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At least 163 records · Page 9

List of Commercial and Advanced Developmental Niobium-Based Alloys of the Space Age

This report compiles a list of commercial and developmental niobium-based alloys developed during the Space Age (late 1950s through mid-1970s) for extreme-temperature applications, including rocket engine thrust chambers, hypersonic re-entry thermal protection systems, and space fission reactor loops. Niobium (Nb) was widely pursued because it provided the lowest density (~8.6 g/cc) among the primary refractory metals, a high melting temperature (~2470°C), exceptional low-temperature ductility, good formability, and compatibility with liquid alkali metals. An evaluation of physical metallurgy mechanisms, focusing on solid-solution strengthening via heavy refractory solutes (W, Mo, Ta), dual-purpose reactive solutes (Hf, Zr, Ti), and dispersion strengthening using carbides, nitrides, and oxides is presented. Additionally, the report compares Western and Soviet Union metallurgical approaches, explaining how supply chain factors and manufacturing infrastructure influenced element selection, interstitial chemistry, and alloy identification/naming conventions. Cataloging these historical alloy chemical compositions serves as a foundational reference for modern alloy additive manufacturing, thermodynamic CALPHAD modeling, and machine-learning discovery pipelines for next-generation extreme-environment niobium-based alloys.

Physical Metallurgy↗

Solution Growth of Crystals in Zero-Gravity

In a low-g environment, buoyancy driven convection effects in solution crystal growth are greatly reduced and, thus, one can study diffusion mass transport which in 1-g is masked by convective phenomena. Crystals of triglycine sulfate (TGS) will be grown aboard the Spacelab 3 mission, using a specially developed Fluids Experiments System (FES). The objectives of the experiment are: (1) to develop a technique for solution crystal growth in a low-g environment, (2) to characterize the growth environment provided by an orbiting spacecraft and to determine the influence of the environment on the growth behavior, and (3) to determine how gravity in a low-gravity environment influences the properties of a resulting TGS crystal. Single crystals of TGS have been grown using conventional low-temperature solution crystal growth method and the growth process has been extensively characterized. Various physical properties of TGS solution have been measured. Also, a unique technique of growing solution growth crystals by extracting heat at a programmed rate from the crystal through a semi-insulating sting has been developed and tested in 1-g environment.

Lal, R. B.↗

Low-frequency oscillations in radiative-convective systems

Although eastward propagation has long been considered one of the essential features of the Madden-Julian waves, recent observations have revealed a stationary or quasi-stationary component in the oscillations, particularly in measures of the diabatic heating rate. Wave-CISK theories of the low-frequency oscillations have struggled to explain the observed period and vertical structure of the waves. On the other hand, theoretical and numerical studies have shown that low-frequency waves strongly resembling the observed oscillations can be excited by specified low-frequency oscillations of the convective heating. A problem with the latter set of theories is that the cause of the oscillatory heating has not been satisfactorily explained. It is proposed here that the observed low-frequency wave motions are the response to forcing by an essentially stationary, self-excited oscillating heat source that is produced by nonlinear interactions among radiation, cumulus convection, and the surface fluxes of sensible heat and moisture. Feedback of the large-scale motions on the latent heating is not required. Results from two very different one-dimensional models are presented to support this hypothesis. The physical processes included in the models are essentially the same, that is, radiation, cumulus convection, and the surface fluxes of sensible heat and moisture; the first model is highly simplified, however, while the second includes relatively sophisticated parameterizations of all the relevant physical processes. Results from both models show low-frequency oscillations of the latent heating, temperature, and moisture. Experiments show that the oscillations are favored by a warm sea surface and weak surface wind speeds, consistent with the observed conditions over the Indian Ocean and the tropical western Pacific Ocean.

Hu, QI↗

The Formation of Solid Particles from their Gas-Phase Molecular Precursors in Cosmic Environments with NASA Ames' COSmIC Facility

We present and discuss the unique characteristics and capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for Cosmic Simulation Chamber and is dedicated to the study of molecules and ions under the low temperature and high vacuum conditions that are required to simulate interstellar, circumstellar and planetary physical environments in space. COSmIC integrates a variety of state-of-the-art instruments that allow forming, processing and monitoring simulated space conditions for planetary, circumstellar and interstellar materials in the laboratory. COSmIC is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a free jet supersonic expansion coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a Cavity Ring Down Spectroscopy (CRDS) system for photonic detection and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent, unique, laboratory astrophysics results that were obtained using the capabilities of COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid gains from their gas-phase molecular precursors in environments as varied as stellar/circumstellar outflow and planetary atmospheres. Plans for future, next generation, laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics will also be addressed as well as the implications of these studies for current and upcoming space missions.

