of 1 m or below at 0.7 m field and 5 m at full field. The maximum chief ray angle is less than 1.7 , providing good telecentricity. An additional feature of this lens is that it is made exclusively with glasses that provide good transmission up to 2,300 nm and even some transmission to 2,500 nm; thus, the lens can be used in applications that cover the entire solar-reflected spectrum. Alternative realizations are possible that provide enhanced resolution and even less transverse color over a narrower wavelength range.

Mouroulis, Pantazis↗

NASA NTRS2019

GOES-16 ABI Solar Reflective Channel Validation for Earth Science Application

This paper presents the validation results of GOES-16 Satellite's Advanced Baseline Imager (ABI) obtained from a reflectance-based field campaign undertaken at the Salar de Uyuni in Bolivia in June 2017. In situ ground measurements are used to characterize the surface reflectance and the atmosphere in order to constrain the radiative transfer code and predict at-sensor reflectance (also referred to as top-of-atmosphere (TOA) reflectance) to compare with concurrent GOES-16 ABI measurements. The five-day field campaign provided repeated TOA reflectance estimates, allowing assessment not only of the calibration accuracy of the ABI reflective channels 1, 2, 3, 5 and 6, but also of its stability over the duration of the campaign. The results show that the accuracy of the ABI reflective channels calibration is within specification for channels 1, 3, 5, and 6 - average biases within 2%; for channel 2 the bias is 5%. The estimated uncertainty on the derived biases is 2–2.4%. Some calibration stability issues were present in the ABI calibration at the time of the campaign: (i) a jump on the order of 2% in channels 1 and 6, coincident with an ABI solar calibration event, reflects an instability of the ABI gains in these channels, and (ii) short-term variability in channels 1 and 2 is due to striping (ABI detector-todetector calibration differences). Continued validation and subsequent reprocessing of ABI reflectance imagery would allow Earth scientists to fully benefit from the high spatial and spectral fidelity of the GOES-16 ABI diurnal measurements at the continental scale.

Joel McCorkel↗

NASA NTRS2020

Source and Propagation of a Streamer Blowout Coronal Mass Ejection Observed by the Parker Solar Probe

In the ﬁrst orbit of the Parker Solar Probe (PSP), in situ thermal plasma and magnetic ﬁeld measurements were collected as close as 35RSun from the Sun, an environment that had not been previously explored. During the ﬁrst orbit of PSP, the spacecraft ﬂew through a streamer blowout coronal mass ejection (SBO-CME) on 2018 November 11 at 23:50 UT as it exited the science encounter. The SBO-CME on November 11 was directed away from the Earth and was not visible by L1 or Earth-based telescopes due to this geometric conﬁguration. However, PSP and the STEREO-A spacecraft were able to make observations of this slow (v ≈ 380 kms−1) SBO-CME. Using the PSP data, STEREO-A images, and Wang–Sheeley–Arge model, the source region of the CME is found to be a helmet streamer formed between the northern polar coronal hole and a mid-latitude coronal hole. Using the YGUAZU-A model, the propagation of the CME is traced from the source at the Sun to PSP. This model predicts the travel time of the ﬂux rope to the PSP spacecraft as 30 hr, which is within 0.33 hr of the actual measured arrival time. The in situ Solar Wind Electrons Alphas and Protons data were examined to determine that no shock was associated with this SBO-CME. Modeling of the SBO-CME shows that no shock was present at PSP; however, at other positions along the SBO-CME front, a shock could have formed. The geometry of the event requires in situ and remote sensing observations to characterize the SBO-CME and further understand its role in space weather.

Kelly Elizabeth Korreck↗

NASA NTRS1997

Miniature Magnetic Resonance Spectrometers

For the purpose of in-situ planeatry exploration, such as chemical characterization of Martian surface materials by miniature instruments, we have developed miniature Magnetic Resonance Spectrometers (MRS) namely, Nuclear Magnetic Resonance (NMR) and Electron Paramagnetic Resonance (EPR) spectrometers at JPL.

