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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

The influence of electrochemical cycling protocols on capacity loss in nickel-rich lithium-ion batteries

The transition towards electric vehicles and more sustainable transportation is dependent on lithium-ion battery (LIB) performance. Ni-rich layered transition metal oxides, such as NMC811 (LiNi 0.8 Mn 0.1 Co 0.1 O 2 ), are promising cathode candidates for LIBs due to their higher specific capacity and lower cost compared with lower Ni content materials. However, complex degradation mechanisms inhibit their use. In this work, tailored aging protocols are employed to decouple the effect of electrochemical stimuli on the degradation mechanisms in graphite/NMC811 full cells. Using these protocols, impedance measurements, and differential voltage analysis, the primary drivers for capacity fade and impedance rise are shown to be large state of charge changes combined with high upper cut-off voltage. Focused ion beam-scanning electron microscopy highlights that extensive microscale NMC particle cracking, caused by electrode manufacturing and calendering, is present prior to aging and not immediately detrimental to the gravimetric capacity and impedance. Scanning transmission electron microscopy electron energy loss spectroscopy reveals a correlation between impedance rise and the level of transition metal reduction at the surfaces of aged NMC811. The present study provides insight into the leading causes for LIB performance fading, and highlights the defining role played by the evolving properties of the cathode particle surface layer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Targeting Drugs Against Fibroblast Growth Factor(s)-Induced Cell Signaling

Background:: The fibroblast growth factor (FGF) family is comprised of 23 highly regulatedmonomeric proteins that regulate a plethora of developmental and pathophysiological processes,including tissue repair, wound healing, angiogenesis, and embryonic development. Binding ofFGF to fibroblast growth factor receptor (FGFR), a tyrosine kinase receptor, is facilitated by a glycosaminoglycan,heparin. Activated FGFRs phosphorylate the tyrosine kinase residues that mediateinduction of downstream signaling pathways, such as RAS-MAPK, PI3K-AKT, PLCγ, andSTAT. Dysregulation of the FGF/FGFR signaling occurs frequently in cancer due to gene amplification,FGF activating mutations, chromosomal rearrangements, integration, and oncogenic fusions.Aberrant FGFR signaling also affects organogenesis, embryonic development, tissue homeostasis,and has been associated with cell proliferation, angiogenesis, cancer, and other pathophysiologicalchanges. Objective:: This comprehensive review will discuss the biology, chemistry, and functions of FGFs,and its current applications toward wound healing, diabetes, repair and regeneration of tissues, andfatty liver diseases. In addition, specific aberrations in FGFR signaling and drugs that target FGFRand aid in mitigating various disorders, such as cancer, are also discussed in detail. Conclusion:: Inhibitors of FGFR signaling are promising drugs in the treatment of several types ofcancers. The clinical benefits of FGF/FGFR targeting therapies are impeded due to the activationof other RTK signaling mechanisms or due to the mutations that abolish the drug inhibitory activityon FGFR. Thus, the development of drugs with a different mechanism of action for FGF/FGFRtargeting therapies is the recent focus of several preclinical and clinical studies.

Pharmacology & Pharmacy↗
NASA NTRS2016

C/NOFS Observations of Electromagnetic Coupling Between Magnetically Conjugate MSTID Structures

This report demonstrates empirically that couplings between magnetically conjugate medium-scale traveling ionospheric disturbances (MSTIDs) are electromagnetic in nature. This is accomplished by comparing plasma density, electric, and magnetic perturbations sampled simultaneously by sensors on the Communication Navigation Outage Forecasting System (CNOFS) satellite. During the period of interest on 17 February 2010, CNOFS made three consecutive orbits while magnetically conjugate to the field of view of an all-sky imager located at El Leoncito, Argentina (31.8degS, 69.3degW). Imaged 630.0 nm airglow was characterized by alternating bands of relatively bright and dark emissions that were aligned from northeast to southwest and propagated toward the northwest, characteristic of MSTIDs in the southern hemisphere. Measurable Poynting fluxes flow along the Earths magnetic field (S) from generator to load hemispheres. While S was predominantly away from the ionosphere above El Leoncito, interhemispheric energy flows were not one-way streets. Measured Poynting flux intensities diminished with time over the three CNOFS passes, suggesting that source mechanisms of MSTIDs were absent or that initial impedance mismatches between the two hemispheres approached an equilibrium status.

