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At least 163 records · Page 9

Effects of interlayer spacing and applied pressure on the lanthanide transport in MoS 2 -based two-dimensional channels

Rare-earth elements (REEs) are critical to modern industry but difficult to separate due to their subtle and monotonic changes in physicochemical properties. MoS 2 -based two-dimensional (2D) materials offer novel opportunities for enhancing REE separation, exhibiting a distinct volcano-shaped transport performance distribution that peaks at Sm 3+ . However, the specific contributions of thermodynamic and kinetic factors to ion transport within 2D confinement remain unclear. In this study, we conducted a series of non-equilibrium all-atom molecular dynamics (MD) simulations to explore the effects of interlayer spacing and external pressure on the transport of lanthanide ions in Å-scale acetate functionalized 2D MoS 2 (MoS 2 -COOH) channels. We examined ion entry and permeation rates, water flux, dehydration, and binding modes. The simulation results reveal that the transport trends of lanthanide ions are jointly driven by the dehydration degree and the relative-binding strengths of ions to water and to the acetate within the 2D channels. Notably, the dehydration pattern of lanthanide ions during permeation is closely linked to kinetic factors. Overall, this study provides a detailed atomistic understanding of the mechanisms underlying lanthanide ion transport under confinement. These findings point to the significant potential for tuning confinement and chemical functionalization within Å-scale channels for more efficient REE separation.

2D channels↗

Space simulation ultimate pressure lowered two decades by removal of diffusion pump oil contaminants during operation

The complex problem why large space simulation chambers do not realize the true ultimate vacuum was investigated. Some contaminating factors affecting diffusion pump performance have been identified and some advances in vacuum/distillation/fractionation technology have been achieved which resulted in a two decade or more lower ultimate pressure. Data are presented to show the overall or individual contaminating effect of commonly used phthalate ester plasticizers of 390 to 530 molecular weight on diffusion pump performance. Methods for removing contaminants from diffusion pump silicone oil during operation and reclaiming contaminated oil by high vacuum molecular distillation are described.

Buggele, A. E.↗

Space Station Freedom pressurized element interior design process

The process used to develop the on-orbit working and living environment of the Space Station Freedom has some very unique constraints and conditions to satisfy. The goal is to provide maximum efficiency and utilization of the available space, in on-orbit, zero G conditions that establishes a comfortable, productive, and safe working environment for the crew. The Space Station Freedom on-orbit living and working space can be divided into support for three major functions: (1) operations, maintenance, and management of the station; (2) conduct of experiments, both directly in the laboratories and remotely for experiments outside the pressurized environment; and (3) crew related functions for food preparation, housekeeping, storage, personal hygiene, health maintenance, zero G environment conditioning, and individual privacy, and rest. The process used to implement these functions, the major requirements driving the design, unique considerations and constraints that influence the design, and summaries of the analysis performed to establish the current configurations are described. Sketches and pictures showing the layout and internal arrangement of the Nodes, U.S. Laboratory and Habitation modules identify the current design relationships of the common and unique station housekeeping subsystems. The crew facilities, work stations, food preparation and eating areas (galley and wardroom), and exercise/health maintenance configurations, waste management and personal hygiene area configuration are shown. U.S. Laboratory experiment facilities and maintenance work areas planned to support the wide variety and mixtures of life science and materials processing payloads are described.

Hopson, George D.↗

Space Station Freedom pressurized element interior design process

The process used to develop the on-orbit working and living environment of the Space Station Freedom has some very unique constraints and conditions to satisfy. The goal is to provide maximum efficiency and utilization of the available space, in on-orbit, zero G conditions that establishes a comfortable, productive, and safe working environment for the crew. The Space Station Freedom on-orbit living and working space can be divided into support for three major functions: (1) operations, maintenance, and management of the station; (2) conduct of experiments, both directly in the laboratories and remotely for experiments outside the pressurized environment; and (3) crew related functions for food preparation, housekeeping, storage, personal hygiene, health maintenance, zero G environment conditioning, and individual privacy, and rest. The process used to implement these functions, the major requirements driving the design, unique considerations and constraints that influence the design, and summaries of the analysis performed to establish the current configurations are described. Sketches and pictures showing the layout and internal arrangement of the Nodes, U.S. Laboratory and Habitation modules identify the current design relationships of the common and unique station housekeeping subsystems. The crew facilities, work stations, food preparation and eating areas (galley and wardroom), and exercise/health maintenance configurations, waste management and personal hygiene area configuration are shown. U.S. Laboratory experiment facilities and maintenance work areas planned to support the wide variety and mixtures of life science and materials processing payloads are described.

