NMR study of phase transitions in Rochelle salt
Spontaneous polarization measurement of ferroelectric Rochelle salt near Curie point, using nuclear magnetic resonance for phase transitions
Casabella, P. A.↗
SEARCH · Search NASA
Results for “Phase Transitions”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Late time cosmological phase transitions 1: Particle physics models and cosmic evolution
We described a natural particle physics basis for late-time phase transitions in the universe. Such a transition can seed the formation of large-scale structure while leaving a minimal imprint upon the microwave background anisotropy. The key ingredient is an ultra-light pseudo-Nambu-Goldstone boson with an astronomically large (O(kpc-Mpc)) Compton wavelength. We analyze the cosmological signatures of and constraints upon a wide class of scenarios which do not involve domain walls. In addition to seeding structure, coherent ultra-light bosons may also provide unclustered dark matter in a spatially flat universe, omega sub phi approx. = 1.
Frieman, Joshua A.↗
Conjectures about the Chiral Phase Transition in QCD from Anomalous Multi-Instanton Interactions
To date numerical simulations of lattice QCD have not found a chiral phase transition of first order that is expected to occur for sufficiently light pions. We show how the restoration of an exact global chiral symmetry can strongly decrease the breaking of the approximate, anomalous U A ( 1 ) symmetry. This is testable on the lattice through simulations for one through four flavors. In QCD a small breaking of the U A ( 1 ) symmetry in the chirally symmetric phase generates novel experimental signals. Published by the American Physical Society 2024
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
Topological phase transition without single particle gap closing in strongly correlated systems
Here, in this study, we show two models where changing topology does not necessarily close the bulk insulating charge gap as demanded in the standard noninteracting picture. From extensive determinantal and dynamical cluster quantum Monte Carlo simulations of the half-filled and quarter-filled Kane-Mele-Hubbard model, we show that, for sufficiently strong interactions at either half- or quarter-filling, a transition between topological and trivial insulators occurs without the closing of a charge gap. To shed light on this behavior, we illustrate that an exactly solvable model reveals that while the single-particle gap remains, the many-body gap does, in fact, close. These two gaps are the same in the noninteracting system but depart from each other as the interaction turns on. We purport that for interacting systems, the proper probe of topological phase transitions is the closing of the many-body rather than the single-particle gap.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Activation of Semicore Electrons in Alkali Metals and Their Role in the B1–B2 Phase Transition under Pressure
Alkali fluorides are often thought of as archetypical ionic compounds whose structures can be understood in terms of the packing of rigid spheres. At ambient pressure, they assume the rocksalt (B1) structure, while under only a few GPa of pressure, the cesium chloride (B2) structure, with higher coordination numbers, is assumed for KF, RbF, and CsF. NaF requires almost 10 times more pressure to undergo this same phase transition, which has not been observed for LiF. Herein, we provide a detailed analysis, based upon quantum chemical calculations, explaining this behavior. We show that for the heavier alkali metals, the semicore p orbitals engage in metal-metal bonding in the B2 phase, facilitating the pressure-induced B1 → B2 structural transition. Furthermore, these findings suggest that the semicore orbitals of heavy alkali metals can be activated without the need of strong oxidants at very mild levels of compression, resulting in the formation of chemical bonds, challenging both traditional and modern core-valence distinctions. In addition, we argue that Cs 5p-5p bonding in CsCl occurs already at ambient pressure, stabilizing the B2 phase, and suggest experiments that may be able to detect signatures of such bonding.
Anions↗
The phenomenological status of late time phase transition models after cosmic background radiation anisotropy measurements
Some relatively model-independent results for structure formation via late time phase transitions (LTPT) are discussed. In particular, generic LTPT power spectra are presented. The implication of the recent Cosmic Background Explorer (COBE) detection of the cosmic background radiation (CBR) anisotropy at large angular scales (greater than or approximately equal to 7 deg) and the tight upper limits from small angular scales (approximately 1 deg) to LTPT models are discussed. Special attention is focused on the observational constraints and possible non-Gaussian signatures of CBR temperature anisotropies from LTPT and other non-Gaussian models. It is shown that while LTPT have been seriously constrained by the recent data, viable models do remain which provide more power on the 100-200 Mpc scales than do more traditional primordial Gaussian density fluctuation models. Tests for such models are presented, including possible anisotropies on angular scales less than 8 min.