Proton-NMR↗

NASA NTRS2022

Relationship of Multiwavelength Radar Measurements to Ice Microphysics from the IMPACTS Field Program

Coincident radar data with Doppler radar measurements at X, Ku, Ka, and W bands on the NASA ER-2 aircraft overflying the NASA P3 aircraft acquiring in-situ microphysical measurements are used to characterize the relationship between radar measurements and ice microphysical properties. The data were obtained from the Investigation of Microphysics and Precipitation for Atlantic Coast-Threatening Snowstorms (IMPACTS. Direct measurements of the condensed water content as well as coincident Doppler radar measurements were acquired, facilitating improved estimates of ice particle mass, a variable that is an underlying factor for calculating and therefore retrieving the radar reflectivity (Z_(e)), median mass diameter (D_(m)), particle terminal velocity, and snowfall rate (S). The relationship between the measured ice water content (IWC) and that calculated from the particle size distributions (PSD) using relationships developed in earlier studies, and between the calculated and measured radar reflectivity at the four radar wavelengths, are quantified. Relationships are derived between the measured IWC and properties of the PSD, D_(m), Z_(e) at the four radar wavelengths and the dual-wavelength ratio. Because IWC and Z_(e) are measured directly, the coefficients in the mass-dimensional relationship that best match both the IWC and Z_(e) are derived. The relationships developed here, and the mass-dimensional relationship that uses both the measured IWC and Z_(e) to find a best match for both variables, can be used in studies that characterize the properties of wintertime snow clouds.

Andrew Heymsfield↗

NASA NTRSDate not supplied

On-chip Broadband Load Calibrators for Characterizing Transition-Edge Sensor Bolometers

We describe the design and fabrication of on-chip broadband load calibrators for element-by- element and full circuit characterization of transition-edge sensor (TES) bolometers for cosmic microwave background (CMB) polarimetry. Fabricated in a 4 X 4 grid on a 100 mm silicon wafer, the chips allow systematic testing of individual detector circuit elements without the need for an external blackbody source. This in-situ testing approach provides rapid and efficient characterization of various pixel designs in order to optimize the optical efficiency and control of systematic effects of the detectors. In this work, we demonstrate the on-chip calibrators on the Cosmology Large Angular Scale Surveyor (CLASS) W-band pixels. In particular, we investigate the loss on microstrip transmission lines and measure the performance of various designs of TESs, magic-tees, via-less crossovers, and signal terminations. We also test a filter-bank spectrometer with eight resonators spanning 80 – 105 GHz to characterize the spectral response of circuit elements across the detector bandwidth.

Sumit Dahal↗

NASA NTRS2007

A Comprehensive Plan for the Long-Term Calibration and Validation of Oceanic Biogeochemical Satellite Data

The primary objective of this planning document is to establish a long-term capability and validating oceanic biogeochemical satellite data. It is a pragmatic solution to a practical problem based primarily o the lessons learned from prior satellite missions. All of the plan's elements are seen to be interdependent, so a horizontal organizational scheme is anticipated wherein the overall leadership comes from the NASA Ocean Biology and Biogeochemistry (OBB) Program Manager and the entire enterprise is split into two components of equal sature: calibration and validation plus satellite data processing. The detailed elements of the activity are based on the basic tasks of the two main components plus the current objectives of the Carbon Cycle and Ecosystems Roadmap. The former is distinguished by an internal core set of responsibilities and the latter is facilitated through an external connecting-core ring of competed or contracted activities. The core elements for the calibration and validation component include a) publish protocols and performance metrics; b) verify uncertainty budgets; c) manage the development and evaluation of instrumentation; and d) coordinate international partnerships. The core elements for the satellite data processing component are e) process and reprocess multisensor data; f) acquire, distribute, and archive data products; and g) implement new data products. Both components have shared responsibilities for initializing and temporally monitoring satellite calibration. Connecting-core elements include (but are not restricted to) atmospheric correction and characterization, standards and traceability, instrument and analysis round robins, field campaigns and vicarious calibration sites, in situ database, bio-optical algorithm (and product) validation, satellite characterization and vicarious calibration, and image processing software. The plan also includes an accountability process, creating a Calibration and Validation Team (to help manage the activity), and a discussion of issues associated with the plan's scientific focus.

