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At least 163 records · Page 9

Effects of repetitive bending on the magnetoresistance of a flexible spin-valve

A positive magnetostrictive single layer (CoFe) and top-pinned spin-valve structure with positive magnetostrictive free (NiFe) and pinned (CoFe) layers were deposited on flexible polyethylene terephthalate film to investigate the changes in the magnetic properties in flexible environments, especially with a repetitive bending process. It was found that the stress, applied by repetitive bending, changes significantly the magnetic anisotropy of both layers in a single and spin-valve structure depending on the direction of applied stress. The changes in magnetic anisotropy were understood in terms of the inverse magnetostriction effect (the Villari effect) and the elastic recovery force from the flexibility of the polymer substrate. Repetitive bending with tensile stress transverse (or parallel) to the magnetic easy axis was found to enhance (or reduce) the magnetic anisotropy and, consequently, the magnetoresistance ratio of a spin-valve. The observed effects of bending stress in this study should be considered for the practical applications of electro-magnetic devices, especially magneto-striction sensor.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Structural origin for the local strong anisotropy in melt-spun Fe-Ga-Tb: Tetragonal nanoparticles

Soluting rare earth atoms Tb or Dy into body centered cubic (BCC) Fe-Ga through rapid cooling significantly enhances the magnetostriction due to strong localized magnetocrystalline anisotropy. Origin of the local strong anisotropy, however, awaits comprehensive microstructural investigation. In this letter, formation of tetragonal nanoparticles with c/a ∼ 0.979 has been found in the giant magnetostrictive ribbons Fe{sub 82.89}Ga{sub 16.88}Tb{sub 0.23} due to local symmetry breaking of the BCC lattice using high resolution transmission electronic microscopy. First principal calculations suggest that random replacement of Tb atoms for Fe or Ga in the ordered DO{sub 3} superlattice is beneficial in the formation of such tetragonal symmetry. Exchange couplings between the nearest Tb-Fe or Tb-Tb pairs of the tetragonal nanoparticles might generate strong localized magnetocrystalline anisotropy, leading to extraordinary magnetostriction enhancement.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α{sub E,31} = 2.8 V ⋅ cm{sup −1} ⋅ Oe{sup −1} is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors.

36 MATERIALS SCIENCE↗

Prediction of magnetic moment collapse in ZrFe{sub 2} under hydrostatic pressure

Electronic structure and magnetic properties of ZrFe{sub 2} in the cubic Laves phase are investigated by calculations based on density functional theory. The magnetic moment decreases with the increase of the hydrostatic pressure in an unusual way: Two-step magnetic collapse is predicted. The first one is a continuous change from 1.53 μ{sub B}/Fe to 0.63 μ{sub B}/Fe at about 3.6 GPa, and the other is from 0.25 μ{sub B}/Fe to the nonmagnetic state at about 15 GPa in a first order manner under the local spin density approximation of the exchange correlation potential. A metastable state with intermediate spin moment about 0.15 μ{sub B}/Fe may exist before that. We understand this process by the changes of density of states during it. The magnetic moment decreases under the pressure in the vicinity of the experimental lattice constant with dlnm/dp=−0.038 GPa{sup −1}. The spontaneous volume magnetostriction is 3.6%, which is huge enough to find potential applications in magnetostriction actuators and sensors. We suggest that the Invar effect of this compound may be understood when considering the magnetic moment variation according to the magnetostrictive model of Invar.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Successive field-induced transitions in BiFeO 3 around room temperature

The effects of high magnetic fields applied perpendicular to the spontaneous ferroelectric polarization on single crystals of BiFeO 3 were investigated in this paper through magnetization, magnetostriction, and neutron diffraction measurements. The magnetostriction measurements revealed lattice distortion of 2 x 10 -5 during the reorientation process of the cycloidal spin order by applied magnetic fields. Furthermore, anomalous changes in magnetostriction and electric polarization at a larger field demonstrate an intermediate phase between cycloidal and canted antiferromagnetic states, where a large magnetoelectric effect was observed. Neutron diffraction measurements clarified that incommensurate spin modulation along the [110] hex direction in the cycloidal phase becomes Q = 0 commensurate along this direction in the intermediate phase. Finally, theoretical calculations based on the standard spin Hamiltonian of this material suggest an antiferromagnetic cone-type spin order in the intermediate phase.