Luo, Xiaochun↗
The Transition Phase in the Take-Off of an Airplane, Special Report
An investigation was undertaken to determine the character and importance of the transition phase between the ground run and steady climb in the takeoff of an airplane and the effects of various factors on this phase and on the airborne part of the takeoff as a whole. The information was obtained from a series of step-by-step integrations, which defined the motion of the airplane during the transition and which were based on data derived from actual takeoff tests of a Verville AT airplane. Both normal and zoom takeoffs under several loading and takeoff speed conditions were considered. The effects of a moderate wind with a corresponding wind gradient and the effect of proximity of the ground were also investigated. The results show that, for normal takeoffs, the best transition was realized at the lowest possible takeoff speed. Moreover, this speed gave the shortest overall takeoff distance for normal takeoffs. Zoom takeoffs required a shorter overall takeoff run than normal takeoffs, particularly with a heavy landing, if the obstacle to be cleared was sufficiently high (greater than 50 feet); no advantage was indicated to the airplane with a light loading if the height to be cleared was less. The error resulting from the neglect of the transition in the calculation of the airborne distance of takeoff was found to vary from 4% with the heaviest loading considered to -4% with the lightest loading for normal takeoffs over a 100-ft obstacle; the percentage error was twice as great for a 50-foot obstacle. For zoom takeoffs the error attained much greater values. The average wind gradient corresponding to a 5-mile-per-hour surface wind reduced the airborne distance required to clear a 50-foot obstacle by about 9% with the lightest loading and 16% with the heaviest loading; for both cases. The overall reduction due to this wind was approximately twice that resulting from the wind gradient alone. A simple expression for the reduction of observed takeoff performance to no-wind conditions is presented. Ground effect is shown to reduce the airborne distance to attain a height of 50 foot by 10% with the lightest loading and 16% with the heaviest loading; for a 100-foot obstacle the percentage reduction was about 1/2 as great.
Wetmore, J. W.↗
The Transition Phase in the Take-Off of an Airplane
Report presents the results of an investigation to determine the character and importance of the transition phase between the ground run and steady climb in the take-off of an airplane and the effects of various factors on this phase and on the air-borne part of the take-off as a whole. The information was obtained from a series of step-by-step integrations, which defined the motion of the airplane during the transition and which were based on data derived from actual take-off tests of a Verville AT airplane. Both normal and zoom take-offs under several loading and take-off speed conditions were considered. The effects of a moderate wind with a corresponding wind gradient and the effect of proximity of the ground were also investigated.
Wetmore, J W↗
Precise Measurements of the Density and Critical Phenomena Near Phase Transitions in Liquid Helium
The first-year progress for the project of precise measurements of the density and critical phenomena of helium near phase transitions is summarized below: (1) completion of a cryogenic sample probe for the proposed measurements, and the rehabilitation of a designated laboratory at Caltech for this project; (2) construction and testing of a superconducting niobium cavity; (3) acquisition of one phase-locked-loop system for high-resolution frequency control and read- out; (4) setting up high-resolution thermometry (HRT) for temperature readout and control; (5) developing new approaches for calibrating the coefficient between the resonant frequency shift (delta f) and the helium density (rho), as well as for measuring the effect of gravity on T(sub lambda) to a much better precision; (6) programming of the interface control of all instruments for automatic data acquisition; and (7) improving data analyses and fitting procedures.
Yeh, Nai-Chang↗
Study of crystalization, crosslinking and dimensional changes during the crystal-liquid phase transition of oriented polymeric systems Semiannual report for period ending 1 Sep. 1968
Crystallization, crosslinking, and dimensional changes during crystal-liquid phase transition of oriented polymeric systems
Mandelkern, L.↗
Deconfining phase transition and the continuum limit of lattice quantum chromodynamics
A large-scale Monte Carlo calculation is presented of the deconfining phase-transition temperature in lattice quantum chromodynamics without fermions. By using the Wilson action, it is found that the transition temperature as a function of the lattice coupling g is consistent with scaling behavior dictated by the perturbative beta function for 6/g-squared greater than 6.15.
Gottlieb, S. A.↗
String mediated phase transitions
It is demonstrated from first principles how the existence of string-like structures can cause a system to undergo a phase transition. In particular, the role of topologically stable cosmic string in the restoration of spontaneously broken symmetries is emphasized. How the thermodynamic properties of strings alter when stiffness and nearest neighbor string-string interactions are included is discussed.
Copeland, ED↗
Quenching through the QCD chiral phase transition
We present a detailed numerical and analytical study of the out-of-equilibrium dynamics of Model G, the dynamical universality class relevant to the chiral phase transition. We perform numerical 3D stochastic (Langevin) simulations of the 𝑂(4) critical point for large lattices in the chiral limit. We quench the system from the high-temperature unbroken phase to the broken phase and study the nonequilibrium dynamics of pion fields. Strikingly, the nonequilibrium evolution of the two-point functions exhibits a regime of growth, a parametrically large enhancement, and a subsequent slow relaxation to equilibrium. We analyze our numerical results using dynamic critical scaling and mean-field theory. The growth of the two-point functions is determined by the nonlinear dynamics of an ideal non-Abelian superfluid, which is a limit of Model G that reflects the broken chiral symmetry. We also relate the nonequilibrium two-point functions to a long-lived parametric enhancement of soft pion yields relative to thermal equilibrium following a quench.
