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At least 163 records · Page 9

An Overview of SAL

To become practical for assurance, automated formal methods must be made more scalable, automatic, and cost-effective. Such an increase in scope, scale, automation, and utility can be derived from an emphasis on a systematic separation of concerns during verification. SAL (Symbolic Analysis Laboratory) attempts to address these issues. It is a framework for combining different tools to calculate properties of concurrent systems. The heart of SAL is a language, developed in collaboration with Stanford, Berkeley, and Verimag for specifying concurrent systems in a compositional way. Our instantiation of the SAL framework augments PVS with tools for abstraction, invariant generation, program analysis (such as slicing), theorem proving, and model checking to separate concerns as well as calculate properties (i.e., perform, symbolic analysis) of concurrent systems. We. describe the motivation, the language, the tools, their integration in SAL/PAS, and some preliminary experience of their use.

Bensalem, Saddek↗

NASA GeneLab Concept of Operations

NASA's GeneLab aims to greatly increase the number of scientists that are using data from space biology investigations on board ISS, emphasizing a systems biology approach to the science. When completed, GeneLab will provide the integrated software and hardware infrastructure, analytical tools and reference datasets for an assortment of model organisms. GeneLab will also provide an environment for scientists to collaborate thereby increasing the possibility for data to be reused for future experimentation. To maximize the value of data from life science experiments performed in space and to make the most advantageous use of the remaining ISS research window, GeneLab will apply an open access approach to conducting spaceflight experiments by generating, and sharing the datasets derived from these biological studies in space.Onboard the ISS, a wide variety of model organisms will be studied and returned to Earth for analysis. Laboratories on the ground will analyze these samples and provide genomic, transcriptomic, metabolomic and proteomic data. Upon receipt, NASA will conduct data quality control tasks and format raw data returned from the omics centers into standardized, annotated information sets that can be readily searched and linked to spaceflight metadata. Once prepared, the biological datasets, as well as any analysis completed, will be made public through the GeneLab Space Bioinformatics System webb as edportal. These efforts will support a collaborative research environment for spaceflight studies that will closely resemble environments created by the Department of Energy (DOE), National Center for Biotechnology Information (NCBI), and other institutions in additional areas of study, such as cancer and environmental biology. The results will allow for comparative analyses that will help scientists around the world take a major leap forward in understanding the effect of microgravity, radiation, and other aspects of the space environment on model organisms. These efforts will speed the process of scientific sharing, iteration, and discovery.

Space Life Science↗

PHENIX U.S.-Japan Collaboration Investigation of Thermal and Mechanical Properties of Thermal Neutron–Shielded Irradiated Tungsten

The United States and Japan have collaborated on fusion materials research in a series of agreements reaching back to 1981. The PHENIX collaboration is the latest U.S.-Japan project which spans 2013 to 2019 and has the goal of assessing technical feasibility of tungsten-based, helium-cooled plasma-facing component concepts for a demonstration fusion power reactor (DEMO). Task 2 within the PHENIX project is focused on evaluating the neutron irradiation effects in tungsten. For tungsten, the transmutation to Re and Os is at least as important to determining its properties after irradiation as the displacement damage, and the transmutation rate depends on the energy spectrum of the reactor. A large-scale, instrumented irradiation capsule with thermal neutron shielding to better mimic fusion conditions was irradiated in the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory. The tungsten specimens were irradiated in different temperature zones between 500°C and 1200°C to doses of ~0.2 to 0.7 displacements per atom. More than 20 varieties of pure tungsten and tungsten alloys were included in the irradiation, and they were evaluated in the 3025E hot-cell facility and at the Low Activation Materials Development and Analysis Laboratory. The elevated temperature tensile, fracture toughness, hardness, thermal conductivity, electrical resistivity, density, elemental composition, and microstructure properties of the irradiated materials are being collected. Furthermore, this paper overviews the experimental design, specimen matrix, and the initial results of postirradiation examinations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Test of Harmonic Coil Accuracy Using a Multi Vertex Probe

