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NASA NTRS1993

Software Products

MAST is a decision support system to help in the management of dairy herds. Data is collected on dairy herds around the country and processed at regional centers. One center is Cornell University, where Dr. Lawrence Jones and his team developed MAST. The system draws conclusions from the data and summarizes it graphically. CLIPS, which is embedded in MAST, gives the system the ability to make decisions without user interaction. With this technique, dairy managers can identify herd problems quickly, resulting in improved animal health and higher milk quality. CLIPS (C Language Integrated Production System) was developed by NASA's Johnson Space Center. It is a shell for developing expert systems designed to permit research, development and delivery on conventional computers.

Source record↗
NASA NTRS2002

Irradiated HMEC from A-T Heterozygous Breast Tissue

Women who are heterozygous for ataxia-telangiectasia (A-T) carry a single defective ATM gene in chromosome 11 q22-23, and have been statistically determined with high significance within a defined database to be approximately 5-fold more susceptible for developing breast cancer than their noma1 counterpart. Breast cancer susceptibility of these A-T heterozygotes has been hypothesized to include consequence of response to damage caused by low levels of ionizing radiation. Prophylactic mastectomy specimens were donated by a 41 year-old obligate A-T heterozygote who was located prior to her elective surgery through an existing pedigree. Harvest of that breast tissue provided an isolate of long-term growth human mammary epithelial cells (HMEC), designated WH612/3. An isolate of presumed normal long-term growth HMEC, designated 48R, was obtained from Dr. Martha Stampfer (Lawrence Berkeley Laboratory, University of California), and the A-T heterozygous HMEC were transformed with E6 and E7 oncogenes of human papilloma virus Type-16 in the laboratory of Dr. Ray White (Hunt- Cancer Institute, University of Utah) for use in this study. The objective of this study is to study the expression of end points that may bear on cancer outcome following irradiation of HMEC. Specific end points are cell survival, cell cycle, p53 expression, and apoptosis. Survival curves, immunostaining, and flow cytometery are used to examine these end points. Radiation-induced cell killing shows less shoulder development in the survival curve for WH61U3 compared to 48R HMEC, suggesting less repair of damage in the former HMEC. Additional information is included in the original extended abstract.

Richmond, Robert↗
NASA NTRS2002

Reactive Carbon from Life Support Wastes for Incinerator Flue Gas Cleanup

This paper presents the results from a joint research initiative between NASA Ames Research Center and Lawrence Berkeley National lab. The objective of the research is to produce activated carbon from life support wastes and to use the activated carbon to adsorb and chemically reduce the NO(sub x) and SO(sub 2) contained in incinerator flue gas. Inedible biomass waste from food production is the primary waste considered for conversion to activated carbon. Results to date show adsorption of both NO(sub x) and SO(sub 2) in activated carbon made from biomass. Conversion of adsorbed NO(sub x) to nitrogen has also been observed.

Fisher, J. W.↗
NASA NTRS2002

An Illumination Modeling System for Human Factors Analyses

Seeing is critical to human performance. Lighting is critical for seeing. Therefore, lighting is critical to human performance. This is common sense, and here on earth, it is easily taken for granted. However, on orbit, because the sun will rise or set every 45 minutes on average, humans working in space must cope with extremely dynamic lighting conditions. Contrast conditions of harsh shadowing and glare is also severe. The prediction of lighting conditions for critical operations is essential. Crew training can factor lighting into the lesson plans when necessary. Mission planners can determine whether low-light video cameras are required or whether additional luminaires need to be flown. The optimization of the quantity and quality of light is needed because of the effects on crew safety, on electrical power and on equipment maintainability. To address all of these issues, an illumination modeling system has been developed by the Graphics Research and Analyses Facility (GRAF) and Lighting Environment Test Facility (LETF) in the Space Human Factors Laboratory at NASA Johnson Space Center. The system uses physically based ray tracing software (Radiance) developed at Lawrence Berkeley Laboratories, a human factors oriented geometric modeling system (PLAID) and an extensive database of humans and environments. Material reflectivity properties of major surfaces and critical surfaces are measured using a gonio-reflectometer. Luminaires (lights) are measured for beam spread distribution, color and intensity. Video camera performances are measured for color and light sensitivity. 3D geometric models of humans and the environment are combined with the material and light models to form a system capable of predicting lighting conditions and visibility conditions in space.