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
Phase transitions in fermionic systems with many-body interaction
A linearized version of the Hartree-Fock method is used as a probe to investigate phase transitions in fermionic systems with many-body interactions. An application to a new exactly solvable model which includes two- and three-body forces is shown.
Bozzolo, G.↗
Imaging nanomagnetism and magnetic phase transitions in atomically thin CrSBr
Since their first observation in 2017, atomically thin van der Waals (vdW) magnets have attracted significant fundamental, and application-driven attention. However, their low ordering temperatures, T c , sensitivity to atmospheric conditions and difficulties in preparing clean large-area samples still present major limitations to further progress, especially amongst van der Waals magnetic semiconductors. The remarkably stable, high-T c vdW magnet CrSBr has the potential to overcome these key shortcomings, but its nanoscale properties and rich magnetic phase diagram remain poorly understood. Here we use single spin magnetometry to quantitatively characterise saturation magnetization, magnetic anisotropy constants, and magnetic phase transitions in few-layer CrSBr by direct magnetic imaging. We show pristine magnetic phases, devoid of defects on micron length-scales, and demonstrate remarkable air-stability down the monolayer limit. We furthermore address the spin-flip transition in bilayer CrSBr by imaging the phase-coexistence of regions of antiferromagnetically (AFM) ordered and fully aligned spins. Our work will enable the engineering of exotic electronic and magnetic phases in CrSBr and the realization of novel nanomagnetic devices based on this highly promising vdW magnet.
36 MATERIALS SCIENCE↗
Instabilities and phase transitions in architected metamaterials: a gradient-enhanced continuum approach
Architected metamaterials such as foams and lattices exhibit a wide range of properties governed by microstructural instabilities and emerging phase transitions. Their macroscopic response–including energy dissipation during impact, large recoverable deformations, morphing between configurations, and auxetic behavior–remains difficult to capture with conventional continuum models, which often rely on discrete approaches that limit scalability. In this work, we propose a nonlocal continuum formulation that captures both stable and unstable responses of elastic architected metamaterials. The framework extends anisotropic hyperelasticity by introducing nonlocal variables and internal length scales reflective of microstructural features. Local polyconvex free-energy models are systematically augmented with two families of non-(poly)convex energies, enabling both metastable and bistable responses. Implementation in a finite element framework enables solution using a hybrid monolithic–staggered strategy. Simulations capture densification fronts, forward and reverse transitions, hysteresis loops, imperfection sensitivity, and globally coordinated auxetic modes. Overall, this framework provides a robust foundation for accelerated modeling of instability-driven phenomena in architected metamaterials, while enabling extensions to anisotropic, dissipative, and active systems as well as integration with data-driven and machine learning approaches.
42 ENGINEERING↗
Nonexcitonic mechanism for electronic and structural phase transitions in Ta 2 Ni(Se,S) 5
Here, we present a first-principles study based on density functional theory (DFT) on the electronic and structural properties of Ta 2 NiSe 5 , a layered transition metal chalcogenide that has been considered as a possible candidate for an excitonic insulator. Our systematic DFT results however provide a nonexcitonic mechanism for the experimentally observed electronic and structural phase transitions in Ta 2 NiSe 5 , in particular explaining why sulfur substitution of selenium reduces the distortion angle in the low-temperature phase and potassium dosing closes the gap in the electronic structure. Moreover, the calculations show that these two effects couple to each other. Further, our first-principles calculations predict several changes in both the crystal structure and electronic structure under the effects of uniform charge dosing and uniaxial strain, which could be tested experimentally.
Tang, Weichen [University of California, Berkeley,↗
Hexagonal and nematic phases of chains. I - Correlation functions. II - Phase transitions
The statistical mechanics of a system of semiflexible chains, which can represent polymer liquid crystals, long-chain biomolecules, stiff wormlike micelles, or columns of discotic liquid crystals, are examined. A continuum theory is used to calculate static correlation functions in the hexagonal and nematic phases. Two correlation functions are considered: (1) the structure factor which describes fluctuations in the density; and (2) the director fluctuation spectrum, which describes fluctuations in the local optical axis. In addition, a model is developed for the phase transitions of a system of infinitely long, semiflexible chains which interact through a steric, excluded-volume repulsion. The model yields generic phase diagrams in terms of pressure or density vs. persistence length or temperature.
Selinger, Jonathan V.↗