Magnets are integral components of particle accelerators, with different multipoles used to perform various beam conditioning functions, like steering and focusing. Testing accelerator magnets to ensure compliance with specification is a crucial step of fabrication. One of the most popular techniques for verifying magnetic field strength and integrity is the harmonic coil probe. Harmonic coil probes are comprised of passive loops that are rotated around the aperture of a magnet and are used to measure magnetic flux. Oftentimes the measurements of the harmonic coil probe are affected by transverse vibrations along the axis of rotation and torsional vibrations of the position closure sensor, both causing spurious harmonics. To make matters challenging, it is difficult to distinguish between the real harmonics of the magnet and the spurious harmonics during analysis. This research explores the use of a novel configuration of harmonic coil probe, Multi-Vertex Probe (MVP), to address multiple factors that affect the accuracy and repeatability of harmonic coil probe measurement. Most of the results are based on simulation data, in which artificial torsional distortions are introduced and removed with the proposed processing method. In addition to implementing torsional vibration removal in simulation, laboratory analysis regarding the source of vibrations was performed using a pre-fabricated MVP. More specifically, various mechanical conditions were used to explore the standard deviation of main harmonic’s flux amplitude. The conditions included: coupling type (rigid or soft), rotation speed, probe starting position within magnetic field, and cabling location inside the magnetic field. Along with this, the MVP’s measured noise floor in and outside a magnetic field was quantified.

Lofquist, Claire [Northern Illinois U.]↗

Sampling and Analysis Plan for LSL2 Underground Storage Tank Evaluation of PFAS in Soil: Protection of Groundwater

This SAP gathers all pertinent information relevant to the sampling and analysis of soil at the removal site for a former 10,000-gallon UST and reference sites in the vicinity of the excavation site. Data Quality Objectives establishes the process and steps for the acquisition of data. Data Flow Diagram establishes the decisions and next steps. Quality Assurance Project Plan establishes the quality requirements for data collection, including planning, implementation, and assessment of sampling, field measurements, and laboratory analysis. The work is being completed for DOE-SC Pacific Northwest Site Office.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Petrographic and spectral study of hydrothermal mineralization in drill core from Hawaii: A potential analog to alteration in the martian subsurface

Abstract Continuous rock core was collected for 1764 m (5786’) on the Pohakuloa Army Training base near the center of the big island of Hawaii. The core traverses basaltic lava flows from the volcano's shield-building phase, and perched aquifers and higher temperature groundwaters were encountered. The collected samples record water-rock interactions of basaltic materials in a setting that may be a model for groundwater interactions on Mars. We collected visible and infrared point spectra of materials in the lowest portion of the core, where alteration was noted to become more prominent. We identified three types of phyllosilicate spectral signatures and three types of zeolites. The phyllosilicates show similarity to those identified on Mars using data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). Based on the field survey, 25 depths were selected for sampling and petrographic analysis of thin sections. The spectral data and thin section work have a strong agreement in the types of materials identified by the two different techniques. Both the spectral and petrographic data indicate low to moderate temperature geothermal alteration occurred in the lower half of the core. The field spectra are a useful reconnaissance tool for selecting mineralogic diversity for subsequent higher resolution and more time-consuming laboratory analysis.

Geochemistry & Geophysics↗

Some considerations on velocity vector accuracy in dust trajectory analysis

The relative contributions of comets and asteroids to the reservoir of dust in the interplanetary medium is not known. There are direct observations of dust released from comets and there is evidence to associate the IRAS dust bands with possible collisions of asteroids in the main belt. A means towards sorting out the parent sources has been proposed in the establishment of a dust collector in orbit about the Earth. The purpose of such a facility would be to collect not only cosmic dust particles intact but also the state vectors, as they arrive at the detector, the idea being that one may combine analytical laboratory analysis of the physics and chemistry of the captured particles with orbital data in order to help distinguish between bodies and identify parent bodies. The theoretical study of dust particle orbits in the solar system takes on greatly more importance if we use collected trajectory data. The orbital motion of dust when radiation and forces alone are acting is well understood. When gravitational forces due to the planets are included, the motion can become quite complex. In order to characterize the orbits of particles as they crossed the Earth's orbits, a study of the long-time dust orbital evolution was undertaken. We have considered various parameters associated with these dust orbits to see if one may in a general way discriminate between particles evolved from comets and asteroids. We proceed in this study as we have done previously. That is, we considered the dust particles as ideal black bodies, of density 1 gm/cc, spherical, with radii 10-100 microns. Particles of this size are affected by radiation forces, photon pressure, and Poynting-Robertson drag. Account was also taken of solar wind drag, which amounts to about 30 percent of the Poynting-Robertson drag negligible. The gravitational forces due to the planets are included, unlike in our previous study; the planetary orbits are those of true n-body interaction so that the possibility of secular resonance is included. Our method was to calculate explicitly by a numerical procedure the orbits of dust particles after they left their parent bodies. The motion is determined numerically with the implicit Runge-Kutta integrator using Gauss-Radau spacings.