Huynh, Thong↗
NASA NTRS2002

Formation of Brown Dwarfs LTSA 2001

The goals of the work funded by this grant are: (1) The measurement of the mass function and minimum mass of free-floating brown dwarfs down to the mass of Jupiter; (2) The measurement of the frequency of wide brown dwarf and planetary companions down to the mass of Jupiter as function of primary mass (0.02-2 Msun), age (1-10 Myr), and environment (clusters vs. dispersed regions). For the first objective, we have completed the design of guaranteed SIRTF observations of nearby star-forming regions and now await the launch of the mission in April 2003. In support of these upcoming observations, in the fall of 2002 we obtained optical spectroscopy at the MMT and the 1.5-meter telescope at Fred Lawrence Whipple Observatory for candidate young low-mass stars and brown dwarfs in the IC348 and Taurus star-forming regions. Two papers that include these data in new measurements of the mass functions in these regions are near completion and will be submitted for publication to the Astrophysical Journal in January. We have also proposed deep optical and near-IR imaging of the SIRTF fields in the IC348, Chamaeleon, and Ophiuchus star-forming regions with the MMT, Magellan, and Gemini North telescopes in early 2003. For the second objective, we have used deep HST WFPC2 images to search for young giant planets and brown dwarfs around approximately 100 low-mass stars and brown dwarfs in the nearby cluster IC 348. We have completed all data reduction and have checked these data for candidate companions. We are in the process of writing a paper that describes these candidate companions and presents the companion detection limits that were achieved with HST. We will attempt followup spectroscopy of the most promising candidate companions to confirm their nature as cool companions rather than background field stars during the commissioning of the facility adaptive optics system for the Gemini North telescope early in 2003. In addition, in SIRTF guaranteed time observations we plan to search for wide substellar companions (greater than 10 inches) around the youngest nearby field stars (ages of 30-100 Myr, d less than 30 pc). We have proposed to use Keck adaptive optics imaging to search these same stars for close-in planets and brown dwarfs at 0.1-l0 inches, which will perfectly complement our SIRTF observations.

Luhman, Kevin L.↗
NASA NTRS2001

Reflection Grating Array Associated with the Reflection Grating Spectrometer Developed by the Space Research Organization of the Netherlands for the X-ray Multi-Mirror Mission (XMM)

The University of California, Berkeley (UCB) served as the Principal Investigator institution for the United States participation in the development of the Reflection Grating Spectrometer (RGS) which included the design, development, fabrication, and testing of the Reflection Grating Assembly (RGA). UCB was assisted in this role by the Lawrence Livermore National Laboratory and Columbia University who provided the primary facilities, materials, services and personnel necessary to complete the development. UC Berkeley's Dr. Steven Kahn provided the technical and scientific oversight for the design. development and testing of the RGA units by monitoring the performance of the units at various stages in their development. Dr. Kahn was also the primary contact with the Space Research Organization of the Netherlands (SRON) and represented the RGA development at all SRON and European Space Agency (ESA) reviews of the RGA status. In accordance with the contract, the team designed and developed novel optical technology to meet the unique requirements of the RGS. The ESA XMM-Newton Mission carries two identical Reflection Grating Spectrometers (RGS) behind two of its three nested sets of Wolter I type mirrors. The instrument allows high-resolution measurements in the soft X-ray range (6 to 38 angstroms or 2.1 to 0.3 keV) with a maximum effective area of about 140 sq cm at 15 angstroms. Its design is optimized for the detection of the K-shell transitions of carbon, nitrogen, oxygen, neon, magnesium, and silicon. as well as the L shell transitions of iron. The RGA itself consists of two units. A structure for each unit was designed to hold up to 220 gratings. In its final configuration, one unit holds 182 gratings and the second hold 181 gratings.

Kahn, Steven M.↗
NASA NTRS2003

Spectral Diagnostics of Galactic and Stellar X-Ray Emission from Charge Exchange Recombination

The proposed research uses the electron beam ion trap at the Lawrence Livermore National Laboratory to study the X-ray emission from charge-exchange recombination of highly charged ions with neutral gases. The resulting data fill a void in the existing experimental and theoretical data and are needed to explain all or part of the observed X-ray emission from the Galactic Ridge, solar and stellar winds, the Galactic Center, supernova ejecta, and photoionized nebulae.