36 MATERIALS SCIENCE↗

Effect of Mechanical Stresses and Annealing on the Magnetic Structure and the Magnetic Impedance of Amorphous CoFeSiBCr Microwires

The structural and magnetic properties of amorphous ferromagnetic microwires can undergo significant measurements under the action of external mechanical stresses and heat treatment. The study of transformations occurring in this case is important for designing various sensors of mechanical stresses, loading, and temperature and also for inducing in the wires a certain type of magnetic anisotropy that plays a significant role in the realization of various effects in them. In this work, the influence of external stresses and annealing on the processes of the magnetization and the magnetic impedance of Co{sub 71}Fe{sub 5}B{sub 11}Si{sub 10}Cr{sub 3} microwires having a low positive magnetostriction (~10{sup -8}) in amorphous state has been studied. The influence of external stresses leads to a sharp change in the character of the magnetization reversal curve, which was due to the change in the sign of the magnetostriction and the type of magnetic anisotropy. The amplitude of higher harmonics and the value of the magnetic impedance, respectively, are sensitive to mechanical stresses. Elastic stresses in the wires with a partial crystallization do not lead to a marked change in the magnetic properties; however, annealing can lead to a substantial increase in the axial magnetic anisotropy of the wires existing in the stressed state. The experimental results are analyzed in the framework of a magnetostriction model of induced magnetic anisotropy.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Ultrasonic Transducer Irradiation Test Results

Ultrasonic technologies offer the potential for high-accuracy and -resolution in-pile measurement of a range of parameters, including geometry changes, temperature, crack initiation and growth, gas pressure and composition, and microstructural changes. Many Department of Energy-Office of Nuclear Energy (DOE-NE) programs are exploring the use of ultrasonic technologies to provide enhanced sensors for in-pile instrumentation during irradiation testing. For example, the ability of small diameter ultrasonic thermometers (UTs) to provide a temperature profile in candidate metallic and oxide fuel would provide much needed data for validating new fuel performance models. Other ongoing efforts include an ultrasonic technique to detect morphology changes (such as crack initiation and growth) and acoustic techniques to evaluate fission gas composition and pressure. These efforts are limited by the lack of identified ultrasonic transducer materials capable of long term performance under irradiation test conditions. For this reason, the Pennsylvania State University (PSU) was awarded an ATR NSUF project to evaluate the performance of promising magnetostrictive and piezoelectric transducers in the Massachusetts Institute of Technology Research Reactor (MITR) up to a fast fluence of at least 10 21 n/cm 2 . The goal of this research is to characterize and demonstrate magnetostrictive and piezoelectric transducer operation during irradiation, enabling the development of novel radiation-tolerant ultrasonic sensors for use in Material Testing Reactors (MTRs). As such, this test is an instrumented lead test and real-time transducer performance data is collected along with temperature and neutron and gamma flux data. The current work bridges the gap between proven out-of-pile ultrasonic techniques and in-pile deployment of ultrasonic sensors by acquiring the data necessary to demonstrate the performance of ultrasonic transducers. To date, one piezoelectric transducer and two magnetostrictive transducers have demonstrated reliable operation under irradiation. The irradiation is ongoing.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Higher harmonic ultrasonic guided waves for structural integrity assessment of dry storage canisters - 15381