COSmIC↗

X-Ray Amorphous Phases in Antarctica Dry Valley Soils: Insight into Aqueous Alteration Processes on Mars?

The Chemistry and Mineralogy (CheMin) instrument onboard the Mars Curiosity rover has detected abundant amounts (approx. 25-30 weight percentage) of X-ray amorphous materials in a windblown deposit (Rocknest) and in a sedimentary mudstone (Cumberland and John Klein) in Gale crater, Mars. On Earth, X-ray amorphous components are common in soils and sediments, but usually not as abundant as detected in Gale crater. One hypothesis for the abundant X-ray amorphous materials on Mars is limited interaction of liquid water with surface materials, kinetically inhibiting maturation to more crystalline phases. The objective of this study was to characterize the chemistry and mineralogy of soils formed in the Antarctica Dry Valleys, one of the driest locations on Earth. Two soils were characterized from different elevations, including a low elevation, coastal, subxerous soil in Taylor Valley and a high elevation, ultraxerous soil in University Valley. A variety of techniques were used to characterize materials from each soil horizon, including Rietveld analysis of X-ray diffraction data. For Taylor Valley soil, the X-ray amorphous component ranged from about 4 weight percentage in the upper horizon to as high as 15 weight percentage in the lowest horizon just above the permafrost layer. Transmission electron microscopy indicated that the presence of short-range ordered (SRO) smectite was the most likely candidate for the X-ray amorphous materials in the Taylor Valley soils. The SRO smectite is likely an aqueous alteration product of mica inherited from granitic materials during glaciation of Taylor Valley. The drier University Valley soils had lower X-ray amorphous contents of about 5 weight percentage in the lowest horizon. The X-ray amorphous materials in University Valley are attributed to nanoparticles of TiO2 and possibly amorphous SiO2. The high abundance of X-ray amorphous materials in Taylor Valley is surprising for one of the driest places on Earth. These materials may have been physically and chemical altered during soil formation, however, the limited interaction with water and low temperatures may result in the formation of "immature" X-ray amorphous or SRO materials. Perhaps, a similar process contributes to the formation of the high content of X-ray amorphous materials detected on Mars.

Ming, D. W.↗

Synthesis and Spectroscopy of Large Carbon Molecules with Ames' COSmIC Facility in Support of NASA's Space Missions

We present and discuss the unique characteristics and capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar and planetary analogs in the laboratory. COSmIC stands for Cosmic Simulation Chamber and is dedicated to the study of molecules and ions under the low temperature and high vacuum conditions that are required to simulate interstellar, circumstellar and planetary physical environments in space. COSmIC integrates a variety of state-of-the-art instruments that allow forming, processing and monitoring simulated space conditions for planetary, circumstellar and interstellar materials in the laboratory. COSmIC is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a free jet supersonic expansion coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a Cavity Ring Down Spectroscopy (CRDS) system for photonic detection and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent, unique, laboratory astrophysics results that were obtained using the capabilities of COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid gains from their gas-phase molecular precursors in environments as varied as stellar/circumstellar outflow and planetary atmospheres. Plans for future, next generation, laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics will also be addressed.

Spectroscopy↗

Laboratory Studies of Cosmic Dust with NASA Ames' COSmIC Facility – Applications to Interstellar and Planetary Issues

I will present and discuss the unique characteristics and capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for Cosmic Simulation Chamber and is dedicated to the study of molecules and ions under the low temperature and high vacuum conditions that are required to simulate interstellar, circumstellar and planetary physical environments in space. COSmIC integrates a variety of state-of-the-art instruments that allow forming, processing and monitoring simulated space conditions for planetary, circumstellar and interstellar materials in the laboratory. COSmIC is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a free jet supersonic expansion coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a Cavity Ring Down Spectroscopy (CRDS) system for photonic detection and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent, unique, laboratory astrophysics results that were obtained using the capabilities of COSmIC will be discussed, in particular the progress that have been achieved in deciphering the diffuse interstellar bands (DIBs) and in monitoring in the laboratory the formation of solid dust grains from their gas-phase molecular precursors in environments as varied as stellarcircumstellar outflow and planetary atmospheres. Plans for future, next generation, laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics will also be addressed as well as the implications of these studies for current and upcoming space missions.

