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At least 163 records · Page 9

Selective Functionalization of Carbon Nanotubes: Part II

An alternative method of low-temperature plasma functionalization of carbon nanotubes provides for the simultaneous attachment of molecular groups of multiple (typically two or three) different species or different mixtures of species to carbon nanotubes at different locations within the same apparatus. This method is based on similar principles, and involves the use of mostly the same basic apparatus, as those of the methods described in "Low-Temperature Plasma Functionalization of Carbon Nanotubes" (ARC-14661-1), NASA Tech Briefs, Vol. 28, No. 5 (May 2004), page 45. The figure schematically depicts the basic apparatus used in the aforementioned method, with emphasis on features that distinguish the present alternative method from the other. In this method, one exploits the fact that the composition of the deposition plasma changes as the plasma flows from its source in the precursor chamber toward the nanotubes in the target chamber. As a result, carbon nanotubes mounted in the target chamber at different flow distances (d1, d2, d3 . . .) from the precursor chamber become functionalized with different species or different mixtures of species. In one series of experiments to demonstrate this method, N2 was used as the precursor gas. After the functionalization process, the carbon nanotubes from three different positions in the target chamber were examined by Fourier-transform infrared spectroscopy to identify the molecular groups that had become attached. On carbon nanotubes from d1 = 1 cm, the attached molecular groups were found to be predominantly C-N and C=N. On carbon nanotubes from d2 = 2.5 cm, the attached molecular groups were found to be predominantly C-(NH)2 and/or C=NH2. (The H2 was believed to originate as residual hydrogen present in the nanotubes.) On carbon nanotubes from d3 = 7 cm no functionalization could be detected - perhaps, it was conjectured, because this distance is downstream of the plasma source, all of the free ions and free radicals of the plasma had recombined into molecules.

Meyyappan, Meyya

Measurements of the Plasma Parameters and Low Frequency Oscillations in the Fisk Plasma Source

A new plasma device, the Fisk Plasma Source (FPS), has been developed at Fisk University. This plasma device is used to study the physics of low temperature plasmas and plasma-material interactions. The FPS device is a stainless steel vacuum 6-way cross vacuum vessel with at 10-inch inner diameter. Low temperature argon plasmas are generated using DC glow discharge and thermionic filament techniques. Spatial profiles of the plasma density, plasma potential, and electron temperature are measured using Langmuir probes. We present initial experimental measurements of density and temperature profiles in the FPS device. Experimental and theoretical studies of low frequency oscillations observed in the FPS device are also presented.

Thomas, Edward, Jr.

Coordinated XTE/EUVE Observations of Algol

We performed a coordinated RXTE observation of the prototypical eclipsing binary Algol in conjunction with EUVE and ASCA observations. Observing the x-ray spectrum of Algol with ASCA, EUVE, and RXTE provides critical, near-simultaneous constraints on the distribution of the hottest temperature plasma in the Agol system: this is required to unambiguously determine the coronal Fe abundance. After some initial shuffling of observatory schedules with the help of mission planners, the coordinated multiwavelength observation was successfully performed in February, 1996. Analysis of the data, including development of new, IDL-based global model fitting routines, was accomplished from mid-1996 to mid-1997. The results indicate that the initial estimates of [Fe/H] approximately 0.3 dex (Stern et al.) are confirmed, and the Algol high temperature plasma thus has an Fe deficiency relative to the (Anders and Grevesse) solar abundance.

Stern, Robert A.

Unstable-magnetic-drift waves in a plasma with temperature anisotropy

It is pointed out that under certain conditions, such as a weak electron temperature anisotropy, the magnetic-drift wave instability can become rather important, and the growth rate can be greater than the ion gyrofrequency when the scale length of the density gradient is comparable to, or shorter than, the thermal ion gyroradius. The instability is attributed to wave-electron interactions, and the growth rate is far greater than the case investigated by Krall and Rosenbluth (1963) who attributed the instability to wave-ion interactions. The anticipated vanishing of the instability is observed as epsilon sub n/epsilon sub B approaches zero. The presently observed instability may be used to explain the low-frequency fluctuations evidenced by the Active Particle Tracer Explorer Ion Release Module magnetometer measurements, and may contribute to the acceleration of ions along the plasma cometary tail.

Wu, C. S.

