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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Initial Testing of a Small Gamma Detector (GR1+) for Detection of Holdup in HEPA Filters

Measuring and assessing holdup is a key component of proper inventorying of a Material Balance Area (MBA). The Nuclear Material Control and Accountability (NMC&A) group at the Savannah River Site is responsible for ensuring that the methods used to determine holdup in the MBAs are valid for the conditions of that MBA. Holdup can be contained inside processing equipment or inside ventilation systems that that pulls air out of the glovebox through HEPA filters and stainless steel piping.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Cost Competitive Process of Battery Grade Oxides Preparation from Aged LIBS

The increasing demand for lithium-ion batteries (LIBs ) is driving development of advanced recycling and refining methods. In this project, new cathode active materials are prepared from recycled lithium battery materials and subsequently electrochemically evaluated in coin cells. In detail, scrap LIBs were mechanically processed into a metal rich black mass, then reductive acid leached into an aqueous metal solution, and finally high-purity metal hydroxide precursor materials were prepared by selective electrochemical flow precipitation. Closed-loop LIB recycling into active electrode materials will enable US manufacturers to break their reliance on foreign sources of critical materials. For example, electroextraction process used here has potential to significantly reduce chemical & water use as compared to traditional metallurgic techniques. To this end, electroextracted materials refined from used batteries were collected and processed to be tested as precursor cathode active material (pCam).During this project ,samples of high-purity recycled NMC hydroxide (~2kg each) were received from Nth Cycle. In the first received batch some impurities like cadmium, calcium, and sodium are present in quantities that would negatively impact battery performance. Nth Cycle indicated that the impurities such as cadmium are present due to poor battery separation and co-shredding of NiCd batteries with with LIB. Cadmium was not present in the two subsequent batches as Nth Cycle processed cadmium free black mass. Thus, effective recycled battery sorting is critical to closed-loop LIB recycling into active electrode materials.

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2025

Cost Competitive Process of Battery Grade Oxides Preparation from Aged LIBS

The increasing demand for lithium-ion batteries (LIBs) is driving development of advanced recycling and refining methods. In this project, new cathode active materials are prepared from recycled lithium battery materials and subsequently electrochemically evaluated in coin cells. In detail, scrap LIBs were mechanically processed into a metal rich black mass, then reductive acid leached into an aqueous metal solution, and finally high-purity metal hydroxide precursor materials were prepared by selective electrochemical flow precipitation. Closed-loop LIB recycling into active electrode materials will enable US manufacturers to break their reliance on foreign sources of critical materials. For example, electroextraction process used here has potential to significantly reduce chemical & water use as compared to traditional metallurgic techniques. To this end, electroextracted materials refined from used batteries were collected and processed to be tested as precursor cathode active material (pCam). During this project , samples of high-purity recycled NMC hydroxide (~2 kg each) were received from Nth Cycle. In the first received batch some impurities like cadmium, calcium, and sodium are present in quantities that would negatively impact battery performance. Nth Cycle indicated that the impurities such as cadmium are present due to poor battery separation and co-shredding of NiCd batteries with with LIB. Cadmium was not present in the two subsequent batches as Nth Cycle processed cadmium free black mass. Thus, effective recycled battery sorting is critical to closed-loop LIB recycling into active electrode materials.

