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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Minimum dV for Targeted Spacecraft Disposal

The density scale height of the Earth's atmosphere undergoes significant reduction in the final phases of a natural decay. It can be shown that for most realistic ballistic numbers, it is possible to exploit this effect to amplify available spacecraft dV by using it at the penultimate perigee to penetrate into higher drag regions at final apogee. The drag at this lower pass can more effectively propel a spacecraft towards the final target region than applying the same dV direct Hohmann transfer at that final apogee. This study analyzes the potential use of this effect-- in combination with small phasing burns--to calculate the absolute minimum delta-V that would be required to reliably guide a spacecraft to any specified safe unoccupied ocean region as a function of ballistic number, orbit inclination, and initial eccentricity. This calculation is made for controllable spacecraft in several orbit inclinations and eccentricities with arbitrary initial LAN and ArgP one week before final entry, under three-sigma atmospheric perturbations. The study analyzes the dV required under varying levels of final controllable altitude at which dV may be imparted, and various definitions of the length and location of a "safe" disposal area. The goal of such research is to improve public safety by creating assured safe disposal strategies for low-dV and/or low-thrust spacecraft that under more traditional strategies would need to be abandoned to a fully random decay.

Bacon, John↗

SCaN Transportable Communication Platform (STCP)

NASA Glenn Research Center required a satellite communication trailer that served dual purposes; 24/7 Emergency Communication Services (ECS) in the event of a natural or manmade disaster that disrupted conventional communications, and a Ka Band NASA TDRS capability providing a research capability for over the air evaluations/characterizations. The trailer was to be field deployable, environmentally controlled and self-contained providing local area networks (LANs) and Wide Area Networks (WAN's) with user access both wired (Ethernet) and wireless (802.11) supporting VoIP, Internet Web access and Email. The TDRSS terminal included a 200W TWT amplifier mounted on the feed boom, individual up and down converters, and custom integrated waveguide and a supporting feed system. Other features such as a mast, generator, electrical, lighting, surveillance, and storage capabilities were also required. The Trailer was developed and demonstrated these original requested capabilities. New Requirements are defined and the trailer is now being evolved and upgraded to be a backup for the Near- Earth Network (NEN) Stations at KSC that will support the launch phase of EM-1. This paper presents the current and future capabilities of the trailer and additional options that will make it a valuable deployable asset to support remote operations from any launch from location.

Ka Band↗

Advanced Utilization of the Payload Executive Processor (PEP) Ethernet Port to Support JSL Based Payloads

Increased interest by Payload Developers in utilization of the Joint Station LAN (Local Area Network) (JSL) for command and data transactions has driven the investigation of providing bi-directional Ethernet communication with PEP (Payload Executive Processor). Ethernet-only payload developers are interested in taking advantage of the services provided by PEP. Enabling Ethernet communications within PEP requires more than just turning on the hardware. PEP contains no Operating System (OS) or Ethernet stack so it does not inherit any built in functionality for Ethernet support. Both hardware drivers and application software must be developed from scratch. In the absence of an OS (Operating System) the design must address security issues in terms of access and data transferred, i.e. blocking unauthorized users and preventing denial of service. Developing a design to process Ethernet data within the existing real-time constraints of PEP requires a few compromises: data rates, supported protocols, custom packet format and limited client connections to name a few. Integration of the light weight internet protocol (LwIP). Ethernet stack provides a customizable solution for the embedded real-time environment. As utilization of the JSL increases, the successful implementation of an Ethernet interface enhances the utilization of PEP, and provides a new path for future Ethernet-only payloads to gain access to around the clock command and data services.