Hopson, George D.↗

Development of higher operating pressure extravehicular space-suit glove assemblies

Longer space flights and the advent of extravehicular (EV) operations required drastic improvements in the areas of comfort and mobility, and the incorporation of an EV-hazards protective coverlayer. The current advanced glove designs represent a series of evolutionary engineering efforts aimed at systematically improving higher operating pressure EV glove performance capabilities. Glove design complexity increases with the differential pressure between the glove and the vacuum of space and with the EV activity mobility task requirements. Current space-suit glove design activities associated with the development of candidate higher operating pressure (57.2 kN/sq m) glove assemblies are described.

Kosmo, Joseph J.↗

Partial pressure analysis in space testing

For vacuum-system or test-article analysis it is often desirable to know the species and partial pressures of the vacuum gases. Residual gas or Partial Pressure Analyzers (PPA's) are commonly used for this purpose. These are mass spectrometer-type instruments, most commonly employing quadrupole filters. These instruments can be extremely useful, but they should be used with caution. Depending on the instrument design, calibration procedures, and conditions of use, measurements made with these instruments can be accurate to within a few percent, or in error by two or more orders of magnitude. Significant sources of error can include relative gas sensitivities that differ from handbook values by an order of magnitude, changes in sensitivity with pressure by as much as two orders of magnitude, changes in sensitivity with time after exposure to chemically active gases, and the dependence of the sensitivity for one gas on the pressures of other gases. However, for most instruments, these errors can be greatly reduced with proper operating procedures and conditions of use. In this paper, data are presented illustrating performance characteristics for different instruments and gases, operating parameters are recommended to minimize some errors, and calibrations procedures are described that can detect and/or correct other errors.

Tilford, Charles R.↗

Effects of Varying Surface Inclines and Suit Pressure: Implications on Space Suit Design

Suited human performance studies in reduced gravity environments to date include limited observations from Apollo Lunar surface Extravehicular Activities (EVA) and from previous studies conducted in partial gravity simulation environments. The Constellation Program EVA Systems Project office has initiated tests to develop design requirements for the next generation Lunar EVA suit. Theses studies were conducted in the Space Vehicle Mock-Up Facility (SVMF) at Johnson Space Center from which the results provided recommendations for suit weight, mass, center of gravity, pressure, and suit kinematic constraints that optimize human performance in partial gravity environments.

Clowers, Kurt↗

Tank Pressure Control Experiment on the Space Shuttle

The tank pressure control experiment is a demonstration of NASA intent to develop new technology for low-gravity management of the cryogenic fluids that will be required for future space systems. The experiment will use freon as the test fluid to measure the effects of jet-induced fluid mixing on storage tank pressure and will produce data on low-gravity mixing processes critical to the design of on-orbit cryogenic storage and resupply systems. Basic data on fluid motion and thermodynamics in low gravity is limited, but such data is critical to the development of space transfer vehicles and spacecraft resupply facilities. An in-space experiment is needed to obtain reliable data on fluid mixing and pressure control because none of the available microgravity test facilities provide a low enough gravity level for a sufficient duration to duplicate in-space flow patterns and thermal processes. Normal gravity tests do not represent the fluid behavior properly; drop-tower tests are limited in length of time available; aircraft low-gravity tests cannot provide the steady near-zero gravity level and long duration needed to study the subtle processes expected in space.

Source record↗

High pressure water electrolysis for space station EMU recharge

A high pressure oxygen recharge system (HPORS), is being developed for application on board the Space Station. This electrolytic system can provide oxygen at up to 6000 psia without a mechanical compressor. The Hamilton standard HPORS based on a solid polymer electrolyte system is an extension of the much larger and succesful 3000 psia system of the U.S. Navy. Cell modules have been successfully tested under conditions beyond which spacecraft may encounter during launch. The control system with double redundancy and mechanical backups for all electronically controlled components is designed to ensure a safe shutdown.

Lance, Nick↗

Sonic boom pressure signatures for the space shuttle launch vehicle

Sonic boom pressure signatures were measured in supersonic and hypersonic wind tunnels for models of the space shuttle launch vehicle at 0 deg angle of attack with and without solid body simulations of the exhaust plumes. Data were measured at 30 deg increments in roll angle from 90 deg to 180 deg at Mach numbers from 3.02 to 5.56.

Mendoza, J. P.↗

Simple Fabry-Perot based Instrument for Surface Pressure Sensing from Space

Mitchel and O'Brien observed in 1989 that a passive satellite measurement using the oxygen A band could exhibit a precision of better than 1% when used to make a surface pressure measurement. I will present a design and performance simulation for a Fabry-Perot interferometer based instrument which should exceed this level of performance. The design is small, inexpensive, and rugged. Preliminary results from a laboratory prototype of the instrument will be presented.

