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Current Scientific Progress and Future Scientific Prospects Enabled by Spaceborne Precipitation Radar Measurements

First, we examine current scientific progress and understanding that have been possible through use of spaceborne precipitation radar measurements being provided by the TRMM and CloudSat satellites. Second, we look across a future 20-year time frame to assess how and why anticipated improvements in space radar systems will further advance scientific progress into topic areas once considered beyond the realm of space-based remote sensing. JAXA's 13.8 GHz Ku-band cross-track scanning Precipitation Radar (PR) developed for flight on NASA's non-sun-synchronous, diurnally-precessing TRMM satellite, was the first Earth radar flown in space that was designed specifically for precipitation measurement. Its proven accuracy in measuring global rainfall in the tropics and sub-tropics and its unanticipated longevity in continuing these measurements beyond a full decade have established the standards against which all follow-up and future space radars will be evaluated. In regards to the current PR measurement time series, we will discuss a selection of major scientific discoveries and impacts which have set the stage for future radar measuring systems. In fact, the 2nd contemporary space radar applicable for terrestrial precipitation measurement, i.e., JPL-CSA's 94 GHz nadir-staring Cloud Profiling Radar (CPR) flown on NASA's sun-synchronous CloudSat satellite, although designed primarily for measurement of non-precipitating cloud hydrometeors and aerosols, has also unquestionably advanced precipitation measurement because CPR's higher frequency and greatly increased sensitivity (approximately 30 dBZ) has enabled global observations of light rain rate spectrum processes (i.e., rain rates below 0.05 mm per hourand of precipitation processes in the high troposphere (particularly ice phase processes). These processes are beyond reach of the TRMM radar because the PR sensitivity limit is approximately 17 dBZ which means its lower rain rate cutoff is around 0.3 mm per hour and its vertical profiling acuity is greatly limited above the melting layer. Thus, the newer CPR measurements have become important for a variety of scientific reasons that will be highlighted and assessed. In considering scientific progress likely to stem from future precipitation radar systems, we will specifically examine possible scientific impacts from three anticipated missions for which NASA and various of its space agency partners are expected to lead the way. These three missions are: (1) the nearterm Global Precipitation Measuring (GPM) Mission; (2) the decadal timeline Aerosol and Cloud Experiment (ACE) Mission; and the post-decadal timeline NEXRAD in Space (NIS) Mission. The observational capabilities of the planned radar systems for each of these three satellite missions are distinct from each other and each provides progressive improvements in precipitation measuring and scientific research capabilities relative to where we are now -- insofar as TRMM PR and the CloudSat CPR capabilities. The potential innovations in scientific research will be discussed in a framework of likely synergisms between next-generation radar capabilities and accessible dynamical and microphysical properties that have heretofore evaded detection.

Smith, Eric A.↗

Land Surface Precipitation and Hydrology in MERRA-2

The Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2), provides global, 1-hourly estimates of land surface conditions for 1980-present at 50-km resolution. Outside of the high latitudes, MERRA-2 uses observations-based precipitation data products to correct the precipitation falling on the land surface. This paper describes the precipitation correction method and evaluates the MERRA-2 land surface precipitation and hydrology. Compared to monthly GPCPv2.2 observations, the corrected MERRA-2 precipitation (M2CORR) is better than the precipitation generated by the atmospheric models within the cyclingMERRA-2 system and the earlier MERRA reanalysis. Compared to 3-hourlyTRMM observations, the M2CORR diurnal cycle has better amplitude but less realistic phasing than MERRA-2 model-generated precipitation. Because correcting the precipitation within the coupled atmosphere-land modeling system allows the MERRA-2 near-surface air temperature and humidity to respond to the improved precipitation forcing, MERRA-2 provides more self-consistent surface meteorological data than were available from the earlier, offline MERRA-Land reanalysis. Overall, MERRA-2 land hydrology estimates are better than those of MERRA-Land and MERRA. A comparison against GRACE satellite observations of terrestrial water storage demonstrates clear improvements in MERRA-2 over MERRA in South America and Africa but also reflects known errors in the observations used to correct the MERRA-2 precipitation. The MERRA-2 and MERRA-Land surface and root zone soil moisture skill vs. in situ measurements is slightly higher than that of ERA-Interim Land and higher than that of MERRA (significantly for surface soil moisture). Snow amounts from MERRA-2 have lower bias and correlate better against reference data than do those of MERRA-Land and MERRA, with MERRA-2 skill roughly matching that of ERA-Interim Land. Seasonal anomaly R values against naturalized stream flow measurements in the United States are, on balance, highest for MERRA-2 and ERA-Interim Land, somewhat lower for MERRA-Land, and lower still for MERRA.

