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At least 163 records · Page 9
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NASA NTRS2014

On the Relationship between Cosmic Ray Exposure Ages and Petrography of CM Chondrites

Carbonaceous (C) chondrites are potentially the most primitive among chondrites because they mostly escaped thermal metamorphism that affected the other chondrite groups. C chondrites are chemically distinguished from other chondrites by their high Mg/Si ratios and refractory elements, and have experienced various degrees of aqueous alteration. They are subdivided into eight subgroups (CI, CM, CO, CV, CK, CR, CB and CH) based on major element and oxygen isotopic ratios. Their elemental ratios vary over a wide range, in contrast to those of ordinary and enstatite chondrites which are relatively uniform. It is critical to know how many separate bodies are represented by the C chondrites. In this study we defined 4 distinct cosmic-ray exposure (CRE) age groups of CMs and systematically characterized the petrography in each of the 4 CRE age groups to determine whether the groups have significant petrographic differences with such differences probably reflecting different parent body (asteroid) geological processing, or multiple original bodies. We have reported the results of a preliminary grouping at the NIPR Symp. in 2013 [3], however, we revised the grouping and here report our new results.

Takenouchi, A.↗
NASA NTRSDate not supplied

Exploring the Atmosphere of Uranus with Small Next-generation Atmospheric Probe (SNAP)

In-situ atmospheric exploration of giant planets is a top priority of the planetary science community and NASA. The Galileo Probe a Jupiter made the first and only in-situ composition measurements of the atmosphere. Most importantly, the noble gas and isotopic ratio can be made only through in-situ measurements, and the Galileo Probe measurements must be followed up by similar measurements at Saturn, Uranus, and Neptune. In addition, abundances of condensable cloud-forming species are also needed to measure the vertical distribution of those molecules to provide ground-truths measurements for remote-sensing measurements. My talk will focus on the Small Next-generation Atmospheric Probe (SNAP) design developed in partnership by Hampton University and NASA Langley Research Center to enable delivery of multiple probes. Using SNAP as a reference design, I will also discuss key instrument trades and the state of the art in the atmospheric composition instruments.

Kunio Sayanagi↗
NASA NTRS2015

Characterization of Meteorites by Focused Ion Beam Sectioning: Recent Applications to CAIs and Primitive Meteorite Matrices

Focused ion beam (FIB) sectioning has revolutionized preparation of meteorite samples for characterization by analytical transmission electron microscopy (TEM) and other techniques. Although FIB is not "non-destructive" in the purest sense, each extracted section amounts to no more than nanograms (approximately 500 cubic microns) removed intact from locations precisely controlled by SEM imaging and analysis. Physical alteration of surrounding material by ion damage, fracture or sputter contamination effects is localized to within a few micrometers around the lift-out point. This leaves adjacent material intact for coordinate geochemical analysis by SIMS, microdrill extraction/TIMS and other techniques. After lift out, FIB sections can be quantitatively analyzed by electron microprobe prior to final thinning, synchrotron x-ray techniques, and by the full range of state-of-the-art analytical field-emission scanning transmission electron microscope (FE-STEM) techniques once thinning is complete. Multiple meteorite studies supported by FIB/FE-STEM are currently underway at NASA-JSC, including coordinated analysis of refractory phase assemblages in CAIs and fine-grained matrices in carbonaceous chondrites. FIB sectioning of CAIs has uncovered epitaxial and other overgrowth relations between corundum-hibonite-spinel consistent with hibonite preceding corundum and/or spinel in non-equilibrium condensation sequences at combinations of higher gas pressures, dust-gas enrichments or significant nebular transport. For all of these cases, the ability of FIB to allow for coordination with spatially-associated isotopic data by SIMS provides immense value for constraining the formation scenarios of the particular CAI assemblage. For carbonaceous chondrites matrix material, FIB has allowed us to obtain intact continuous sections of the immediate outer surface of Murchison (CM2) after it has been experimentally ion processed to simulate solar wind space weathering. The surface amorphization and loss of OH produced by the irradiation provides important clues regarding space weathering on primitive asteroids such as the OSIRIS-Rex target 101955 Bennu.

