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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS2008

Improving Coastal Ocean Color Validation Capabilities through Application of Inherent Optical Properties (IOPs)

Understanding how the different components of seawater alter the path of incident sunlight through scattering and absorption is essential to using remotely sensed ocean color observations effectively. This is particularly apropos in coastal waters where the different optically significant components (phytoplankton, detrital material, inorganic minerals, etc.) vary widely in concentration, often independently from one another. Inherent Optical Properties (IOPs) form the link between these biogeochemical constituents and the Apparent Optical Properties (AOPs). understanding this interrelationship is at the heart of successfully carrying out inversions of satellite-measured radiance to biogeochemical properties. While sufficient covariation of seawater constituents in case I waters typically allows empirical algorithms connecting AOPs and biogeochemical parameters to behave well, these empirical algorithms normally do not hold for case I1 regimes (Carder et al. 2003). Validation in the context of ocean color remote sensing refers to in-situ measurements used to verify or characterize algorithm products or any assumption used as input to an algorithm. In this project, validation capabilities are considered those measurement capabilities, techniques, methods, models, etc. that allow effective validation. Enhancing current validation capabilities by incorporating state-of-the-art IOP measurements and optical models is the purpose of this work. Involved in this pursuit is improving core IOP measurement capabilities (spectral, angular, spatio-temporal resolutions), improving our understanding of the behavior of analytical AOP-IOP approximations in complex coastal waters, and improving the spatial and temporal resolution of biogeochemical data for validation by applying biogeochemical-IOP inversion models so that these parameters can be computed from real-time IOP sensors with high sampling rates. Research cruises supported by this project provides for collection and processing of seawater samples for biogeochemical (pigments, DOC and POC) and optical (CDOM and POM absorption coefficients) analyses to enhance our understanding of the linkages between in-water optical measurements (IOPs and AOPs) and biogeochemical constituents and to provide a more comprehensive suite of validation products.

Mannino, Antonio↗
DOE OSTI2022

First-Principles Study of Ferroelectric and Optical Properties in Derivatives of Thiourea

Organic ferroelectric materials in the form of molecular crystals are promising alternatives to well-known ferroelectric perovskite oxides due to their structural flexibility, tunability, and ease of processing. First-principles density functional theory calculations combined with group theory analyses are employed in this work to discuss polar nature of a class of derivatives of thiourea: CH 4 N 2 A where A = O, S, Se, and Te. Further, optical properties in the UV range along with thermodynamic and dynamic stability of such materials are also evaluated in the study. We find that CH 4 N 2 Te with bandgap energy of ~3.33 eV shows large spontaneous polarization of P = 10.92 μC/cm 2 . The electronic and optical properties become tunable under strain.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Photoaging of phenolic secondary organic aerosol in the aqueous phase: evolution of chemical and optical properties and effects of oxidants

Abstract. While gas-phase reactions are well established to have significant impacts on the mass concentration, chemical composition, and optical properties of secondary organic aerosol (SOA), the aqueous-phase aging of SOA remains poorly understood. In this study, we performed a series of long-duration photochemical aging experiments to investigate the evolution of the composition and light absorption of the aqueous SOA (aqSOA) from guaiacyl acetone (GA), a semivolatile phenolic carbonyl that is common in biomass burning smoke. The aqSOA was produced from reactions of GA with hydroxyl radical (•OH-aqSOA) or a triplet excited state of organic carbon (3C∗-aqSOA) and was then photoaged in water under conditions that simulate sunlight exposure in northern California for up to 48 h. The effects of increasing aqueous-phase •OH or 3C∗ concentration on the photoaging of the aqSOA were also studied. High-resolution aerosol mass spectrometry (HR-AMS) and UV–Vis spectroscopy were utilized to characterize the composition and the light absorptivity of the aqSOA and to track their changes during aging. Compared to •OH-aqSOA, the 3C∗-aqSOA is produced more rapidly and shows less oxidation, a greater abundance of oligomers, and higher light absorption. Prolonged photoaging promotes fragmentation and the formation of more volatile and less light-absorbing products. More than half of the initial aqSOA mass is lost, and substantial photobleaching occurs after 10.5 h of prolonged aging under simulated sunlight illumination for 3C∗-aqSOA and 48 h for •OH-aqSOA. By performing positive matrix factorization (PMF) analysis of the combined HR-AMS and UV–Vis spectral data, we resolved three generations of aqSOA with distinctly different chemical and optical properties. The first-generation aqSOA shows significant oligomer formation and enhanced light absorption at 340–400 nm. The second-generation aqSOA is enriched in functionalized GA species and has the highest mass absorption coefficients in 300–500 nm, while the third-generation aqSOA contains more fragmented products and is the least light absorbing. These results suggest that intermediately aged phenolic aqSOA is more light absorbing than other generations, and that the light absorptivity of phenolic aqSOA results from a competition between brown carbon (BrC) formation and photobleaching, which is dependent on aging time. Although photoaging generally increases the oxidation of aqSOA, a slightly decreased O/C of the •OH-aqSOA is observed after 48 h of prolonged photoaging with additional •OH exposure. This is likely due to greater fragmentation and evaporation of highly oxidized compounds. Increased oxidant concentration accelerates the transformation of aqSOA and promotes the decay of BrC chromophores, leading to faster mass reduction and photobleaching. In addition, compared with •OH, photoaging by 3C∗ produces more low-volatility functionalized products, which counterbalances part of the aqSOA mass loss due to fragmentation and evaporation.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1991