MERRA-↗

Chapter 7: Precipitation Change in the United States

Annual precipitation has decreased in much of the West, Southwest, and Southeast and increased in most of the Northern and Southern Plains, Midwest, and Northeast. A national average increase of 4% in annual precipitation since 1901 is mostly a result of large increases in the fall season. Heavy precipitation events in most parts of the United States have increased in both intensity and frequency since 1901. There are important regional differences in trends, with the largest increases occurring in the northeastern United States. In particular, mesoscale convective systems (organized clusters of thunderstorms)-the main mechanism for warm season precipitation in the central part of the United States-have increased in occurrence and precipitation amounts since 1979. The frequency and intensity of heavy precipitation events are projected to continue to increase over the 21st century (high confidence). Mesoscale convective systems in the central United States are expected to continue to increase in number and intensity in the future. There are, however, important regional and seasonal differences in projected changes in total precipitation: the northern United States, including Alaska, is projected to receive more precipitation in the winter and spring, and parts of the southwestern United States are projected to receive less precipitation in the winter and spring. Northern Hemisphere spring snow cover extent, North America maximum snow depth, snow water equivalent in the western United States, and extreme snowfall years in the southern and western United States have all declined, while extreme snowfall years in parts of the northern United States have increased. Projections indicate large declines in snowpack in the western United States and shifts to more precipitation falling as rain than snow in the cold season in many parts of the central and eastern United States.

Easterling, D. R.↗

Assessment of Precipitation Anomalies in California Using TRMM and MERRA Data

After more than a decade of moderate seasonal deviations from the expected climate, it is easy to forget that California is actually prone to instabilities in precipitation patterns that occur on various scales. Using modern satellite and reanalysis data we reassess certain aspects of the precipitation climate in California from the past three decades. California has a well-pronounced rain season that peaks in December-February. However, the 95% confidence interval around the climatological precipitation during these months imply that deviations on the order of 60% of the expected amounts are very likely during the most important period of the rain season. While these positive and negative anomalies alternate almost every year and tend to cancel each other, severe multi-year declines of precipitation in California seem to appear on decadal scales. The 1986-1994 decline of precipitation was similar to the current one that started in 2011, and is apparent in the reanalysis data. In terms of accumulated deficits of precipitation, that episode was no less severe than the current one. While El Niño (the warm phase of the El Niño Southern Oscillation, ENSO) is frequently cited as the natural forcing expected to bring a relief, our assessment is that ENSO has been driving at best only 6% of precipitation variability in California in the past three decades. It means El Niño needs to be stronger and longer, in order to have a higher likelihood of a positive impact, and the current one does not match these criteria. Using fractional risk analysis of precipitation populations during normal and dry periods, we show that the likelihood of losing the most intensive precipitation events drastically increases during the multi-year drying events. Since storms delivering up to 50% of precipitation in California are driven by atmospheric rivers making landfall, thus the importance of their suppression and blockage by persistent ridges of atmospheric pressure in the northeast Pacific.