Hooker, Stanford B.↗

NASA NTRS2012

Characterizing of a Mid-Latitude Ice-Rich Landing Site on Mars to Enable in Situ Habitability Studies

We suggest an ice-rich landing site at 188.5E 46.16N within Amazonis Planitia as a candidate location to support a Mars lander mission equipped to study past habitability and regions capable of preserving the physical and chemical signs of life and organic matter. Studies of the ice-rich subsurface on Mars are critical for several reasons. The subsurface environment provides protection from radiation to shield organic and biologic compounds from destruction. The ice-rich substrate is also ideal for preserving organic and biologic molecules and provides a source of H2O for biologic activity. Examination of martian ground ice can test several hypotheses such as: 1) whether ground ice supports habitable conditions, 2) that ground ice can preserve and accumulate organic compounds, and 3) that ice contains biomolecules evident of past or present biological activity on Mars. This Amazonis site, located near the successful Viking Lander 2, shows indirect evidence of subsurface ice (ubiquitous defined polygonal ground, gamma ray spectrometer hydrogen signature, and numerical modeling of ice stability) and direct evidence of exposed subsurface ice. This site also provides surface conditions favorable to a safe landing including no boulders, low rock density, minimal rough topography, and few craters.

Heldmann, J.↗

NASA NTRS2019

The NASA Orbital Debris Engineering Model 3.1: Development, Verification, and Validation

The NASA Orbital Debris Program Office has developed the Orbital Debris Engineering Model (ORDEM) primarily as a tool for spacecraft designers and other users to understand the long-term risk of collisions with orbital debris. The newest version, ORDEM 3.1, incorporates the latest and highest fidelity datasets available to build and validate representative orbital debris populations encompassing low Earth orbit (LEO) to geosynchronous orbit (GEO) altitudes for the years 2016-2050. ORDEM 3.1 models fluxes for object sizes > 10 μm within or transiting LEO and > 10 cm in GEO. The deterministic portion of the populations in ORDEM 3.1 is based on the U.S. Space Surveillance Network (SSN) catalog, which provides coverage down to approximately 10 cm in LEO and 1 m in GEO. Observational datasets from radar, in situ, and optical sources provide a foundation from which the model populations are statistically extrapolated to smaller sizes and orbit regions that are not well-covered by the SSN catalog, yet may pose the greatest threat to operational spacecraft. Objects in LEO ranging from approximately 5 mm to 10 cm are modeled using observational data from ground-based radar, namely the Haystack Ultrawideband Satellite Imaging Radar (HUSIR – formerly known as Haystack). The LEO population smaller than approximately 3 mm in size is characterized based on a reanalysis of in situ data from impacts to the windows and radiators of the U.S. Space Transportation System orbiter vehicle, i.e., the Space Shuttle. Data from impacts on the Hubble Space Telescope are also used to validate the sub-millimeter model populations in LEO. Debris in GEO with sizes ranging from 10 cm to 1 m is modeled using optical measurement data from the Michigan Orbital DEbris Survey Telescope (MODEST). Specific, major debris-producing events, including the Fengyun-1C, Iridium 33, and Cosmos 2251 debris clouds, and unique populations, such as sodium-potassium droplets, have been re-examined and are modeled and added to the ORDEM environment separately. The debris environment greater than 1 mm is forecast using NASA’s LEO-to- GEO ENvironment Debris model (LEGEND). Future explosions of intact objects and collisions involving objects greater than 10 cm are assessed statistically, and the NASA Standard Satellite Breakup Model is used to generate fragments from these events. Fragments smaller than 10 cm are further differentiated based on material density categories, i.e., high-, medium-, and low-density, to better characterize the potential debris risk posed to spacecraft. The future projection of the sub-millimeter environment is computed using a special small-particle degradation model where small particles are created from intact spacecraft and rocket bodies. This work discusses the development, features, and capabilities of the ORDEM 3.1 model; the ne new data analyses used to build the model populations; and sample verification and validation results.

Matney, M.↗