Development of a sealed lead-acid battery for use in space Final report
Development of sealed lead-acid battery with lead- calcium grid for space application
LEAD ALLOY↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Ionene membrane battery separator
Ionic transport characteristics of ionenes, insoluble membranes from soluble polyelectrolyte compositions, are studied for possible application in a battery separator. Effectiveness of the thin film of separator membrane essentially determines battery lifetime.
Moacanin, J.↗
Space Electrochemical Research and Technology
Individual papers presented at the conference address the following topics: development of a micro-fiber nickel electrode for nickel-hydrogen cell, high performance nickel electrodes for space power application, bending properties of nickel electrodes for nickel-hydrogen batteries, effect of KOH concentration and anions on the performance of a Ni-H2 battery positive plate, advanced dependent pressure vessel nickel hydrogen spacecraft cell and battery design, electrolyte management considerations in modern nickel hydrogen and nickel cadmium cell and battery design, a novel unitized regenerative proton exchange membrane fuel cell, fuel cell systems for first lunar outpost - reactant storage options, the TMI regenerable solid oxide fuel cell, engineering development program of a closed aluminum-oxygen semi-cell system for an unmanned underwater vehicle, SPE OBOGS on-board oxygen generating system, hermetically sealed aluminum electrolytic capacitor, sol-gel technology and advanced electrochemical energy storage materials, development of electrochemical supercapacitors for EMA applications, and high energy density electrolytic capacitor.
Richard M Wilson↗
Electrochemistry-based Battery Modeling for Prognostics
Batteries are used in a wide variety of applications. In recent years, they have become popular as a source of power for electric vehicles such as cars, unmanned aerial vehicles, and commericial passenger aircraft. In such application domains, it becomes crucial to both monitor battery health and performance and to predict end of discharge (EOD) and end of useful life (EOL) events. To implement such technologies, it is crucial to understand how batteries work and to capture that knowledge in the form of models that can be used by monitoring, diagnosis, and prognosis algorithms. In this work, we develop electrochemistry-based models of lithium-ion batteries that capture the significant electrochemical processes, are computationally efficient, capture the effects of aging, and are of suitable accuracy for reliable EOD prediction in a variety of usage profiles. This paper reports on the progress of such a model, with results demonstrating the model validity and accurate EOD predictions.
battery↗
The 1982 Goddard Space Flight Center Battery Workshop
Various topics concerned with advanced battery technology are addressed including lithium cell and battery safety developments, mathematical modelling, charge control of aerospace power systems, and the application of nickel hydrogen cells/batteries vis-a-vis nickel cadmium cells/batteries.
G Halpert↗
Improving Adhesive Bondline Time of Flight Predictions During Autoclave Cure Utilizing Machine Learning
Composite materials are increasingly being used in aerospace applications due to their superior strength-to-weight ratio compared to commonly used metals. A current limitation to widespread adoption is the certification of adhesively bonded joints. One approach to improving adhesive bonding in composites is accurately measuring the thickness of adhesive bondlines in composite laminates. Precise bondline thickness control is essential for aerospace applications where adhesive layer thickness directly affects joint fracture properties and structural performance. This study focused on implementing machine learning techniques to determine the ultrasonic time of flight (directly correlated to thickness) in adhesive bondlines throughout autoclave cure cycles. A high-temperature (use up to 180°C) ultrasonic scanning system was deployed in an autoclave to provide time of flight data through composite panels. Three experiments were conducted on the curing of 305 mm × 305 mm unidirectional composite panels. In the first experiment, a piecewise function was fit for the temperature correction factor to account for changing autoclave temperatures. Due to deficiencies in the first calibration experiment, a second experiment was run, and the results were used to train a machine learning model. The revised experiment, in combination with the machine learning model, significantly increased the accuracy of the bondline time of flight predictions (~14% error reduced to <1%). Data was processed using the Regression Learner Application in MATLAB®, with a Support Vector Machine selected for the model. The result was a machine learning algorithm capable of reliably quantifying ultrasonic time of flight through adhesive bondlines. The third experiment provided independent test data for the machine learning model, demonstrating that the model produces accurate predictions from data beyond its training set.