Wargelin, B.↗
NASA NTRS2003

A Climatology of Tropospheric CO over the Central and Southeastern United States and the Southwestern Pacific Ocean Derived from Space, Air, and Ground-based Infrared Interferometer Spectra

This final report summarizes all research activities and publications undertaken as part of NASA Atmospheric Chemistry and Modeling Analysis Program (ACMAP) Grant NAG-1-2022, 'A Climatology of Tropospheric CO over the Central and Southeastern United States and the Southwestern Pacific Ocean Derived from Space, Air, and Ground-based Infrared Interferometer Spectra'. Major project accomplishments include: (1) analysis of more than 300,000 AERI spectra from the ARM SGP site yielding a 5-year (1998-2002) timeseries of CO retrievals from the Lamont, OK AERI; (2) development of a prototype CO profile retrieval algorithm for AERI spectra; (3) validation and publication of the first CO retrievals from the Scanning High-resolution Interferometer Sounder (SHIS); and (4) development of a prototype AERI tropospheric O3 retrieval algorithm. Compilation and publication of the 5-year Lamont, OK timeseries is underway including a new collaboration with scientists at the Lawrence Berkeley National Laboratory. Public access to this data will be provided upon article submission. A comprehensive CO analysis of the archive of HIS spectra of remains as the only originally proposed activity with little progress. The greatest challenge faced in this project was motivating the University of Wisconsin Co-Investigators to deliver their archived HIS and AERIOO data along with the requisite temperature and water vapor profiles in a timely manner. Part of the supplied HIS dataset from ASHOE may be analyzed as part of a Master s Thesis under a separate project. Our success with the SAFARI 2000 SHIS CO analysis demonstrates the utility of such aircraft remote sensing data given the proper support from the instrument investigators. In addition to the PI and Co-I s, personnel involved in this CO climatology project include one Post Doctoral Fellow, one Research Scientist, two graduate students, and two undergraduate students. A total of fifteen presentations regarding research related to this project were delivered at eleven different scientific meetings. Thus far, three publications have resulted from this project with another five in preparation. No subject inventions resulted from this research project.

McMillian, W. Wallace↗
NASA NTRS2002

Emission Line Spectra in the Soft X-ray Region 20 - 75 Angstroms

As part of a project to complete a comprehensive catalogue of astrophysically relevant emission lines in support of new-generation X-ray observatories using the Lawrence Livermore electron beam ion traps EBIT-I and EDIT-II, emission lines of argon and sulfur in the soft X-ray and extreme ultraviolet region were studied. Observations of Ar IX through Ar XVI and S VII through S XIV between 20 and 75 Angstrom are presented to illustrate our work.

Lepson, J. K.↗
NASA NTRS2002

Laboratory Study of the Diagnostic Utility of the 3C/3D Line Ratio in Fe XVII

Fe XVII X-ray emission is present in a multitude of sources, such as the corona of the Sun, Capella, and Procyon. Two of the strongest lines observed in these spectra are the resonance and intercombination lines located at 15.01 and 15.26 A, respectively. As part of the laboratory astrophysics program at the electron beam ion traps EBIT-I & EBIT-II located at the Lawrence Livermore National Laboratory we have measured this line ratio for the case where the relative abundance of Fe XVI to Fe XVII is approx. 1. Our results show that an Fe XVI innershell satellite line coincides with the intercombination line and can significantly reduce the relative intensity, R, of the resonance to intercombination line. The fact that the apparent relative intensity of the resonance and intercombination line in Fe XVII is sensitive to the strength of an Fe XVI innershell satellite, and therefore, tho relative abundance of Fe XVI to Fe XVII, makes the line ratio a diagnostic of temperature, and explains the anomalously low ratios observed in the solar and stellar coronae.

Brown, G. V.↗
NASA NTRS2002

Laboratory Astrophysics at the LLNL Electron Beam Ion Traps: EBIT-I and EBIT-II

In order to provide a complete, accurate set of atomic data for interpreting spectra provided by missions such as XMM-Newton, the Chandra X-Ray Observatory, and Astro-E2, we have harnessed the Lawrence Livermore National Laboratory's electron beam ion traps EBIT-I. EBIT-II, and Super-EBIT for laboratory astrophysics. In support of this work we have developed a number of unique techniques, including the ability to experimentally simulate a Maxwellian distribution of electron energies and measuring low-energy charge exchange cross sections using the magnetic trapping mode. We have also built and operated a full suite of spectrometers spanning the 1-7000 Angstrom wavelength band, the most recent being a spectrometer based on a spare Astro-E (6 x 6) microcalorimeter array. Results of our efforts include a complete list of wavelengths of the Fe L-shell transitions, measurements of absolute and relative cross sections for direct impact, dielectronic, and resonance excitation, and measurements of low energy charge transfer reactions. A brief overview of the LLNL ebit facility, its capabilities, and some results will be discussed.