Christoffersen, Roy↗
NASA NTRS1994

A statistical equilibrium analysis of interstellar CO toward zeta Ophiuchi as recorded by the Goddard High Resolution Spectrograph

High-resolution and high signal-to-noise ratio echelle observations made by the Goddard High Resolution Spectrograph (GHRS), aboard the Hubble Space Telescope, of molecular (12)C(16)O and (13)C(16)O in the absorbing gas toward zeta Oph are reported. A statistical equilibrium model, incorporating a different way of dealing with the radiation field in the interstellar clouds, is presented. Based upon previous observations, two velocity components of the gas at V(sub LSR) = - 0.79 and 0.39 km/s, corresponding to solar velocity = -14.6 and -13.4 km/s, together with three different sets of velocity dispersions are adopted in our models. The ratios of the computed emergent intensities (I(sub em)) resulting from the emission lines in the lowest transitions (J = 1 goes to 0, 2 goes to 1, 3 goes to 2) of ground state of CO are presented. The ratios for the two velocity components, (I(sub em)(1 goes to 0)(sub 1))/(I(sub em)(1 goes to 0)(sub 2)), and (I(sub em)(2 goes to 1)(sub 1))/I(sub em)(1 goes to 0)(sub 1)) are comparable to the observed corrected antenna temperature ratios. From the solutions to the statistical equilibrium equations including the six lowest rotational transitions of CO and from multiple Voigt profile fits, the observed (12)CO and (13)CO UV abroption features are successfully reproduced. Profile fitting and double cloud curve-of-growth analysis using the GHRS and Copernicus data indicate that the abundance of CO is (1.8 +/- 0.2) x 10(exp 15)/sq cm. The most recently measured wavelength of the (6 goes to 0) (13)CO band by Haridass & Huber (R(0) = 1370.616 A) shows that the tentative (13)CO features in the GHRS data are unquestionably identified. If there is no blending from any other unknown interstellar species, the isotope ratio of (12)CO/(13)CO is approximately 82 +/- 25. This result is close to the terrestrial value of 90 and implies that the CO is not substantially fractionated, and (12)C(16)O experiences little preferential self-shielding through the selective isotopic photodissociation process. This conclusion differs strongly with that of Sheffer et al. Other implications of the results are discussed.

Lyu, Cheng-Hsuan↗
NASA NTRS2016

Catastrophic Impact of Silicon on Silicon: Unraveling the Genesis Impact Using Sample 61881

The Genesis mission collected solar wind and brought it back to Earth in order to provide precise knowledge of solar isotopic and elemental compositions. The ions in the solar wind were stopped in the collectors at depths on the order of 10 to a few hundred nanometers. This shallow implantation layer is critical for scientific analysis of the composition of the solar wind and must be preserved throughout sample handling, cleaning, processing, distribution, preparation and analysis. The current work is motivated by the need to understand the interaction of the Genesis payload with contamination during the crash in the Utah desert. Silicon contamination has been found to be notoriously difficult to remove from silicon samples despite multiple cleanings with multiple techniques. However, the question has been posed, "Does the silicon really need to be removed for large area analyses?." If the recalcitrant silicon contamination is all pure silicon from fractured collectors, only a very tiny fraction of that bulk material will contain solar wind, which could skew the analyses. This could be complicated if the silicon trapped other materials and/or gases as it impacted the surface.