Jackson, A. A.↗

Can Agricultural Management Induced Changes in Soil Organic Carbon Be Detected Using Mid-Infrared Spectroscopy?

A major limitation to building credible soil carbon sequestration programs is the cost of measuring soil carbon change. Diffuse reflectance spectroscopy (DRS) is considered a viable low-cost alternative to traditional laboratory analysis of soil organic carbon (SOC). While numerous studies have shown that DRS can produce accurate and precise estimates of SOC across landscapes, whether DRS can detect subtle management induced changes in SOC at a given site has not been resolved. Here, we leverage archived soil samples from seven long-term research trials in the U.S. to test this question using mid infrared (MIR) spectroscopy coupled with the USDA-NRCS Kellogg Soil Survey Laboratory MIR spectral library. Overall, MIR-based estimates of SOC%, with samples scanned on a secondary instrument, were excellent with the root mean square error ranging from 0.10 to 0.33% across the seven sites. In all but two instances, the same statistically significant (p < 0.10) management effect was found using both the lab-based SOC% and MIR estimated SOC% data. Despite some additional uncertainty, primarily in the form of bias, these results suggest that large existing MIR spectral libraries can be operationalized in other laboratories for successful carbon monitoring.

54 ENVIRONMENTAL SCIENCES↗

Monitoring physical and chemical parameters of Delaware Bay waters with an ERTS-1 data collection platform

The author has identified the following significant results. Results of the analysis of data collected during the summer of 1974 demonstrate that the ERTS Data Collection Platform (DCP) is quite responsive to changing water parameters and that this information can be successfully transmitted under all weather conditions. The monitoring of on-site probe outputs reveals a rapid response to changing water temperature, salinity, and turbidity conditions on incoming tides as the tidal salt wedge passes the probe location. The changes in water properties were corroborated by simultaneously sampling the water for subsequent laboratory analysis. Fluctuations observed in the values of salinity, conductivity, temperature and water depth over short time intervals were extremely small. Due to the nature of the probe, 10% to 20% fluctuations were observed in the turbidity values. The use of the average of the values observed during an overpass provided acceptable results. Good quality data was obtained from the satellite on each overpass regardless of weather conditions. Continued use of the DCP will help provide an indication of the accuracy of the probes and transmission system during long term use.

Klemas, V.↗

A Balanced Model for Exploration of the Terrestrial Planets: Lessons from the Lunar Experience

The Moon is the only extraterrestrial rocky body for which we have a combination of surface-selected samples, high-resolution orbital photography (Lunar Orbiter), manned and robotic surface exploration (Surveyor, Apollo, Luna), and global compositional, mineralogical, and geophysical data (Galileo, Clementine, Lunar Prospector). Beginning in 1998, CAPTEM organized a series of workshops and conference sessions aimed at integrating these diverse data sets. The insights gained by bringing together scientists from the remote-sensing and sample-analysis communities have been singularly rewarding. Not least of these has been the recognition by both groups that having both kinds of data maximizes the scientific return and permits reconciling information from diverse scales and perspectives. The 20-20 hindsight of the Lunar experience thus provides important lessons; learning from mistakes as well as successes, we can derive a sensible scientific program for Mars exploration. In this abstract, we describe examples of key information from (a) in-situ geologic investigation, (b) laboratory analysis of returned samples whose geologic context and location are known, and (c) global remote sensing of mineralogy, composition, and geophysical parameters. We then show the value of integrating these diverse data sets.

