Thermal metamorphism of primitive meteorites. IV - Comparison with trends for ten trace elements in terrestrial basalt BCR-1 heated at 500-1000 C
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Possible heating mechanisms for an intense thermal cycle in the early solar system are considered, and inductive asteroid heating in a T Tauri environment is examined. Calculations of thermal models based on recent measurements of the electrical conductivity of carbonaceous meteorites are reported which are presumably more representative of actual conditions in the early solar nebula. Asteroidal thermal evolution is computed using a highly simplified code that restricts induction to the dc limit of the TM mode, approximates the complete unipolar-generation differential equation by a simple series-resistance model, and restricts the modeling of thermal conduction to a calculation of heat transfer across a thin planar shell of given thickness increasing with time, which blankets a body assumed to have an isothermal core. A grid of results is obtained for 20 combinations of asteroid radius and solar distance representing the populaton of asteroids. It is found that there is a relative heating maximum with respect to body radius, that this effect is due to the operation of two distinct heating-rate restrictions which have opposite radius dependences, and that the maximum current density is roughly proportional to the inverse of interior radius.
Three intermingled lithologies are identified in the Shaw L-group chondrite: a light-colored lithology with a poikilitic texture, consisting of olivine and augite crystals surrounded by larger orthopyroxene grains; a dark-colored lithology containing remnant chondrules and exhibiting a microgranular texture; and a gray lithology which appears to be intermediate between the other two. Contrary to published opinions, the Shaw meteorite contains normal L-group chondrite abundances of metal and troilite, though these phases are irregularly distributed. The lithological analyses suggest that 4.52 Byr ago an impact took place on the L-group chondrite parent object of Shaw.
Noble gases, C and S, are lost from Allende samples heated for 1 week at temperatures of 400-1000 C in a low pressure environment. In the extreme, losses of He-3 and He-4 are about 100 x while for C, S and Ne, Ar and Kr isotopes and Xe-132 these are less than or equal to 10 x. Except for He, these losses are less severe than those of Bi or Tl from samples heated in the same runs. Significant He, Ne and Ar isotopic fractionation during heating indicates preferential outgassing of specific reservoirs. Next to He, Ar-40 is the most labile of those species considered here but still less so than Bi or Tl. L-group (but not H- or LL-group) chondrites may have lost mobile elements like Tl while being outgassed after late impact-associated heating. A less likely alternative involving a collateral relation between condensation conditions and depth in a parent object may also explain the L-group trend.
Feldspathic granulite 79215, an annealed polymict breccia which has a bulk composition between anorthositic gabbro and gabbroic anorthosite, contains numerous oxide complexes in the matrix. An Ar-39-Ar-40 stepwise heating experiment gives a well-defined plateau corresponding to an age of 4.03 + or - 0.02 AE. The polmict character of this breccia and the variability of the complexes suggest that they formed as a consequence of reactions between spinel-rich clasts and matrix under the high-T low-P conditions of an ejecta blanket. The duration of annealing is estimated to have been less than 10 million yr; the absence of a KREEP component may indicate an inhomogeneous distribution of this component at the lunar surface at 4.0 AE.
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The paper deals with an extensive series of shock-recovery experiments performed on both nonporous crystalline basalt and its granulated and sieved counterpart to study the role of porosity and grain size in shock motomorphic effects under otherwise identical conditions. Shocked samples are compared with unshocked starting material in terms of textural and mineralogical modifications attributable to shock. A comparative petrographic and chemical characterization is presented of pulverized and sieved lunar basalt 75035 shocked between 6 and 75 GPa in comparison with holocrystalline disks of the same basalts shocked in 10 earlier experiments. Specifically, a petrographic classification of shock features is given, along with an estimation of relative amounts of shock glasses and a chemical characterization of shock glasses in each shocked granular basalt.
The paper reports on a series of controlled shock recovery experiments which have been performed on over 40 samples including monocrystalline, polycrystalline, dunite, and porous particulate olivine-bearing targets. Results of the mineralogical and petrological analyses of these samples are used to establish a general and comparative diagnosis of shock effects generated in various olivine-bearing materials. Finally, some experiments are conducted under different ambient pO2 conditions so that information on the distribution of observed impact features is derived as a function not only of peak pressure and texture of the target sample, but also of specific environmental conditions.
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Shock experiments in the pressure range 15-73 GPa were performed on lunar soil 15101 in order to investigate the effect of a single impact event on the formation of soil breccias and agglutinates. The study has demonstrated that the propagation of a shock wave emanating from a single impact in porous particulate samples causes collision and shear of grains, collapse of pore spaces, and compaction which is sufficient to indurate soil at low pressures (15-18 GPa) without significant melting (less than 5%). These low pressures create soil breccias or weakly shocked soil fragments from loose regolith. At pressures above 65 GPa, shock melting produces a pumiceous whole-soil glass which is equivalent to agglutinate glass, glass fragments, or ropy glasses depending on the abundance of lithic fragments and relict grains.
New thermoluminescence (TL) sensitivity measurements on 17 finds and one fall are presented, and petrologic assignments are made on the basis of TL sensitivity and silicate heterogeneity. The correlation that exists between TL sensitivity and glow curve shape is discussed, with the difference in the glow curve shapes of meteorite types 3.4 and less and type 3.5 and greater being tentatively attributed to an order-disorder transition in plagioclase, the TL phosphor. A correlation between TL sensitivity and heteogeneity of the silicate composition is found, but it tends to break down in the most heterogeneous meteorites. For Antarctic meteorites, the TL data show a much more restricted range in TL sensitivity than in silicate heterogeneity. The Quinyambie meteorite is the only one not consistent with the observed trend. Several explanations are offered, none of them totally satisfactory.
The effective grain size of a material on a planetary surface affects the strength of absorption features observed in the reflectance of a particulate surface. In the case of a planetary surface containing volatile ices, the absorption characteristics can change in connection with processes leading to a change in the grain size of the material. The present investigation is concerned with an evaluation regarding the occurrence of such processes and the implications for remote sensing applications. It is found that quantitative modeling of the kinetics of grain growth and destruction by thermal and nonthermal processes can provide a means to reconcile apparent optical paths in the volatile portions of planetary surfaces with the physical history of those surfaces. Attention is also given to conditions in the case of the Pluto/Triton system, Uranus and Saturnian satellites, and the Galilean system.
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