Burke, W. J.↗
DOE OSTI2021

A BEAM SCREEN TO PREPARE THE RHIC VACUUM CHAMBER FOR EIC HADRON BEAMS: CONCEPTUAL DESIGN AND REQUIREMENTS

The Electron Ion Collider (EIC) Hadron Storage Ring (HSR) will use the existing Relativistic Heavy Ion Collider storage rings, including the superconducting magnet arcs [1]. The vacuum chambers in the superconducting magnets and the cold mass interconnects were not designed for EIC beams and so must be updated to reduce resistive-wall heating and to suppress e-clouds. To do so without compromising the EIC luminosity goal, a stainless steel beam screen with colaminated copper and a thin layer of amorphous carbon will be installed. This paper describes the main requirements that our solution for the hadron ring vacuum chamber needs to satisfy, including impedance, aperture limitations, vacuum, thermal and structural stability, mechanical design, installation and operation. The conceptual design of the beam screen currently under development is introduced.

43 PARTICLE ACCELERATORS↗
DOE OSTI2023

Electrochemical Response of Alkaline Batteries Subject to Quasi-Static and Dynamic Loading

We report electrochemical changes were successfully monitored through the coupling of external loading, electrochemical impedance spectroscopy (EIS), and distribution of relaxation times (DRT) analysis. The development of the testing methods allows for detailed observation of changes due to mechanical loading and distinguishes responses between different cell geometries. Comparison of the force vs displacement, voltage vs displacement, and distribution of relaxation times plots to the different cell geometries display failure modes specific to geometry as well as the impact of different loading profiles. Numerical modeling confirmed the movement within individual cells and predicted locations with the most deformation based on the external loading condition applied. The results gathered from combining mechanical loading, electrochemical response, and numerical modeling, yield a viable approach to establishing an improved understanding of the effects of mechanical loading on the electrochemical response of multiple battery geometries and the methods herein may be extensible to additional battery chemistries.

25 ENERGY STORAGE↗
DOE OSTI2021

Microwave impedance microscopy and its application to quantum materials

We report materials in which quantum mechanical effects lead to novel properties on the macroscopic scale are of interest both fundamentally and for applications. For such quantum materials, the ability to measure local conductivity and permittivity with nanoscale spatial resolution, minimal sample preparation, in a contact-free fashion and under a wide range of external conditions (such as temperature and magnetic field) is highly desirable. To this end, microwave impedance microscopy, a scanning probe technique that measures tip–sample admittance (inverse of impedance) in a non-contact geometry at microwave frequencies, has matured over the past decade to become a tool that can do just that. This Technical Review describes its fundamental working principles and practical implementations, discusses its application to a wide range of quantum materials, including correlated, topological and 2D van der Waals materials, and outlines future opportunities in expanding the capabilities of microwave impedance microscopy.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Lignin impairs Cel7A degradation of in vitro lignified cellulose by impeding enzyme movement and not by acting as a sink

Abstract Background Cellulose degradation by cellulases has been studied for decades due to the potential of using lignocellulosic biomass as a sustainable source of bioethanol. In plant cell walls, cellulose is bonded together and strengthened by the polyphenolic polymer, lignin. Because lignin is tightly linked to cellulose and is not digestible by cellulases, is thought to play a dominant role in limiting the efficient enzymatic degradation of plant biomass. Removal of lignin via pretreatments currently limits the cost-efficient production of ethanol from cellulose, motivating the need for a better understanding of how lignin inhibits cellulase-catalyzed degradation of lignocellulose. Work to date using bulk assays has suggested three possible inhibition mechanisms: lignin blocks access of the enzyme to cellulose, lignin impedes progress of the enzyme along cellulose, or lignin binds cellulases directly and acts as a sink. Results We used single-molecule fluorescence microscopy to investigate the nanoscale dynamics of Cel7A from Trichoderma reesei , as it binds to and moves along purified bacterial cellulose in vitro. Lignified cellulose was generated by polymerizing coniferyl alcohol onto purified bacterial cellulose, and the degree of lignin incorporation into the cellulose meshwork was analyzed by optical and electron microscopy. We found that Cel7A preferentially bound to regions of cellulose where lignin was absent, and that in regions of high lignin density, Cel7A binding was inhibited. With increasing degrees of lignification, there was a decrease in the fraction of Cel7A that moved along cellulose rather than statically binding. Furthermore, with increasing lignification, the velocity of processive Cel7A movement decreased, as did the distance that individual Cel7A molecules moved during processive runs. Conclusions In an in vitro system that mimics lignified cellulose in plant cell walls, lignin did not act as a sink to sequester Cel7A and prevent it from interacting with cellulose. Instead, lignin both blocked access of Cel7A to cellulose and impeded the processive movement of Cel7A along cellulose. This work implies that strategies for improving biofuel production efficiency should target weakening interactions between lignin and cellulose surface, and further suggest that nonspecific adsorption of Cel7A to lignin is likely not a dominant mechanism of inhibition.