Kuhlman, K. R.↗
NASA NTRS2023

PAHs, Hydrocarbons, and Dimethylsulfides in Asteroid Ryugu Samples A0106 and C0107 and the Orgueil (CI1) Meteorite

Evaluating the molecular distribution of organic compounds in pristine extraterrestrial materials is cornerstone to understanding the abiotic synthesis of organics and allows us to better understand the molecular diversity available during the formation of our solar system and before the origins of life on Earth. In this work we identify multiple organic compounds in solvent extracts of asteroid Ryugu samples A0106 and C0107 and the Orgueil meteorite using two-dimensional gas chromatography and time-of-flight high resolution mass spectrometry (GC×GC-HRMS). Our analyses found similarities between the molecular distribution of organic compounds in Ryugu and the CI carbonaceous chondrite Orgueil. Specifically, several PAHs and organosulfides were found in Ryugu and Orgueil suggesting an interstellar and parent body origin for these compounds. We also evaluated the common relationship between Ryugu, Orgueil, and comets like Wild-2; however, until comprehensive compound-specific isotopic analyses for these organic species are undertaken, and until the effects of parent body processes and Earth’s weathering processes on meteoritic organics are better understood, their parent-daughter relationships will remain unanswered. Finally, the study of organic compounds in Ryugu samples and the curation practices for the future preservation of these unvaluable materials are also of special interest for future sample return missions, including NASA’s OSIRIS-REx asteroid sample return mission.

Hayabusa2↗
NASA NTRS2011

Plasma IMS Composition Measurements for Europa, Ganymede, and the Jovian Systems

NASA and ESA are now planning a reduced version of the joint Europa Jupiter System Mission (EJSM), potentially including a radically descoped Jupiter Europa Orbiter (JEO) but still with magnetometer and plasma instruments. Similar field and plasma instrumentation would also reside on ESA's Jupiter Ganymede Orbiter (JGO), which conceivably could carry out multiple flybys of Europa before entering orbit at Ganymede. We are developing the 3D Ion Mass Spectrometer (IMS) designed to measure both major and minor ion species within the high radiation environment of Jupiter s magnetosphere and the icy Galilean moons. The IMS covers the energy range from 10 eV to 30 keV, wide field-ofview (FOV) capability and 10-60 sec time resolution for major ions. This instrument has two main goals: 1) measure the plasma interaction between Europa and Jupiter s magnetosphere and 2) infer the global surface composition to trace elemental and significant isotopic levels; these goals are also applicable for in-situ measurements at Ganymede and Callisto, and remotely everywhere via the iogenic plasma for Io. The first goal supports the magnetometer (MAG) measurements, primarily directed at detection of Europa's sub-surface ocean, while the second goal gives information about transfer of material between the Galilean moons, e.g. mainly from Io to the other moons, and further allows detection of oceanic materials emergent to the moon surfaces from subsurface layers putatively including salt water oceans. Outgassed exospheric materials are probed by the IMS by measuring pickup ions accelerated up to spacecraft altitudes of approximately 100-200 km in electric fields extending through the local magnetospheric environment and moon exosphere to the surface. Our 3D hybrid kinetic model of the moon-magnetosphere interaction is used to construct a global model of electric and magnetic fields for tracing of pickup ion trajectories back to the sources at approximate surface resolution of 100 km. We show that Europa's exospheric ionosphere is dominated by pickup ions with energies of 100-1000 eV. We also expect field aligned polar ion outflows driven by ionospheric electrons via the polarization electric field at Europa; the IMS will observe such outflows and thus sample the ionosphere below spacecraft orbit altitude approximately 100 km. Based on previous Ganymede studies, we also comment on IMS applications to a Ganymede orbiter. The IMS and the Europa interaction model are respectively being developed with support from NASA's Astrobiology Instrument Development (ASTID) and Outer Planets Research (OPR) programs.