Machine Learning↗
A nickel-cadmium battery reconditioning circuit
The circuit presented is simple and small enough to be included in a typical battery charge/power control assembly, yet provides the advantage of a complete ground-type battery reconditioning discharge. Test results on the circuit when used to recondition two 24 cell, 20 A-h nickel-cadmium batteries are given. These results show that a battery reconditioned with this circuit returns to greater than 90 percent of its original capacity (greater than nameplate capacity) and follows a typical new battery degradation curve even after over 20,000 simulated orbital cycles for a 4 year period. Applications of the circuit are considered along with recommendations relative to its use. Its application in low voltage (22 to 36 Vdc) power systems and in high voltage (100 to 150 Vdc) power systems is discussed. The implications are that the high voltage systems have a greater need for battery reconditioning than their low voltage counterparts, and that using these circuit techniques, the expected life of a battery in low Earth orbit can be up to 5 years.
Lanier, R.↗
Lubricating Properties of Ceramic-Bonded Calcium Fluoride Coatings on Nickel-Base Alloys From 75° to 1900° F
The endurance life and the friction coefficient of ceramic-bonded calcium fluoride (CaF2) coatings on nickel-base alloys were determined at temperatures from 75° to 1900° F. The specimen configuration consisted of a hemispherical rider (3/16-in. rad.) sliding against the flat surface of a rotating disk. Increasing the ambient temperature (up to 1500° F) or the sliding velocity generally reduced the friction coefficient and improved coating life. Base-metal selection was critical above 1500° F. For instance, cast Inconel sliding against coated Inconel X was lubricated effectively to 1500° F, but at 1600° F severe blistering of the coatings occurred. However, good lubrication and adherence were obtained for René 41 sliding against coated René 41 at temperatures up to 1900° F; no blisters developed, coating wear life was fairly good, and the rider wear rate was significantly lower than for the unlubricated metals . Friction coefficients were 0.12 at 1500° F, 0.15 at 1700° F, and 0.17 at 1800° and 1900° F. Because of its ready availability, Inconel X appears to be the preferred substrate alloy for applications in which the temperature does not exceed 1500° F. René 41 would have to be used in applications involving higher temperatures. Improved coating life was derived by either preoxidizing the substrate metals prior to the coating application or by applying a very thin (<0.0002 in.) burnished and sintered overlay to the surface of the coating. Preoxidation did not affect the friction coefficient. The overlay generally resulted i n a higher friction coefficient than that obtained without the overlay. The combination of both modifications resulted in longer coating life and in friction coefficients intermediate between those obtained with either modification alone.
Nickel alloy↗
The 27th Aerospace Mechanisms Symposium
The proceedings of the 27th Aerospace Mechanisms Symposium, which was held at ARC, Moffett Field, California, on 12-14 May 1993, are reported. Technological areas covered include the following: actuators, aerospace mechanism applications for ground support equipment, lubricants, latches, connectors, robotic mechanisms, and other mechanisms for large space structures.
Mancini, Ron↗
Battery charge regulator is coulometer controlled
Coulometer controlled battery charge regulator controls nickel/cadmium type primary cells used in space applications. The use of the coulometer as an ampere hour measuring device permits all available current to go to the battery until full charge state is reached, at which time the charge rate is automatically reduced.
Paulkovich, J.↗
Mathematical Storage-Battery Models
Empirical formula represents performance of electrical storage batteries. Formula covers many battery types and includes numerous coefficients adjusted to fit peculiarities of each type. Battery and load parameters taken into account include power density in battery, discharge time, and electrolyte temperature. Applications include electric-vehicle "fuel" gages and powerline load leveling.