Savtchenko, Andrey K.↗

Global Precipitation Means and Variations with the New Version of GPCP

Knowledge of global precipitation means, patterns and variations is essential for understanding the global water cycle. The observation-based global analysis of the Global Precipitation Climatology Project (GPCP) has been a key input to many such studies, including those related to means of the global (and regional) water and energy cycles. A new version (Version 3.1) of the GPCP monthly analysis is now available (1983-2019), with finer spatial resolution (0.5º latitude/longitude), updated satellite algorithms, latest gauge analysis over land from the Global Precipitation Climatology Center (GPCC), and with ocean climatologies adjusted using information from the Tropical Rainfall Measuring Mission (TRMM), the Global Precipitation Measurement (GPM) mission and CloudSat. The presentation will give key findings from the new analysis, compare with the previous version, link to studies of the water cycle and compare to CMIP6 climate model results. The GPCP Monthly V3.1 analysis uses a Tropical Composite Climatology (TCC) using 22 years (1998-2019) of TRMM and GPM-based surface precipitation estimates from passive microwave, radar and combined passive microwave and radar observations to adjust the long-term mean values in the tropics over ocean. At higher latitudes over ocean climatological values of merged CloudSat and GPM combined passive microwave and radar surface precipitation estimates are used. The result of the new algorithms and procedures is an ocean mean value 60º N to 60º S of 3.2 mm/d, an increase of 7% from the older V2.3. Over land the gauge analysis (from GPCC in Germany), combined with satellite estimates results in a small decrease (~ 0.5%) from the previous version, giving a total global precipitation mean of 2.81 mm/d for V3.1, an increase of 4.5%. Variations from inter-annual to trend scales over most of the ocean are driven by the Colorado State University (CSU) Goddard Profiling (GPROF) algorithm applied to SSMI/SSMIS satellite data. The new GPCP version retains a near zero trend of global precipitation, with significant positive trends in the deep tropics along the Pacific ITCZ and elsewhere, countered by middle latitude decreases, very similar to the previous version of the GPCP Monthly analysis. The pattern of trends is similar to that of AMIP climate model results, driven by observed SSTs for the period in question, but very different from results for “free-running” CMIP historical ensembles, likely due in part to the relatively short comparison period and effects of inter-decadal variations in the GPCP and AMIP results that are not in the “history” models. Interannual variations are also nearly the same in the new version, but with finer detail, although ENSO variations over the ocean have slightly larger amplitude than before, an effect likely related to the change in ocean satellite algorithm used in Version 3. For precipitation intensity (percentiles) at the monthly scale, especially in the tropics, GPCP shows a positive trend for the upper one third of the percentiles (Pct ≥ 70th) and a much weaker positive trend for the lowest percentiles (Pct ≤ 10th), while negative trends appear for the middle one-half percentiles (20th-65th). AMIP results agree with those from the GPCP in terms of the sign of the changes/trends for high and intermediate percentiles. The CMIP historical results also agree in the sign of the trends, but the trends are weaker. Comparisons with other types of CMIP historical simulations including the GHG-only, aerosol-only, and nature-only runs suggest that the observed changes/trends in precipitation amount and intensity during the GPCP period are dominated by a combination of the effects of the Pacific Decadal Oscillation (PDO) and anthropogenic GHG-related surface warming.

Robert Adler↗

Improving Cross-track Scanning Radiometers’ Precipitation Retrieval over Ocean by Morphing