Sittler, E.↗
NASA NTRS2011

Plasma IMS Composition Measurements for Europa, Ganymede, and the Jovian System

NASA and ESA are now planning a reduced version of the joint Europa Jupiter System Mission (EJSM), potentially including a radically descoped Jupiter Europa Orbiter (JEO) but still with magnetometer and plasma instruments. Similar field and plasma instrumentation would also reside on ESA's Jupiter Ganymede Orbiter (JGO), which conceivably could carry out multiple flybys of Europa before entering orbit at Ganymede. We are developing the 3D Ion Mass Spectrometer (IMS) designed to measure both major and minor ion species within the high radiation environment of Jupiter's magnetosphere and the icy Galilean moons. The IMS covers the energy range from 10 eV to 30 keY, wide field-of-view (FOV) capability and 10-60 sec time resolution for major ions. This instrument has two main goals: 1) measure the plasma interaction between Europa and Jupiter's magnetosphere and 2) infer the global surface composition to trace elemental and significant isotopic levels; these goals are also applicable for in-situ measurements at Ganymede and Callisto, and remotely everywhere via the iogenic plasma for 10. The first goal supports the magnetometer (MAG) measurements, primarily directed at detection of Europa's sub-surface ocean, while the second goal gives information about transfer of material between the Galilean moons, e.g. mainly from 10 to the other moons, and further allows detection of oceanic materials emergent to the moon surfaces from subsurface layers putatively including salt water oceans. Outgassed exospheric materials are probed by the IMS by measuring pickup ions accelerated up to spacecraft altitudes of approximately 100-200 km in electric fields extending through the local magnetospheric environment and moon exosphere to the surface. Our 3D hybrid kinetic model of the moon-magnetosphere interaction is used to construct a global model of electric and magnetic fields for tracing of pickup ion trajectories back to the sources at approximate surface resolution of 100 km. We show that Europa's exospheric ionosphere is dominated by pickup ions with energies of 100-1000 eV. We also expect field aligned polar ion outflows driven by ionospheric electrons via the polarization electric field at Europa; the IMS will observe such outflows and thus sample the ionosphere below spacecraft orbit altitude approximately 100 km. Based on previous Ganymede studies, we also comment on IMS applications to a Ganymede orbiter. The IMS and the Europa interaction model are respectively being developed with support from NASA's Astrobiology Instrument Development (ASTID) and Outer Planets Research (OPR) programs.

Sittler, E. C., Jr.↗
NASA NTRSDate not supplied

Development of Radioluminescent Tritium Polymeric Material for High Visibility Applications

The Development of Radioluminescent Tritium Polymeric Material for High Visibility Applications effort investigates the nature and properties of materials consisting of tritium lights combined with various silicone adhesives. Physical, mechanical, and optical properties will be observed/measured, including their durability in the low earth orbit environment. Tritium or hydrogen-three is a radioactive isotope of hydrogen that emits beta particles as it undergoes a process called beta decay. A beta particle is a high-energy, high-speed electron (or positron) emitted from radioactive decay of an atomic nucleus. Because it is a gas, tritium must be bound to a material or encapsulated in a sealed glass container. The gaseous tritium can then be combined with a phosphor source which when struck with beta particles, fluoresces and emits light. Such a light source is referred to as a gaseous tritium light source (GTLS). A self-powered, radioluminescent tritium material capable of surviving multiple space environments has the potential to fulfill visibility requirements levied on space flight hardware and facilitate additional long term internal and external lighting needs such as for imaging, docking, tracking, and xEMU suits for lunar exploration on the moon.

Lauren Fisher↗
NASA NTRS1974

The continuous measurement of hydrogen chloride in the ambient atmosphere using the dual isotope infrared absorption technique

The results of a program to develop a prototype gas filter correlation NDIR analyzer capable of providing the required HCl measurement capability, while maintaining an adequate rejection of any other gases anticipated in the atmosphere are presented. Examples of the performance of the prototype analyzer are presented which show an rms noise equivalent concentration of 0.06 ppm of HCl was achieved while maintaining an electronically determined 10% to 90% time response to gas samples of about 2 seconds. No measureable response was observed to CO2, CO, and H2O while maintaining an adequate rejection of the hydrocarbons, for example CH4 and n-hexane. The experiments were performed which demonstrate that the span stability of the HCl gas filter correlation analyzer is unaffected by the presence of water vapor and which support the belief that the incorporation of a relatively open-volume, multiple path sample cell into the instrument would enable ground station as well as airborne measurements of trace quantities of HCl in the ambient atmosphere to be performed.