Temperature dependence of optical properties of GaAs

The effect of temperature on the optical properties of GaAs was investigated using spectroscopic ellipsometry measurements, between room temperature and about 610 C in increments of 50 C, of pseudodielectric functions and related optical constants of GaAs. A quantitative analysis of the pseudodielectric function spectrum was carried out using a harmonic-oscillator approximation (HOA) to fit the measured dielectric functions. Good fits were obtained with this model, which provides a convenient means of reproducing the GaAs dielectric function at any temperature, by using the temperature-dependent oscillator parameters. The HOA analysis also provides information about band-gap variation with temperature. Using the measured optical constants at a number of fixed temperatures, an algorithm was developed for computing the dielectric function spectrum at an arbitrary temperature in the range 22-610 C.

Yao, Huade↗
NASA NTRS1988

Containerless laser-induced flourescence study of vaporization and optical properties for sapphire and alumina

Evaporation of aluminum oxide was studied from 1800 to 2327 K by laser-induced flourescence (LIF) detection of Al atom vapor over sapphire and alumina spheres that were levitated in an argon gas jet and heated with a continuous wave CO2 laser. Optical properties were determined from apparent specimen temperatures measured with an optical pyrometer and true temperatures deduced from the LIF intensity versus temperature measurements using the known temperature dependence of the Al atom vapor concentration in equilibrium with Al2O3. The effects of impurities and dissolved oxygen on the high-temperature optical properties of aluminum oxide were discussed.

Nordine, Paul C.↗
NASA NTRS1990

Optical properties of KD*P modulators

Longitudinal KD*P modulators are used in ground-based solar magnetographs to eliminate seeing effects. Although the modulators can be used as variable retarders, the optical properties when zero voltage is applied influences the performance on instruments requiring very accurate polarization measurements. Measurements at the Marshall Space Flight Center are discussed in terms of the optical properties of KD*P modulators when zero voltage is applied. The measurements can be used to predict the modulation characteristics of the devices and to determine the polarization accuracy that can be expected from the vector magnetograph.

West, E. A.↗
NASA NTRS2004

Initial Validation and Results of Geoscience Laser Altimeter System Optical Properties Retrievals

Verification of Geoscience Laser Altimeter System (GLAS) optical retrievals is . problematic in that passage over ground sites is both instantaneous and sparse plus space-borne passive sensors such as MODIS are too frequently out of sync with the GLAS position. In October 2003, the GLAS Validation Experiment was executed from NASA Dryden Research Center, California to greatly increase validation possibilities. The high-altitude NASA ER-2 aircraft and onboard instrumentation of Cloud Physics Lidar (CPL), MODIS Airborne Simulator (MAS), and/or MODIS/ASTER Airborne Simulator (MASTER) under-flew seven orbit tracks of GLAS for cirrus, smoke, and urban pollution optical properties inter-comparisons. These highly calibrated suite of instruments are the best data set yet to validate GLAS atmospheric parameters. In this presentation, we will focus on the inter-comparison with GLAS and CPL and draw preliminary conclusions about the accuracies of the GLAS 532nm retrievals of optical depth, extinction, backscatter cross section, and calculated extinction-to-backscatter ratio. Comparisons to an AERONET/MPL ground-based site at Monterey, California will be attempted. Examples of GLAS operational optical data products will be shown.