Previous studies showed that conical scanning radiometers greatly outperform cross-track scanning radiometers for precipitation retrieval over ocean. This study demonstrates a novel approach to improve precipitation rates at the cross-track scanning radiometers’ observation time by propagating the conical scanning radiometers’ retrievals to the cross-track scanning radiometers’ observation time. The improved precipitation rate is a weighted average of original cross-track radiometers’ retrievals and retrievals propagated from a conical scanning radiometer. The cross-track scanning radiometers include the Advanced Technology Microwave Sounder (ATMS) on board the SNPP satellite and four Microwave Humidity Sounders (MHSs). The conical scanning radiometers include the Advanced Microwave Scanning Radiometer 2 (AMSR2) and three Special Sensor Microwave Imager/Sounders (SSMISs), while the precipitation retrievals from the Global Precipitation Measurement (GPM) Microwave Imager (GMI) are taken as the reference. Results show that the morphed precipitation rates agree much better with the reference. The degree of improvement depends on several factors, including the propagated precipitation source, the time interval between the cross-track scanning radiometer and the conical scanning radiometer, the precipitation type (convective versus stratiform), the precipitation events’ size, and the geolocation. The study has potential to greatly improve high-impact weather systems monitoring (e.g., hurricanes) and multisatellite precipitation products. It may also enhance the usefulness of future satellite missions with cross-track scanning radiometers on board.

Yalei You↗

NASA’s Atmosphere Observing System (AOS), From A Precipitation Perspective

NASA is developing the Atmosphere Observing System (AOS) mission as part of its Earth System Observatory (ESO) in response to priorities identified in the 2017 Earth Science Decadal Survey. AOS addresses the Decadal Survey’s call for missions measuring the targeted observables “clouds, convection, and precipitation”; “aerosol and cloud radiative properties”, and “aerosol vertical profiles”. AOS is currently in Phase A, the concept and technology development phase, with plans for satellite launches in the late 2020’s and early 2030’s, and suborbital measurements to include field campaigns after those satellite launches. Key precipitation-related instrumentation includes Doppler radars capable of measuring clouds and precipitation, and passive microwave radiometers with channels between 89-700 GHz. Other instrumentation includes dual-wavelength backscatter lidars, a multi-wavelength and multi-angle polarimeter, a far infrared imaging radiometer, and aerosol and moisture limb sounders that will contribute to studies of coupled aerosol-cloud-precipitation processes. From the perspective of precipitation science, a Ku-band Doppler radar in a 55° inclined orbit provided by JAXA will continue the heritage of precipitation radar measurements made by the Tropical Rainfall Measuring Mission (TRMM) and Global Precipitation Mission (GPM), while adding information about Doppler-derived particle vertical motions. With assumptions about particle terminal velocities, the Doppler measurements will enable estimates of the vertical air motion in storms. A higher frequency (W and/or Ka band) radar on a satellite in a polar sun-synchronous orbit will add similar information with greater sensitivity to clouds and to light precipitation. Passive microwave radiometers for AOS will be less capable than those from TRMM and GPM from a precipitation-measurement perspective, but more capable of adding information about cloud processes. Synergies among these and other instruments are expected to advance process-level understanding of aerosols, clouds, and precipitation.

Daniel J Cecil↗

Changing Characteristics of Tropical Extreme Precipitation-Cloud Regimes in Warmer Climates