Guyette, Greg↗

Effects of Spin-Orbit Resonance in Stability for Low Altitude Mars Orbits

Orbit stability has been thoughtfully studied in various celestial bodies. The increasing interest in Mars orbiters brings the question of the likelihood of natural decay in low altitude regimes. This paper studies the shape change of low altitude Mars orbits by carrying out large sets of numerical high fidelity simulations. Results showed that various configurations of the orbital elements gave perturbations that resulted in unstable orbits. The paper also studies the potential causes of the observed unstable regions. We computed theoretical spin-orbit resonances to study their implications in the stability at low altitudes. The resonances were tested at different initial Longitudes of the Ascending Node (LAN) and orbit inclinations to check the potential existence of latitude/longitude implications on the stability.

Spin-Orbit Resonance↗

Flight Readiness of Mochii S: Portable Spectroscopic Scanning Electron Microscope Facility on the International Space Station (ISS)

The ISS (International Space Station) currently lacks the capability to image and chemically analyze nano-to-micron scale particles from numerous engineering systems. To identify these particles, we must wait for a re-entry vehicle to return them from low earth orbit for ground-based SEM (Scanning Electron Microscope) / EDS (Energy Dispersive X-Ray Spectroscopy) analysis. This may take months, potentially delaying the affected system. Having an EDS-equipped SEM (Mochii S) aboard the ISS will accelerate response time thereby enhancing crew and vehicle safety by rapid and accurate identification of microscopic threats, especially in time-critical situations.The Mochii S payload will be stationed in the Japanese Experiment Module (JEM) powered by 120 VAC (Volts Alternating Current) inverter and connected to station Ethernet and WiFi (Fig. 1). To date the Mochii S payload has undergone testing for command and data handling, power quality, flight vibration, and radiation testing at Johnson Space Center (JSC). Mochii's high-RPM (Revolutions Per Minute) rotating vacuum pumps and high voltage systems have been reviewed to meet safety standards by JSC (Johnson Space Center) Engineering. Topology of the system in the JEM module has been baselined by ISS Safety and JAXA (Japan Space Exploration Agency). Digital controls to and from ISS over Joint Station LAN (Local Area Network) uplink have been simulated and the latencies and data rates have been found to be sufficient for successful operation of the payload from ground.Transporting sensitive electron optical instruments aboard a rocket that sustains 7G acceleration for 8 minutes and then operating it the unique microgravity (micro-g) environment is no trivial matter. To meet strict safety requirements and increase robustness for mission success, over 500 unique verifications must be completed before the payload is certified for spaceflight. Two of which will be discussed in detail are: vibroacoustic testing and magnetic susceptibility shielding and validation.

Mochii↗

Using Manufacturing Message Specification for Monitor and Control at Venus

A new approach to the monitor and control of spacecraft tracking systems has been developedbased on the Open Systems Interconnection (OSI) process control standard Manufacturing MessageSpecification (MMS). Station subsystems are interconnected using commercial MMS software tosupport interprocessor communication across a Local Area Network (LAN). Significant cost savingsare realized through the incorporation of commercial Software Control and Data Acquisition(SCADA) packages to support the operator interface. A pilot system has been installed and is inoperation at the Deep Space Network (DSN) experimental Venus complex. The DSN operates a new34-meter beam waveguide antenna (DSS-13) at the Goldstone Venus complex in California. The complex composed of various pieces of equipment with some equipment under computer automated control...

Urista, J.↗

Interoperable Services to Mitigate Lunar Position, Navigation, and Timing Challenges