09 BIOMASS FUELS↗
DOE OSTI2024

Effect of H + Exchange and Surface Impurities on Bulk and Interfacial Electrochemistry of Garnet Solid Electrolytes

Contact loss and current constriction pose significant challenges at the Li metal interface of solid-state batteries. For garnet-structured Li 7 La 3 Zr 2 O 12 (LLZO), these effects are amplified by Li + /H + exchange and surface contamination reactions, which lead to conductivity losses and poor Li wetting. In this study, we utilize a variety of surface treatment processes across 37 cells to selectively induce proton exchange and contamination reactions in LLZO. The resulting bulk and surface chemistry is systematically characterized and correlated to changes in electrochemical properties. Additionally, we combine impedance analysis and finite element method modeling to deconvolute sources of impedance contributions at the Li metal interface. Specifically, we show that constriction impedance at the Li metal interface arises not solely from voids, but also from ionically-resistive surface contaminants. Further, these findings emphasize the connection between ionic conductivity and constriction, demonstrating that micron-scale ionically-resistive components increase constriction even with identical contact geometries. Finally, we leverage our comprehensive dataset to highlight unstable overpotential growth as a failure mechanism, additionally showing that the phase of a cell’s impedance is a sensitive indicator for the onset of interfacial instability. Overall, this study clarifies the impacts of proton exchange and surface contamination on electrochemical properties at the Li|solid electrolyte interface and elucidates insights that are generalizable to other solid-state battery systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1991

5-year lifetime hybrid superfluid helium dewar for the AXAF X-Ray Spectrometer (XRS)

The focal plane of the AXAF X-Ray Spectrometer requires an operating temperature of 0.1 K with a mission lifetime of 5 yrs. This demanding task is accomplished with a hybrid cryogenic subsystem consisting of mechanical coolers, a superfluid helium dewar and an adiabatic demagnetization refrigerator. By using mechanical coolers to remove heat from the dewar outer vapor-cooled shield, a 5-yr lifetime is achievable with only a 483-liter tank. This approach takes advantage of flight-proven, high-performance dewar technology and recent success in the development of split, Stirling-cycle mechanical coolers. Although the dewar design principles are similar to those used previously, parasitic heat flow is reduced to a new level by an optimized tension strap support system and careful attention to insulation system details. The benefit of the mechanical coolers is maximized by dewar interface design features that minimize parasitic heating and thermal impedance of the coupling. The dewar design and thermal performance analysis are discussed. Helium lifetime sensitivities and the effects of mechanical cooler failures are predicted.

Nieczkoski, Stephen J.↗
NASA NTRS1979

Effect of grazing flow on the acoustic impedance of Helmholtz resonators consisting of single and clustered orifices

A semiempirical fluid mechanical model is derived for the acoustic behavior of thin-walled single orifice Helmholtz resonators in a grazing flow environment. The incident and cavity sound fields are connected in terms of an orifice discharge coefficient whose values are determined experimentally using the two-microphone method. Measurements show that at high grazing flow speeds, acoustical resistance is almost linearly proportional to the grazing flow speed and almost independent of incident sound pressure. The corresponding values of reactance are much smaller and tend towards zero. For thicker-walled orifice plates, resistance and reactance were observed to be less sensitive to grazing flow as the ratio of plate thickness to orifice diameter increased. Loud tones were observed to radiate from a single orifice Helmholtz resonator due to interaction between the grazing flow shear layer and the resonator cavity. Measurements showed that the tones radiated at a Strouhal number equal to 0.26. The effects of grazing flow on the impedance of Helmholtz resonators consisting of clusters of orifices was also studied. In general, both resistance and reaction were found to be virtually independent of orifice relative spacing and number. These findings are valid with and without grazing flow.

