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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS2011

Discovery and Identification of Dimethylsilanediol as a Contaminant in ISS Potable Water

In September 2010, analysis of ISS potable water samples was undertaken to determine the contaminant(s) responsible for a rise of total organic carbon (TOC) in the Water Processor Assembly (WPA) product water. As analysis of the routine target list of organic compounds did not reveal the contaminant, efforts to look for unknown compounds were initiated, resulting in discovery of an unknown peak in the gas chromatography/mass spectrometry (GC/MS) analysis for glycols. A mass spectrum of the contaminant was then generated by concentrating one of the samples and analyzing it by GC/MS in full-scan mode. Although a computer match of the compound identity could not be obtained with the instrument database, a search with a more up-to-date mass spectral library yielded a good match with dimethylsilanediol (DMSD). Inductively coupled plasma/mass spectrometry (ICP/MS) analyses showed abnormally high silicon levels in the samples, confirming that the unknown compound(s) contained silicon. DMSD was then synthesized to confirm the identification and provide a standard to develop a calibration curve. Further confirmation was provided by external direct analysis in real time time of flight (DART TOF) mass spectrometry. To routinely test for DMSD in the future, a quantitative method was needed. A preliminary GC/MS method was developed and archived samples from various locations on ISS were analyzed to determine the extent of the contamination and provide data for troubleshooting. This paper describes these events in more detail as well as problems encountered in routine GC/MS analyses and the subsequent development of high performance liquid chromatography and LC/MS/MS methods for measuring DMSD.

Rutz, Jeffrey A.↗
NASA NTRSDate not supplied

Source Contaminant Control System Design, Operation, and Testing for the Trash Compaction and Processing System

The Trash Compaction and Processing System (TCPS) aims to reduce volume, biologically safen, physically stabilize, manage effluents, and recover resources from astronaut trash in the International Space Station (ISS). This process involves heating the trash to high temperatures, which in turn releases gaseous contaminants. Effluent management scenarios involve releasing these gases back to the ISS cabin after processing and/or directly venting these gases out to space via the Vacuum Exhaust System (VES). Concerns for recovering the gases back to cabin are crew health, safety, and spacecraft environmental impact. The Heat Melt Compactor (HMC) at NASA Ames Research Center (ARC) serves as a test system that supports TCPS development by conducting risk reduction activities associated with an ISS flight demonstration. Previous gas effluent studies were conducted on the HMC. The results consisted of contaminants from the trash exhaust to exceed Spacecraft Maximum Allowable Concentrations (SMAC), which are selected airborne contaminants that can elicit toxicity symptoms to crewmembers via exposure. The Source Contaminant Control System (SCCS) aims to reduce that risk by converting the contaminants into carbon dioxide (CO2) and water (H2O) vapor. The SCCS is composed of a carbon adsorbent bed, to avoid catalyst poisoning, and a catalytic oxidizer (CatOx), which promotes oxidation of the contaminants to CO2 and H2O. In turn, the gases coming out of the SCCS should be compatible to the ISS cabin and systems such as the Trace Contaminant Control System (TCCS). Preparation for SCCS testing alongside the HMC Gen 3 are currently underway at ARC. The main objectives are to evaluate CatOx efficiency by CO2 conversion and characterize effectiveness of removal by comparing contaminant results before and after CatOx. This paper will report on the SCCS design, operation, and testing with results.