In this paper, we have investigated the changing characteristics of climatic scale (monthly) tropical extreme precipitation in warming climates using the Energy Exascale Earth System Model (E3SM). Results are from Atmospheric Model Intercomparison Project (AMIP)-type simulations driven by a) control experiment with present-day sea surface temperature (SST) and CO 2 concentration, b) P4K, same as in a) but with uniform increase by 4K in SST globally, and c) same as in a), but with imposed SST and CO 2 concentration from outputs of coupled E3SM forced by 4xCO 2 concentration. We find that as the surface warms under P4K and 4xCO 2 , both convective and stratiform rain increase. Importantly, there is increasing fractional contribution of stratiform rain as a function of precipitation intensity, with the most extreme but rare events occurring preferentially over land more than ocean, more so under 4xCO 2 than P4K. Extreme precipitation is facilitated by increased precipitation efficiency, reflecting accelerated rates of recycling of precipitation-cloud water (both liquid and ice phases) in regions with colder anvil cloud tops. Changes in vertical profiles of clouds, condensation heating and vertical motions indicate increasing precipitation-cloud-circulation organization from control, P4K to 4xCO 2 . Results suggest that large-scale ocean warming, i.e., P4K, is the primary cause contributing to organization structure resembling the well-known Mesoscale Convective System (MCS) for increased extreme precipitation on shorter (hourly to daily) time scales. Additional 4xCO 2 atmospheric radiative heating, and dynamically consistent anomalous SST further amplifies the MCS organization under P4K. Analyses of the surface moist static energy distribution show that increase in surface moisture (temperature) under P4K and 4xCO 2 is the key driver leading to enhanced convective instability over tropical ocean (land). However, the fast and large increase in land surface temperature and lack of available local moisture result in strong reduction in land surface relative humidity, reflecting severe drying and enhanced convective inhibition (CIN). It is argued that very extreme and rare “record-breaking” precipitation events found over land under P4K, more so under 4xCO 2 , are likely due to the delayed onset of deep convection, i.e., the longer the suppression of deep convection by CIN, the more severe the extreme precipitation when eventually occur, due to the release of large amount of stored surplus convective available potential energy in the lower troposphere during prolonged CIN.

climate-scale extreme tropical precipitation↗

Stimulating β -Series Precipitation in Mg–Nd Alloys Via Microalloying: A Comparison of Electron Microscopy and Small-Angle Scattering Techniques

The Mg–Nd alloy system is of particular interest in the development of high-strength, lightweight structural alloys due to the formation of strengthening metastable Mg–Nd β-series precipitates during heat treatment. The strengthening is primarily provided by a combination of the β''' and β 1 precipitation. It is therefore important to understand how the precipitation behavior can be enhanced by other common alloying elements. In this work, the effects of 0.2 wt pct Zn and Ca on β-series precipitation were studied. Small-angle/ultra-small-angle X-ray scattering (SAXS/USAXS) techniques in combination with scanning transmission electron microscopy (STEM) were used to study the evolution of precipitation microstructure. Here, it is found that the Zn additions refine the precipitates, leading to an increase in hardness with aging at 200 °C. On the other hand, the Ca additions result in an acceleration in the formation of larger β 1 precipitates and chains which provides less strengthening. The β 1 chains are surrounded by precipitate-free zones (PFZs) that further contribute to the decreases in hardness observed in the over-aged condition. This paper demonstrated that SAXS/USAXS provides a powerful tool for an in situ study of the early stages of precipitation in the Mg–Nd-based alloys.

36 MATERIALS SCIENCE↗

A stress-sensitive precipitate nucleation model beyond classical nucleation theory

The dynamic evolution of precipitates and second phases dictates the strength and stability of most engineering alloys. By design, or as a consequence of thermo-mechanical aging, engineering metals and alloys often form precipitates of second phases when subjecting to diverse thermal and mechanical loads. Precipitation is governed by several factors, including the alloy’s composition, processing/operating temperature, and stresses — either as a result of external loads or from residual stresses. However, state-of-the-art models for precipitate nucleation (i.e., classical nucleation theory) typically lacks consistent method to capture the effects of externally applied and/or internal stresses on nucleation; thereby severely limiting the applicability of these models to complex materials systems and to representative loading scenarios. Here, in this work, we extend upon classical nucleation theory to account for the effect of stresses on precipitation kinetics and thermodynamics. This is achieved via the use of an Eshelbian micromechanics framework keeping track of (i) the stress build up resulting from second phase formation as a function of mechanical load and, (ii) the effects of dislocations on precipitate formation. This new model is applied to σ precipitate in Fe–Cr binary alloys and M 23 C 6 precipitate in 316H stainless steel (SS). Simulations demonstrate the important role of both the remotely applied loads and dislocation pile ups on precipitate nucleation.

36 MATERIALS SCIENCE↗

Were kinetics of Archean calcium carbonate precipitation related to oxygen concentration?