Dry storage of used fuel from nuclear power plants has gone from an interim storage solution to a longer-term solution, which necessitates monitoring the integrity of the stainless steel canister that confines the used fuel. Since the storage facilities are located around the country in a variety of different environments there is a wide range of degradation mechanisms that could occur over time in the cylindrical canister. One potential degradation mode that has created significant concern is stress corrosion cracking. We propose using higher harmonic ultrasonic guided waves as a tool to nondestructively inspect used fuel canisters. Higher harmonics are generated when a wave propagates through a nonlinear elastic media. These higher harmonics have been shown to be quite sensitive to microstructural features such as dislocation substructures, persistent slip bands, precipitates, etc. The use of ultrasonic guided waves to inspect the canister is attractive due to the size of the canister and the ability of guided waves to inspect a reasonably large domain relative to traditional bulk wave ultrasonics. We will highlight our recent progress on theory, numerical simulations, and laboratory experiments to develop higher harmonic guided waves as a tool to detect microstructural changes that precede macro-scale damage. Analyzed structures include plates and hollow cylinders, and we focus on localized damage initiation, as is the case for stress corrosion cracking. Recent experiments focus on using magnetostrictive transducers in activating the fundamental shear horizontal mode (SH0) and the third harmonic that is generated due to the material nonlinearity. The magnetostrictive transducer comprises a thin iron-cobalt foil, a meandering electric coil, and a permanent magnet. These transducers are inexpensive, easy to use, and are very efficient at generating shear waves. In applications where the wavelength is larger than the plate thickness, the waves are guided by the traction free boundary conditions and propagate in the plane of the plate. For this canister application, the shear horizontal waves energize the entire thickness of the canister and propagate along the shell in the direction dictated by the meander coil. Experiments indicate that magnetostrictive transducers can generate waves that propagate in plate thicknesses of 1 mm to at least 16 mm. The SH0 mode is nondispersive and generates a third harmonic of the same mode that is shown to be sensitive to localized plastic strain and unseen fatigue damage. It has a strong potential to detect the very early stages of stress corrosion cracking. Due to the geometric configuration of dry storage casks, the transducers will need to be delivered to the inspection points by a robotic system that navigates through the cask ventilation system. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Coexistence of Low Damping and Strong Magnetoelastic Coupling in Epitaxial Spinel Ferrite Thin Films

Low‐loss magnetization dynamics and strong magnetoelastic coupling are generally mutually exclusive properties due to opposing dependencies on spin–orbit interactions. So far, the lack of low‐damping, magnetostrictive ferrite films has hindered the development of power‐efficient magnetoelectric and acoustic spintronic devices. Here, magnetically soft epitaxial spinel NiZnAl‐ferrite thin films with an unusually low Gilbert damping parameter (<3 × 10 −3 ), as well as strong magnetoelastic coupling evidenced by a giant strain‐induced anisotropy field (≈1 T) and a sizable magnetostriction coefficient (≈10 ppm), are reported. This exceptional combination of low intrinsic damping and substantial magnetostriction arises from the cation chemistry of NiZnAl‐ferrite. At the same time, the coherently strained film structure suppresses extrinsic damping, enables soft magnetic behavior, and generates large easy‐plane magnetoelastic anisotropy. These findings provide a foundation for a new class of low‐loss, magnetoelastic thin film materials that are promising for spin‐mechanical devices.

Emori, Satoru↗

Probing of Local Structure in Laves Compound TbFe 2

Abstract The Laves compounds Tb 1‐x Dy x Fe 2 have attracted much interest due to the giant magnetostriction effect appearing at their morphotropic phase boundary compositions. Although previous studies have established the relationship between the average structure and magnetostrictive properties in these compounds, there is a lack of characterization of their local structures. In this paper, as a first step toward this goal, the evolution of the local structure of the terminal compound (TbFe 2 ) of this system is reported, in an attempt to provide useful information about interatomic bonding in this system. The pair distribution function (PDF) results suggest that the compound presents the rhombohedral local crystal symmetry. The lattice at the local scale shows abnormal thermal expansion which is different from the long scale structure. The different role of the Tb─Fe bond and Fe─Fe bond in affecting the crystal lattice is revealed. These findings highlight the important role of local structure in determining the magnetostrictive properties of the Laves compounds.

Kou, Ronghui↗

Magnetic ordering in terbium at high pressures and low temperatures

We have investigated magnetic ordering in the heavy lanthanide terbium (Tb) for pressures up to 70 GPa and temperatures down to 20 K by synchrotron x-ray diffraction at the Advanced Photon Source, Argonne National Laboratory. The x-ray diffraction studies were complemented by neutron diffraction studies at the Spallation Neutron Source, Oak Ridge National Laboratory. We focused on the higher-pressure phases of Tb, such as the double hexagonal close-packed (dhcp, above 16 GPa), distorted face-centered cubic (hR24, above 30 GPa), and orthorhombic (oF16, above 51 GPa) phases. We observed the phenomenon of spontaneous magnetostriction in the dhcp and hR24 phases, where magnetic ordering at low temperatures gives rise to subtle splitting in x-ray diffraction peaks. The neutron diffraction study of the dhcp phase at 20 GPa revealed magnetic peaks that can be assigned a propagation vector k = ($\frac{1}{2}$, 0, $\frac{1}{2}$), and a magnetic ordering temperature that is consistent with the magnetostriction effect observed with x-ray diffraction. The high-pressure and low-temperature x-ray diffraction study at 70 GPa in the collapsed oF16 phase did not show any evidence of magnetostriction, indicating a significant decrease in the magnetic moment of the 4f-shell due to band broadening at ultra-high compression.