The effects on the ionosphere of inertia in the high latitude neutral thermosphere

High-latitude ionospheric currents, plasma temperatures, densities, and composition are all affected by the time-dependent response of the neutral thermosphere to ion drag and Joule heating through a variety of complex feedback processes. These processes can best be studied numerically using the appropriate nonlinear numerical modeling techniques in conjunction with experimental case studies. In particular, the basic physics of these processes can be understood using a model, and these concepts can then be applied to more complex realistic situations by developing the appropriate simulations of real events. Finally, these model results can be compared with satellite-derived data from the thermosphere. We used numerical simulations from the National Center of Atmospheric Research Thermosphere/Ionosphere General Circulation Model (NCAR TIGCM) and data from the Dynamic Explorer 2 (DE 2) satellite to study the time-dependent effects of the inertia of the neutral thermosphere on ionospheric currents, plasma temperatures, densities, and composition. One particular case of these inertial effects is the so-called 'fly-wheel effect'. This effect occurs when the neutral gas, that has been spun-up by the large ionospheric winds associated with a geomagnetic storm, moves faster than the ions in the period after the end of the main phase of the storm. In these circumstances, the neutral gas can drag the ions along with them. It is this last effect, which is described in the next section, that we have studied under this grant.

Burns, Alan

Dataset, Code, and Models for Training Deep Learning Potentials for Low Temperature Plasma-Surface Interactions

This repository contains datasets, training scripts, and finished models, and test simulations used in the development of DeepREBO— a machine-learned interatomic potential trained to emulate the REBO2 empirical potential. The data was generated to study deep potential development for simulations of plasma-surface interactions. It uses an active learning framework, starting from a minimal dataset and iteratively expanding it. Included are those generated datasets, the trained models, and simulations used to evaluate the performance of the training process. This resource supports reproducibility and provides a reference framework for training deep potentials in plasma-surface interaction studies.

active learning

Nonlinear interactions of electromagnetic waves with a thermally generated cesium plasma.

The interaction of a large‐amplitude disturbing wave with a thermally generated, highly ionized cesium plasma has been investigated using a small‐amplitude sensing wave as a probe. The subsequent interaction between the disturbing and sensing waves is related to the plasma electron temperature. The plasma was contained in a magnetic field of 500–1000 G and had an electron plasma frequency near 10 GHz and an electron gyromagnetic frequency around 2 GHz. The sensing wave was a 10 GHz plane wave of approximately 1.5 mW input power and the disturbing wave was 7.5 GHz plane wave of about 1.2 W peak power. Measurements of the sensing‐wave transmitted power were made using standard microwave techniques. A notch filter in the sensing‐wave receiving circuit reduced the scattered disturbing‐wave interference to an immeasurably low level. Langmuir probes were used to detect disturbing‐wave modulation and to measure plasma temperatures and densities. Measurements of the interaction were correlated with a solution of the Boltzmann transport equation for a perturbed Maxwellian distribution function with binary Coulomb collisions.

Jack G Hewitt, Jr

ASCA X-ray observations of pre-main-sequence stars

The results of recent Advanced Satellite for Cosmology and Astrophysics (ASCA) X-ray observations of two pre-main sequence stars are presented: the weak emission line T Tauri star HD 142361, and the Herbig Ae star HD 104237. The solid state imaging spectrometer spectra for HD 142361 shows a clear emission line from H-like Mg 7, and spectral fits reveal a multiple temperature plasma with a hot component of at least 16 MK. The spectra of HD 104237 show a complex temperature structure with the hottest plasma at temperatures of greater than 30 MK. It is concluded that mechanisms that predict only soft X-ray emission can be dismissed for Herbig Ae stars.

Skinner, S. L.

Mixing the Solar Wind Proton and Electron Scales: Effects of Electron Temperature Anisotropy on the Oblique Proton Firehose Instability

The double adiabatic expansion of the nearly collisionless solar wind plasma creates conditions for the firehose instability to develop and efficiently prevent the further increase of the plasma temperature in the direction parallel to the interplanetary magnetic field. The conditions imposed by the firehose instability have been extensively studied using idealized approaches that ignore the mutual effects of electrons and protons. Recently, more realistic approaches have been proposed that take into account the interplay between electrons and protons, unveiling new regimes of the parallel oscillatory modes. However, for oblique wave propagation the instability develops distinct branches that grow much faster and may therefore be more efficient than the parallel firehose instability in constraining the temperature anisotropy of the plasma particles. This paper reports for the first time on the effects of electron plasma properties on the oblique proton firehose (PFH) instability and provides a comprehensive vision of the entire unstable wave-vector spectrum, unifying the proton and the smaller electron scales. The plasma β and temperature anisotropy regimes considered here are specific for the solar wind and magnetospheric conditions, and enable the electrons and protons to interact via the excited electromagnetic fluctuations. For the selected parameters, simultaneous electron and PFH instabilities can be observed with a dispersion spectrum of the electron firehose (EFH) extending toward the proton scales. Growth rates of the PFH instability are markedly boosted by the anisotropic electrons, especially in the oblique direction where the EFH growth rates are orders of magnitude higher.

plasmas