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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

The transport of nitric oxide by the mean circulation and planetary waves

The effects of planetary waves on atmospheric nitric oxide (NO) concentration were investigated using a time-dependent numerical model. The model is used to calculate planetary wave and zonal mean winds, which in turn are used to calculate mean and perturbation NO distribution. The time-dependent model is used to determine equilibrium NO distributions resulting from time-dependent lower boundary planetary wave forcings. The factors which contribute to the zonal mean NO concentration are examined. NO chemistry is modelled using a simplified source sink approach. Changes in the initial NO distribution which result from the addition of planetary-wave winds are described. Planetary waves are found to induce a wavelike structure in the NO distribution which resembles that derived from observational data. These waves affect the NO concentration through wave-induced changes in the mean meridional circulation and through the NO perturbation induuced by the wave winds themselves.

Jones, G. A.↗
NASA NTRS1987

Airborne intercomparison of nitric oxide measurement techniques

Results from an airborne intercomparison of techniques to measure tropospheric levels of nitric oxide (NO) are discussed. The intercomparison was part of the National Aeronautics and Space Administration's Global Tropospheric Experiment and was conducted during missions flown in the fall of 1983 and spring of 1984. Instruments intercompared included a laser-induced fluorescence (LIF) system and two chemiluminescence instruments (CL). NO mixing ratios from below 5 pptv (parts per trillion by volume) to greater than 100 pptv were reported, with the majority less than 20 pptv. Good correlation was observed between the measurements reported by the CL and LIF techniques. The general level of agreement observed for the ensemble of measurements obtained during the two missions provides the basis from which one can conclude that equally 'valid' measurements of background levels of NO can be expected from either CL or LIF instruments. At the same time the periods of disagreement that were observed between the CL and LIF instruments as well as between the two CL instruments highlight the difficulty of obtaining reliable measurements with NO mixing ratios in the 5-20 pptv range and emphasize the vigilance that should be maintained in future NO measurements.

Hoell, James M., Jr.↗
NASA NTRS1988

Enhanced biogenic emissions of nitric oxide and nitrous oxide following surface biomass burning

Recent measurements indicate significantly enhanced biogenic soil emissions of both nitric oxide (NO) and nitrous oxide (N2O) following surface burning. These enhanced fluxes persisted for at least six months following the burn. Simultaneous measurements indicate enhanced levels of exchangeable ammonium in the soil following the burn. Biomass burning is known to be an instantaneous source of NO and N2O resulting from high-temperature combustion. Now it is found that biomass burning also results in significantly enhanced biogenic emissions of these gases, which persist for months following the burn.

Anderson, Iris C.↗
NASA NTRS1992

Nitric oxide in the middle to upper thermosphere

The results of six rocket observations of thermospheric nitric oxide are reviewed and reconciled with the available laboratory photochemical data. The impact of the recently revised recommendation for the N (S-4) + O2 rate coefficient on photochemical models is assessed. Use of the new rate coefficient leads to significantly enhanced production of NO, particularly at F-region altitudes during solar maximum conditions. A comparison of photochemical calculations with the rocket profiles indicates that the new rate coefficient introduces a significant discrepancy which can be resolved if the recombination reaction of N + NO is temperature dependent. Calculations using the preposed rate coefficient predict the NO solar cycle variation at 180 km to be less than at 140 km, which is also in agreement with the observations.

Siskind, David E.↗
NASA NTRS1998

Development of UV Optical Measurements of Nitric Oxide and Hydroxyl Radical at the Exit of High Pressure Gas Turbine Combustors

Measurements of nitric oxide (NO) and hydroxyl radical (OR) have been made in a laboratory flat flame at pressures up to 30 atm using line-of-sight resonant absorption. Data are reported at equivalence ratios of 0.98 and 1.3 and pressures of 1, 5, 10, 20 and 30 atm. The performance of the in-situ LTV absorption technique with assessed at these elevated pressures by comparing the measured absorption with those predicted by detailed theoretical spectroscopic models for NO and OH. Previous to this experiment the resonant models had not been verified at pressures greater than two atmospheres. Agreement within 25% was found between the measurements and predictions with only slight modification of the existing models for both NO and OH to account for line center shifting and pressure broadening. Continuum interference of hot oxygen (O2) on the NO absorption spectra was not significant in the interpretation of the data. The optical methods used in this study are distinct from laser-based diagnostics such as laser induced fluorescence and, hence, have the potential to provide independent verification of the laser-based measurements. The methodology is also of sufficient simplicity to be hardened into a portable optical measurement system that can be deployed in gas turbine engine test cells. A miniature fiber optic couple portable instrument is described.

