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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

A Decade of Salt Marsh Elevation Change in New York City’s Coastal Urban Parks

Coastal salt marshes of the eastern United States are particularly vulnerable to accelerated sea level rise, and urban marshes are at greater risk of erosion, inundation, and conversion to mudflat if left unmanaged. To guide New York City (NYC) salt marsh restoration strategies, NYC Parks collected up to 10 years of salt marsh elevation change data through 2020 at six salt marsh sites using the Surface Elevation Table-Marker Horizon (SET-MH) method, conducted a salt marsh trends analysis to determine shoreline change from 1974 to 2012, and conducted a salt marsh conditions assessment. We found that the citywide average surface elevation trend of 3.31 mm yr −1 was not significantly different from the 30-year (1990–2020) Relative Sea Level Rise of 4.23 mm yr −1 at The Battery, NY, tide station, probably due to high variability across and within sites. We also found that accretion rates differed across sites and watersheds, and sites situated lower in the tidal zone had higher accretion rates. Notably, Jamaica Bay’s Idlewild salt marsh, long suspected of being sediment-starved and ranking lowest in our conditions assessment, had the highest accretion rate at 9.5 mm yr −1 . Our salt marsh trends analysis also showed marsh loss at the shoreline edge, bare ground cover, and other indicators of marsh degradation. In mitigating marsh loss, the design grades for our recent wetland restoration projects enlarge the upper elevation ranges of the low- and high-marsh zones and incorporate wider and more gradual slopes in upland transition zones to enable inland marsh migration.

Salt marsh elevation change↗

Positive Anharmonicities: The Oxonide Anion as an Example

An accurate ab initio quartic force field for the ozonide anion has been determined at the singles and doubles coupled-cluster level of theory that includes a perturbational estimate of the effects of connected triple excitations, denoted CCSD(T), using the augmented valence triple-zeta correlation consistent one-particle basis set. Convergence of the harmonic frequencies with respect to the one-particle basis set has been demonstrated by computing quadratic force fields at the CCSD(T) level using augmented valence double-zeta and quadruple-zeta basis sets. Fundamental vibrational frequencies have been determined via second-order ro-vibrational perturbation theory and also using exact variational methods. Agreement is very good, and they both show that the antisymmetric O-O stretch, v 3, possesses a positive anharmonic correction (that is, the fundamental frequency is predicted to be higher in energy than the harmonic frequency). Comparison of the O_3 and O3 quartic force fields shows that the positive anharmonic correction is the result of a particularly large F3333 symmetry internal coordinate force constant. The reasonableness of this force constant has been tested by computing both F33 and F3333 at the CCSD, CCSD(T), and CASPT2 levels of theory. A discussion of known positive anharmonicities for stretching modes is presented.

Lee, Timothy J.↗

Adaptive grid embedding for the two-dimensional Euler equations

A numerical algorithm is presented for solving the two-dimensional flux-split Euler equations using a multigrid method with adaptive grid embedding. The method uses an unstructured data set along with a system of pointers for communication on the irregularly shaped grid topologies. An explicit two-stage time advancement scheme is implemented. A multigrid algorithm is used to provide grid level communication and to accelerate the convergence of the solution to steady state. Results are presented for an NACA 0012 airfoil in a freestream with Mach numbers of 0.95 and 1.054. Excellent resolution of the shock structures is obtained with the adaptive grid embedding method with significantly fewer grid points than the comparable structured grid.

Warren, Gary P.↗

Performability evaluation of the SIFT computer

The paper deals with the models, techniques, and evaluation methods that were successfully used to test the performance of the SIFT degradable computing system. The performance of the computer plus its air transport mission environment is modeled as a random variable, taking values in a set of 'accomplishment level'. The levels are defined in terms of four attributes of total system (computer plus environment) behavior, namely safety, no change in mission profile, no operational penalties, and no economic penalties. The base model of the total system is a stochastic process, whose states describe the internal structure of SIFT and the relevant conditions of its computational environment. Base model state trajectories are related to accomplishment levels via a special function, and solution methods are then used to determine the performability of the total system for various parameters of the computer and environment.