25 ENERGY STORAGE↗
DOE OSTI2025

Application of Raman Spectroscopy to Determine Uranium Content in ADUN Solution

The work presented in this report is part of the ongoing efforts to address the nuclear material control and accounting needs for advanced reactor fuel fabrication facilities. This work was supported by the Materials Protection, Accounting, and Control Technologies (MPACT) program under the US Department of Energy Office of Nuclear Energy‘s Nuclear Fuel Cycle and Supply Chain program. The activities and engagements under the MPACT program are designed to support a robust US civilian nuclear energy enterprise. In the work described in this report, we supported MPACT objectives by developing measurement techniques that could be used for material accounting and process monitoring and by working with industry partners to identify existing gaps and areas for improvement. Oak Ridge National Laboratory has been working with commercial tristructural isotropic (TRISO) fuel fabricators such as Standard Nuclear to develop technology for rapid and cost-effective uranium content assessment. This work has focused on demonstrating advanced measurement techniques (e.g., Raman spectroscopy) that can be used for rapid, reliable, and cost-effective routine measurements of uranium content in feed solutions and liquid waste streams as well as for monitoring in-line process measurements and product streams. Specifically, this report explores techniques for accurately determining uranium content in acid-deficient uranyl nitrate (ADUN) solutions and detecting low uranium concentrations in ammonia solutions. Developing such measurement techniques will benefit TRISO fuel fabrication facilities, facilities involved in other parts of the fuel cycle that require online monitoring of aqueous solutions, and potentially molten salt fuel reactors. This work supports developing Raman spectroscopy procedures to determine uranium concentrations in ADUN solutions, which are used as feedstock in the sol–gel process for creating TRISO fuel. Some additional benefits of using Raman spectroscopy for uranium quantification in fabrication facilities include enabling online monitoring of the chemical process, which would provide near real-time feedback; eliminating the need for sample transfers, preparation, or dilution; providing nondestructive measurements; and user friendliness. In this fiscal year, FY25, we determined the identity of the unknown Raman band at approximately 853 cm−1 that was discovered in ADUN Raman spectra in FY24, created calibration curves and determined uranium concentrations of two ADUN solutions, and compared the Raman results to results obtained from inductively coupled plasma mass spectrometry and Davies–Gray titration. Furthermore, we have identified focus areas for experimentation in future fiscal years. A key result is that the accuracy of using Raman can provide accuracy comparable to destructive analysist techniques, With a well-developed calibration curve, using standards and a large number of samples (more than five samples), uncertainty on the order of 1%–3% is achievable. Given that the uncertainties achieved by Raman spectroscopy were on the order of the uncertainties achieved using ICP-MS, we conclude that with a well-developed procedure Raman spectroscopy can be used to determine uranium concentrations in ADUN solutions for NMC&A applications. The benefits of such an approach are that the time and effort will be less than that of comparable destructive analysis techniques, with approximately the same level of technical expertise. This will be attractive to operators of fuel fabrication facilities as it will lower costs and improve efficiencies.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

In-Situ FTIR Detection of Transition Metal (TM)-Ion Dissolution From Cathodes in Li-Ion Batteries

Transition metal (TM) ions, commonly Ni and Mn, play a crucial role in Li-ion battery cathodes as the reaction centers for rapid redox reactions. A major challenge with TM-based cathodes is capacity degradation, particularly at higher operating voltages. This degradation is closely linked to the dissolution of TMs from the cathode materials and their subsequent deposition on the anode. This process not only modifies the surface structure of the cathode but, more significantly, alters the SEI composition on the anode [1-2]. The dissolution of TMs cations into a liquid electrolyte from cathode materials, such as Mn-ion dissolution from Mn-rich cathode (LMR), is detrimental to the cycling performance of Li-ion batteries [3-4]. Much attention has been paid to this issue but there remains a lack of characterization techniques which can detect the TM-ion dissolution from the cathode during electrochemical measurements. In our study, we use in-situ ATR-FTIR as an effective technique to probe the TM-ion dissolution from the cathode. We have first demonstrated the detrimental effects of TM ions on the electrochemical performance of Li-ion batteries by adding a small amount of TM salt (50 mM Mn(PF6)) to the electrolyte of a Li-ion coin cell with LFP and graphite electrode. We observed a rapid capacity fade after the first delithiation cycle. To investigate TM ion dissolution, we established a baseline IR spectrum for various TM solvation states (such as Mn and Ni) by measuring concentration-dependent IR spectra. This baseline spectrum helps us detect TM ion dissolution during battery cycling. In this work, we discuss in detail the effect of TM ions on the electrochemical performance of Li-ion batteries and the detection of TM ions during battery cycling using in-situ FTIR spectroscopy. We will compare TM dissolution between coated and uncoated cathodes to examine the effect of cathode coatings to mitigate degradation due to TM dissolution and cross-over from cathode to anode. References: (1) Zhan, C.; Wu, T.; Lu, J.; Amine, K. Dissolution, migration, anddeposition of transition metal ions in Li-ion batteries exemplified byMn-based cathodes - a critical review. Energy Environ. Sci. 2018, 11,243-257. (2) Jung, R.; Linsenmann, F.; Thomas, R.; Wandt, J.; Solchenbach,S.; Maglia, F.; Stinner, C.; Tromp, M.; Gasteiger, H. A. Nickel,Manganese, and Cobalt Dissolution from Ni-Rich NMC and TheirEffects on NMC622-Graphite Cells. J. Electrochem. Soc. 2019, 166,A378-A389. (3) Zhao, L.; Chenard, E.; Capraz, O. O.; Sottos, N. R.; White, S.R. Direct Detection of Manganese Ions in Organic Electrolyte by UV-Vis Spectroscopy. J. Electrochem. Soc. 2018, 165, A345-A348 (4) Zhang, Y.; Hu, A.; Xia, D.; Hwang, S.; Sainio, S.; Nordlund, D.;Michel, F. M.; Moore, R. B.; Li, L.; Lin, F. Operando characterization and regulation of metal dissolution and redeposition dynamics nearbattery electrode surface. Nat. Nanotechnol. 2023, 18, 790.