Across the Earth, both civilian and government endeavors enjoy a built-in reliance on a position, navigation, and timing (PNT) infrastructure to which they are largely blind. Whether walking, driving, flying, or orbiting, Earth-centric PNT systems that have evolved over decades provide a core functionality to which we have grown accustomed for these pursuits. As NASA joins with other government space agencies and commercial partners to return humans to the Moon in a sustained manner within the current decade, expectations for PNT knowledge and timeliness at the Moon rival those on Earth. The need exists to develop a viable lunar-centric PNT infrastructure to support the planned human and robotic exploits. Navigating within the influence of the Moon presents its own set of challenges. Identification, understanding, and use of a unified reference frame and time system on which navigation is based becomes a fundamental need at the Moon. In addition to the unified foundational elements, measurement liability, dynamic conditions that require Earth-independent autonomous operations, and standards for PNT signals and message-based data exchange each represent distinct challenges to navigation in a burgeoning operational lunar environment. The PNT services planned as part of the lunar communications and navigation relay architecture known as LunaNet aid in surmounting the challenges. LunaNet interoperability specifications stipulate standards for signal parameters, messages, and lunar reference systems for PNT services. Within LunaNet’s defined interoperability resides the concept of a Reference Signal to provide communication signals specifically structured to enable measurement of pseudorange, Doppler, and time transfer by the recipient. One such signal type, the Augmented Forward Signal (AFS), functions as the mainstay for LunaNet PNT, while also serving the data needs for ubiquitous broadcast of network access and rapid unscheduled dissemination of alerts and messages. The presence of a geometrically distributed network of orbiting nodes transmitting the AFS forms the basis for the Lunar Augmented Navigation System (LANS), that delivers both radio navigation and data to multiple users in the lunar environment simultaneously. After reviewing the challenges associated with lunar navigation, this paper will describe the concepts and rationale behind the LunaNet PNT services. By borrowing techniques from Earth-centric Global Navigation Satellite Services (GNSS), the Tracking and Data Relay Satellite System, and the Consultative Committee for Space Data Standards, PNT from LunaNet aids to overcome challenges faced for accurate lunar navigation.

LunaNet↗

Interoperable Services to Mitigate Lunar Position, Navigation, and Timing Challenges

Across the Earth, both civilian and government endeavors enjoy a built-in reliance on a position, navigation, and timing (PNT) infrastructure to which they are largely blind. Whether walking, driving, flying, or orbiting, Earth-centric PNT systems that have evolved over decades provide a core functionality to which we have grown accustomed for these pursuits. As NASA joins with other government space agencies and commercial partners to return humans to the Moon in a sustained manner within the current decade, expectations for PNT knowledge and timeliness at the Moon rival those on Earth. The need exists to develop a viable lunar-centric PNT infrastructure to support the planned human and robotic exploits. Navigating within the influence of the Moon presents its own set of challenges. Identification, understanding, and use of a unified reference frame and time system on which navigation is based becomes a fundamental need at the Moon. In addition to the unified foundational elements, measurement liability, dynamic conditions that require Earth-independent autonomous operations, and standards for PNT signals and message-based data exchange each represent distinct challenges to navigation in a burgeoning operational lunar environment. The PNT services planned as part of the lunar communications and navigation relay architecture known as LunaNet aid in surmounting the challenges. LunaNet interoperability specifications stipulate standards for signal parameters, messages, and lunar reference systems for PNT services. Within LunaNet’s defined interoperability resides the concept of a Reference Signal to provide communication signals specifically structured to enable measurement of pseudorange, Doppler, and time transfer by the recipient. One such signal type, the Augmented Forward Signal (AFS), functions as the mainstay for LunaNet PNT, while also serving the data needs for ubiquitous broadcast of network access and rapid unscheduled dissemination of alerts and messages. The presence of a geometrically distributed network of orbiting nodes transmitting the AFS forms the basis for the Lunar Augmented Navigation System (LANS), that delivers both radio navigation and data to multiple users in the lunar environment simultaneously. After reviewing the challenges associated with lunar navigation, this paper will describe the concepts and rationale behind the LunaNet PNT services. By borrowing techniques from Earth-centric Global Navigation Satellite Services (GNSS), the Tracking and Data Relay Satellite System, and the Consultative Committee for Space Data Standards, PNT from LunaNet aids to overcome challenges faced for accurate lunar navigation.