Brown, G. V.↗
NASA NTRS2003

The Solar Chromosphere/Corona Interface: FUV-EUV Observations and Modeling of Unresolved Coronal Funnels - I

A coronal funnel model, developed by Rabin (199l), was tested against a calibrated spectroheliogram recorded in 171 - 175 Angstrom bandpass. This image was recorded on board a sounding rocket experiment flown on 1994 November 3, called the Multi-Spectral Solar Telescope Array, II (MSSTA II), MSSTA, a joint project of Stanford University, the NASA Marshall Space Flight Center and the Lawrence Livermore National Laboratory, is an observing platform composed of a set of normal-incidence, multilayer-coated optics designed to obtain narrow bandpass, high resolution images (1 - 3 arc sec) at selected FUV, EUV and soft X-ray wavelengths (44 Angstroms - 1550 Angstroms). Using full-disk images centered at 1550 Angstroms (C IV) and 173 Angstroms (FE IX/X), the funnel model, which is based on coronal back-heating, was tested against the data incorporating observed constraints on global coverage and measured flux. Found, was a class of funnel models that could account for the quiescent, globally diffuse and unresolved emission seen in the 171 - 175 Angstrom bandpass, where the funnels are assumed to be rooted in the C IV supergranular network. These models, when incorporated with the Chianti spectral code, suggest that this emission is mostly of upper transition region origin and primarily composed of FE IX plasma. The funnels are found to have constrictions, Gamma approx. 6 - 20, which is in good agreement with the observations. Further, the fitted models simultaneously satisfy global areal constraints seen in both images; namely, that a global network of funnels must cover approx. 70 - 95 % of the total solar surface area seen in the 171 - 175 Angstrom image, and = 45 % of the disk area seen in the 1550 Angstrom bandpass. These findings support the configuration of the EUV magnetic network as suggested by Reeves et af. (1974) and put forth in more detail by Gabriel (1976). Furthermore, the models are in good agreement with differential emission measure estimates made of the transition region by Raymond & Doyle (1981) for temperatures, 250,000 K = T = 650,000 K, based on full-disk observations made on board by SkyLab.

Martinez-Galarce, D. S.↗
NASA NTRS2003

Formation of Brown Dwarfs LTSA 2001

The goals of the work funded by this grant are: 1) The measurement of the mass function and minimum mass of free-floating brown dwarfs down to the mass of Jupiter; 2) The measurement of the frequency of wide brown dwarf and planetary companions down to the mass of Jupiter as function of primary mass (0.02-2 Msun), age (1-10 Myr), and environment (clusters vs. dispersed regions). For the first objective, we have completed the design of guaranteed SIRTF observations of nearby star-forming regions. With the successful launch of the SIRTF mission in August of 2003, we now await the execution of these observations, which should begin in early 2004. In support of these upcoming observations, in the fall of 2002 and spring of 2003 we obtained optical spectroscopy at the MMT, the 1.5 meter telescope at Fred Lawrence Whipple Observatory, and Magellan Observatory for several hundred candidate young low-mass stars and brown dwarfs in the IC348, Taurus, and Chamaeleon star-forming regions. All of these data have been published in three papers in The Astrophysical Journal. We also recently used the MMT to obtain deep near-IR images of IC348 to accompany the SIRTF images and have time in the next month at the IRTF and Keck for spectroscopy of candidate brown dwarfs in IC348 and Taurus. We have submitted proposals for deep optical and near-IR imaging of the SIRTF fields in Chamaeleon and Ophiuchus for spring 2004 with Magellan and the AAT. Results from this research have been presented in invited talks at UU Symposium 221 (July 2003) and at the SIRTF Galactic Science Workshop (August 2003). For the second objective, we have used deep HST WFPC2 images to search for young giant planets and brown dwarfs around approx. 100 low-mass stars and brown dwarfs in the nearby cluster IC348. We have completed all data reduction and have checked these data for candidate companions. We expect to submit the paper describing these observations to The Astrophysical Journal by the end of the year. In addition, in SIRTF guaranteed time observations we plan to search for wide substellar companions (>10 sec) around the youngest nearby field stars (ages of 30-100 Myr, d<30 pc). We have submitted a proposal to use Keck adaptive optics imaging to search these same stars for close-in planets and brown dwarfs at 0.1-10 sec, which will perfectly complement our SIRTF observations.