Liscinsky, D. S.↗
NASA NTRS2015

Nitric Oxide PLIF Visualization of Simulated Fuel-Air Mixing in a Dual-Mode Scramjet

Nitric oxide (NO) planar induced laser fluorescence (PLIF) measurements have been performed in a small scale scramjet combustor at the University of Virginia Aerospace Research Laboratory at nominal simulated Mach 5 flight. A mixture of NO and N2 was injected at the upstream end of the inlet isolator as a surrogate for ethylene fuel, and the mixing of this fuel simulant was studied with and without a shock train. The shock train was produced by an air throttle, which simulated the blockage effects of combustion downstream of the cavity flame holder. NO PLIF signal was imaged in a plane orthogonal to the freestream at the leading edge of the cavity. Instantaneous planar images were recorded and analyzed to identify the most uniform cases, which were achieved by varying the location of the fuel injection and shock train. This method was used to screen different possible fueling configurations to provide optimized test conditions for follow-on combustion measurements using ethylene fuel. A theoretical study of the selected NO rotational transitions was performed to obtain a LIF signal that is linear with NO mole fraction and approximately independent of pressure and temperature.

Cantu, Luca M. L.↗
DOE OSTI2024

Diversity and evolution of nitric oxide reduction in bacteria and archaea

Nitrous oxide is a potent greenhouse gas whose production is catalyzed by nitric oxide reductase (NOR) members of the heme-copper oxidoreductase (HCO) enzyme superfamily. We identified several previously uncharacterized HCO families, four of which (eNOR, sNOR, gNOR, and nNOR) appear to perform NO reduction. These families have novel active-site structures and several have conserved proton channels, suggesting that they might be able to couple NO reduction to energy conservation. We isolated and biochemically characterized a member of the eNOR family from the bacterium Rhodothermus marinus and found that it performs NO reduction. These recently identified NORs exhibited broad phylogenetic and environmental distributions, greatly expanding the diversity of microbes in nature capable of NO reduction. Phylogenetic analyses further demonstrated that NORs evolved multiple times independently from oxygen reductases, supporting the view that complete denitrification evolved after aerobic respiration.

Science & Technology - Other Topics↗
NASA NTRS1996

Fluid flow stimulates rapid and continuous release of nitric oxide in osteoblasts

Interstitial fluid flow may mediate skeletal remodeling in response to mechanical loading. Because nitric oxide (NO) has been shown to be an osteoblast mitogen and inhibitor of osteoclastic resorption, we investigated and characterized the role of fluid shear on the release of NO in osteoblasts. Rat calvarial cells in a stationary culture produced undetectable levels of NO. Fluid shear stress (6 dyn/cm2) rapidly increased NO release rate to 9.8 nmol.h-1.mg protein-1 and sustained this production for 12 h of exposure to flow. Cytokine treatment also induced NO synthesis after a 12-h lag phase of zero production, followed by a production rate of 0.6 nmol.h-1.mg protein-1. Flow-induced NO production was blocked by the NO synthase (NOS) inhibitor NG-amino-L-arginine, but not by dexamethasone, which suggests that the flow stimulated a constitutive NOS isoform. This is the first time that a functional constitutively present NOS isoform has been identified in osteoblasts. Moreover, fluid flow represents the most potent stimulus of NO release in osteoblasts reported to date. Fluid flow-induced NO production may therefore play a primary role in bone maintenance and remodeling.