Hlavka, Dennis L.↗
DOE OSTI2020

Variable optical properties of light-harvesting complex II revisited

Understanding photosynthetic light harvesting requires knowledge of the molecular mechanisms that dissipate excess energy in thylakoids. However, it remains unclear how the physical environment of light-harvesting complex II (LHCII) influences the process of chlorophyll de-excitation. Here, we demonstrate that protein-protein interactions between LHCIIs affect the optical properties of LHCII and thus influence the total energy budget. Aggregation of LHCII in the dark altered its absorption properties, independent of the amount of prior light exposure. We also revisited the triplet excited state involved in light-induced fluorescence quenching and found another relaxation pathway involving emission in the green region, which might be related to triplet excited energy transfer to neighboring carotenoids and annihilation processes that result in photoluminescence. LHCII- containing liposomes with different protein densities exhibited altered fluorescence and scattering properties. Our results suggest that macromolecular reorganization affects overall optical properties, which need to be addressed to compare the level of energy dissipation.

Iwai, Masakazu↗
NASA NTRS2020

The NASA MODIS-VIIRS Continuity Cloud Optical Properties Products

The NASA Aqua MODIS and Suomi National Polar-Orbiting Partnership (SNPP) Visible Infrared Imaging Radiometer Suite (VIIRS) climate data record continuity cloud properties products (CLDPROP) were publicly released in April 2019 with an update later that year (Version 1.1). These cloud products, having heritage with the NASA Moderate-resolution Imaging Spectroradiometer (MODIS) MOD06 cloud optical properties product and the NOAA GOES-R Algorithm Working Group (AWG) Cloud Height Algorithm (ACHA), represent an effort to bridge the multispectral imager records of NASA’s Earth Observing System (EOS) and NOAA’s current generation of operational weather satellites to achieve a continuous, multi-decadal climate data record for clouds that can extend well into the 2030s. CLDPROP offers a “continuity of approach,” applying common algorithms and ancillary datasets to both MODIS and VIIRS, including utilizing only a subset of spectral channels available on both sensors to help mitigate instrument differences. The initial release of the CLDPROP_MODIS and CLDPROP_VIIRS data records spans the SNPP observational record (2012-present). Here, we present an overview of the algorithms and an evaluation of the intersensor continuity of the core CLDPROP_MODIS and CLDPROP_VIIRS cloud optical property datasets, i.e., cloud thermodynamic phase, optical thickness, effective particle size, and derived water path. The evaluation includes analyses of pixel-level MODIS/VIIRS co-locations as well as spatial and temporal aggregated statistics, with a focus on identifying and understanding the root causes of individual dataset discontinuities. The results of this evaluation will inform future updates to the CLDPROP products and help scientific users determine the appropriate use of the product datasets for their specific needs.

satellite remote sensing↗
DOE OSTI2022

Synthesis, Crystal and Electronic Structures, Nonlinear Optical Properties, and Magnetic Properties of Two Thiophosphates: KInP 2 S 7 and KCrP 2 S 7

Two thiophosphates, KInP 2 S 7 and KCrP 2 S 7 , were structurally characterized without investigating any optical properties. Herein in this work, KInP 2 S 7 and KCrP 2 S 7 were revisited to investigate their optical and magnetic properties, respectively. Pure polycrystalline samples and crystals of KInP 2 S 7 and KCrP 2 S 7 were grown by high temperature solid state reactions, where mm-sized crystals of KCrP 2 S 7 were collected. KCrP 2 S 7 is isostructural to KInP 2 S 7 , which features a layered structure. KInP 2 S 7 and KCrP 2 S 7 possess close relationship to the layered thiophosphate M 2 P 2 S 6 (M = Fe, Co, Zn, etc.). The bonding pictures of KInP 2 S 7 were studied using the electron localization function (ELF) coupled with crystal orbital Hamilton population (COHP) calculations. The intrinsically distorted [PS 4 ] tetrahedra and [InS 6 ] octahedra are made by strong covalent P-S interactions and ionic In-S interactions, respectively. Electronic structure analysis confirmed that the optical properties of KInP 2 S 7 are mainly contributed to by [PS 4 ] tetrahedra together with small amounts of the contributions coming from [InS 6 ] octahedra. Magnetic measurement on mm-sized crystals of KCrP 2 S 7 verified that there is an antiferromagnetic transition around 21 K, and the Cr atoms are trivalent. KInP 2 S 7 is predicated to be an indirect bandgap semiconductor of 2.38 eV, which is confirmed by the UV-Vis measurement of 2.4(1) eV. KInP 2 S 7 is not a type-I phase-matching material and exhibits moderate second harmonic generation (SHG) response (0.51 × AgGaS 2 , sample of particle size of 100 µm). The laser damage threshold (LDT) of KInP 2 S 7 is very high of 5.2 × AgGaS 2 . Bandgap engineering were undergone to enhance the SHG response of KInP 2 S 7 .