25 ENERGY STORAGE↗
DOE OSTI2026

In Situ Li Seed Formation Enables Uniform Plating in Anode-Free Solid-State Batteries

Anode-free solid-state batteries (AFSSBs) are a promising route toward achieving high energy density. In these cells, the anode contains no pre-stored lithium (Li). Instead, all Li inventory originates from the cathode and is freshly deposited onto a bare current collector during charging. However, achieving uniform and defect-free Li plating on this bare current collector remains a major challenging, often resulting in low Li plating/stripping efficiency and rapid capacity decay. Here, for the first time, operando neutron imaging is employed to visualize Li plating/stripping behavior in an anode-free full cell with LiNi 0.82 Mn 0.07 Co 0.11 O 2 (NMC) as the cathode. Operando measurements reveal that complete stripping of Li leaves isolated Li residues on the current collector, which degrades interfacial contact between the current collector and solid-state electrolyte. To mitigate this interfacial issue and promote more uniform Li deposition, we implement a discharge cutoff voltage strategy that intentionally retains a thin residual Li layer after stripping. This thin Li layer, serving as an in situ–formed seed layer, not only enables more homogeneous subsequent Li plating but also improves interfacial contact. As a result, the anode-free cell with a controlled discharge voltage of 3.5 V exhibits excellent long-term cycling stability, maintaining a discharge capacity of 116 mAh g -1 with a retention rate of 83.4% and an average Coulombic efficiency of approximately 99.9% after 430 cycles at 0.25 C. In contrast, the cell with a conventional discharge cutoff voltage of 2.8 V exhibits rapid capacity decay, retaining only 59.7 mAh g -1 after 50 cycles with a capacity retention of 40.7%. This work offers a practical strategy to unlock the long-term viability of anode-free solid-state batteries.

25 ENERGY STORAGE↗
NASA NTRS1972

A sample computation of kinematic properties from cloud motion vectors.

Distributions of relative vorticity and balanced height have been computed from the cloud velocities associated with the cloud structure of an extratropical cyclone over the continental United States during a three-day period in March 1970. Cloud motions are assigned either to a 'mid-level,' or to a 'high level.' Derived vorticity and balanced height are compared with concurrent National Meteorological Center (NMC) analyses and also with similar kinematic quantities obtained from rawins at three constant-pressure levels. The computations of relative vorticity using mid-level cloud motion vectors show encouraging results. Patterns of computed cyclonic vorticity are related to the development, location, and movement of the surface cyclone. The analyses suggest that the 'mid-level' corresponds best to the 700-mb level. The vorticity analysis from the 'high-level' motion vectors presented difficulties.

Viezee, W.↗
NASA NTRS1974

Short-range forecasts with the GISS model of the global atmosphere

A nine-layer, primitive equation (PE) model of the global atmosphere developed at the Goddard Institute for Space Studies (GISS) has been used to generate six 48-hr forecasts during December 1972 and January 1973. Operational analyses north of 18 N and experimental global analyses made available by the National Meteorological Center (NMC), NOAA, were used as the initial conditions; the operational analyses were used to verify the forecasts at 12-hr intervals over the Northern Hemisphere north of 22 N. The combined analyses were used to verify the forecasts in the global domain. RMS errors of the sea-level pressure, 1000-mb heights, and vector geostrophic winds, and 500-mb heights and vector geostrophic winds indicate that the GISS forecasts have skill comparable to those made by operational PE models.