Archean carbonates commonly contain decimetre- to metre-thick beds consisting entirely of fibrous calcite and neomorphosed fibrous aragonite that precipitated in situ on the sea floor. The fact that such thick accumulations of precipitated carbonate are rare in younger marine carbonates suggests an important change in the modes of calcium carbonate precipitation through time. Kinetics of carbonate precipitation depend on the concentration of inhibitors to precipitation that reduce crystallization rates and crystal nuclei formation, leading to kinetic maintenance of supersaturated solutions. Inhibitors also affect carbonate textures by limiting micrite precipitation and promoting growth of older carbonate crystals on the sea floor. Fe2+, a strong calcite-precipitation inhibitor, is thought to have been present at relatively high concentrations in Archean seawater because oxygen concentrations were low. The rise in oxygen concentration at 2.2-1.9 Ga led to the removal of Fe2+ from seawater and resulted in a shift from Archean facies, which commonly include precipitated beds, to Proterozoic facies, which contain more micritic sediment and only rare precipitated beds.

Non-NASA Center↗

Observation-Corrected Precipitation Estimates in GEOS-5

Several GEOS-5 applications, including the GEOS-5 seasonal forecasting system and the MERRA-Land data product, rely on global precipitation data that have been corrected with satellite and or gauge-based precipitation observations. This document describes the methodology used to generate the corrected precipitation estimates and their use in GEOS-5 applications. The corrected precipitation estimates are derived by disaggregating publicly available, observationally based, global precipitation products from daily or pentad totals to hourly accumulations using background precipitation estimates from the GEOS-5 atmospheric data assimilation system. Depending on the specific combination of the observational precipitation product and the GEOS-5 background estimates, the observational product may also be downscaled in space. The resulting corrected precipitation data product is at the finer temporal and spatial resolution of the GEOS-5 background and matches the observed precipitation at the coarser scale of the observational product, separately for each day (or pentad) and each grid cell.

Data Assimilation↗

Supporting Hydrometeorological Research and Applications with Global Precipitation Measurement (GPM) Products and Services

Precipitation is an important dataset in hydrometeorological research and applications such as flood modeling, drought monitoring, etc. On February 27, 2014, the NASA Global Precipitation Measurement (GPM) mission was launched to provide the next-generation global observations of rain and snow (http:pmm.nasa.govGPM). The GPM mission consists of an international network of satellites in which a GPM Core Observatory satellite carries both active and passive microwave instruments to measure precipitation and serve as a reference standard, to unify precipitation measurements from a constellation of other research and operational satellites. The NASA Goddard Earth Sciences (GES) Data and Information Services Center (DISC) hosts and distributes GPM data. The GES DISC is home to the data archive for the GPM predecessor, the Tropical Rainfall Measuring Mission (TRMM). GPM products currently available include the following:1. Level-1 GPM Microwave Imager (GMI) and partner radiometer products2. Goddard Profiling Algorithm (GPROF) GMI and partner products (Level-2 and Level-3)3. GPM dual-frequency precipitation radar and their combined products (Level-2 and Level-3)4. Integrated Multi-satellitE Retrievals for GPM (IMERG) products (early, late, and final run)GPM data can be accessed through a number of data services (e.g., Simple Subset Wizard, OPeNDAP, WMS, WCS, ftp, etc.). A newly released Unified User Interface or UUI is a single interface to provide users seamless access to data, information and services. For example, a search for precipitation products will not only return TRMM and GPM products, but also other global precipitation products such as MERRA (Modern Era Retrospective-Analysis for Research and Applications), GLDAS (Global Land Data Assimilation Systems), etc.New features and capabilities have been recently added in GIOVANNI to allow exploring and inter-comparing GPM IMERG (Integrated Multi-satelliE Retrievals for GPM) half-hourly and monthly precipitation products as well as other precipitation products such as TRMM, MERRA, NLDAS, GLDAS, etc. GIOVANNI is a web-based tool developed by the GES DISC, to visualize and analyze Earth science data without having to download data and software. During the GPM era, the GES DISC will continue to develop and provide data services for supporting applications. We will update and enhance existing TRMM applications (Current Conditions, the USDA Crop Explorer, etc.) with higher spatial resolution IMERG products. In this presentation, we will present GPM data products and services with examples.