Meyer, J. F.↗

Theoretical study of the dipole moment function of OH(X 2Pi)

A complete theoretical electric dipole moment function mu(r) is computed for OH(X 2Pi) at the full configuration-interaction (FCI) level for DZP + diffuse Gaussian basis set. The energy and dipole moment are also determined with 2d functions on oxygen at seven r values. The following methods are compared to the FCI for both the oxygen 1d and 2d basis sets: single-reference singles-plus-doubles configuration interaction (SDCI), SDCI with Davidson's correction, the coupled pair functional approach (CPF) and a modified form of CPF, CASSCF, and CASSCF-MRSDCI, and the external contracted CI(CCI) method. The dipole moments are evaluated both as an expectation value and by finite-field methods. The results support the superiority of evaluating the dipole moment as an energy derivative rather than as an expectation value.

Langhoff, Stephen R.↗

A local area computer network expert system framework

Over the past years an expert system called LANES designed to detect and isolate faults in the Goddard-wide Hybrid Local Area Computer Network (LACN) was developed. As a result, the need for developing a more generic LACN fault isolation expert system has become apparent. An object oriented approach was explored to create a set of generic classes, objects, rules, and methods that would be necessary to meet this need. The object classes provide a convenient mechanism for separating high level information from low level network specific information. This approach yeilds a framework which can be applied to different network configurations and be easily expanded to meet new needs.

Dominy, Robert↗

Aerospace engineering design by systematic decomposition and multilevel optimization

A method for systematic analysis and optimization of large engineering systems, by decomposition of a large task into a set of smaller subtasks that is solved concurrently is described. The subtasks may be arranged in hierarchical levels. Analyses are carried out in each subtask using inputs received from other subtasks, and are followed by optimizations carried out from the bottom up. Each optimization at the lower levels is augmented by analysis of its sensitivity to the inputs received from other subtasks to account for the couplings among the subtasks in a formal manner. The analysis and optimization operations alternate iteratively until they converge to a system design whose performance is maximized with all constraints satisfied. The method, which is still under development, is tentatively validated by test cases in structural applications and an aircraft configuration optimization.

Sobieszczanski-Sobieski, J.↗

Advanced reliability methods for structural evaluation

Fast probability integration (FPI) methods, which can yield approximate solutions to such general structural reliability problems as the computation of the probabilities of complicated functions of random variables, are known to require one-tenth the computer time of Monte Carlo methods for a probability level of 0.001; lower probabilities yield even more dramatic differences. A strategy is presented in which a computer routine is run k times with selected perturbed values of the variables to obtain k solutions for a response variable Y. An approximating polynomial is fit to the k 'data' sets, and FPI methods are employed for this explicit form.

Wirsching, P. H.↗

The Fraternal Twins of Quartet O4(+)

Eleven stationary geometries of quartet O4(+) have been studied by ab initio methods. The geometries were optimized at the Complete Active Space Self-Consistent Field (CASSCF) level of theory and the energies were calculated by the multiconfigurational second order pertubation method (CASPT2), using Double-Zeta Plus polarization (DZP), Triple-Zeta Plus Double Polarization (TZ2P), average Atomic Natural Orbital (ANO) (5s4p2d) and average ANO (6s5p3d2f) basis sets. The rectangular and trans-planar structures are found to be the most stable, with an energy barrier to conversion between the two at the threshold of dissociation. Both have a delocalized hole and are stable relative to separated 02 and 02(+)by 11.0 and 11.5 kcal/mol for the rectangular and the 2 trans-planar structure, respectively, compared with the experimentally deduced energy in the range of 9.2 to 10.8 kcal/mol. The adiabatic ionization potentials of 04 and 02 are computed to be 11.67 and 12.21 eV, while experimental values are 11.66 and 12.07 eV, respectively. The vibrational frequencies have been computed for all degrees of freedom at the CASSCF level of theory. Symmetry breaking is found to be a particular problem in the computation of the antisymmetric stretch frequency for the delocalized structures at the CASSCF level of theory. Attempts to rectify these problems using the restricted active space self-consistent field (RASSCF) method leads to additional difficulties, but further analysis yields insight into the symmetry breaking and problems with earlier calculations. Finally, a nonorthogonal configuration interaction (CI) calculation based on the interaction of localized CASSCF wave functions using the Complete Active Space State Interation (CASSI) method leads to a balanced treatment of the antisymmetric stretch which is free from symmetry breaking. The study explains the four most prominent absorption frequencies observed in the partially unassigned IR spectrum of O4(+) isolated in solid neon as the antisymmetric OO stretch, and the combination band of the symmetric and antisymmetric 00 stretch of both the rectangular and trans-planar structures.