Hersch, A. S.↗
DOE OSTI2025

Non-destructive electrochemical diagnosis of failure mechanisms in aqueous zinc batteries

The early detection of secondary reactions that affect the life and performance of zinc manganese oxide batteries requires a shift from conventional time-consuming and often destructive procedures to rapid lifetime-predictive techniques. In this work, an electrochemical approach is employed to elucidate independent signatures for four common types of failure mechanisms in zinc manganese dioxide (Zn||MnO2) batteries—namely, the loss of zinc inventory, the loss of active material at the cathode, electrolyte depletion, and increased cell impedance. Our findings, specific to coin cell configurations, reveal that each induced failure mechanism can be distinctively modeled and identified based on responses from the rest voltage and columbic-efficiency data for prompt detection. For instance, electrolyte depletion response manifests a distinctive abrupt (>80 %) decrease in columbic efficiency (CE) and charge-rest voltage (Vc) while the discharge-rest voltage remained constant at ~1.3 V. Furthermore, electrolyte rejuvenation of the cell increased the CE to >95 % and restored Vc from ~0.3 to >1.7 V. Recovery experiments and reference performance tests demonstrated consistency between electrochemical descriptors and their associated failure mechanisms. Further, the outcomes of this work provide valuable insights and data models for some of the dominant failure mechanisms present in zinc manganese battery chemistries, which are beneficial to accelerated early-lifetime diagnosis and advancement of Zn batteries development.

25 ENERGY STORAGE↗
NASA NTRS2012

Capacitance Probe Resonator for Multichannel Electrometer

A multichannel electrometer voltmeter has been developed that employs a mechanical resonator with voltage-sensing capacitance-probe electrodes that enable high-impedance, high-voltage, radiation-hardened measurement of an Internal Electrostatic Discharge Monitor (IESDM) sensor. The IESDM is new sensor technology targeted for integration into a Space Environmental Monitor (SEM) subsystem used for the characterization and monitoring of deep dielectric charging on spacecraft. The resonator solution relies on a non-contact, voltage-sensing, sinusoidal-varying capacitor to achieve input impedances as high as 10 petaohms as determined by the resonator materials, geometries, cleanliness, and construction. The resonator is designed with one dominant mechanical degree of freedom, so it resonates as a simple harmonic oscillator and because of the linearity of the variable sense capacitor to displacement, generates a pure sinusoidal current signal for a fixed input voltage under measurement. This enables the use of an idealized phase-lock sensing scheme for optimal signal detection in the presence of noise.

Blaes, Brent R.↗
DOE OSTI2023

Characterization and Electrochemical Analysis of Acidic Condensate-Induced Corrosion on Aluminized Coating on Steel in Residential Heaters

Condensing furnace residential heaters are starting to replace outdated and less efficient non-condensing units in homes across the US. However, the burning of natural gas in these new units produces acidic gases, which can form acid droplets (H 2 SO 4 , HNO 3 , H 2 CO 3 , etc.) that are corrosive to low-grade heat exchanger metallic materials. Type-1 aluminized steel has been used in industrial applications, such as marine, heating, and automobile parts, due to its resistance to oxidation at elevated temperature. Many components of the condensing furnaces, including heat exchangers, are made from type-1 aluminized steel. We investigated the interaction of type-1 aluminized steel substrates with two acidic condensate liquids by 500 h corrosion exposures as well as short-term electrochemical impedance measurements. SEM plan and cross-sectional view images revealed damage to the Al-Si rich layer and exposure of the steel substrate. The non-uniform damage in the Al-Si rich layer was likely attributed to a pitting corrosion mechanism and induced by high acidity of the condensate liquid. Electrochemical impedance measurements in an acidic condensate revealed lower corrosion resistance of the aluminized steel surface with a weld line, identifying welded sections as preferential corrosion initiation sites.

36 MATERIALS SCIENCE↗
NASA NTRS2012

Novel Phased Array Scanning Employing A Single Feed Without Using Individual Phase Shifters

Phased arrays afford many advantages over mechanically steered systems. However, they are also more complex, heavy, and most of all costly. The high cost mainly originates from the complex feeding structure. This paper proposes a novel feeding scheme to eliminate all phase shifters and achieve scanning via one-dimensional motion. Beam scanning is achieved via a series fed array incorporating feeding transmission lines whose wave velocity can be mechanically adjusted. Along with the line design, ideal element impedances to be used in conjunction with the line are derived. Practical designs are shown which achieve scanning to +/-30deg from boresight. Finally, a prototype is fabricated and measured, demonstrating the concept.