Druyan, L. M.↗
NASA NTRS1976

NASA Global Atmospheric Sampling Program (GASP). Data report for tape VL0001

Atmospheric trace constituents in the upper troposphere and lower stratosphere are now being measured as part of the NASA Global Atmospheric Sampling Program (GASP), using fully automated air sampling systems on board commercial 747 aircraft in routine airline service. Measurements of atmospheric ozone and related meteorological and flight information obtained during several GASP flights in March 1975 are now available from the National Climatic Center, Asheville, North Carolina. In addition to the data from the aircraft, tropopause pressure data obtained from the National Meteorological Center (NMC) archives for the dates of the flights are included. This report is the first of a series of reports which describes the data currently available from GASP, including flight routes and dates, instrumentation, the data processing procedure used, and data tape specifications.

Holdeman, J. D.↗
NASA NTRS1976

NASA Global Atmospheric Sampling Program (GASP) data report for tape VL0003

Atmospheric ozone, and related flight and meteorological data for May 1975, obtained during 49 flights of a Pan American World Airways 747, are available as GASP tape VL0003 from the National Climatic Center, Asheville, North Carolina. In addition to the GASP data, tropopause pressure fields obtained from NMC archives for the dates of the GASP flights are included on the data tape. Flight routes and dates, instrumentation, data processing procedures, and data tape specifications are described.

Holdeman, J. D.↗
NASA NTRS1977

NASA Global Atmospheric Sampling Program (GASP) data report for tape VL0005

Atmospheric ozone, water vapor, and related flight and meteorological data were obtained during 214 flights of a United Airlines B-747 and two Pan American World Airways B-747's from March through June 1976. In addition, trichlorofluoromethane data obtained from laboratory analysis of two whole air samples collected in flight are reported. These data are available on GASP tape VL0005 from the National Climatic Center, Asheville, North Carolina. In addition to the GASP data, tropopause pressure fields obtained from NMC archives for the dates of the GASP flights are included on the data tape. Flight routes and dates, instrumentation, data processing procedures, and data tape specifications are described in this report. Selected analyses including ozone and sample bottle data are also presented.

Holdeman, J. D.↗
NASA NTRS1976

Atmospheric ozone measurements made from B-747 airliners - Spring 1975

Atmospheric ozone in the upper troposphere and lower stratosphere north of the equator has been registered aboard two commercial B-747 airliners during the Spring of 1975. This monitoring is part of a much broader and continuing project developed by NASA and known as the Global Atmospheric Sampling Program (GASP). Additional flight and meteorological conditions have also been automatically recorded on board concurrent with the ozone measurements. Independently-derived tropopause pressure information was available from NMC data archives and was used to identify stratospheric and tropospheric flight. The composite ozone, flight and meteorological data are reported for selected dates in March, April, and May. Attention is drawn particularly to the vertical profiles of atmospheric ozone mixing ratio as a function of both distance from the tropopause and curvature of the streamlines. The GASP observations suggest that ozone levels typical of the lower stratosphere are often embedded in the upper troposphere, principally during occasions when cyclonic wind curvature was noted.

Falconer, P. D.↗
NASA NTRS1979

NASA Global Atmospheric Sampling Program (GASP) data report for tapes VL0010 and VL0012

The GASP atmospheric trace constituent data currently available are considered. Included on tapes are in-situ measurements of atmospheric ozone, carbon monoxide, water vapor, and clouds, data from laboratory analysis of filters exposed in flight, and related flight and meteorological data. Measurements of ozone levels within the first class cabin of these aircraft are also reported. In addition to the GASP data, tropopause pressures obtained from time and space interpolation of NMC archived data for the dates of the flights are included. Reported herein are the flight routes and dates, instrumentation, data processing procedures, data tape specifications, and analyses of the cabin ozone measurements.