Navigation↗

X-57 Cruise Motor GVT Using Fixed-Base Correction Technique

The National Aeronautics and Space Administration (NASA) Armstrong Flight Research Center (AFRC) completed a modal survey of the X-57 Maxwell aircraft cruise motor system to help inform cruise motor redesign efforts. X-57 Maxwell was an electric propulsion demonstrator aircraft developed by NASA to inform airworthiness standards for electrified-aircraft. The cruise motor system modal survey was completed in spring of 2023 utilizing the fixed-base correction (FBC) ground vibration test (GVT) technique developed by ATA Engineering, to decouple the motor modes from the aircraft modes. Previously during the full aircraft GVT, a detailed modal assessment of the cruise motors was not performed. Owing to the X-57 project’s phase in the aircraft development cycle when the motor redesign effort occurred, the cruise motor GVT could only be performed with the cruise motor system installed on the aircraft, with most of its installation hardware (wiring, baffling, sensors, etc.) attached. An impact hammer was used to provide excitation input at various locations within the tight confines of the cruise motor installation. To better support motor redesign efforts, the FBC methodology was utilized to fix, separate and de-couple the cruise motor modes from aircraft modal response. During the GVT, this required additional impact tap tests on candidate fixed-boundary points for each degree of freedom (DOF) to be fixed. Additional triaxial accelerometers installed at the candidate points were used to compute frequency response functions (FRFs) in X, Y, and Z directions to enable those DOFs to be numerically fixed. Test data was acquired using Hottinger Brüel & Kjær’s LAN-XI data acquisition hardware and BK Connect software. FBC post-test processing was performed using the Structural Modification Using Frequency Response Functions (SMURF) technique with ATA Engineering’s Interface between MATLAB, Analysis, Test (IMAT) software. Utilizing the FBC technique relieved test engineers from having to instrument the entire aircraft to identify and separate aircraft response from cruise motor modes of interest. The FBC technique also permitted structural analysis engineers to omit secondary components from their finite element model (FEM) of the cruise motor system. This FBC modal survey was successful, and the first time NASA AFRC utilized the FBC method on an aircraft rather than a test fixture, and also using an impact hammer rather than multiple shakers allowing significant project schedule and cost savings

Modal Survey↗

International Coordination and Cooperation on LunaNet Spectrum

LunaNet is planned to be the network of networks operated by a set of cooperating organizations to provide interoperable Communications, networking, Position, Navigation, and Timing (CPNT) services to users on and around the Moon based on a framework of mutually agreed-upon standards, protocols, frequency bands and interface requirements. LunaNet follows a service-oriented architecture that is agnostic about the types of organizations that provide services, e.g., government, industry, or academia. LunaNet is open, scalable, resilient, secure, and extensible. To achieve these goals, LunaNet Service Providers (LNSP) must coordinate with each other to define and develop the architecture, to plan initial and evolved capabilities, and to operate their networks. One of the central LunaNet tenets is the use of shared spectrum. For example, the Lunar Augmented Navigation Service (LANS) acts like a Global Navigation Satellite System (GNSS) such as the US Global Positioning System (GPS) or European Galileo but the LNSPs’ contributions to LunaNet must use the same frequency band (2483.5 MHz-2500.0 MHz) and transmit the same waveform synchronized by highly accurate clocks so that Users ‘see’ one virtual network and use the same multilateration algorithm to determine their positions. This necessitates a high degree of spectrum coordination. NASA’s Lunar and Human Spaceflight Spectrum Management Team has been actively supporting development of the LunaNet Interoperability Specification (LNIS), soliciting inputs from spectrum policy and planning experts across NASA, ESA and JAXA. Cislunar spectrum use considerations have been studied and adjudicated within the Space Frequency Coordination Group (SFCG) and inform the ongoing discussion of a lunar communication and navigation architecture within the existing radio regulatory framework of the International Telecommunication Union, leading to the 2027 World Radiocommunication Conference (WRC-27). The frequency plan contained in the publicly released draft of the LunaNet Interoperability Specification reflects the initial phase of exploration (roughly to 2030) defining an optimal set of radio frequencies in appropriately allocated services consistent with WRC-23 decisions for use by known or planned CPNT applications, while striving to maximize coexistence and compatibility amongst cislunar systems and other systems within the near-Earth regime (< 2 million km from Earth). Important considerations include: protection of extremely sensitive receive-only radio astronomy systems on the lunar far side, known as the Shielded Zone of the Moon (SZM); compatibility between Direct with Earth (DWE) communications links and links needed to support relay satellites in lunar orbit with their customer systems on orbit or on the lunar surface; compatibility between multiple lunar surface communications systems and capabilities over varied and challenging terrain and distances; as well as ensuring compatibility and interoperability between navigation systems which either leverage Earth-based or in-situ lunar systems. In addition, the lunar CPNT architecture is envisioned to be the basis – with adjustments – of the future Mars CPNT architecture as we expand into the solar system using Interplanetary Networking (IPN). The second phase of lunar spectrum definition will address planned international capabilities for the next decade that will require action at WRC-27 and beyond. This paper will discuss each of these considerations in more depth and how the current LunaNet frequency plan addresses them.