36 MATERIALS SCIENCE↗

Temperature dependence of magnetic anisotropy and magnetoelasticity from classical spin-lattice calculations

Here we present a classical molecular-spin dynamics (MSD) methodology that enables accurate computations of the temperature dependence of the magnetocrystalline anisotropy as well as magnetoelastic properties of magnetic materials. The nonmagnetic interactions are accounted for by a spectral neighbor analysis potential (SNAP) machine-learned interatomic potential, whereas the magnetoelastic contributions are accounted for using a combination of an extended Heisenberg Hamiltonian and a Néel pair interaction model, representing both the exchange interaction and spin-orbit-coupling effects, respectively. All magnetoelastic potential components are parameterized using a combination of first-principles and experimental data. Our framework is applied to the α phase of iron. Initial testing of our MSD model is done using a 0 K parametrization of the Néel interaction model. After this, we examine how individual Néel parameters impact the $B$ 1 and $B$ 2 magnetostrictive coefficients using a moment-independent δ sensitivity analysis. The results from this study are then used to initialize a genetic algorithm optimization which explores the Néel parameter phase space and tries to minimize the error in the B 1 and B 2 magnetostrictive coefficients in the range of 0–1200 K. Our results show that while both the 0 K and genetic algorithm optimized parametrization provide good experimental agreement for $B$ 1 and $B$ 2 , only the genetic algorithm optimized results can capture the second peak in the $B$ 1 magnetostrictive coefficient which occurs near approximately 800 K.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Structural, Magnetic, and Magentostrictive Properties of Dy{sub 1−x}(Tb{sub 0.2}Pr{sub 0.8}){sub x}Fe{sub 1.93} (0≤ x ≤ 0.5) Compounds

The structural, magnetic, and magnetostrictive properties of light rare earth Pr-contained Dy{sub 1−x}(Tb{sub 0.2}Pr{sub 0.8}){sub x}Fe{sub 1.93} (0≤ x ≤ 0.5) compounds were investigated by means of X-ray diffraction, vibrating sample magnetometer and strain gauge technique. A single Laves phase with MgCu{sub 2}-type structure was obtained in the composition range of 0.0≤ x ≤ 0.25. The lattice parameter of the Lave phase increases with increasing x due to the large radius of Pr{sup 3+} and Tb{sup 3+}. The Curie temperature of the Laves phase decreases with increasing x, indicating weakening strength of 3d-4f coupling. The saturation magnetization decreases with increasing x, which could be ascribed to the opposite magnetic moment alignments of Pr and (Td,Dy) with Fe. The magnetostriction of Dy{sub 1−x}(Tb{sub 0.2}Pr{sub 0.8}){sub x}Fe{sub 1.93} increases with increasing x, peaks at x = 0.25 and then decreases with further increasing x.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Tricritical point from high-field magnetoelastic and metamagnetic effects in UN

Uranium nitride (UN) is one of the most studied actinide materials as it is a promising fuel for the next generation of nuclear reactors. Despite large experimental and theoretical efforts, some of the fundamental questions such as degree of 5 f–electron localization/delocalization and its relationship to magneto-vibrational properties are not resolved yet. We show that the magnetostriction of UN measured in pulsed magnetic fields up to 65 T and below the Néel temperature is large and exhibits complex behavior with two transitions. While the high field anomaly is a field-induced metamagnetic-like transition and affects both magnetisation and magnetostriction, the low field anomaly does not contribute to the magnetic susceptibility. Our data suggest a change in the nature of the metamagnetic transition from first to second order-like at a tricritical point at T tri ~24 K and H tri ~52 T. The induced magnetic moment at 60 T might suggest that only one subset of magnetic moments has aligned along the field direction. Using the results obtained here we have constructed a magnetic phase diagram of UN. Our studies demonstrate that dilatometry in high fields is an effective method to investigate the magneto-structural coupling in actinide materials.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Electric-field-induced spin wave generation using multiferroic magnetoelectric cells