Janine Young↗
NASA NTRS2001

Standardization of Rocket Engine Pulse Time Parameters

Plumes of bipropellant thrusters are a source of contamination. Small bipropellant thrusters are often used for spacecraft attitude control and orbit correction. Such thrusters typically operate in a pulse mode, at various pulse lengths. Quantifying their contamination effects onto spacecraft external surfaces is especially important for long-term complex-geometry vehicles, e.g. International Space Station. Plume contamination tests indicated the presence of liquid phase contaminant in the form of droplets. Their origin is attributed to incomplete combustion. Most of liquid-phase contaminant is generated during the startup and shutdown (unsteady) periods of thruster pulse. These periods are relatively short (typically 10-50 ms), and the amount of contaminant is determined by the thruster design (propellant valve response, combustion chamber size, thruster mass flow rate, film cooling percentage, dribble volume, etc.) and combustion process organization. Steady-state period of pulse is characterized by much lower contamination rates, but may be lengthy enough to significantly conh'ibute to the overall contamination effect. Because there was no standard methodology for thruster pulse time division, plume contamination tests were conducted at various pulse durations, and their results do not allow quantifying contaminant amounts from each portion of the pulse. At present, the ISS plume contamination model uses an assumption that all thrusters operate in a pulse mode with the pulse length being 100 ms. This assumption may lead to a large difference between the actual amounts of contaminant produced by the thruster and the model predictions. This paper suggests a way to standardize thruster startup and shutdown period definitions, and shows the usefulness of this approach to better quantify thruster plume contamination. Use of the suggested thruster pulse time-division technique will ensure methodological consistency of future thruster plume contamination test programs, and allow accounting for thruster pulse length when modeling plume contamination and erosion effects.

Larin, Max E.↗
NASA NTRS2016

On-Orbit Calibration and Performance of S-NPP VIIRS DNB

The S-NPP VIIRS instrument has successfully operated since its launch in October 2011. The VIIRS Day-Night Band (DNB) is a panchromatic channel covering wavelengths from 0.5 to 0.9 m that is capable of observing Earth scenes during both day and nighttime orbits at a spatial resolution of 750 m. To cover the large dynamic range, the DNB operates at low, mid, or high gain stages, and it uses an onboard solar diffuser (SD) for its low gain stage calibration. The SD observations also provide a means to compute gain ratios of low-to-mid and mid-to-high gain stages. This paper describes the DNB on-orbit calibration methodologies used by the VIIRS Characterization Support Team (VCST) in supporting the NASA earth science community with consistent VIIRS sensor data records (SDRs) made available by the Land Science Investigator-led Processing Systems (SIPS). It provides an assessment and update of DNB on-orbit performance, including the SD degradation in the DNB spectral range, detector gain and gain ratio trending, stray light contamination and its correction. Also presented in this paper are performance validations based on earth scenes and lunar observations.

Chen, H.↗
NASA NTRS2017

Suomi-NPP VIIRS Day-Night Band On-Orbit Calibration and Performance

The Suomi national polar-orbiting partnership Visible Infrared Imaging Radiometer Suite (VIIRS) instrument has successfully operated since its launch in October 2011. The VIIRS day-night band (DNB) is a panchromatic channel covering wavelengths from 0.5 to 0.9 microns that is capable of observing Earth scenes during both daytime and nighttime at a spatial resolution of 750 m. To cover the large dynamic range, the DNB operates at low-, middle-, and high-gain stages, and it uses an on-board solar diffuser (SD) for its low-gain stage calibration. The SD observations also provide a means to compute the gain ratios of low-to-middle and middle-to-high gain stages. This paper describes the DNB on-orbit calibration methodology used by the VIIRS characterization support team in supporting the NASA Earth science community with consistent VIIRS sensor data records made available by the land science investigator-led processing systems. It provides an assessment and update of the DNB on-orbit performance, including the SD degradation in the DNB spectral range, detector gain and gain ratio trending, and stray-light contamination and its correction. Also presented in this paper are performance validations based on Earth scenes and lunar observations, and comparisons to the calibration methodology used by the operational interface data processing segment.

Chen, Hongda↗
NASA NTRS1990

Corrosion Prevention in Copper Combustion Chamber Liners of Liquid Oxygen/Methane Booster Engines

