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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Chemical composition of HAL, an isotopically-unusual Allende inclusion

Samples of hibonite, black rim, and portions of friable rim from an unusual Allende inclusion, named HAL, were analyzed by INAA and RNAA for 37 major, minor, and trace elements. An unusually low amount of Ce was found in HAL, although it otherwise was highly enriched in REE compared to C1 chondrites. HAL is also depleted in Sr, Ba, U, V, Ru, Os, and Ir relative to other refractory elements. It is concluded that the distribution of REE between hibonite and rims was established when hibonite and other refractory minerals were removed at slightly different temperatures from a hot, oxidizing gas in which they previously coexisted as separate grains. Possible locations for the chemical and mass dependent isotopic fractionation are considered to be in ejecta from the low temperature helium-burning zone of a supernova and in the locally oxidizing environment generated by evaporation of interstellar grains of near-chondritic chemical composition.

Davis, A. M.↗
NASA NTRS1983

Al-Sm-Eu-Sr systematics of eucrites and moon rocks Implications for planetary bulk compositions

Constraints are placed on the bulk compositions of the eucrite parent body (EPB) and the moon through analysis of the Eu and Sr 'anomalies' of eucrites and lunar rooks. It is noted that the elements Al, REE, and Sr are incompatible with the major minerals of these small, low-f(O2) bodies,except for plagioclase. Predictions can be derived about the concentrations of Al, REE, and Sr in samples affected by plagioclase fractionation, based on the hypothesis that these elements in the EPB and moon are all in proportions close to those in the bulk solar system. It is determined that the predictions are almost idealy fulfilled by eucrites and lunar samples. For the EPB, the ratios REE/Al, Sr/Al, and Sr/REE are found to be constrained probably within 10 percent of the chondritic ratios. For the moon, the constraints are found to be less precise: REE/Al is very probably within 25 percent of chondritic; Sr/Al and Sr/REE are probably within 35 percent of chondritic; Sr/Al and Sr/REE are probably within 35 percent of chondritic. It is concluded that there is a very strong similarity between the bulk compositions of the planets and the compositions of chondritic meteorites.

Warren, P. H.↗
NASA NTRS1983

Continental crustal composition and lower crustal models

The composition of the upper crust is well established as being close to that of granodiorite. The upper crustal composition is reflected in the uniform REE abundances in shales which represent an homogenization of the various REE patterns. This composition can only persist to depths of 10-15 km, for heat flow and geochemical balance reasons. The composition of the total crust is model dependent. One constraint is that it should be capable of generating the upper granodioritic (S.L.) crust by partial melting within the crust. This composition is based on the andesite model, which assumes that the total crust has grown by accretion of island arc material. A representation of the growth rate of the continental crust is shown. The composition of the lower crust, which comprises 60-80% of the continental crust, remains a major unknown factor for models of terrestrial crustal evolution. Two approaches are used to model the lower crust.

Taylor, S. R.↗
NASA NTRS1983

Chemistry of the Apollo 11 highland component

Thirty-eight Apollo 11 lunar highland fragments from coarse fines 10085 have been subjected to petrologic and chemical study. Six major chemical groups are identified: (a) high-K KREEP; (b) anorthosite with a 10X chondrite positive Eu anomaly and anorthosite with 30X positive Eu anomaly; (c) ANT; (d) LKFM; (e) anorthositic gabbro with no Eu anomaly, with a positive Eu anomaly, and with a negative Eu anomaly; and (f) dominant Highland component, 2X-10X chondrite with a positive 10X-14X Eu anomaly. Newly recognized groups are presented based on the REE patterns: (a) ANT group with 5X La and a 22X positive Eu anomaly; (b) 10X flat with 14X positive Eu anomaly; and (c) 2-3X flat with a 10X positive Eu anomaly. The highland suite is very low in K and REE, and is overall quite similar to the Apollo 16 suite.

Laul, J. C.↗
NASA NTRS1984

Lu-Hf and Sm-Nd evolution in lunar mare basalts

Existing cumulate remelting models for mare basalt genesis are evaluated in light of Lu-Hf, Rb-Sr, Sm-Nd data and overall REE characteristics in order to determine the simplest model that can account for these data. A data base for comparing Lu-Hf evolution in the lunar mantle as inferred from Lu-Hf analyses of oceanic basalts is presented along with a preliminary comparison of Lu-Hf and Sm-Nd evolution betwee mare basalts and terrestrial oceanic basalts. It is found that Lu/Hf characteristics of mare basalts cannot be explained in terms of modal melting of cumulate sources formed from a magma ocean with chondritic Lu/Hf. The data are consistent with a model in which the cumulate sources formed from a light REE + HF-enriched magma ocean. Nonmodal melting of ilmenite in the sources is also required. The Lu-Hf data suggest that even the high-Ti basalt sources contained no more than about 3 percent ilmenite.