36 MATERIALS SCIENCE↗
NASA NTRS1990

The effects of compositional inhomogeneities and fractal dimension on the optical properties of astrophysical dust

Mathis and Whiffen (1989) have recently suggested that interstellar dust particles are fluffy aggregates of submicron-size particles composed of various astronomical minerals. These dust particles should exhibit optical properties that are quite different from standard dust, characterized by spherical particles of various homogeneous mineral composition. In this paper, the discrete dipole approximation (DDA) method is used to examine the effects of chemical inhomogeneities and spatial structure on the optical properties of interstellar Mathis-Whiffen-type dust particles. The spatial structure of the dust is represented by its fractal dimension, and the chemical inhomogeneities are simulated by randomly assigning the composition of the occupied sites in the structure to be either carbon or silicate. It is found that compositional inhomogeneities are the dominant parameter affecting the shape of the 9.7 and 18 micron silicate bands. Some bands-shape variations can be attributed to the fractal dimension of the dust. The results derived here can be used to explain or constrain variations in these parameters among various astronomical objects.

Bazell, David↗
NASA NTRS2021

Variabilities in Pm2.5 and Black Carbon Surface Concentrations Reproduced by Aerosol Optical Properties Estimated by In-Situ Data, Ground Based Remote Sensing and Modeling

Because of the increased temporal and spatial resolutions of the sensors onboard recently launched satellites, satellite-based surface aerosol concentration, which is usually estimated from the aerosol optical depth (AOD), is expected to become a strategic tool for air quality studies in the future. By further exploring the relationships of aerosol concentrations and their optical properties using ground observations, the accuracies of these products can be improved. Here, we analyzed collocated observations of surface mass concentrations of fine particulate matter (PM2.5) and black carbon (BC), as well as columnar aerosol optical properties from a sky radiometer and aerosol extinction profiles obtained by multi-axis differential optical absorption spectroscopy (MAX-DOAS), during the 2019–2020 period. We focused the analyses on a daily scale, emphasizing the role of the ultraviolet (UV) spectral region. Generally, the correlation between the AOD of the fine fraction (i.e., fAOD) and the PM2.5 surface concentration was moderately strong, regardless of considerations of boundary layer humidity and altitude. In contrast, the fAOD of the partial column below 1 km, which was obtained by combining sky radiometer and MAX-DOAS retrievals, better reproduced the variability of the PM2.5 and resulted in a linear relationship. In the same manner, we demonstrated that the absorption AOD of the fine fraction (fAAOD) of the partial column was related to the variability of the BC concentration. Analogous analyses based on aerosol products from the Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2) confirmed these findings and highlighted the importance of the shape of the aerosol profile. Overall, our results indicated a remarkable consistency among the retrieved datasets, and between the datasets and MERRA-2 products. These results confirmed the well-known sensitivity to aerosol absorption in the UV spectral region; they also highlighted the efficacy of combined MAX-DOAS and sky radiometer observations.