Lindh, Roland↗

Bond length, dipole moment, and harmonic frequency of CO

A detailed comparison of some properties of CO is given, at the modified coupled-pair functional, single and double excitation coupled-cluster (CCSD), and CCSD(T) levels of theory (including a perturbational estimate for connected triple excitations), using a variety of basis sets. With very large one-particle basis sets, the CCSD(T) method gives excellent results for the bond distance, dipole moment, and harmonic frequency of CO. In a (6s 5p 4d 3f 2g 1h) + (1s 1p 1d) basis set, the bond distance is about 0.005a0 too large, the dipole moment about 0.005 a.u. too small, and the frequency about 6/cm too small, when compared with experimental results.

Barnes, Leslie A.↗

Theoretical study of the bonding of the first- and second-row transition-metal positive ions to methylene

The geometries of the molecules formed by the interaction of the first- and second-row transition-metal cations with methylene are optimized at the modified coupled-pair functional (MCPF) level of theory using large Gaussian basis sets, and their dissociation energies are computed employing both the MCPF and internally contracted averaged coupled-pair functional (ICACPF) methods. The computed binding energies are generally in good agreement with the available experimental results, although the calculations indicate that the experimental values for ScCH2(+), TiCH2(+), and NbCH2(+) are probably too large. The nature of the bonding in each case and trends in the bonding patterns across the transition-metal rows are discussed.

Bauschlicher, Charles W., Jr.↗

Reconciling Simulated and Observed Views of Clouds: MODIS, ISCCP, and the Limits or Instrument Simulators

The properties of clouds that may be observed by satellite instruments, such as optical depth and cloud top pressure, are only loosely related to the way clouds m-e represented in models of the atmosphere. One way to bridge this gap is through "instrument simulators," diagnostic tools that map the model representation to synthetic observations so that differences between simulator output and observations can be interpreted unambiguously as model error. But simulators may themselves be restricted by limited information available from the host model or by internal assumptions. This paper considers the extent to which instrument simulators are able to capture essential differences between MODIS and ISCCP, two similar but independent estimates of cloud properties. The authors review the measurements and algorithms underlying these two cloud climatologies, introduce a MODIS simulator, and detail data sets developed for comparison with global models using ISCCP and MODIS simulators, In nature MODIS observes less mid-level doudines!> than ISCCP, consistent with the different methods used to determine cloud top pressure; aspects of this difference are reproduced by the simulators running in a climate modeL But stark differences between MODIS and ISCCP observations of total cloudiness and the distribution of cloud optical thickness can be traced to different approaches to marginal pixels, which MODIS excludes and ISCCP treats as homogeneous. These pixels, which likely contain broken clouds, cover about 15 k of the planet and contain almost all of the optically thinnest clouds observed by either instrument. Instrument simulators can not reproduce these differences because the host model does not consider unresolved spatial scales and so can not produce broken pixels. Nonetheless, MODIS and ISCCP observation are consistent for all but the optically-thinnest clouds, and models can be robustly evaluated using instrument simulators by excluding ambiguous observations.