Luhman, Kevin L.↗
NASA NTRS2004

From Runway to Orbit: Reflections of a NASA Engineer

In his remarkable memoir Runway to Orbit, Dr. Kenneth W. Iliff - the recently retired Chief Scientist of the NASA Dryden Flight Research Center- tells a highly personal, yet a highly persuasive account of the last forty years of American aeronautical research. His interpretation of events commands respect, because over these years he has played pivotal roles in many of the most important American aeronautics and spaceflight endeavors. Moreover, his narrative covers much of the second half of the first 100 years of flight, a centennial anniversary being celebrated this year. aerospace knowledge. He arrived at the then NASA Flight Research Center in 1962 as a young aeronautical engineer and quickly became involved in two of the seminal projects of modern flight, the X-15 and the lifting bodies. In the process, he pioneered (with Lawrence Taylor) the application of digital computing to the reduction of flight data, arriving at a method known as parameter estimation, now applied the world over. Parameter estimation not only enabled researchers to acquire stability and control derivatives from limited flight data, but in time allowed them to obtain a wide range of aerodynamic effects. Although subsequently involved in dozens of important projects, Dr. Iliff devoted much of his time and energy to hypersonic flight, embodied in the Shuttle orbiter (or as he refers to it, the world s fastest airplane). To him, each Shuttle flight, instrumented to obtain a variety of data, represents a research treasure trove, one that he has mined for years. This book, then, represents the story of Dr. Ken Iliff s passion for flight, his work, and his long and astoundingly productive career. It can be read with profit not just by scientists and engineers, but equally by policy makers, historians, and journalists wishing to better comprehend advancements in flight during the second half of the twentieth century. Dr. Iliff's story is one of immense contributions to the nation s repository of

Iliff, Kenneth W.↗
NASA NTRS2004

Comparison of the Proton-Induced Dark Current and Charge Transfer Efficiency Responses of N- and P-Channel CCDs

The proton-induced CTE behavior for the Lawrence Berkeley National Laboratory (LBNL) p-CCD (being developed for the Supernovae Acceleration Project (SNAP) and Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3) n-CCDs were compared using 55Fe, EPER and FPR techniques. CTE performance of the p-CCD is about an order of magnitude better after a 63 MeV fluence of 2.5 x 10(sup 9)/sq cm, which is equivalent to 2.5 years in the shielded HST orbit. Notched n- and p-CCDs yielded factor of two improvement in CTE performance as compared to their un-notched versions. The introduction rate of hot pixels was greater in p-CCD as compared to n-CCD, and also greater in notched than un-notched devices.

Marshall, Cheryl↗
NASA NTRS2003

The Solar Chromosphere/Corona Interface. I. Far-Ultraviolet to Extreme-Ultraviolet Observations and Modeling of Unresolved Coronal Funnels

A coronal funnel model, developed by D. Rabin, was tested against a calibrated spectroheliogram recorded in the 170-1 75 A bandpass. This image was recorded on board a sounding-rocket experiment flown on 1994 November 3, called the Multi-Spectral Solar Telescope Array II (MSSTA II). MSSTA, a joint project of Stanford University, the NASA Marshall Space Flight Center, and the Lawrence Livermore National Laboratory' is an observing platform composed of a set of normal-incidence, multilayer-coated optics designed to obtain narrow-bandpass, high-resolution images (1 sec.- 3 sec.) at selected far-ultraviolet (FUV), extreme-ultraviolet (EUV), and soft X-ray wavelengths (44-1550 A). Using full disk images centered at 1550 A (C IV) and 173 A (Fe IX/X), the funnel model, which is based on coronal back-heating, was tested against the data incorporating observed constraints on global coverage and measured flux. Found was a class of funnel models that could account for the quiescent, globally diffuse and unresolved emission seen in the 171-175 A bandpass, where the funnels are assumed to be rooted in the C IV supergranular network. These models, when incorporated with the CHIANTI spectral code, suggest that this emission is mostly of upper transition region origin and primarily composed of Fe IX plasma. The funnels are found to have constrictions, Gamma approx. 6-20, which is in good agreement with the observations. Further, the fitted models simultaneously satisfy global areal constraints seen in both images; namely,that a global network of funnels must cover approx. 700 - 95% of the total solar surface area seen in the 171-175 A image, and a 5% of the disk area seen in the 1550 A bandpass. These findings support the configuration of the EUV magnetic network as suggested by Reeves et al. and put forth in more detail by Gabriel. Furthermore, the models are in good agreement with differential emission measure estimates made of the transition region by J. C. Raymond & J. G. Doyle for temperatures 250,000 K less than or = T less than or = 650,000 K, based on full-disk observations made on board Skylab.