Prior research conducted by United Technologies Research Center and Rockwell International Rocketdyne Division encountered severe copper corrosion while flowing hydrocarbon fuels through copper cooling tubes. These experimental results have very important implications for the development of low-cost, regeneratively cooled, oxygen/hydrocarbon bipropellant booster engines. Aerojet TechSystems undertook a program sponsored by NASA/Lewis Research Center in 1986 with two objectives: (1) to define the corrosive interaction process that occurs between hydrocarbon fuels and copper combustion chamber liner materials, using both static and dynamic test methods, and (2) to identify and demonstrate protective measures against this corrosive process. The results of the first program task demonstrated that the most damaging corrosive process was caused by trace amounts of sulfur-containing impurities in the hydrocarbon fuel which react with the copper chamber liner material to form cuprous sulfide (Cu2S), as reported in Paper No. AlAA 88-3215. Experiments were conducted which demonstrated this corrosive process with Mil-Spec RP-1, propane, and methane fuels in contact with OFHC, NASA-Z, and ZrCu coppers. The preliminary results of the second program task demonstrated that electrodeposited gold and platinum coatings held promise of preventing corrosion of copper chamber liners by methane contaminated with sulfur-containing impurities, as reported in Paper No. AIAA 89-2738. Experiments were conducted which demonstrated greatly reduced corrosion of copper by hydrogen sulfide (H2S) and methyl mercaptan (CH3SH) as measured impurities in methane. This paper presents the concluding, confirmatory results from the second program task. The efficacy of a protective gold coating on NASA-Z copper cooling channel walls was conclusively demonstrated. Tests were conducted in the Aerojet Carbothermal Test Facility which provide realistic simulations of booster engine cooling channel conditions such as temperature, pressure, flow velocity, and heat flux. Dynamic test series were performed with methane containing 5 and 10 ppm (by volume) hydrogen sulfide. Gold-plated and unplated copper alloy specimens were evaluated. The tests demonstrated that gold coatings were effective in preventing corrosion of the copper. Posttest metallographic examinations of the unplated specimens showed severe corrosion as a result of reaction with the sulfur containing contaminant in the fuel. In contrast, posttest metallographic examination of the gold-coated specimens showed no corrosion under similar operating conditions. The findings from metallurgical and chemical analyses of the copper specimens, chemical analysis of the methane, and description of all test conditions are provided. Conclusions are reached as to the efficacy of the plating methods and the effectiveness of the metal coatings in the prevention of corrosion in hydrocarbon-fueled booster engine combustion chamber liners.

S D Rosenberg↗
NASA NTRS2001

Further Investigations of the Passive Optical Sample Assembly (POSA) - I Flight Experiment

The Passive Optical Sample Assembly-I (POSA-I), part of the Mir Environmental Effects Payload (MEEP), was designed to study the combined effects of contamination, atomic oxygen, ultraviolet radiation, vacuum, then-nal cycling, and other constituents of the space environment on spacecraft materials. The MEEP program is a Phase I International Space Station Risk Mitigation Experiment. Candidate materials for the International Space Station (ISS) were exposed in a specially designed "suitcase" carrier, with identical specimens facing either Mir or space. The payload was attached by EVA to the exterior of the Mir docking module during the STS-76 mission (f'ig. 1). It was removed during the STS-86 mission after an 18-month exposure. During the mission, it received approximately 7 x 1019 atoMS/CM2 atomic oxygen, as calculated by polymer mass loss, and 413 ESH of solar ultraviolet radiation on the Mir-facing side. The side facing away from Mir received significant contaminant deposition, so atomic oxygen fluence has not been reliably determined. The side facing away from Mir received 571 ESH of solar UV. Contamination was observed on both the Mir-facing and space-facing sides of the POSA-I experiment , with a greater amount of deposition on the space facing side than the Mir side. The contamination has been determined to be outgassed silicone photofixed by ultraviolet radiation and converted to silicate by atomic oxygen interaction. Electron spectroscopy for chemical analysis (ESCA) with depth profiling indicated the presence of 26 - 31 nm silicate on the Mir-facing side and 500 - 1000 nm silicate on the space-facing side. The depth profiling also showed that the contaminant layer was uniform, with a small amount of carbon present on the surface and trace amounts of nitrogen, phosphorus, sulfur, and tin. The surface carbon layer is likely due to post-flight exposure in the laboratory and is similar to carbonaceous deposits on control samples. EDAX and FTIR analysis concurred with ESCA for the presence of silicon, oxygen, and carbon. Nearly 400 samples were exposed on POSA-I, which included materials such as thermal control coatings polymeric films, optical materials, and multi-layer insulation blankets. A previous paper discussed the effects of the space environment exposure and contaminant deposition on candidate materials for ISS, including Z93P inorganic thermal control coating, various anodizes, and multi-layer insulation blankets. This paper details the investigation of environmental effects on the remainder of POSA-I samples, particularly the innovative conductive thermal control coatings developed by AZ Technology of Huntsville, AL and HT Research Institute of Chicago, IL. The silicone/silicate contamination had a significant impact on the solar absorptance of white inorganic thermal control coatings on the space-facing side of POSA-I. The effect of contamination on electrical conductivity is discussed. Samples of conductive anodized aluminum developed by Boundary Technologies of Buffalo Grove, IL were also exposed on POSA-I. The effects of the space environment and contaminant deposition on the optical and electrical properties of the conductive anodized aluminum are discussed.