Unruh, D. M.↗
NASA NTRS1986

The Kolar Schist Belt: A possible Archaean suture zone

The Kolar Schist Belt represents a N-S trending discontinuity in the structures, lithologies, and emplacement and metamorphic ages of late Archean gneisses. The suggestion of a much older basement on the west side of the belt is not seen on the east. Within the schist belt amphibolites from each side have distinctly different chemical characteristics, suggesting different sources at similar mantle depths. These amphibolites were probably not part of a single volcanic sequence, but may have formed about the same time in two completely different settings. Could the amphibolites with depleted light REE patterns represent Archean ocean floor volcanics which are derived from a mantle source with a long term depletion of the light REE? Why are the amphibolites giving an age which may be older than the exposed gneisses immediately on either side of the belt? These results suggest that it is necessary to seriously consider whether the Kolar Schist Belt may be a suture between two late Archean continental terranes.

Hanson, G. N.↗
NASA NTRS1985

Chondrules in the Qingzhen type-3 enstatite chondrite Possible precursor components and comparison to ordinary chondrite chondrules

The mineral composition of chondrules from a fragment of Qingzhen (EH3) fall was analyzed by neutron activation method. Unlike the ordinary chondrite (OC) chondrules (Gooding and Keil, 1981), the Qingzhen radial pyroxene (RP) and porphyritic pyroxene (PP) chondrules have similar bulk compositions. Porphyritic olivine-pyroxene (POP) chondrules are richer than PP and RP chondrules in refractory lithophiles and siderophiles. Elements in each of the following sets intercorrelate significantly: (1) Fe-Co-Ni-Ir-Au, probably derived from a metal component; (2) Ca-Eu-Se, which suggests an oldhamite-rich precursor; (3) Al-Sc-Hf, occurring in high concentrations in POP chondrules, this set suggesting the existence of a refractory lithophile-rich and olivine-rich component; (4) Na REE; and (5) Cl-Br. Sets (2) and (4) were not precursors of OC. The interelement ratios of refractory lithophiles such as Ca, Al, Ti, Sc, and REE are similar to CI ratios, suggesting that they originated in the earliest phases as silicates, which were sulfurized before chondrule formation.

Grossman, J. N.↗
NASA NTRS1986

Chemical systematics of the Shergotty meteorite and the composition of its parent body (Mars)

Sixty elements in two bulk samples of Shergotty meteorite and 30 elements in various mineral separates of Shergotty were identified, using mainly INAA and RNAA techniques. In addition, elements leached out from powdered samples of Shergotty and EETA 79001 meteorites by 0.1 N HCl, as well as the elements of their residues, were analyzed. The results have indicated that Shergotty meteorite is homogeneous in its major element composition, but heterogeneous with respect to large-ion lithophile elements, such as K, Ba, Sr, Zr, Hf, Ta, Th, and rare-earth elements (REEs). It is even more heterogeneous with respect to volatile elements, such as Cd, Te, Tl, and Bi, and the siderophiles Au and Ag. The REE patterns of the Shergotty and EETA 79001 residues are identical, indicating that the parent magmas of both meteorites are compositionally similar. However, their leachate (phosphate) patterns are different, suggesting two components for the Shergotty, one of which is similar to the EETA 79001 leachate.

Laul, J. C.↗
NASA NTRS1987

Petrology and geochemistry of alkali gabbronorites from lunar breccia 67975

Detailed results of petrologic and compositional studies of three clasts found in thin sections of the Apollo 16 lunar breccia 67975 and of four clasts extracted from the breccia (for instrumental neutron activation analysis) prior to thin sectioning are reported. The alkali gabbronorites of the breccia form two distinct subgroups, magnesian and ferroan. The magnesian gabbronorites are composed of bytownitic plagioclase, hypersthene, augite, a silica mineral, and trace Ba-rich K-feldspar. The ferroan gabbronorites are composed of ternary plagioclase, pigeonite, augite, Ba-rich K-feldspar, and a silica mineral. Trace minerals in both subgroups are apatite, REE-rich whitlockite, and zircon. The magnesian and ferroan alkali gabbronorites appear to have formed by progressive differentiation of the same, or closely related, parent REE-rich magmas.

James, Odette B.↗
NASA NTRS1987

The trace element chemistry of CaS in enstatite chondrites and some implications regarding its origin

The trace element distribution in oldhamite (CaS) extracted from enstatite chondrites was determined by INAA. Prior to extraction, the petrologic setting of the grains was studied microscopically, and their minor element contents determined by microprobe analysis; samples that displayed a wide range of minor element contents were selected for detailed elementary analysis. Those samples of CaS suspected to be more primitive on the basis of their minor element and petrologic siting contain the entire inventory of the host meteorite's light REE (LREE) and Eu, plus 30-50 percent of the heavy-REE inventory. In less primitive samples, the LREE are less enriched although Eu remains highly concentrated. Several other elements, including lithophiles and chalcophiles, are most enriched in the most primitive CaS. It is suggested that oldhamite played a key role in the redistribution of these elements during the metamorphism and evolution of enstatite-rich material.