COSmIC↗

X-ray Amorphous Materials in Soils from the Antarctica Dry Valleys: Insights into Aqueous Alteration Processes on Mars

The CheMin XRD instrument onboard the Curiosity rover has discovered abundant quantities of X-ray amorphous materials (25-40 wt. %) in windblown deposits and sedimentary rocks on Mars. The large amounts of X-ray amorphous materials on Mars is surprising because these materials are usually not found in large abundances in terrestrial soils. We have previously identified short-range ordered or X-ray amorphous materials in Antarctica Dry Valleys (ADV) soils. The ADV are one of the driest and coldest environments on Earth and provide an ideal process analog environment for Mars. The objective of this study was to further characterize the chemistry and mineralogy of ADV soils, specifically to quantify and characterize the X-ray amorphous materials. Two soils were characterized from different elevations in the ADV - a low elevation, coastal, subxerous soil in Taylor Valley and a high elevation, ultraxerous soil in University Valley. Rietveld analysis of XRD patterns generated with a CheMin-like analog instrument indicated up to 40 and 15 wt. % X-ray amorphous materials in the Taylor and University Valley soils, respectively. The high abundance of X-ray amorphous materials in Taylor Valley is surprising for one of the driest places on Earth. These materials may have been physically and chemical altered during soil formation, however, the limited interaction with water and low temperatures may have resulted in the formation of “immature” X-ray amorphous or SRO materials. Perhaps, a similar process contributes to the formation of the high content of X-ray amorphous materials detected on Mars.

Antarctica↗

Challenges in Characterizing Low-Temperature Regolith Properties

The success or failure of in-situ resource utilization for planetary surface exploration--be it for scientific, colonization or commercialization purposes--relies heavily on the ability to design and implement systems which effectively process the associated regolith and exploit its benefits. In most cases this challenge necessarily includes the characterization of low-temperature (cryogenic) properties; as many celestial destinations of interest, such as the moon, Mars and asteroids, have little or no atmosphere to help sustain the consistently "high" surface temperatures seen on planets such as Earth, and therefore can experience permanent cryogenic temperatures or dramatic cyclical changes. Characterization of physical properties (such as specific heat, thermal and electrical conductivity, etc.) over the entire temperature profile is undoubtedly an important piece of the puzzle; however, the impact on mechanical properties due to the introduction of icy deposit must also be explored in order to devise effective and robust excavation technologies. Currently the Granular Mechanics and Regolith Operations Lab and the Cryogenics Test Lab at NASA Kennedy Space Center are developing technologies and experimental methods to address these challenges and aid in the characterization of physical and mechanical properties of regolith at cryogenic temperatures. This presentation will review the current state of knowledge concerning lunar regolith at low temperature including that of icy regolith.

Cryogenics↗

The Origin of Life--Did It Occur at High Temperatures

A high-temperature origin of life has been proposed, largely for the reason that the hyperthermophiles are claimed to be the last common ancestor of modern organisms. Even if they are the oldest extant organisms, which is in dispute, their existence can say nothing about the temperatures of the origin of life, the RNA world, and organisms preceding the hyperthermophiles. There is no geological evidence for the physical setting of the origin of life because there are no unmetamorphosed rocks from that period. Prebiotic chemistry points to a low-temperature origin because most biochemicals decompose rather rapidly at temperatures of 100 C (e.g., half-lives are 73 min for ribose, 21 days for cytosine, and 204 days for adenine). Hyperthermophiles may appear at the base of some phylogenetic trees because they outcompeted the mesophiles when they adapted to lower temperatures, possibly due to enhanced production of heat-shock proteins.