Finckenor, Miria M.↗
NASA NTRSDate not supplied

Modeling of Multicomponent Trace Contaminant Adsorption on Activated Carbon

Modeling of multicomponent trace contaminant adsorption on activated carbon for spacecraft life support applications presents challenges due to the very low contaminant concentrations in cabin air coupled with very strong adsorption of heavier components such as cyclic polydimethylsiloxanes. Both gas-phase and solid-phase micropore mass transfer resistances can be important, and competitive interactions between adsorbed components can result in behavior such as roll-up where lighter components displaced by heavier components have a higher concentration at the outlet than at the inlet. This paper describes the further development of a dynamic trace contaminant adsorption model based on Ideal Adsorbed Solution Theory (IAST). Alternative 1-dimensional and 2-dimensional versions of the model are described with different mass transfer resistance and driving force assumptions. Optimization of solution methods for speed and stability is also described. Mass balance equations are scaled to provide sensitivity over the wide range of component concentrations in cabin air. Model parameters are estimated from isotherm and breakthrough test data on single adsorbate and binary adsorbate systems. Multicomponent results are compared against predictions of a heritage model used extensively by NASA for trace contaminant control system (TCCS) carbon bed sizing. Finally, efforts to implement the model in a second software platform for wider access are described.

Kevin E Lange↗
NASA NTRS1980

Alumina barrier for vacuum brazing

Heating platens of vacuum-brazing press will not stick to workpiece if aluminum oxide "paper" is interposed. Paper does not disintegrate in press, will not contaminate braze alloy, and helps form smoothly contoured, regular fillet at brazed edges.

Beuyukian, C. S.↗
NASA NTRS1984

Progress in natural laminar flow research

For decades, since the earliest attempts to obtain natural laminar flow (NLF) on airplanes, three classical objections to its practicality have been held in the aeronautical community. These objectives concerned first, the capability to manufacture practical airframe surfaces smooth enough for NLF; second, the apparent inherent instability and sensitivity of NLF; and third, the accumulation of contamination such as insect debris in flight. This paper explains recent progress in our understanding of the achieveability and maintainability of NLF on modern airframe surfaces. This discussion explains why previous attempts to use NLF failed and what has changed regarding the three classical objections to NLF practicality. Future NASA research plans are described concerning exploring the limits of NLF usefulness, production tolerances, operational considerations, transition behavior and measurement methods, and NLF design applications.

Holmes, B. J.↗
NASA NTRS1992

Evaluation of capillary electrophoresis for in-flight ionic contaminant monitoring of SSF potable water

Until 1989, ion chromatography (IC) was the baseline technology selected for the Specific Ion Analyzer, an in-flight inorganic water quality monitor being designed for Space Station Freedom. Recent developments in capillary electrophoresis (CE) may offer significant savings of consumables, power consumption, and weight/volume allocation, relative to IC technology. A thorough evaluation of CE's analytical capability, however, is necessary before one of the two techniques is chosen. Unfortunately, analytical methods currently available for inorganic CE are unproven for NASA's target list of anions and cations. Thus, CE electrolyte chemistry and methods to measure the target contaminants must be first identified and optimized. This paper reports the status of a study to evaluate CE's capability with regard to inorganic and carboxylate anions, alkali and alkaline earth cations, and transition metal cations. Preliminary results indicate that CE has an impressive selectivity and trace sensitivity, although considerable methods development remains to be performed.