Alessandro Damiani↗
NASA NTRS1972

Density and optical properties of SPARCS plumes

Propellant gases emitted by attitude control systems such as SPARCS (Solar Pointing Aerobee Rocket Control System) and possible interference with experiments aboard the payloads are discussed. The optical properties of seven actual and potential gases emitted by propellant systems (CF4, N2H4, NH3, N2, CO2, Ar, and He) are presented. A compilation of absorption coefficients from 1 Angstrom to 50 microns and a summary of fluorescent spectra and efficiencies are provided. Since Freon-14 (CF4) is of primary importance to SPARCS, an experimental search for the fluorescent spectrum of CF4 was performed by exciting the gas with 920 Angstrom UV photons. The result was compared with an electron impact induced spectrum of CF4, and conclusions drawn about the nature of the radiating species. A detailed study of the CF4 flow fields and plume densities for typical SPARCS controlled payloads was made using gas dynamic codes which included the effects of vehicle shading and condensation. The importance of the optical properties of CF4 plumes was investigated and it is concluded that absorption is negligible but fluoresence may be significant in some cases.

Brown, W. A.↗
NASA NTRS2002

Correlations among the Optical Properties of Cirrus-Cloud Particles: Microphysical Interpretation

Cirrus measurements obtained with a ground-based polarization Raman lidar at 67.9 deg N in January 1997 reveal a strong positive correlation between the particle optical properties, specifically depolarization ratio delta(sub par) and extinction- to-backscatter (lidar) ratio S, for delta(sub par) less than approximately 40%, and an anti-correlation for delta(sub par) greater than approximately 40%. Over the length of the measurements the particle properties vary systematically. Initially, delta (sub par) approximately equals 60% and S approximately equals 10sr are observed. Then, with decreasing delta(sub par), S first increases to approximately 27sr (delta(sub par) approximately equals 40%) before decreasing to values around 10sr again (delta(sub par) approximately equals 20%). The analysis of lidar humidity and radiosonde temperature data shows that the measured optical properties stem from scattering by dry solid ice particles, while scattering by supercooled droplets, or by wetted or subliming ice particles can be excluded. For the microphysical interpretation of the lidar measurements, ray-tracing computations of particle scattering properties have been used. The comparison with the theoretical data suggests that the observed cirrus data can be interpreted in terms of size, shape, and, under the assumption that the lidar measurements of consecutive cloud segments can be mapped on the temporal development of a single cloud parcel moving along its trajectory, growth of the cirrus particles: Near the cloud top in the early stage of cirrus development, light scattering by nearly isometric particles that have the optical characteristics of hexagonal columns (short, column-like particles) is dominant. Over time the ice particles grow, and as the cloud base height extends to lower altitudes characterized by warmer temperatures they become morphologically diverse. For large S and depolarization values of approximately 40%, the scattering contributions of column- and plate-like particles are roughly the same. In the lower ranges of the cirrus clouds, light scattering is predominantly by plate-like ice particles. This interpretation assumes random orientation of the cirrus particles. Simulations with a simple model suggest, however, that the positive correlation between S and delta(sub par) which is observed for depolarization ratios less than 40% mainly at low cloud altitudes, can be alternatively explained by horizontal alignment of a fraction of the cirrus particle population.

Reichardt, J.↗
NASA NTRS1991

Recent studies of the optical properties of dust and cloud particles in the Mars atmosphere and the interannual frequency of global dust storms

The results of research with two distinctly separate sets of observations yield new information on the optical properties of particulate scatterers in the Mars atmosphere, and on the interannual variability of the abundance of such scatterers in the Mars atmosphere. The first set of observations were taken by the IRTM (Infrared Thermal Mapper) instrument onboard the Viking Orbiters, during the period 1976 to 1980. Several hundred emission phase function (EPF) sequences were obtained over the Viking mission, in which the IRTM visual brightness channel observed the same area of surface/atmosphere as the spacecraft passed overhead. The 1 to 2 percent accuracy of calibration and the phase-angle coverage that characterizes these data make them ideally suited to determining both the optical depths and optical properties of dust and cloud scatterers in the Mars atmosphere versus latitude, longitude, seasons (L sub s), and surface elevation over the extended period of Viking observations. The EPF data were analyzed with a multiple scattering radiative transfer code to determine dust single scattering albedos which are distinctly higher than indicated by the Viking Lander observations. The second set of observations regard ground-based observations of the 1.3 to 2.6 mm rotational transitions of CO in the Martian atmosphere. The low-to-mid latitude average of the atmospheric temperature profile (0 to 70 km altitude) were derived from a number of such observations over the 1980 to 1990 period.

Clancy, R. T.↗