Chapman, C. P.↗
Recommended Practices in Laser-Induced Fluorescence (LIF) Diagnostics for Electric Propulsion
Laser-induced fluorescence (LIF) spectroscopy uses Doppler-shifted laser photons to excite a bound electron transition in an atom or ion, with subsequent fluorescence emission detected in order to measure the local velocity distribution function (VDF) and/or particle density. Due to its non-invasive nature, high spatial resolution, and acceptable difficulty of implementation, LIF has become a favored diagnostic for electric propulsion (EP) plasmas, particularly in the study of Hall thrusters. This paper presents recommended best practices for LIF measurements in electric thrusters, drawn from over three decades of implementation heritage in the EP community. Focusing on both single-photon LIF (typically used to measure VDFs) and two-photon LIF (TALIF, typically used to determine densities), the paper covers selection of atomic transitions to target, experimental setups, and interpretation of data. A number of special topics and advanced applications are discussed, including uncertainty analysis, techniques for high-speed measurements, and applications to a variety of propellants.
plasma plume↗
Evaluation of Long-Term Storage Stability and Operational Efficiency of Rapid Cycle Amine Adsorbents
With the recent incorporation of Mars Extravehicular Activity (EVA) into the 2025 NASA roadmap, Rapid Cycle Amine (RCA) technology advancement within the Exploration Extravehicular Mobility Unit (xEMU) applies to both the upcoming Lunar Artemis missions and future human exploration of Mars. The incorporation of commercial spacesuit vendors to service NASA’s crewed-space programs since 2021 has increased the demand for regenerable, RCA-based carbon dioxide (CO2) and humidity control adsorbents. The regenerable RCA subunit is the most advanced, long-term solution for CO2 removal and humidity control, enabling both lunar and Martian EVAs. The adsorbent selected for use within the RCA unit must exhibit sufficient storage stability and operational efficiency for prolonged missions. As XploSafe worked to simultaneously develop both a recirculating sub-atmospheric test rig and adsorbents for the RCA system within the xEMU, several novel adsorbents were evaluated for long-term storage stability in support of future extended-duration missions. The chosen materials were periodically evaluated by nuclear magnetic resonance (NMR) spectroscopy, thermal desorption-coupled with gas chromatography/mass spectrometry (TD-GC/MS), and CO2 adsorption to assess long-term storage efficacy across various environmental storage conditions. NMR spectroscopy was utilized by extracting the active CO2 adsorbing chemical from the solid support with deuterated solvent and comparing the spectra over time for degradation and change. The solid adsorbents were also analyzed via TD-GC/MS to reveal any potential off-gassing chemicals over time. Additionally, XploSafe’s breakthrough test rig was utilized to dose the solid adsorbents with a 585 BTU/h metabolic rate flow-equivalent CO2 stream and monitored for 0–99% CO2 breakthrough. The performance metrics from the breakthrough analysis were compared over the storage study duration for CO2 removal and humidity control. Xplo-SA9T was evaluated for 24 months, whereas two additional adsorbent variants, MMPA-Sorbent and LPEI-Sorbent, were each evaluated for 12 months.
John R Tidwell↗
Space Mission Options for Reconnaissance and Mitigation of Asteroid 2024 YR4
Near-Earth asteroid 2024 YR 4 was discovered on 2024-12-27 and its probability of Earth impact in December 2032 peaked at about 3% on 2025-02-18. Additional observations ruled out Earth impact by 2025-02-23. However, the probability of lunar impact in December 2032 then rose, reaching about 4% by the end of the apparition in May 2025. James Webb Space Telescope (JWST) observations on 2025-03-26 estimated the asteroid's diameter at 60 +/- 7 m. Studies of 2024 YR 4 's potential lunar impact effects suggest lunar ejecta could increase micrometeoroid debris flux in low Earth orbit up to 1000 times above background levels over just a few days, possibly threatening astronauts and spacecraft. In this work, we present options for space missions to 2024 YR 4 that could be utilized if lunar impact is confirmed. We cover flyby & rendezvous reconnaissance, deflection, and robust disruption of the asteroid. We examine both rapid-response and delayed launch options through 2032. We evaluate chemical and solar electric propulsion, various launch vehicles, optimized deep space maneuvers, and gravity assists. Re-tasking extant spacecraft and using built spacecraft not yet launched are also considered. The best reconnaissance mission options launch in late 2028, leaving only approximately three years for development at the time of this writing in August 2025. Deflection missions were assessed and appear impractical. However, kinetic robust disruption missions are available with launches between April 2030 and April 2032. Nuclear robust disruption missions are also available with launches between late 2029 and late 2031. Finally, even if lunar impact is ruled out there is significant potential utility in deploying a reconnaissance mission to characterize the asteroid.