Ackerman, Steven A.↗

Spacecraft Cabin Ventilation Fan Research at NASA

NASA has recently made the geometry and solid model for a spacecraft cabin ventilation fan prototype available to the public via electronic file downloads from the NASA Technical Report Server. This fan can be used for research and development by many organizations. The fan is 3.5 inches in diameter, 9 inches long, and weighed 3.6 lb. The NASA Quiet Space Fan was designed to make 3.64 inches of water pressure rise at 150.3 cfm of airflow at 12,000 rpm at standard air conditions of 70ºF and 14.7 psia. The performance of the metal version of the fan was measured to be 3.48 inches of water at 150.6 cfm at design speed. A low-noise blade-vane count was chosen to try to reduce tone noise generated by this fan by cutting off the first three blade passing frequency tones. In-duct microphone array measurements indicated that the most evident tones occur for frequencies of 1800 Hz (1 BPF) and 7200 Hz (4 BPF). Using reverberant room standard testing methods, the A-weighted sound power level for the fan operating at design point conditions was measured to be 71 dBA. This report describes the current set of publicly available information for this fan. The fan was designed, optimized, and tested with tools and techniques that NASA has traditionally used for turbofan engine research. This is one way that technology developed for aerospace applications can be used more broadly, since quiet and efficient fans are needed for many ventilation systems on spacecraft, aircraft, watercraft, land vehicles, and buildings.

fan, noise, ventilation↗

Spacecraft Cabin Ventilation Fan Research at NASA

NASA has recently made the geometry and solid model for a spacecraft cabin ventilation fan prototype available to the public via electronic file downloads from the NASA Technical Reports Server. This fan can be used for research and development by many organizations. The NASA Quiet Space Fan is 8.89 cm (3.50 in) in diameter, 22.9 cm (9.00 in) long, and the metal fan weighs 1.63 kg (3.6 lbm). The fan was designed to generate a system total pressure rise of 906 Pa (3.64 inches of water) at 0.709 m3/s (150.3 cfm) of airflow at 12,000 rpm (at 21.1ºC (70ºF) and 14.7 psia). Performance measured using standardized techniques showed good agreement with design and predicted values. A low-noise blade-vane count was chosen to reduce tonal noise generated by rotor-stator interaction for the first three blade passing frequency harmonics. In-duct microphone array measurements indicated that the most evident tones occur at frequencies of 1,800 Hz (1 BPF) and 7,200 Hz (4 BPF). Using reverberant room standard testing methods, the A-weighted sound power level for the fan operating at design point conditions was measured to be 71 dBA. This report describes the current set of publicly available information for this fan. The fan was designed, optimized, and tested with tools and techniques that NASA has traditionally used for turbofan engine research. This demonstrates that technology developed for aerospace applications can be used more broadly, since quiet and efficient fans are needed for many ventilation systems in spacecraft, aircraft, watercraft, land vehicles, and buildings.