NASA Discipline Cell Biology↗
NASA NTRS1999

Role of the anterior region of the third ventricle in the cardiovascular responses produced by systemic injection of a nitric oxide synthase inhibitor

This study examined whether a prior electrolytic lesion of the tissue surrounding the anteroventral third ventricle (AV3V) would affect the increase in mean arterial blood pressure (MAP) and the fall in heart rate (HR) produced by systemic injection of the nitric oxide synthesis (NOS) inhibitor, NG-nitro-L-arginine methyl ester (L-NAME; 25 micromol/kg, i.v.) in conscious rats. L-NAME produced a smaller increase in MAP in AV3V-lesion than in sham-lesion rats (+19+/-3 vs. +40+/-3 mmHg, respectively; P<0.05). In contrast, L-NAME produced similar falls in HR in the AV3V-lesion and sham-lesion rats (-103+/-15 vs. -97+/-8 bpm, respectively; P<0.05). These findings demonstrate that the L-NAME-induced pressor response is dependent upon the integrity of the AV3V region, whereas the L-NAME-induced bradycardia is not. Copyright 1999 Elsevier Science B. V.

Non-NASA Center↗
NASA NTRS1972

Electron-impact excitation of nitric oxide.

The absolute cross sections for the excitation of the nitrosyl cation Baer-Miescher bands, two nitric oxide bands, and several atomic nitrogen multiplets in the vacuum UV by electron impact on NO have been measured over an energy range extending from threshold to 300 eV. The variation of the dipole transition moment for the nitrosyl cation band system was also determined.

Stone, E. J.↗
NASA NTRS1974

Ultraviolet source for rocket measurements of nitric oxide in the upper atmosphere

An ultraviolet source suitable for balloon and rocket payloads for measurements of nitric oxide in the lower D-region of the ionosphere was developed. The source primarily emits 1236 A and 1165 A photons obtained from an R.F.-excited krypton discharge in a resonator of coaxial geometry. Ultraviolet flux output greater than 10 to the 14th power photons/sec can be obtained from this source. A systematic design philosophy is developed which enables the photon output to be optimized with respect to photon wavelength, gas pressure, R.F., resonator geometry, and gas to be used. Critical factors in the design are discussed in detail.

Siddiqui, J. M. H.↗
NASA NTRS1977

Nitric oxide gamma band emission rate factor

Molecular fluorescence emission rate factors for the strong bands of the nitric oxide gamma system have been calculated using recent branching ratios and different temperatures. For the 1-0 gamma band the effects of self-absorption by NO have been taken into account, and effective emission rate factors were calculated for a range of NO column densities at several different temperatures. For column densities near 10 to the 16th/sq cm self-absorption corrections to the emission rate factor can be significant. The emission rate factor for the 1-0 gamma band is 7.19 or 7.68 x 10 to the -6th photons/molecule/sec depending upon the use of experimental or theoretical branching ratios.

Cravens, T. E.↗
NASA NTRS2020

Nitric Oxide Laser-Induced Fluorescence Rotational Thermometry in a Hypersonic Non-Equilibrium Flow

Spatially-resolved nitric oxide (NO) planar laser-induced fluorescence (PLIF) rotational thermometry was performed on a Mach 5 non-equilibrium flow around a blunt-body specimen in the Hypersonic Materials Environmental Test System (HyMETS) arc-heat wind tunnel at the NASA Langley Research Center. Transitions within the (0,0) band in the A(exp⁡ 2)∑(sup⁡ +) - X(exp⁡ 2)Π system of NO were excited with a 10 Hz pulsed ultra-violet laser. A multi-line fitting algorithm was applied to the PLIF spectra and transitions were filtered based on an iterative method that maximizes thermometry accuracy. NO PLIF thermometry results are compared to non-equilibrium computational fluid dynamics (CFD) simulations reported in the literature. Differences between the experiment and CFD are quantified for the free-stream, post-shock, shear-layer, and expansion-fan regions of the flow. Potential sources of error, applicable to both the CFD and experiment, are discussed.