Miller, Stanley L.↗

Airborne infrared low level wind shear predictor

The operating principles and test performance of an airborne IR (13-16 micron) temperature-sensing detection and warning system for low-level wind shear (LLWS) are presented. The physics of LLWS phenomena and of the IR radiometer are introduced. The cold density-current outflow or gust front related to LLWS is observed in the IR spectrum of CO2 by a radiometer with + or - 0.5-C accuracy at 0.5-Hz sampling rate; LLWS alerts are given on the basis of specific criteria. Test results from the JAWS experiments conducted at Denver in July 1982, are presented graphically and discussed. The feasibility of the passive IR system is demonstrated, with an average warning time of 51 sec, corresponding to a distance from touchdown of about 2 miles.

Kuhn, P. M.↗

Water in the Martian regolith

The state of water in the Martian regolith is addressed. The water-ice phase composition, adsorption-desorption and evaporation phenomena, and brine compositions of six antarctic soils that are considered to be good terrestrial analogues of the Martian surface materials are examined. Experiments have shown that, for temperatures below freezing and relative humidities less than 100 percent, absorbed water and vapor are the only stable phases in the regolith. When the relative humidity reaches 100 percent, ice may form and coexist with the absorbed liquid phase. The absorbed water content declines with decreasing temperature; however, the presence of dissolved solutes can result in appreciable adsorbed liquid phase at temperatures as low as 210 K. Such properties may have a profound influence on martial geomorphology, physical and chemical weathering, and the exchange of water between the atmosphere and regolith.

Anderson, Duwayne M.↗

The Role of Molecular Weight and Temperature on the Elastic and Viscoelastic Properties of a Glassy Thermoplastic Polyimide

Mechanical testing of the elastic and viscoelastic response of an advanced thermoplastic polyimide (LaRC-SI) with known variations in molecular weight was performed over a range of temperatures below the glass transition temperature. The notched tensile strength was shown to be a strong function of both molecular weight and temperature, whereas stiffness was only a strong function of temperature. A critical molecular weight was observed to occur at a weight average molecular weight of M, approx. 22,000 g/mol below which, the notched tensile strength decreases rapidly. This critical molecular weight transition is temperature-independent. Low, molecular weight materials tended to fail in a brittle manner, whereas high molecular weight materials exhibited ductile failure. Furthermore, low molecular weight materials have increased creep compliance and creep compliance rate, and are more sensitive to temperature than the high molecular weight materials. At long timescales (less than 1100 hours) physical aging serves to significantly decrease the creep compliance and creep rate of all the materials tested. Low molecular weight materials are less influenced by the effects of physical aging.

Nicholson, Lee M.↗

Adsorption Heat Pump Development At JPL

In simple sorption refrigeration system, low pressure gases are physically adsorbed onto or chemically absorbed into various solids, typically near ambient temperatures or above.

Joule-Thomson valve gases liquefied refrigeration ↗

Interstellar and Planetary Analogs in the Laboratory

We present and discuss the unique capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to investigate the interaction of ionizing radiation (UV, charged particles) with molecular species (neutral molecules, radicals and ions) and carbonaceous grains in the Solar System and in the Interstellar Medium (ISM). COSmIC stands for Cosmic Simulation Chamber, a laboratory chamber where interstellar and planetary analogs are generated, processed and analyzed. It is composed of a pulsed discharge nozzle (PDN) expansion that generates a free jet supersonic expansion in a plasma cavity coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a cavity ring down spectroscopy (CRDS) system for photonic detection and a Reflectron time-of-flight mass spectrometer (ReTOF-MS) for mass detection. This setup allows the study of molecules, ions and solids under the low temperature and high vacuum conditions that are required to simulate some interstellar, circumstellar and planetary physical environments providing new fundamental insights on the molecular level into the processes that are critical to the chemistry in the ISM, circumstellar and planet forming regions, and on icy objects in the Solar System. Recent laboratory results that were obtained using COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid particles from their gas-phase molecular precursors in environments as varied as circumstellar outflow and planetary atmospheres.