Williams, K. G.↗
NASA NTRS2011

The 100th Anniversary of the Fall of Nakhla: The Subdivision of BM1913,25

This year marks the 100th anniversary of the fall of Nakhla, a cumulate clinopyroxenite of martian origin that fell near Alexandria, Egypt in 1911. Multiple fragments of the meteorite were seen to fall over an area of 4.5 km in diameter. Approximately 40 stones were recovered with a combined weight of about 10 kg. Most of the larger specimens found their way to museums and meteorite collections in Cairo, Paris, Berlin, and the Smithsonian, to name a few. In 1998, the British Museum sent a 641g (BM1913,25), fully fusion crusted stone of Nakhla to the Johnson Space Center (JSC) for processing in the Antarctic Meteorite Lab in order to allocate samples to the scientific community. The stone was split in half in a dry nitrogen glove box. One half of the stone was sent back to the museum and the other half (346g) was used for sample allocations. From 1998-2001, 37 scientists requested 65 separate samples of Nakhla, including 2 thin sections This set of allocations was especially important in that all of the sample splits are from the same piece of Nakhla and it had a known history since it was acquired by the museum in 1913. With the multiple fragments of Nakhla, it is not known from what pieces the main bulk of research has been done, what variation may exist between all the pieces and to what contaminants the fragments may have been exposed, (i.e. water, solvents or cutting fluids, etc.). All of the allocations prepared at JSC were processed in a nitrogen cabinet using only stainless steel, aluminum, and Teflon tools and containers to reduce the chance of introducing any new contaminants. The focused effort to subdivide and distribute samples of Nakhla to the meteorite community resulted in enhanced under-standing of Nakhla and nakhlites in general: organic geochemistry, weathering, sulfur isotopes, radiometric age, and magmatic history. There are 13 Nakhlites that have been recovered to date: Nakhla, Layfayette, Governador Valdares, three from NW Africa, three from Yamato and four from Miller Range regions in Antarctica. The Yamato Nakhlites are paired as are the Miller Range samples.

McBridge, Kathleen M.↗
NASA NTRS2005

In-situ exploration of Venus on a global scale : direct measurements of origins and evolution, meterology, dynamics, and chemistry by a long-duration aerial science station

Drifting in the strong winds of Venus under benign Earth-like temperature and pressure conditions, an instrumented balloon-borne science station presents a viable means to explore, in-situ, the Venusian atmosphere on a global scale. Flying over the ground at speeds exceeding 240 km/hour while floating in the Venusian skies near 55 km altitude for several weeks, such an aerostat can conduct a 'world tour' of our neighboring planet, as it circumnavigates the globe multiple times during its flight from equatorial to polar latitudes. Onboard science sensors can repeatedly and directly sample gas compositions, atmospheric pressures and temperatures and cloud particle properties, giving unprecedented insight into the chemical processes occurring within the sulfuric clouds. Additionally, interferometric tracking via Earth-based radio observatories can yield positions and windspeeds to better than 10 cm/sec over one-hour periods, providing important information for understanding the planet's meridional circulation and enigmatic zonal super-rotation, as well as local dynamics associated with meteorological processes. As well, hundreds of GCMS spectra collected during the flight can provide measurements of noble gas compositions and their isotopes with unprecedented accuracy, thereby enabling fundamental new insights into Venus's origin and evolution.

Venus↗
NASA NTRS2013

The Impact and Oxidation Survival of Selected Meteoritic Compounds: Signatures of Asteroid Organic Material on Planetary Surfaces

Polar, non-volatile organic compounds may be present on the surfaces (or near surfaces) of multiple Solar System bodies. If found, by current or future missions, it would be desirable to determine the origin(s) of such compounds, e.g., asteroidal or in situ. To test the possible survival of meteoritic compounds both during impacts with planetary surfaces and under subsequent (possibly) harsh ambient conditions, we subjected known meteoritic compounds to relatively high impact-shock pressures and/or to varying oxidizing/corrosive conditions. Tested compounds include sulfonic and phosphonic acids (S&P), polyaromatic hydrocarbons (PAHs) amino acids, keto acids, dicarboxylic acids, deoxy sugar acids, and hydroxy tricarboxylic acids (Table 1). Meteoritic sulfonic acids were found to be relatively abundant in the Murchison meteorite and to possess unusual S-33 isotope anomalies (non mass-dependent isotope fractionations). Combined with distinctive C-S and C-P bonds, the S&P are potential signatures of asteroidal organic material.