LunaNet↗

Enhancing Hydrogen Production from Bioenergy Crops via Photoreforming

Photoreforming perennial bioenergy crops (willow, Miscanthus , and poplar) has the potential to produce H 2 with reduced environmental impacts. To understand the compositional effects of the biomass on the average rate of H 2 production over the first 30 min of reaction ( r H 2 ), the r H 2 values of model biomass component (i.e., cellulose, hemicellulose, and lignin) mixtures were compared with those from the raw biomass. The higher cellulose or hemicellulose content in multicomponent mixtures resulted in higher r H 2 , whereas lignin reduced the hydrogen production rate. However, with raw biomass, the ratio of biomass components alone did not determine the r H 2 via photoreforming, with rates of hydrogen production for different varieties of willow ranging between 1.9 μmol h -1 and 12.3 μmol h -1 , 11.8 μmol h -1 for a poplar, and 6.8 μmol h -1 for a miscanthus biomass. In addition, comparable r H 2 values of raw poplar and its extracted cellulose via an IonoSolv treatment indicated the possibility of using raw biomass materials without delignification for generating H 2 via photoreforming. Importantly, r H 2 was positively correlated with the interaction between water and the biomass, as assessed by NMR relaxation via an examination of the T 1 /T 2 ratio. A stronger water-biomass interaction resulted in a higher r H 2 . Genetic modification of biomass has been suggested as a putative way to improve the r H 2 of biomass with an enhanced interaction with water. This research enhances the understanding of factors influencing H 2 production from lignocellulosic biomass by photoreforming and supports the breeding and management of perennial biomass crops to maximize H 2 yields while minimizing land area requirements.

biomass↗

Trend Detection of Atmospheric Time Series: Incorporating Appropriate Uncertainty Estimates and Handling Extreme Events

This paper is aimed at atmospheric scientists without formal training in statistical theory. Its goal is to, 1) provide a critical review of the rationale for trend analysis of the time series typically encountered in the field of atmospheric chemistry; 2) describe a range of trend-detection methods; and 3) demonstrate effective means of conveying the results to a general audience. Trend detections in atmospheric chemical composition data are often challenged by a variety of sources of uncertainty, which often behave differently to other environmental phenomena such as temperature, precipitation rate, or stream flow, and may require specific methods depending on the science questions to be addressed. Some sources of uncertainty can be explicitly included in the model specification, such as autocorrelation and seasonality, but some inherent uncertainties are difficult to quantify, such as data heterogeneity and measurement uncertainty due to the combined effect of short- and long-term natural variability, instrumental stability, and aggregation of data from sparse sampling frequency. Failure to account for these uncertainties might result in an inappropriate inference of the trends and their estimation errors. On the other hand, the variation in extreme events might be interesting for different scientific questions, for example, the frequency of extremely high surface ozone events and their relevance to human health. In this study we aim to, 1) review trend detection methods for addressing different levels of data complexity in different chemical species; 2) demonstrate that the incorporation of scientifically interpretable covariates can outperform pure numerical curve fitting techniques in terms of uncertainty reduction and improved predictability; 3) illustrate the study of trends based on extreme quantiles that can provide insight beyond standard mean or median based trend estimates; and 4) present an advanced method of quantifying regional trends based on the inter-site correlations of multi-site data. All demonstrations are based on time series of observed trace gases relevant to atmospheric chemistry, but the methods can be applied to other environmental data sets.