Martinez-Galarce, Dennis S.↗
NASA NTRS2001

Physical and biological studies with protons and HZE particles in a NASA supported research center in radiation health

NASA has established and supports a specialized center for research and training (NSCORT) to specifically address the potential deleterious effects of HZE particles on human health. The NSCORT in radiation health is a joint effort between Lawrence Berkeley National Laboratory (LBNL) and Colorado State University (CSU). The overall scope of research encompasses a broad range of subjects from microdosimetric studies to cellular and tissue responses to initial damage produced by highly energetic protons and heavy charged particles of the type found in galactic cosmic rays (GCR) spectrum. The objectives of the microdosimetry studies are to determine the response of Tissue Equivalent Proportional Counter (TEPC) to cosmic rays using ground based accelerators. This includes evaluation of energy loss due to the escape of high-energy delta rays and increased energy deposition due to the enhanced delta ray production in the wall of the detector. In this report major results are presented for 56Fe at 1000, 740, 600 and 400 MeV/nucleon. An assessment of DNA repair and early development of related chromosomal changes is extremely important to our overall understanding of enhanced biological effectiveness of high LET particle radiation. Results are presented with respect to the fidelity of the rejoining of double strand breaks and the implications of misrejoining. The relationship between molecular and cytogenetic measurements is presented by studying damage processing in highly heterochromatic supernumerary (correction of sypernumerary) X chromosomes and the active X-chromosome. One of the important consequences of cell's inability to handle DNA damage can be evaluated through mutation studies. Part of our goal is the assessment of potential radioprotectors to reduce the mutation yield following HZE exposures, and some promising results are presented on one compound. A second goal is the integration of DNA repair and mutation studies. Results are presented on a direct comparison of initial double strand breaks induction, the time course and fidelity of double strand break rejoining, cell killing and mutation induction in the same human model system. In order to understand the carcinogenic potential of protons and HZE particles, the role of damaged microenvironment in this process must be understood. In this project it has been postulated that radiation affects the microenvironment, which then modifies cell interactions in a manner conducive to neoplastic progression. Both TGF-beta and FGF-2 are important components of microenvironment. A recent result on the assessment of the role of FGF-2 and its cross-talk with TGF-beta as a function of radiation quality is presented. Theoretical modeling has so far played a central role in analyzing and integrating experimental data on repair and mutation studies and predicting new phenomena. The integrated NSCORT program also provides a broad training experience for students and postdoctoral fellows in space radiation health.

NASA Discipline Radiation Health↗
NASA NTRS2004

Modeling of Isotope Fractionation in Stratospheric CO2, N2O, CH4, and O3: Investigations of Stratospheric Chemistry and Transport, Stratosphere-Troposphere Exchange, and Their Influence on Global Isotope Budgets

We investigated the isotopic fractionation of CH4 and hydrogen (H2) in the stratosphere by incorporating isotope-specific rate coefficients into the Lawrence Livermore National Laboratory (LLNL) 2D model and comparing the model results with new observations from the NASA ER-2 aircraft (funded through a separate task under the Upper Atmosphere Research Program). The model results reveal that fractionation which occurs in the stratosphere has a significant influence on isotope compositions in the free troposphere, an important point which had previously been ignored, unrecognized or unquantified for many long-lived trace gases, including CH4 and H2 which we have focused our efforts on to date. Our analyses of the model results and new isotope observations have also been used to test how well the kinetic isotope effects are known, at least to within the uncertainties in model chemistry and transport. Overall, these results represent an important step forward in our understanding of isotope fractionation in the atmosphere and demonstrate that stratospheric isotope fractionation cannot be ignored in modeling studies which use isotope observations in the troposphere to infer the global budgets of CH4 (an important greenhouse gas) and of H2 (a gas whose atmospheric budget must be better quantified, particularly before a large human perturbation from fuel cell use is realized). Our analyses of model results and observations from the NASA ER-2 aircraft are briefly summarized separately below for CH4, H2, and H2O and for the contribution of these modeling studies to date to our understanding of isotope fractionation for N2O, CO2, and O3 as well.

Boering, Kristie A.↗