Asteroid Disruption↗
High Mach Number, Low-Cowl-Drag, External-Compression Inlet With Subsonic Dump Diffuser
A zero-cowl-drag, all-external-compression inlet with an abrupt area discontinuity or subsonic dump diffuser has been proposed and demonstrated for high Mach number application. Isentropic compression was focused at the lip of a cylindrical cowl and limited by the requirements for shock attachment. Theoretical calculations of the performance of such an inlet showed that it may be suited for application at Mach numbers of 4 and above. In an experimental investigation at Mach 3.85, a 4.75-inch-diameter inlet attained a total-pressure recovery of 0.41 at a corresponding mass-flow ratio of 0.92. Subsonic diffusion over an area ratio of about 3.5 to 1.0 was accomplished in 1.25 inlet diameters. Essentially no difference in performance was obtained in a comparison of the dump and a conventional subsonic diffuser. On a range basis, the over-all performance of this inlet was at least comparable with that of the best on-design isentropic external-compression inlet previously reported. A variable Mach number configuration utilizing a telescoping spike with a subsonic dump diffuser is also included.
James F Connors↗
Reports of Planetary Geology and Geophysics Program, 1984
Topics include outer planets and satellites; asteroids and comets; Venus; lunar origin and solar dynamics; cratering process; planetary interiors, petrology, and geochemistry; volcanic processes; aeolian processes and landforms; fluvial processes; geomorphology; periglacial and permafrost processes; remote sensing and regolith studies; structure, tectonics, and stratigraphy; geological mapping, cartography, and geodesy; and radar applications.
Henry E Holt↗
SMS/GOES cell and battery data analysis report
The nickel-cadmium battery design developed for the Synchronous Meteorological Satellite (SMS) and Geostationary Operational Environmental Satellite (GOES) provided background and guidelines for future development, manufacture, and application of spacecraft batteries. SMS/GOES battery design, development, qualification testing, acceptance testing, and life testing/mission performance characteristics were evaluated for correlation with battery cell manufacturing process variables.
Armantrout, J. D.↗
NASA Small Spacecraft and Distributed Systems: Recent and Upcoming Technology Demonstrations and Development Efforts
NASA’s Small Spacecraft & Distributed Systems (SSDS) program strengthens U.S. ability to conduct unique missions by rapidly developing and demonstrating capabilities for SmallSat exploration, science, and commercial space. In collaboration with NASA Centers, other government agencies, commercial industry, and academia, SSDS advances next generation SmallSat technologies like power, processing, propulsion, communications, autonomous navigation, architectures (swarms), and applications (AI/ML/Edge Computing)—to extend missions beyond LEO into cislunar and planetary space. Various investment mechanisms exist for SSDS to select and fund projects that will ultimately advance NASA’s Moon to Mars Architecture. Presented here are the latest achievements and findings from recently completed SSDS projects, along with updates from ongoing efforts and planned future work. Successful missions like Starling and CAPSTONE continue to demonstrate their capability after several years on-orbit. Advancements in next generation swarm configurations are being implemented by Starling for space traffic monitoring and management applications. Findings from recent SSDS flight projects are discussed: DiskSat, a unique SmallSat platform alternative to canisterized nanosatellites, launched December 2025 and is gathering data; the PTD series of missions concluded in December 2025. Current SSDS efforts are focused on addressing NASA Shortfalls relating to rendezvous and proximity operations, neuromorphic computing, and space situational awareness.
Roger Hunter↗