Jolliff, B. L.↗

Spectral Characterization of Organics and Carbonates in Carbonaceous Chondrites: Implications for Bennu Returned Samples

On September 24th, 2023, the OSIRIS-REx mission returned samples to Earth from the B-type asteroid (101955) Bennu, a carbon- and water-rich asteroid. The preliminary analysis of the Bennu sample shows that this asteroidal material is rich in clay and sulfide minerals, carbon (~5 wt%), and iron oxides. These preliminary results agree with remote sensing observations of Bennu by the OSIRIS-REx Visible and Infrared Spectrometer (OIVRS) instrument. Global remote sensing observations of Bennu revealed that this primitive asteroid is hydrated with a deep 3-µm band (~20%) centered at ~2.74 µm, attributed to OH in phyllosilicates and most similar CM-type carbonaceous chondrites. As part of a NASA Laboratory Analysis of Returned Samples study, we plan to analyze Bennu samples to evaluate the relationship between organic and carbonate phases and their relationship to aqueous processes on the asteroid's parent body. To that end and to constrain the evolution of carbon reservoirs during the secondary processing events (e.g., aqueous alteration) experienced by Bennu, we will use multiple analytical techniques, including reflectance spectroscopy.

Asteroid samples↗

Review of Soil Organic Carbon Measurement Protocols: A US and Brazil Comparison and Recommendation

Soil organic carbon (SOC) change influences the life-cycle assessment (LCA) calculations for globally traded bio-based products. Broad agreement on the importance of SOC measurement stands in contrast with inconsistent measurement methods. This paper focuses on published SOC research on lands managed for maize ( Zea mays L.) in the U.S. and sugarcane ( Saccharum officinarum L.) in Brazil. A literature review found that reported SOC measurement protocols reflect different sampling strategies, measurement techniques, and laboratory analysis methods. Variability in sampling techniques (pits versus core samples), depths, increments for analysis, and analytical procedures (wet oxidation versus dry combustion) can influence reported SOC values. To improve consistency and comparability in future SOC studies, the authors recommend that: (a) the methods applied for each step in SOC studies be documented; (b) a defined protocol for soil pits or coring be applied; (c) samples be analyzed at 10 cm intervals for the full rooting depth and at 20 cm intervals below rooting until reaching 100 cm; (d) stratified sampling schemes be applied where possible to reflect variability across study sites; (e) standard laboratory techniques be used to differentiate among labile and stable SOC fractions; and (f) more long-term, diachronic approaches be used to assess SOC change. Here, we conclude with suggestions for future research to further improve the comparability of SOC measurements across sites and nations.

54 ENVIRONMENTAL SCIENCES↗

Sampling and Analysis Plan for Investigation of Undeclared Nuclear Activities - 20104

The nuclear-centered energy policy in South Korea is moving towards a nuclear-free era. It also facilitates an action or progress on the denuclearization of the Korean peninsula. The Nuclear Safety and Security Commission (NSSC) launched a new R and D project which attempts to verify nuclear activities via analyzing environmental samples. Environmental samples possibly contain significant radiological information relevant to past undeclared activities. In order to precisely verify them, it is essential to provide 1) the concrete information of target facilities, 2) appropriate methodologies and procedures, and 3) well-suited instrumentation and equipment corresponding to sample signatures. It is also important to provide scientific reliability or validity in any process such as sample collection, handling, transportation and laboratory analysis. Therefore, the information of nuclear facilities (fuel fabrication plant, graphite moderated reactor, reprocessing plant) in North Korea are reviewed in order to determine parameters for appropriate sampling methods representing a facility's characteristics. Secondly, a sampling procedure for radioactive elements is being developed based on international and domestic standards such as ASTM (American Society for Testing and Materials), KS (Korean industrial Standards), and International Atomic Energy Agency (IAEA) manuals. The procedure contains some specific information including sampling process, sampling tools, amount of sample, sample identification, and other related information. Developing the qualified national guidelines is most important since sampling and analyzing results can be used as evidences of nuclear activities. The guideline developed through this work will clearly define various methodologies such as document verification, sampling procedures, collection methods, sample storage criteria, chain of custody, and transportation conditions. The final objective of this work is to establish the infrastructure and regulatory framework for assessment of nuclear activities, and provide a national guideline for sampling and analysis. This will bring confidence in the results and play a critical role in complete denuclearization progress in South Korea. (authors)

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Light Isotopes and Trace Organics Analysis of Mars Samples with Mass Spectrometry