Holdeman, J. D.↗
NASA NTRS1977

NASA Global Atmospheric Sampling Program (GASP) data report for tapes VL0007 and VL0008

The Global Atmospheric Sampling Program (GASP) is obtaining measurements of atmospheric trace constituents in the upper troposphere and lower stratosphere using fully automated air sampling systems on board the NASA CV-990 research aircraft and four commerical B-747 aircraft in routine airline service. In-situ measurements of atmospheric ozone and water vapor, data from laboratory analysis of filters exposed in flight, and related flight and meteorological data obtained from September 1976 through January 1977 are reported. These data are now available on GASP tapes VL0007 & VL0008 from the National Climatic Center, Asheville, North Carolina. In addition to the GASP data, tropopause pressure fields obtained from NMC archives for the dates of the GASP flights are included on the data tape. Flight routes and dates, instrumentation, data processing procedures, and data tape specifications are described.

Holdeman, J. D.↗
NASA NTRS1980

Atmospheric variability and air-sea interaction

The topics studied include: (1) processing of Northern Hemispheric precipitation data, in order to fill in the transition seasons to provide a continuous 40 year data base on the variability of continental precipitation; (2) comparison of seasonally averaged fields of sea surface temperature obtained from ship observations in the North Atlantic and North Pacific in 1970 with the corresponding fields inferred from satellite observations; (3) estimation of seasonal average of total precipitable water at those admittedly few oceanic stations where repeated vertical soundings were made in 1970 and comparison with corresponding values inferred from satellite measurements; (4) comparison of seasonally averaged evaporation fields determined from ground based observations in 1970 with the field of divergence of the seasonal total horizontal water vapor flux inferred from satellite total water measurements and NMC wind data for the lower troposphere; (5) examination of meaning of convection-inversion index.

Middleton, J. W.↗
NASA NTRS1980

Major and minor stratospheric warmings and their interactions on the troposphere

The evolution of the kinetic and thermal energy associated with the major and minor stratospheric warmings in the winters of 1975-76 and 1976-77 is investigated on the basis of NMC gridded analysis of meteorological data and then related to changes in the stratosphere and troposphere. It is found that the predominant ultra-long waves in the stratosphere oscillated at periods of 10-20 days, while in the troposphere the predominant long waves oscillated at periods of 8 to 12 days and were almost out-of-phase for the major warming. The kinetic energy of the zonal mean flow in the stratosphere for the minor warming is shown to be much greater than that for the major warming, indicating the dependence of the major warming occurrence on the kinetic energy magnitude of the zonal mean flow relative to that of the meridional convergence of the poleward flux of sensible heat.

Koermer, J. P.↗
NASA NTRS1980

Rocket observations of the vertical distribution of ozone in the polar night and during a mid-winter stratospheric warming

Rocket ozone soundings have been conducted in the stratosphere and lower mesosphere at high latitudes during winter. The collection of soundings show a high degree of variability when compared to ozone distributions measured during summer and at lower latitudes. The concurrently observed temperature and winds also show large variations which can be qualitatively related to the ozone profiles. Two most unusual ozone profiles were observed in January 1979 over Alaska during a stratospheric warming event. Both ozone profiles were consistent in showing the measured mixing ratios to be higher at 50 km than those measured at 40 km, a feature never reported before. This feature is related to the concurrently observed wind and temperature distributions and the NMC analyses of pressure height fields. The polar night ozone observations in the upper stratosphere and lower mesosphere suggest some temperature dependence, but transports seem to play an important role.

Hilsenrath, E.↗
NASA NTRS1981

Ionospheric theory

The effects of the atmospheric dynamics on the ionosphere and neutral chemistry of the stratosphere, mesosphere, and thermosphere were studied. Effects of vertically propagating planetary waves on NO densities in the 70 to 120 km altitude region were investigated. A time dependent model was developed to calculate the transport of NO due to planetary wave induced winds. These transports are sensitive to the planetary wave forcing used at the lower boundary, as well as to the structure of the zonal mean basic state. Fluxes and transport of NO are calculated for the months of January and February, using a separate basic state and boundary forcing for each month. The zonal mean wind profile for the months of January and February were inferred from NMC data. A major stratospheric warming occurred near the end of the month of February. The large planetary wave amplitude and reduction in zonal mean wind velocities due to this warming are reflected in the February average boundary forcing and zonal mean state.

Source record↗