Trace gas↗

High‐Pressure Synthesis of Ultra‐Incompressible, Hard and Superconducting Tungsten Nitrides

Abstract Transition metal nitrides, particularly those of 5 d metals, are known for their outstanding properties, often relevant for industrial applications. Among these metal elements, tungsten is especially attractive given its low cost. In this high‐pressure investigation of the W–N system, two novel ultra‐incompressible tungsten nitride superconductors, namely W 2 N 3 and W 3 N 5 , are successfully synthesized at 35 and 56 GPa, respectively, through a direct reaction between N 2 and W in laser‐heated diamond anvil cells. Their crystal structure is determined using synchrotron single‐crystal X‐ray diffraction. While the W 2 N 3 solid's sole constituting nitrogen species are N 3‐ units, W 3 N 5 features both discrete N 3‐ as well as N 2 4‐ pernitride anions. The bulk modulus of W 2 N 3 and W 3 N 5 is experimentally determined to be 380(3) and 406(7) GPa, and their ultra‐incompressible behavior is rationalized by their constituting WN 7 polyhedra and their linkages. Importantly, both W 2 N 3 and W 3 N 5 are recoverable to ambient conditions and stable in air. Density functional theory calculations reveal W 2 N 3 and W 3 N 5 to have a Vickers hardness of 30 and 34 GPa, and superconducting transition temperatures at ambient pressure (50 GPa) of 11.6 K (9.8 K) and 9.4 K (7.2 K), respectively. Additionally, transport measurements performed at 50 GPa on W 2 N 3 corroborate with the calculations.

Chemistry↗

Impact of Linker Engineering in Core‐Linked Dimeric Acceptors for High‐Performance Organic Solar Cells

Abstract The dimerization of small molecule acceptors (SMAs) is a promising strategy for enhancing the long‐term stability and power conversion efficiency (PCE) of organic solar cells (OSCs). However, the reported DSMAs are primarily limited to end‐linked molecular configurations, highlighting the need for further exploration of various dimer architectures. Herein, the development of two distinct core‐linked dimerized SMAs (DYF‐V and DYF‐E) are reported with tailored linker structures (vinylene and ethynyl, respectively), achieving high‐performance OSCs (PCE = 18.53%). Interestingly, a subtle change in the linker structures results in markedly different molecular properties and photovoltaic performances of the dimer acceptors. DYF‐E with an ethynyl linker exhibits more twisted backbone conformation and mitigated aggregation property compared to DYF‐V, inducing desirable blend morphologies with a polymer donor including high crystallinity, face‐on oriented packing structures, and well‐intermixed domains. Thus, the DYF‐E‐based OSCs exhibit a high PCE (17.02%), which significantly outperforms the DYF‐V‐based OSCs (PCE = 9.98%). Furthermore, the ternary OSCs based on DYF‐E achieve a higher PCE of 18.53%. Thus, this study highlights the significance of selecting an appropriate linker in core‐linked dimerized SMAs for producing high‐performance OSCs.