Mudgett, Paul D.↗
NASA NTRS1992

Dust control research for SEI

A study, at NASA Johnson Space Center, of dust control requirements for surface habitats has focused on identification of the dust problem, identifying dust control techniques and dust control technology areas requiring research development. This research was performed for the Surface Habitats and Construction (SHAC) technology area. Dust control consists of two problems: (1) how to keep it out of the habitat; and (2) once the habitat or airlock is contaminated with dust, how to collect it. This paper describes the dust environment, the Apollo experience and dust control methods used, future EVA operational considerations, and dust control concepts for surface habitats.

Kennedy, Kriss J.↗
NASA NTRS1995

LDEF's contribution to the selection of thermal control coatings for the Space Station

The design of the Space Station presented new challenges in the selection and qualification of thermal control materials that would survive in low Earth orbit for a duration of up to 30 years. Prior to LDEF, flight data were obtained from Orbiting Solar Observatory (OSO) satellites, a number of Orbiter flights, and limited ground tests. The excellent data obtained from the OSO satellites were based on calorimetry and temperature measurements which were transmitted to Earth; these satellites were not recovered. For some of these flight experiments it was difficult to distinguish between changes due to contamination, atomic oxygen (AO), ultraviolet radiation (UV), particle radiation and the synergistic effects between them. The data from Shuttle flights were primarily focused on developing a better understanding of atomic oxygen (AO) effects. Although UV and AO were present, the relatively short duration of the Orbiter flights, about one week, was viewed as too short to show the effects from UV or possible synergistic interactions with AO and contamination. At the beginning of the program in 1989 there was no established design data base for AO resistant thermal control coatings for the Space Station. Then came the Long Duration Exposure Facility (LDEF). It provided the first long life data for materials exposed and recovered from space with a characterized environment. Post flight analysis proved data on the effects of contamination on optical properties in the ram (velocity) and wake directions and the erosion of Teflon and multilayer insulation (MLI) covers. The results from LDEF confirmed and, in some cases, modified the approach used for the Space Station, as well as helped to focus our development activities. These development activities resulted in a number of new technical solutions which are applicable to many spacecraft surfaces and missions. LDEF also showed the detrimental effects that could occur from silicone contamination, an issue that has not been completely resolved. An investigation was initiated in 1993 on the effects of silicone contamination and was continuing at the time this paper was prepared.

Babel, Henry W.↗
NASA NTRS2004

Microlith Based Sorber for Removal of Environmental Contaminants

The development of energy efficient, lightweight sorption systems for removal of environmental contaminants in space flight applications is an area of continuing interest to NASA. The current CO2 removal system on the International Space Station employs two pellet bed canisters of 5A molecular sieve that alternate between regeneration and sorption. A separate disposable charcoal bed removes trace contaminants. An alternative technology has been demonstrated using a sorption bed consisting of metal meshes coated with a sorbent, trademarked and patented as Microlith by Precision Combustion, Inc. (PCI); thesemeshes have the potential for direct electrical heating for this application. This allows the bed to be regenerable via resistive heating and offers the potential for shorter regeneration times, reduced power requirement, and net energy savings vs. conventional systems. The capability of removing both CO2 and trace contaminants within the same bed has also been demonstrated. Thus, the need for a separate trace contaminant unit is eliminated resulting in an opportunity for significant weight savings. Unlike the charcoal bed, zeolites for trace contaminant removal are amenable to periodic regeneration. This paper describes the design and performance of a prototype sorber device for simultaneous CO2 and trace contarninant removal and its attendant weight and energy savings.

Roychoudhury, S.↗
NASA NTRS2007

An Investigation of the Characterization of Cloud Contamination in Hyperspectral Radiances

In regions lacking direct observations, the assimilation of radiances from infrared and microwave sounders is the primary method for characterizing the atmosphere in the analysis process. In recent years, technological advances have led to the launching of more advanced sounders, particularly in the thermal infrared spectrum. With the advent of these hyperspectral sounders, the amount of data available for the analysis process has and will continue to be dramatically increased. However, the utilization of infrared radiances in variational assimilation can be problematic in the presence of clouds; specifically the assessment of the presence of clouds in an instantaneous field of view (IFOV) and the contamination in the individual channels within the IFOV. Various techniques have been developed to determine if a channel is contaminated by clouds. The work presented in this paper and subsequent presentation will investigate traditional techniques and compare them to a new technique, the C02 sorting technique, which utilizes the high spectral resolution of the Atmospheric Infrared Sounder (AIRS) within the framework of the Gridpoint Statistical Interpolation (GSI) 3DVAR system. Ultimately, this work is done in preparation for the assessment of short-term forecast impacts with the regional assimilation of AIRS radiances within the analysis fields of the Weather Research and Forecast Nonhydrostatic Mesoscale Model (WRF-NMM) at the NASA Short-term Prediction Research and Transition (SPORT) Center.