Connor C McDougall↗
NASA NTRS2017

Controlled Nitric Oxide Production via O(1D) + N2O Reactions for Use in Oxidation Flow Reactor Studies

Oxidation flow reactors that use low-pressure mercury lamps to produce hydroxyl (OH) radicals are an emerging technique for studying the oxidative aging of organic aerosols. Here, ozone (O3) is photolyzed at 254 nm to produce O(1D) radicals, which react with water vapor to produce OH. However, the need to use parts-per-million levels of O3 hinders the ability of oxidation flow reactors to simulate NOx-dependent secondary organic aerosol (SOA) formation pathways. Simple addition of nitric oxide (NO) results in fast conversion of NOx (NO+NO2) to nitric acid (HNO3), making it impossible to sustain NOx at levels that are sufficient to compete with hydroperoxy (HO2) radicals as a sink for organic peroxy (RO2) radicals. We developed a new method that is well suited to the characterization of NOx-dependent SOA formation pathways in oxidation flow reactors. NO and NO2 are produced via the reaction O(1D)+N2O->2NO, followed by the reaction NO+O3->NO2+O2. Laboratory measurements coupled with photochemical model simulations suggest that O(1D)+N2O reactions can be used to systematically vary the relative branching ratio of RO2 +NO reactions relative to RO2 +HO2 and/or RO2+RO2 reactions over a range of conditions relevant to atmospheric SOA formation. We demonstrate proof of concept using high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) measurements with nitrate (NO-3 ) reagent ion to detect gas-phase oxidation products of isoprene and -pinene previously observed in NOx-influenced environments and in laboratory chamber experiments.

Lambe, Andrew↗
DOE OSTI2025

Impact of gasoline composition on the effects of nitric oxide on autoignition and knock in a DISI engine

Modern spark-ignition engines use exhaust gas recirculation (EGR) to dilute the charge and suppress knock, enabling the use of higher compression ratios and/or more optimum combustion phasing for higher efficiency. The effectiveness of EGR is affected by the composition of the fuel and its chemical-kinetic interactions with combustion products. Among those, nitric oxide (NO) has been shown to strongly affect autoignition reactivity. However, the impact of fuel composition of the effect of NO on reactivity is not well-understood. Here, in this study, engine experiments were conducted to assess the impact of NO seeded to the intake on knock-limited operation of two gasoline fuels (high cycloalkane content, or HCA, and high olefin content, or HO). Results showed that compositionally-different fuels responded differently to NO. HCA, which was less knock-limited than HO for NO < 200 ppm, became more knock-limited for NO > 200 ppm. Moreover, it was found that differences in knock between fuels were caused by differences in autoignition chemistry and not in the sequential autoignition process of the end gas that occurs due to thermal stratification. Chemical kinetic simulations were performed to better understand the experimental results. For HCA, intermediate-temperature heat release had a greater impact on autoignition reactivity than low-temperature heat release, while the opposite was observed for HO. For both fuels, NO enhances the magnitude of low-temperature heat release via NO + HO 2 → NO 2 + OH. The effect of NO on reactivity was stronger for HCA because OH produced from NO helped to overcome the OH quenching effect of cyclopentane, a main species in HCA. In contrast, HO had relatively strong inherent low-temperature chemistry arising from iso-octane, which reduced the impact of NO on reactivity. For the range of NO mole fractions tested in this study, in-cylinder NO increased fuel’s knock propensity, especially for fuels with mild low-temperature chemistry.

Autoignition↗
NASA NTRS1973

Reactions of HO2 with carbon monoxide and nitric oxide and of O/1 D/ with water.

Investigation of the reactions of the hydroperoxyl radical with carbon monoxide and nitric oxide in a static system, and reexamination of the reaction of O(1 D) with water. The HO2 radicals were generated by the photolysis of N2O at 2139 A in the presence of excess H2O or H2 and smaller amounts of CO and O2. The O(1 D) atoms produced from the photolysis of N2O react with H2O or with H2 to give OH radicals in the case of H2O or OH radicals and H atoms in the case of H2. With H2O, two OH radicals are produced for each O(1 D) removed at low pressures, but the OH yield drops as the pressure is raised. This drop is attributed to an insertion reaction which removes from 10 to 30% of the O(1 D) atoms at about 650 torr of H2O at 200 F. The OH radicals generated can react with either CO or H2 to produce H atoms, which then add to O2 to produce HO2. In the absence of NO, the HO2 radicals could react by two routes, while with NO present NO2 is produced in a long chain process.

Simonaitis, R.↗