Cooper, George↗
NASA NTRS1992

U-Pb isotopic results for single shocked and polycrystalline zircons record 550-65.5-Ma ages for a K-T target site and 2700-1850-Ma ages for the Sudbury impact event

The refractory mineral zircon develops distinct morphological features during shock metamorphism and retains these features under conditions that would anneal them in other minerals. In addition, weakly shocked zircon grains give primary ages for the impact site, while highly reconstituted (polycrystalline) single grains give ages that approach the age of the impact event. Data for a series of originally coeval grains will define a mixing line that gives both of these ages providing that no subsequent geological disturbances have overprinted the isotopic systematics. In this study, we have shown that the three zircon grain types described by Bohor, from both K-T distal ejecta (Fireball layer, Raton Basin, Colorado) and the Onaping Formation, represent a progressive increase in impact-related morphological change that coincides with a progressive increase in isotopic resetting in zircons from the ejecta and basement rocks. Unshocked grains are least affected by isotopic resetting while polycrystalline grains are most affected. U-Pb isotopic results for 12 of 14 single zircon grains from the Fireball layer plot on or close to a line recording a primary age of 550 +/- 10 Ma and a secondary age of 65.5 +/- 3 Ma. Data for the least and most shocked grains plot closest to the primary and secondary ages respectively. The two other grains each give ages between 300 and 350 Ma. This implies that the target ejecta was dominated by 550-Ma rocks and that the recrystallization features of the zircon were superimposed during the impact event at 65.5 Ma. A predominant age of 550 Ma for zircons from the Fireball layer provides an excellent opportunity to identify the impact site and to test the hypothesis that multiple impacts occurred at this time. A volcanic origin for the Fireball layer is ruled out by shock-related morphological changes in zircon and the fact that the least shocked grains are old. Basement Levack gneisses north of the Sudbury structure have a primary age of 2711 Ma. Data for three single zircons from this rock, which record a progressive increase in shock features, are displaced 24, 36, and 45 percent along a Pb-loss line toward the 1850 +/- 1 Ma minimum age for the impact as defined by the age of the norite. Southeast of the structure three shocked grains from the Murray granite record a primary age of 2468 Ma and are displaced 24, 41, and 56 percent toward the 1853 +/- 4 Ma even as defined by coexisting titanite.

Krogh, T. E.↗
NASA NTRS2002

Neutral Gas and Ion Measurements by the CONTOUR Mission

The Neutral Gas and Ion Mass Spectrometer (NGIMS) on the Comet Nucleus Tour (CONTOUR) Mission will measure the chemical and isotopic composition of neutral and ion species in the coma of comet Encke and the subsequent targets of this mission. Currently the second target of this mission is comet Schwassmann-Wachmann 3. This neutral gas and ion data together with complementary data from the dust analyzer and the imaging spectrometer is designed to allow a broad characterization of the molecular and elemental composition of each cometary nucleus. These experiments enable the study of the of the likely variations in chemical conditions present in different regions of the early solar nebula where the comets formed. With these experiments we will also test ideas about cometary contributions of organics, water, and other volatiles to the inner planets. The CONTOUR NGIMS data set from multiple comets is expected to provide an important extension of to the only other detailed in situ data set from a close flyby of a nucleus, that from Halley. CONTOUR will extend this measurement of an Oort cloud comet to the class of short period comets thought to originate in the Kuiper belt. This data will complement the detailed measurements to be carried out at a single nucleus by the Rosetta Mission.