McCarty, William↗
NASA NTRS2009

Status of the ISS Trace Contaminant Control System

A habitable atmosphere is a fundamental requirement for human spaceflight. To meet such a requirement, the cabin atmosphere must be constantly scrubbed to maintain human life and system functionality. The primary system for atmospheric scrubbing of the US on-orbit segment (USOS) of the International Space Station (ISS) is the Trace Contaminant Control System (TCCS). As part of the Environmental Control and Life Support Systems (ECLSS) atmosphere revitalization rack in the US Lab, the TCCS operates continuously, scrubbing trace contaminants generated primarily by two sources: the metabolic offgassing of crew members and the offgassing of equipment in the ISS. It has been online for approximately 95% since activated in February 2001. The TCCS is comprised of a charcoal bed, a catalytic oxidizer, and a lithium hydroxide post-sorbent bed, all of which are designed to be replaced onorbit when necessary. In 2006, all three beds were replaced following an observed increase in the system resistance that occurred over a period several months. The beds were returned to ground and subjected to a test, teardown and evaluation to investigate the root cause(s) of the decrease in flow rate through the system. In addition, various chemical and physical analyses of the bed materials were performed to determine contaminant loading and any changes in performance. This paper will mainly focus on the results of these analyses and how this correlates with what has been observed from archival sampling and onorbit events. This may provide insight into the future performance of the TCCS and rate of change for orbital replacement units in the TCCS.

Macatangay, Ariel V.↗
NASA NTRS2001

The Plume Impingement Contamination II Experiment: Motivation, Design, and Implementation Plan

The International Space Station (ISS) will have a long service life during which it must be able to serve as a capable platform for a wide variety of scientific investigations. In order to provide this capability, the ISS has, at the system level, a design requirement of no more than 100 Angstroms of contaminant deposition per year from "non-quiescent" sources. Non-quiescent sources include the plumes resulting from the firing of reaction control system (ReS) engines on space vehicles visiting the ISS as well as the engines on the ISS itself. Unfortunately, good general plume contamination models do not yet exist. This is due both to the complexity of the problem, making the analytic approach difficult, and to the difficulty in obtaining empirical measurements of contaminant depositions. To address this lack of flight data, NASA Johnson Space Center is planning to fly an experiment, Plume Impingement Contamination-II, to measure the contamination deposition from the Shuttle Orbiter's primary RCS engines as a function angle from plume centerline. This represents the first direct on-orbit measurement of plume impingement contamination away from the nozzle centerline ever performed, and as such is extremely important in validating mathematical models which will be used to quantify the cumulative plume impingement contamination to the ISS over its lifetime. The paper will elaborate further upon the motivation behind making these measurements as well as present the design and implementation plan of this planned experiment.

Lumpkin, Forrest E., III↗
NASA NTRS2011

On Orbit ISS Oxygen Generation System Operation Status

The International Space Station (ISS) United States Orbital Segment (USOS) Oxygen Generation System (OGS) has accumulated almost a year of operation at varied oxygen production rates within the US Laboratory Module (LAB) since it was first activated in July 2007. It was operated intermittently through 2009 and 2010, due to filter clogging and acid accumulation in the recirculation loop. Since the installation of a deionizing bed in the recirculation loop in May of 2011 the OGA has been operated continuously. Filters in the recirculation loop have clogged and have been replaced. Hydrogen sensors have drifted apart, and a power failure may have condensed water on a hydrogen sensor. A pump delta pressure sensor failed, and a replacement new spare pump failed to start. Finally, the voltage across the cell stack increased out of tolerance due to cation contamination, and the cell stack was replaced. This paper will discuss the operating experience and characteristics of the OGS, as well as operational issues and their resolution.

Diderich, Greg S.↗