GPM↗

Extratropical Cyclone Precipitation Life Cycles: A Satellite-Based Analysis

Although extratropical cyclones are the most common midlatitude storms, the relationship between their precipitation life cycle and dynamical strength life cycle has not been thoroughly analyzed. Given that thermodynamic heat exchanges associated with precipitation impact cyclone circulation, there is a need to understand the precipitation/dynamics relationship. Based on Integrated MultisatellitE Retrievals for Global Precipitation MeasurementGPM precipitation and Lagrangian cyclone tracks, the precipitation maximum occurs prior to the dynamical strength maximum 70% of the time. The lag in timing is consistent with the difference in cyclone precipitable water vapor at the two peaks. Conditional subsetting of the cyclone composites shows that if the precipitable water vapor distribution is constrained to be equal throughout the composite life cycle, the precipitation peak occurs very near the time of the peak in cyclone dynamical strength. Thus, the boost in dynamical strength caused by latent heat associated with precipitation manifest itself with little to no time lag.

Extratropical cyclone↗

The Changing Influence of Precipitation on Soil Moisture Drought With Warming in the Mediterranean and Western North America

Anthropogenic climate change has already affected drought severity and risk across many regions, and climate models project additional increases in drought risk with future warming. Historically, droughts are typically caused by periods of below-normal precipitation and terminated by average or above-normal precipitation. In many regions, however, soil moisture is projected to decrease primarily through warming-driven increases in evaporative demand, potentially affecting the ability of negative precipitation anomalies to cause drought and positive precipitation anomalies to terminate drought. Here, we use climate model simulations from Phase Six of the Coupled Model Intercomparison Project (CMIP6) to investigate how different levels of warming (1, 2, and 3°C) affect the influence of precipitation on soil moisture drought in the Mediterranean and Western North America regions. We demonstrate that the same monthly precipitation deficits (25th percentile relative to a preindustrial baseline) at a global warming level of 2°C increase the probability of both surface and rootzone soil moisture drought by 29% in the Mediterranean and 32% and 6% in Western North America compared to the preindustrial baseline. Furthermore, the probability of a dry (25th percentile relative to a preindustrial baseline) surface soil moisture month given a high (75th percentile relative to a preindustrial baseline) precipitation month is 6 (Mediterranean) and 3 (Western North America) times more likely in a 2°C world compared to the preindustrial baseline. For these regions, warming will likely increase the risk of soil moisture drought during low precipitation periods while simultaneously reducing the efficacy of high precipitation periods to terminate droughts.

drought↗

Determination of Interfacial Energy for Solid-State Precipitation

Precipitation of strengthening phases from solid state is a critical process for many materials. For example, the high-temperature creep resistance of Ni-based superalloys is governed by ’ precipitates. However, the interfacial energy which controls the precipitation is expensive to determine experimentally. For simulations, the atomic nature of precipitation events necessitates using Molecular Dynamics (MD) so relying on fitting to a-priori experimental behavior is not required. However, the solid-state precipitation takes orders of magnitude longer time than is accessible for traditional MD simulation. Taking inspiration from Kinetic Monte-Carlo (KMC) methods for simulating diffusion on a rigid lattice, we have developed a hybrid KMC-MD approach to enable simulation of solid-state precipitation (and determination of the interfacial energy). Implementing these methods in LAMMPS, we calculated the interfacial energy for the ’ precipitation out of a super-saturated  phase in Ni-based superalloys. The resulting interfacial energy value for the Ni-Al system is well within the accuracy of experimental values, demonstrating the capability of this method. Enabling the calculation of the interfacial energy without a-priori experimental knowledge of the precipitation unlocks a more efficient ICME-based approach for guiding annealing protocols in Ni-based superalloys and other solid-state precipitation systems.