Oh, Shinbee↗

Structural Basis of Sequential Enantioselective Epoxidation by a Flavin‐Dependent Monooxygenase in Lasalocid A Biosynthesis

Abstract Polyether polyketides are a structurally diverse group of natural products known for their antimicrobial and antiproliferative activities. Lasalocid A is a canonical natural polyether produced by the soil bacteriumStreptomyces lasalocidi. In lasalocid A biosynthesis, a polyene polyketide intermediate is converted into a bisepoxide by the flavin‐dependent monooxygenase enzyme Lsd18. Remarkably, Lsd18 acts on two distinct C═C groups in the substrate molecule, forming two (R,R) epoxides. We have determined the X‐ray crystal structures of Lsd18 in the substrate‐free, substrate‐bound, and product‐bound forms. Our work has revealed that Lsd18 has an extra‐large substrate‐binding pocket that allows the polyene to adopt different conformations within the enzyme pocket. This feature enables Lsd18 to epoxidate both of the C═C groups. Additionally, a subpocket located near the Lsd18 active site controls stereoselectivity by dictating which face of the C═C group is placed next to the flavin. Molecular understanding of how Lsd18 transforms a polyene into a bisepoxide during lasalocid A biosynthesis lays the foundation for the production of designer polyethers for drug development.

Chemistry↗

Circumventing Radical Generation on Fe–V Atomic Pair Catalyst for Robust Oxygen Reduction and Zinc–Air Batteries

Iron–nitrogen–carbon (Fe–N–C) catalysts are considered the most active platinum-free alternative for oxygen reduction reaction (ORR), yet the generated reactive oxygen species (ROS) from general mechanistic pathway rapidly impair the ORR activity and stability of Fe–N–C. Herein, we establish and report an ORR pathway-switching strategy to circumvent ROS generation and fundamentally improve the activity and stability of Fe–N–C via DFT guided catalyst design. The constructed Fe–V atomic pair catalyst (Fe 1 V 1 -NC) with N 2 Fe-N 2 -VN 2 configuration enables side-on adsorption of O 2 and subsequent direct-breaking of the O═O bond to form O*, thereby avoiding the formation of ROS radicals. Importantly, there is intersite electron interaction between FeN 4 and VN 4 , which further boosts the ORR activity. Consequently, Fe 1 V 1 -NC exhibits outstanding ORR activity with onset and half-wave (E 1/2 ) potentials at 1.02 and 0.89 V versus RHE, respectively, in 0.1 M KOH. Record-high stability is achieved on Fe 1 V 1 -NC with a minimal decay in E 1/2 by 16 mV over 50000 cycles, surpassing Fe–N–C counterpart and most of the catalysts reported to date. The Fe 1 V 1 -NC-based zinc-air battery reported here demonstrates exceptional durability up to 400 h at 10 mA·cm −2 . This work identifies the intrinsic correlation between ORR pathway, activity, and stability, advancing development of stable catalytic systems.

Fe-N-C↗

Separation of infrared and bulk in thermal QCD

A new thermal regime of QCD, featuring decoupled scale-invariant infrared glue, has been proposed to exist both in pure-glue (N f =0) and “real-world” (N f =2+1 at physical quark masses) QCD. In this IR phase, elementary degrees of freedom flood the infrared, forming a distinct component independent from the bulk. This behavior necessitates non-analyticities in the theory. In pure-glue QCD, such non-analyticities have been shown to arise via Anderson-like mobility edges in Dirac spectra (λ IR = 0, ±λ A ≠ 0), as manifested in the dimension function d IR (λ). Here, we present the first evidence, based on lattice QCD calculation at a=0.105 fm, that this mechanism is also at work in real-world QCD, thus supporting the existence of the proposed IR regime in nature. An important aspect of our results is that, while at T = 234 MeV we find a dimensional jump between zero modes and lowest near-zero modes very close to unity (d IR = 3 to d IR ≃ 2), similar to the IR phase of pure-glue QCD, at T = 187 MeV we observe a continuous λ-dependence. This suggests that thermal states just above the chiral crossover are non-analytically (in T) connected to thermal state at T = 234 MeV, supporting the key original proposition that the transition into the IR regime occurs at a temperature strictly above the chiral crossover.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