In this work, we report on the demonstration of voltage-driven spin wave excitation, where spin waves are generated by multiferroic magnetoelectric (ME) cell transducers driven by an alternating voltage, rather than an electric current. A multiferroic element consisting of a magnetostrictive Ni film and a piezoelectric [Pb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3}]{sub (1−x)}–[PbTiO{sub 3}]{sub x} substrate was used for this purpose. By applying an AC voltage to the piezoelectric, an oscillating electric field is created within the piezoelectric material, which results in an alternating strain-induced magnetic anisotropy in the magnetostrictive Ni layer. The resulting anisotropy-driven magnetization oscillations propagate in the form of spin waves along a 5 μm wide Ni/NiFe waveguide. Control experiments confirm the strain-mediated origin of the spin wave excitation. The voltage-driven spin wave excitation, demonstrated in this work, can potentially be used for low-dissipation spin wave-based logic and memory elements.

74 ATOMIC AND MOLECULAR PHYSICS↗

Enhanced efficiency in the excitation of higher modes for atomic force microscopy and mechanical sensors operated in liquids

Recent developments in dynamic Atomic Force Microscopy where several eigenmodes are simultaneously excited in liquid media are proving to be an excellent tool in biological studies. Despite its relevance, the search for a reliable, efficient, and strong cantilever excitation method is still in progress. Herein, we present a theoretical modeling and experimental results of different actuation methods compatible with the operation of Atomic Force Microscopy in liquid environments: ideal acoustic, homogeneously distributed force, distributed applied torque (MAC Mode™), photothermal and magnetostrictive excitation. From the analysis of the results, it can be concluded that magnetostriction is the strongest and most efficient technique for higher eigenmode excitation when using soft cantilevers in liquid media.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Local rhombohedral symmetry in Tb{sub 0.3}Dy{sub 0.7}Fe{sub 2} near the morphotropic phase boundary

The recently reported morphotropic phase boundary (MPB) in a number of giant magnetostrictive materials (GMMs) has drawn considerable interest to the local symmetry/structure near MPB region of these materials. In this letter, by in-situ X-ray diffraction and AC magnetic susceptibility measurements, we show that Tb{sub 0.3}Dy{sub 0.7}Fe{sub 2}, the typical composition of Terfenol-D GMMs, has coexistence of rhombohedral and tetragonal phases over a wide temperature range in the vicinity of MPB. High resolution transmission electron microscopy provides direct evidence for local rhombohedral symmetry of the ferromagnetic phase and reveals regular-shaped nanoscale domains below 10 nm. The nano-sized structural/magnetic domains are hierarchically inside a single micron-sized stripe-like domain with the same average magnetization direction. Such domain structures are consistent with the low magnetocrystalline anisotropy and easy magnetic/structural domain switching under magnetic field, thus generating large magnetostriction at low field.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Induced magnetic anisotropy in Si-free nanocrystalline soft magnetic materials: A transmission x-ray diffraction study

In order to better understand the origin of field-induced anisotropy (K{sub u}) in Si-free nanocrystalline soft magnetic alloys, the lattice spacing of the bcc-Fe phase in nanocrystalline Fe{sub 94−x}Nb{sub 6}B{sub x} (x = 10, 12, 14) alloys annealed under an applied magnetic field has been investigated by X-ray diffraction in transmission geometry (t-XRD) with the diffraction vector parallel and perpendicular to the field direction. The saturation magnetostriction (λ{sub s}) of nanocrystalline Fe{sub 94−x}Nb{sub 6}B{sub x} was found to increase linearly with the volume fraction of the residual amorphous phase and is well described by taking into account the volume-weighted average of two local λ{sub s} values for the bcc-Fe nanocrystallites (−5 ± 2 ppm) and the residual amorphous matrix (+8 ± 2 ppm). The lattice distortion required to produce the measured K{sub u} values (∼100 J/m{sup 3}) was estimated via the inverse magnetostrictive effect using the measured λ{sub s} values and was compared to the lattice spacing estimations made by t-XRD. The lattice strain required to produce K{sub u} under the magnetoelastic model was not observed by the t-XRD experiments and so the findings of this study suggest that the origin of magnetic field induced K{sub u} cannot be explained through the magnetoelastic effect.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