Mahaffy, Paul R.↗
NASA NTRS2012

The Spatial Distribution of Organic Matter and Mineralogical Relationships in Carbonaceous Chondrites

Organic matter present within primitive carbonaceous meteorites represents the complex conglomeration of species formed in a variety of physically and temporally distinct environments including circumstellar space, the interstellar medium, the Solar Nebula & Jovian sub-nebulae and asteroids. In each case, multiple chemical pathways would have been available for the synthesis of organic molecules. Consequently these meteorites constitute a unique record of organic chemical evolution in the Universe and one of the biggest challenges in organic cosmochemistry has been in deciphering this record. While bulk chemical analysis has provided a detailed description of the range and diversity of organic species present in carbonaceous chondrites, there is virtually no hard experimental data as to how these species are spatially distributed and their relationship to the host mineral matrix, (with one exception). The distribution of organic phases is nevertheless critical to understanding parent body processes. The CM and CI chondrites all display evidence of low temperature (< 350K) interaction with aqueous fluids, which based on O isotope data, flowed along thermal gradients within the respective parent bodies. This pervasive aqueous alteration may have led to aqueous geochromatographic separation of organics and synthesis of new organics coupled to aqueous mineral alteration. To address such issues we have applied the technique of microprobe two-step laser desorption / photoionization mass spectrometry (L2MS) to map in situ the spatial distribution of a broad range of organic species at the micron scale in the freshly exposed matrices of the Bells, Tagish Lake and Murchison (CM2) carbonaceous chondrites.

Clemett, S. J.↗
NASA NTRS2022

The Co2 Profile and Analytical Model for the Pioneer Venus Large Probe Neutral Mass Spectrometer

We present a significantly updated CO2 altitude profile for Venus (64.2–0.9 km) and provide support for a potential deep lower atmospheric haze of particles (≤17 km). We extracted this information by developing a new analytical model for mass spectra obtained by the Pioneer Venus Large Probe (PVLP) Neutral Mass Spectrometer (LNMS). Our model accounts for changes in LNMS configuration and output during descent and enables the disentanglement of isobaric species via a data fitting routine that adjusts for mass-dependent changes in peak shape. The model yields CO2 in units of density (kg m−3), isotope ratios for 13C/12C and 18O/16O, and 14 measures of CO2 density across 55.4–0.9 km, which represents the most complete altitude profile for CO2 at ≤60 km to date. The CO2 density profile is also consistent with the pressure, temperature, and volumetric gas measurements from the PVLP and VeNeRa spacecraft. Nominal and low-noise operations for the LNMS mass analyzer are supported by the behaviors (e.g., ionization yields, fragmentation yields, and peak shapes) of several internal standards (e.g., CH3+, CH4+, 40Ar+, 136Xe2+, and 136Xe+), which were tracked across the descent. Lastly, our review of the CO2 profile and LNMS spectra reveals hitherto unreported partial and rapidly clearing clogs of the inlet in the lower atmosphere, along with several ensuing data spikes at multiple masses. Together, these observations suggest that atmospheric intake was impacted by particles at ≤17 km and that rapid particle degradation at the inlet yielded a temporary influx of mass signals into the LNMS.

Venus↗
NASA NTRS1983

Influence of the Mediterranean outflow on the isotopic composition of neodymium in waters of the North Atlantic

Measurements of the Nd-143/Nd-144 ratio, expressed as epsilon-Nd(0), made in sea water samples obtained at depths from 0 to 4850 m at stations 95, 101, and 30 of North-Atlantic cruise 109-1 of the RV Atlantis II are reported and analyzed. In the 1000-m sample at station 95, determined by salinity, O2, PO4, NO3, SiO2, potential-temperature, and pressure profiles to correspond to the core of the Mediterranean outflow, an epsilon-Nd(0) value of -9.8 + or - 0.6 was found, a significant increase over the layers above and below, where epsilon-Nd(0) is about -12. Mixing estimations give a value for pure Mediterranean waters of approximately -6; continental drainage or volcanic deep-sea sediments are considered possible sources for this more radiogenic Nd. The epsilon-Nd(0) peak in the western North Atlantic (station 30) is found at the surface, and the deep waters are less radiogenic than in the eastern North Atlantic, suggesting multiple Nd sources. Possible origins and distribution mechanisms are discussed.

Piepgras, D. J.↗