Host, Nicholas K.↗
NASA NTRS2008

Solid Micro Horn Array (SMIHA) for Acoustic Matching

Transduction of electrical signals to mechanical signals and vice-versa in piezoelectric materials is controlled by the material coupling coefficient. In general in a loss-less material the ratio of energy conversion per cycle is proportional to the square of the coupling coefficient. In practical transduction however the impedance mismatch between the piezoelectric material and the electrical drive circuitry or the mechanical structure can have a significant impact on the power transfer. This paper looks at novel methods of matching the acoustic impedance of structures to the piezoelectric material in an effort to increase power transmission and efficiency. In typical methods the density and acoustic velocity of the matching layer is adjusted to give good matching between the transducer and the load. The approach discussed in this paper utilizes solid micro horn arrays in the matching layer which channel the stress and increase the strain in the layer. This approach is found to have potential applications in energy harvesting, medical ultrasound and in liquid and gas coupled transducers.

power transmission↗
NASA NTRS1992

Eddy current characterization of magnetic treatment of materials

Eddy current impedance measuring methods have been applied to study the effect that magnetically treated materials have on service life extension. Eddy current impedance measurements have been performed on Nickel 200 specimens that have been subjected to many mechanical and magnetic engineering processes: annealing, applied strain, magnetic field, shot peening, and magnetic field after peening. Experimental results have demonstrated a functional relationship between coil impedance, resistance and reactance, and specimens subjected to various engineering processes. It has shown that magnetic treatment does induce changes in a material's electromagnetic properties and does exhibit evidence of stress relief. However, further fundamental studies are necessary for a thorough understanding of the exact mechanism of the magnetic-field processing effect on machine tool service life.

Chern, E. James↗
DOE OSTI2021

VTO_2021_APR_LLNL_Ye

Traditional batteries are composed of two-dimensional films that are stacked and/or rolled. Thin film batteries display high power density while their thick film counterparts show good energy density, but it has proven difficult to concurrently achieve both within these planar form factors. In addition, conventional Li-ion batteries based on liquid organic electrolytes or gel polymer electrolytes have raised severe safety concerns due to the intrinsic flammable properties of the organic electrolytes. They are also not ideal for the use of high energy density metallic lithium (Li) anodes due to Li dendrite growth, or sulfur cathodes due to shuttling effects that result in fast capacity fade. There is an urgent need to develop safe, high-performance solid-state batteries (SSBs) with advanced electrolyte and separator technologies. Although in recent years a series of superionic conductors have been developed for electrolytes and separators, their performance does not satisfy demanding criteria due to large impedance from poor solid electrolyte-electrode contact and questionable electrochemical and mechanical stability. Unlike the well-established roll-to-roll fabrication of conventional Li-ion batteries, the processing of SSBs is unique due to the brittleness of solid-state electrolytes (SSEs). The commercially available or lab-developed SSE discs are usually very thick (hundreds of micrometers to millimeters) to overcome their brittle nature, which unfortunately increases the cell impedance and accounts for the majority of the overall cell weight and volume, leading to dramatically decreased power and energy densities. In this project, we will investigate 3D printing techniques to overcome safety, fabrication, mechanical, and electrochemical issues in SSBs. 3D printing builds complex structures in a layer-by-layer fashion, which allows rapid production of hierarchical architectures, gradient and multi-material structures, and multi-component assemblies. 3D printing is an emerging area that could fundamentally transform energy storage devices. For example, 3D printing can produce batteries with arbitrary form factors to fit a product’s specific volume requirements and can create interwoven electrode arrangements over a wide range of length scales to improve transport and increase power density for a given energy density. For SSBs, 3D printing may dramatically reduce the separator thickness from ~1 mm (by hydraulic pressing) to tens of micrometers or less. In addition, the interfacial contact area between the electrolyte and the electrode may be increased via 3D interdigitated designs. Hence, we expect a significant reduction of the overall cell impedance and enhancement of both energy and power densities of SSBs by harnessing an array of 3D printing technologies being developed at Lawrence Livermore National Laboratory (LLNL).

25 ENERGY STORAGE↗