fan↗

Inferred Sea Level Prediction in the NASA GMAO Seasonal Forecasting System

Reliable predictions of sea level anomalies on seasonal timescales with lead times of 1 to 9 months may have relevance to stakeholders – for example, in the advance deployment of resources for coastal flood mitigation. Routine prediction and analysis may also highlight physical processes associated with sea level change and modeling capabilities on seasonal and other timescales. These forecasts may represent interannual changes in the seasonal slope of the ocean surface, teleconnection effects such as the El Niño/Southern Oscillation phenomenon, and variations in seasonal hydrology including precipitation and coastal runoff. Coupled atmosphere/ocean models are routinely used in the seasonal prediction of temperature anomalies, precipitation anomalies, sea ice cover, and climate indices such as the Niño3.4 predictions under the North American Multi-Model Ensemble (NMME) protocol. Within the limits of their configuration, these complex Earth-system models have a potential for depicting regional changes in oceanic column properties, including the sea surface height. Seasonal prediction models generally have no representation of long-term mass contributions from melting land ice, or changes in vertical land motion; their output may be more specifically characterized as predictions of the ocean dynamic sea level. In practice however, the sea surface height prognostic variable is substantially compromised by the forecast model response to initial conditions. Imbalances between the initial, observed hydrologic cycle and the forecast model state produce abrupt adjustments in the model sea surface height. As a result, most seasonal prediction systems employ a constraint on the globally-averaged sea surface height that is applied at each time step. This essentially renders the prognostic sea surface height variable as unserviceable. Several approaches have previously been used to retrieve sea level information from seasonal forecasts beyond the use of the sea surface height variable. Here, we extend a method of relating other prognostic values, including ocean circulation and climate indices, to observed sea level variations. We use the merged altimetry record of the NASA MEaSUREs Gridded Sea Surface Height Anomalies data set and monthly revised local reference gauge observations from the National Oceanography Centre Permanent Service for Mean Sea Level (PSMSL) to evaluate derived prognostic variables from the NASA Global Modeling and Assimilation Office subseasonal-to-seasonal system version 2.1 (GMAO S2S v2.1). We focus on results for the midlatitudes with particular emphasis on US gauge locations. As shown in previous studies, prognostic ENSO-related indices in boreal winter are well correlated with gauge observations for the US west coast, but also for other locations in the southeastern US. Other forecast climate indices such as the North Atlantic Oscillation have relations to sea level that are limited both seasonally and spatially. As expected, surface atmospheric pressure (e.g., inverse barometer effect) is found to be particularly well correlated with observed sea level. We provide a characterization of forecast skill for seasonal sea level with this method.

Richard I Cullather↗

A method for selecting an operations concept to achieve successful mission operations

A procedure is presented for mapping operations concepts into design alternatives for a data system to be used in a generic ground based control center. A set of descriptive categories are developed to characterize the operational environment that relate to responsiveness, automation, and commitment. The operations concept is then developed according to a hierarchical decomposition of a mission statement into lower-level tasks, and the interpretation of the model's output is addressed. The method permits the description of operations concepts in terms of concept categories and ranges of alternatives between those categories. The descriptive framework can provide a mechanism for analyzing competing operations concepts.

Hornstein, Rhoda S.↗

Predictability of Gaseous Impact Ignition Sensitivity from Autoignition Temperature Data

An analysis of cumulative binomial probabilities for a quantal-type test like ASTM G74 indicates that for a probability of reaction in a single trial of 0.05, the probability of obtaining zero reactions in 20 trials is only approximately 36 percent, Because the lack of precision with the ASTM G74 test logic could be potentially misleading, an investigation was conducted to determine if pneumatic impact sensitivity could be predicted more reliably from other, more precise test methods. Pneumatic impact sensitivity tests were conducted following ASTM G74, but employing more rigorous test logics; autoignition temperature tests were conducted per ASTM G72. Polytetrafluoroethylene (PTFE), Viton A, polyethylene, polyoxymethylene polyamide, and silicone were the polymers used. After a fixed number of pneumatic impact tests was performed at set pressures, a plot of reaction frequency over a 3.4 to 24.1 MPa impact pressure range indicated that PTFE, Viton A, and silicone would outperform other polymers. The 50 percent pneumatic impact reactivity level was determined with the Bruceton test method. The data obtained resulted in a strong correlation between the 50 percent reactivity level and the autoignition temperature of polymers, indicating similar ignition mechanisms.

Hirsh, David↗

Application of multigrid and adaptive grid embedding to the two-dimensional flux-split Euler equations

A numerical algorithm is presented for solving the two-dimensional flux-split Euler equations using a multigrid method with adaptive grid embedding. The method uses an unstructured data set along with a system of pointers for communication on the irregularly shaped grid topologies. An explicit two-stage time-advancement scheme is implemented. A multigrid algorithm is used to provide grid level communication and to accelerate the convergence of the solution to steady state. Results are presented for a NACA 0012 aerofoil in a free stream with a Mach number of 0.85 and an angle of attack of 1.0 degree. Excellent resolution of the shock structures is obtained with the adaptive grid embedding method with significantly fewer grid points than the comparable structured grid.

Warren, Gary P.↗