Salama, Farid↗

Computational Investigation of the Effect of Chemistry on Mars Retropropulsion Environments using a Massively Parallel GPU Approach

In this work, we investigate the effects of chemistry on a human-scale Mars lander concept using scale-resolving computational fluid dynamics (CFD) with finite-rate chemistry and a graphics processing unit (GPU)-enabled implementation of the NASA FUN3D flow solver, enabling run-times of a few days for the simulations presented. Simulations are carried out on Summit at Oak Ridge Leadership Computing Facility using thousands of GPUs. Retropropulsion ground tests require significant compromises on physical scale, instrumentation, configuration, and environments. Ground tests of retropropulsion configurations thus far have neglected effects of chemistry due to physical constraints of wind tunnel models and facilities; most experiments use inert simulant gases at low temperatures. As such, a strong reliance on high-fidelity computational analyses such as those presented in this work is required to expand the knowledge of retropropulsion aerodynamics. An overview of the GPU approach will be presented. Results are compared to a previous scaled perfect gas (air) campaign.

retropropulsion↗

Titan's Surface from Cassini RADAR SAR and High Resolution Radiometry Data of the First Five Flybys

The first five Titan flybys with Cassini's Synthetic Aperture RADAR (SAR) and radiometer are examined with emphasis on the calibration and interpretation of the high-resolution radiometry data acquired during the SAR mode (SAR-radiometry). Maps of the 2-cm wavelength brightness temperature are obtained coincident with the SAR swath imaging, with spatial resolution approaching 6 km. A preliminary calibration shows that brightness temperature in these maps varies from 64 to 89 K. Surface features and physical properties derived from the SAR-radiometry maps and SAR imaging are strongly correlated; in general, we find that surface features with high radar reflectivity are associated with radiometrically cold regions, while surface features with low radar reflectivity correlate with radiometrically warm regions. We examined scatterplots of the normalized radar cross-section sigma(exp o) versus brightness temperature, finding differing signatures that characterize various terrains and surface features. Implications for the physical and compositional properties of these features are discussed. The results indicate that volume scattering is important in many areas of Titan's surface, particularly Xanadu, while other areas exhibit complex brightness temperature variations consistent with variable slopes or surface material and compositional properties.

Titan↗

A Climatology of Midlatitude Continental Clouds from the ARM SGP Site: Low-Level Cloud Macrophysical, Microphysical, and Radiative Properties - Part I

A record of single-layer and overcast low cloud (stratus) properties has been generated using approximately 4000 hours of data collected from January 1997 to December 2002 at the Atmospheric Radiation Measurement (ARM) Southern Great Plains Central Facility (SCF). The cloud properties include liquid-phase and liquid-dominant, mixed-phase, low cloud macrophysical, microphysical, and radiative properties including cloud-base and -top heights and temperatures, and cloud physical thickness derived from a ground-based radar and lidar pair, and rawinsonde sounding; cloud liquid water path (LWP) and content (LWC), and cloud-droplet effective radius (r(sub e)) and number concentration (N) derived from the macrophysical properties and radiometer data; and cloud optical depth (tau), effective solar transmission (gamma), and cloud/top-of-atmosphere albedos (R(sub cldy)/R(sub TOA)) derived from Eppley precision spectral pyranometer measurements. The cloud properties were analyzed in terms of their seasonal, monthly, and hourly variations. In general, more stratus clouds occur during winter and spring than in summer. Cloud-layer altitudes and physical thicknesses were higher and greater in summer than in winter with averaged physical thicknesses of 0.85 km and 0.73 km for day and night, respectively. The seasonal variations of LWP, LWC, N. tau, R(sub cldy), and R(sub TOA) basically follow the same pattern with maxima and minima during winter and summer, respectively. There is no significant variation in mean r(sub e), however, despite a summertime peak in aerosol loading, Although a considerable degree of variability exists, the 6-yr average values of LWP, LWC, r(sub e), N, tau, gamma, R(sub cldy) and R(sub TOA) are 150 gm(exp -2) (138), 0.245 gm(exp -3) (0.268), 8.7 micrometers (8.5), 213 cm(exp -3) (238), 26.8 (24.8), 0.331, 0.672, 0.563 for daytime (nighttime). A new conceptual model of midlatitude continental low clouds at the ARM SGP site has been developed from this study. The low stratus cloud amount monotonically increases from midnight to early morning (0930 LT), and remains large until around local noon, then declines until 1930 LT when it levels off for the remainder of the night. In the morning, the stratus cloud layer is low, warm, and thick with less LWC, while in the afternoon it is high, cold, and thin with more LWC. Future parts of this series will consider other cloud types and cloud radiative forcing at the ARM SCF.

Dong, Xiquan↗