Precision measurement of light isotopes in Mars surface minerals and comparison of this isotopic composition with atmospheric gas and other, well-mixed reservoirs such as surface dust are necessary to understand the history of atmospheric evolution from a possibly warmer and wetter Martian surface to the present state. Atmospheric sources and sinks that set these ratios are volcanism, solar wind sputtering, photochemical processes, and weathering. Measurement of a range of trace organic species with a particular focus on species such as amino acids that are the building blocks of terrestrial life are likewise important to address the questions of prebiotic and present or past biological activity on Mars. The workshop topics "isotopic mineralogy" and "biology and pre-biotic chemistry" will be addressed from the point of view of the capabilities and limitations of insitu mass spectrometry (MS) techniques such as thermally evolved gas analysis (TEGA) and gas chromatography (GC) surface experiments using MS, in both cases, as a final chemical and isotopic composition detector. Insitu experiments using straightforward adaptations of existing space proven hardware can provide a substantial improvement in the precision and accuracy of our present knowledge of isotopic composition both in molecular and atomic species in the atmosphere and those chemically bound in rocks and soils. Likewise, detection of trace organic species with greatly improved sensitivity from the Viking GCMS experiment is possible using gas enrichment techniques. The limits to precision and accuracy of presently feasible insitu techniques compared to laboratory analysis of returned samples will be explored. The insitu techniques are sufficiently powerful that they can provide a high fidelity method of screening samples obtained from a diverse set of surface locations such as the subsurface or the interior of rocks for selection of those that are the most interesting for return to Earth.

Mahaffy, P.↗

Continuous Water Quality Sensing for FGD Wastewater

The coal fired plant power industry requires new solutions for on-line monitoring of flue gas desulfurization (FGD) wastewaters for regulated trace metals to reduce recurring operating and off-site laboratory analysis costs and provide a high level of confidence of compliance with state and federal discharge guidelines. The University of Alabama at Birmingham (UAB) developed an integrated water sensor package for continuous water quality monitoring of flue gas desulfurization (FGD) wastewaters for concentration measurements of Selenium (Se). UAB utilized a diverse team of University Professors/Staff Members/Student(s) (Engineering and Innovative Technology Development Group), a University Affiliated Research Institution from the local area (Southern Research), and a cost sharing Industry Partner (Metrohm). The team developed and validated a proprietary wet chemistry batch process for water sample preparation; and implemented this process as a fully automated on-line monitor prototype system. This prototype system’s performance was evaluated in both the laboratory and during in-field deployment to a coal fired power plant. In both environments it was found that the prototype system was unable to recreate the batch process’s success at preparing FGD water samples for total Se measurements with a commercial-off-the-shelf (COTS) cyclic anodic stripping voltammetry (CSV) system. Through this experience, UAB has provided insight into a number of specific areas where improvements can be made with respect to the COTS systems used in this project to yield a more complete and competitive industry solution for on-line monitoring of total Se in industrial wastewater.

20 FOSSIL-FUELED POWER PLANTS↗

Continuous Water Quality Sensing for FGD Wastewater

The coal fired plant power industry requires new solutions for on-line monitoring of flue gas desulfurization (FGD) wastewaters for regulated trace metals to reduce recurring operating and off-site laboratory analysis costs and provide a high level of confidence of compliance with state and federal discharge guidelines. The University of Alabama at Birmingham (UAB) developed an integrated water sensor package for continuous water quality monitoring of flue gas desulfurization (FGD) wastewaters for concentration measurements of Selenium (Se). UAB utilized a diverse team of University Professors/Staff Members/Student(s) (Engineering and Innovative Technology Development Group), a University Affiliated Research Institution from the local area (Southern Research), and a cost sharing Industry Partner (Metrohm). The team developed and validated a proprietary wet chemistry batch process for water sample preparation; and implemented this process as a fully automated on-line monitor prototype system. This prototype system’s performance was evaluated in both the laboratory and during in-field deployment to a coal fired power plant. In both environments it was found that the prototype system was unable to recreate the batch process’s success at preparing FGD water samples for total Se measurements with a commercial-off-the-shelf (COTS) cyclic anodic stripping voltammetry (CSV) system. Through this experience, UAB has provided insight into a number of specific areas where improvements can be made with respect to the COTS systems used in this project to yield a more complete and competitive industry solution for on-line monitoring of total Se in industrial wastewater.

01 COAL, LIGNITE, AND PEAT↗