Precipitation↗

Decreased Northern Hemisphere Precipitation from Consecutive CO 2 Doublings Is Associated with Significant AMOC Weakening

Previous studies found many climate properties such as northern hemisphere (NH) surface temperature and precipitation respond non-monotonically when CO2 is increased from 1× to 8×CO2 relative to pre-industrial levels. Here, we explore the robustness of the non-monotonicity in the NH precipitation response in 11 coupled climate models. Eight models show a decrease in NH precipitation under repeated CO2 doubling, indicating that the non-monotonic response is a common but not universal result. Although common, the critical CO2 level where the NH precipitation decrease first occurs differs widely across models, ranging from 2×CO2 to 8×CO2. These models also show a prominent weakening in the Atlantic meridional overturning circulation (AMOC) at the same critical CO2 level, with the AMOC weakening leading the precipitation decrease. The sensitivities of NH precipitation and the AMOC to CO2 doublings are positively correlated, especially when the AMOC weakens beyond 10 Sv. This suggests that the differences in models' AMOC response can explain their contrasting NH precipitation responses, where models with a large AMOC weakening have decreased NH precipitation. Regionally, this decrease in NH precipitation is the most prominent over the North Atlantic, Europe and the tropical Pacific. Our results suggest that special care must be taken with the use of pattern scaling to inform regional climate decision-making.

Atlantic meridional overturning circulation↗

Unveiling the nucleation and growth of Zr oxide precipitates in internally oxidized Nb3Sn superconductors

We report on atomic-scale analyses of nucleation and growth of Zr oxide precipitates and the microstructural evolution of internally oxidized Nb3Sn wires for high-field superconducting magnet applications, utilizing atom probe tomography (APT), transmission electron microscopy (TEM), and first-principles calculations. APT analyses reveal that oxygen and zirconium are already segregated at grain boundaries (GBs) in the unreacted Nb-1Zr-4Ta (at%) alloy prior to forming Nb3Sn through reacting the Nb alloy with Sn and SnO2. After forming Nb3Sn, Zr oxide precipitates nucleate both at the Nb3Sn/Nb heterophase interfaces and in the Nb3Sn grains, driven by the small solubilities of Zr and O in Nb3Sn compared to their value in Nb. A high number density (Nv) of Zr oxide nanoprecipitates is observed in the Nb3Sn layers, ∼10 23 m −3 , with a mean diameter <10 nm for a heat treatment at 625 °C. Quantitative APT and TEM analyses of the Zr oxide precipitates in the reacted Nb3Sn layers elucidate details of the nucleation, growth, and coarsening processes of the Zr oxide precipitates in Nb3Sn. First-principles calculations and classical nucleation theory are employed to study the nucleation of Zr oxide precipitates in Nb3Sn and to estimate the maximum energy barrier and critical radius for nucleation. Our research unveils the kinetic pathways for nucleation and growth of Zr oxide precipitates and the microstructural evolution of Nb3Sn layers, which helps to understand and improve the superconducting properties of internally oxidized Nb3Sn wires for use in high-field superconducting magnets. •We investigated the nucleation and growth of Zr oxide nanoprecipitates in Nb3Sn superconductors for magnet applications.•APT and TEM analyses reveals the nucleation and growth process of Zr oxide precipitates in Nb3Sn layers.•Classical nucleation theory with DFT is employed to describe the nucleation process of Zr oxide precipitates in Nb3Sn.•We find that the interfacial reactions at Nb/Nb3Sn interface play a critical role in the nucleation of Zr oxide precipitates.•Current study provides a pathway to improve the properties of internally oxidized Nb3Sn superconducting wires.

43 PARTICLE ACCELERATORS↗