Heaps, William S.↗

Multiphase Transport in Porous Media: Gas-Liquid Separation Using Capillary Pressure Gradients International Space Station (ISS) Flight Experiment Development

Advances in the understanding of multiphase flow characteristics under variable gravity conditions will ultimately lead to improved and as of yet unknown process designs for advanced space missions. Such novel processes will be of paramount importance to the success of future manned space exploration as we venture into our solar system and beyond. In addition, because of the ubiquitous nature and vital importance of biological and environmental processes involving airwater mixtures, knowledge gained about fundamental interactions and the governing properties of these mixtures will clearly benefit the quality of life here on our home planet. The techniques addressed in the current research involving multiphase transport in porous media and gas-liquid phase separation using capillary pressure gradients are also a logical candidate for a future International Space Station (ISS) flight experiment. Importantly, the novel and potentially very accurate Lattice-Boltzmann (LB) modeling of multiphase transport in porous media developed in this work offers significantly improved predictions of real world fluid physics phenomena, thereby promoting advanced process designs for both space and terrestrial applications.This 3-year research effort has culminated in the design and testing of a zero-g demonstration prototype. Both the hydrophilic (glass) and hydrophobic (Teflon) media Capillary Pressure Gradient (CPG) cartridges prepared during the second years work were evaluated. Results obtained from ground testing at 1-g were compared to those obtained at reduced gravities spanning Martian (13-g), Lunar (16-g) and zero-g. These comparisons clearly demonstrate the relative strength of the CPG phenomena and the efficacy of its application to meet NASAs unique gas-liquid separation (GLS) requirements in non-terrestrial environments.LB modeling software, developed concurrently with the zero-g test effort, was shown to accurately reproduce observed CPG driven gas-liquid separation phenomena. The design and fabrication of a micropost plate-lamina Hele-Shaw (HS) cell was performed which served as a computationally attainable geometric structure facilitating direct comparison between physical phenomena observed in our laboratory and the LB software predictions.

Wheeler, Richard R., Jr.↗

Providing Pressurized Gasses to the International Space Station (ISS): Developing a Composite Overwrapped Pressure Vessel (COPV) for the Safe Transport of Oxygen and Nitrogen

To supply oxygen and nitrogen to the International Space Station, a COPV tank is being developed to meet requirements beyond that which have been flown. In order to "Ship Full' and support compatibility with a range of launch site operations, the vessel was designed for certification to International Standards (ISO) that have a different approach than current NASA certification approaches. These requirements were in addition to existing NASA certification standards had to be met. Initial risk-reduction development tests have been successful. Qualification is in progress.

Kezirian, Michael↗

Space shuttle: Static surface pressures of the 0.004 scale 049 orbiter in the launch configuration

Wing and lower body surface static pressure data for the space shuttle 049 orbiter while in the launch configuration were obtained. The purpose of the test was to determine the optimum incidence position of the orbiter relative to the hydrogen-oxygen (HO) tank and the optimum radial position of the solid rocket motors (SRM) on the HO tank. The orbiter was mounted on the HO tank at incidence angles of 0 and -1.5 degrees to determine the optimum incidence position. The SRM boosters were tested at radial positions of 75, 90, and 135 degrees on the HO tank to determine their optimum position with respect to the loads imposed on the orbiter. The test was conducted in the tunnel over a Mach number range of 0.6 to 4.96. Angle of attack was varied from -8 to +8 degrees at zero degree angle of sideslip, and at sideslip angles varying from -6 to +6 degrees at zero degree angle of attack.

Buchholz, R. E.↗

Optimization of the Pressurized Logistics Module - A Space Station Freedom analytical study

The analysis for determining the optimum cylindrical length of the Space Station Freedom (SSF) Pressurized Logistics Module, whose task is to transport the SSF pressurized cargo via the NSTS Shuttle Orbiter, is described. The major factors considered include the NSTS net launch lift capability, the pressurized cargo requirements, and the mass properties of the module structures, mechanisms, and subsystems.

Scallan, J. M.↗

Pressurized modules for Space Station Freedom

Crew workstations, storage, and facilities in the SSF Habitation module along with station housekeeping and supporting subsystems (power, thermal, and life support) are considered. The U.S. Laboratory and Habitation modules are based on a common structural design. The pressurized logistics modules (PLMs) have maximum commonality with the other pressurized modules including common ring frames and waffle grid skin; multilayer insulation and debris shield; and one common endcone.

Hopson, George D.↗

Unsteady Surface Pressures on the Space Launch System Block 1B Cargo Liftoff Configuration

A 1.75%-scale model of the NASA Space Launch System Block 1B Cargo vehicle was tested at the NASA Langley Research Center 14- by 22-Foot Subsonic Tunnel. These experiments provided a test bed for validating unsteady surface pressure measurements acquired via lengths of pressure tubing and an ESP pressure scanner. Pressure was measured using an azimuthal array of pressure taps located on the nose of the Block 1B Cargo vehicle. Unique flow physics were observed in the wind tunnel test, especially the interaction between the launch vehicle and the support tower, which produced strong oscillations that were absent in the vehicle-alone configuration. It is suspected that a wake interaction produced resonant flow response when the tower is immediately downstream of the vehicle, and coherent pressure fluctuations were observed at all pressure taps in the azimuthal array.

Lee J Mears↗