Larimer, John W.↗
NASA NTRS1988

Partitioning of rare earth elements between hibonite and melt and implications for nebular condensation of the rare earth elements

The effect of oxygen fugacity on the partitioning of REEs between hibonite and silicate melt is investigated in hibonite-growth experiments at 1470 C. The experimental procedures and apparatus are described, and the results are presented in extensive tables and graphs and characterized in detail. The absolute activity coefficients in hibonite are estimated as 330 for La, 1200 for Eu(3+), and 24,000 for Yb. It is inferred that ideal solution behavior cannot be assumed when calculating REE condensation temperatures for (Ca, Al)-rich inclusions in carbonaceous chondrites.

Drake, Michael J.↗
NASA NTRS1989

Metasomatic products of the lunar magma ocean - The role of KREEP dissemination

The 'urKREEP' hypothesis of Warren and Wasson (1979) is extended by defining KREEP in terms of specific (i.e., constrained) lunar components. It is shown that, the presilicate liquid immiscibility (pre-SLI) composition can be obtained by recombining experimental data on KREEP basalt components, or by calculating from liquid-liquid Kd's. Both calculated urKREEP compositions were lower in MgO and Al2O3 and higher in FeO and P2O5 than reported low- and high-K KREEP compositions. The calculated REE abundances were higher and the REE profiles were slightly more LREE-enriched than the previously reported KREEP compositions.

Neal, Clive R.↗
NASA NTRS1989

Chemistry and petrology of Apollo 17 highland coarse fines - Plutonic and melt rocks

A suite of 21 fragments from the Apollo 17 coarse-fines consists of ferroan anorthosites, anorthositic gabbros, granulitic and regolith breccias, and impact melts. These samples belong to known petrographic and chemical groups. Three ferroan anorthosites were found, including one which appears to be the lowest in REE (La = 0.60X) and probably the purest of the Apollo 17 anorthosites identified thus far. The ferroan suite is a more important component at the Apollo 17 site than previously recognized. The Apollo 17 melt rocks are similar to other samples with LKFM and low-K KREEP compositions and show less diversity in trace elements (REE) than the Apollo 15 melt rocks. Apollo 17 melt rocks consist of aphanitic and poikilitic types that show some compositional variability with identical Ni/Ir, suggesting that either two distinct melt sheets formed by similar projectiles, or compositional heterogeneity within one melt sheet is possible.

Laul, J. C.↗
NASA NTRS1989

The evolution of complex type B Allende inclusion - An ion microprobe trace element study

Results are presented of a detailed trace-element and isotopic analyses of the constituent phases in each of the major textural parts (mantle, core, and islands) of a Type B refractory inclusion, the USNM 5241 inclusion from Allende, first described by El Goresy et al. (1985). The REE data on 5241 were found to be largely consistent with a model in which the mantle and the core of 5241 formed sequentially out of a single melt by fractional crystallization. The numerical models of REE evolution in the 5241 melt, especially that of Eu, require that a significant mass of spinel-free island material was assimilated into the evolving melt during the last half of the solidification history of 5241. The trace element results pbtained thus strongly support the interpretation of El Goresy et al. (1985) that the spinel-free islands in the 5241 are trapped xenoliths.

Macpherson, Glenn J.↗
NASA NTRS1989

Development of the Rocket Extraction Escape System for the Space Shuttle

Six tests have been successfully conducted for a Space Shuttle Rocket Extraction Escape System (REES) for astronauts, using a modified Convair 240 aircraft with a simulated Shuttle Orbiter hatch. All escape trajectories are judged to have been able to clear the Orbiter by an acceptable margin, and the crew-extraction loads were found to be within accepted physiological tolerances. The REES concept can be applied to numerous other aircraft configurations for crew escape.

Langsmith, Owen↗
NASA NTRS1989

Is plagioclase removal responsible for the negative Eu anomaly in the source regions of mare basalts?

The nearly ubiquitous presence of a negative Eu anomaly in the mare basalts has been suggested to indicate prior separation and flotation of plagioclase from the basalt source region during its crystallization from a lunar magma ocean (LMO). Are there any mare basalts derived from a mantle source which did not experience prior plagioclase separation? Crystal chemical rationale for REE substitution in pyroxene suggests that the combination of REE size and charge, M2 site characteristics of pyroxene, fO2, magma chemistry, and temperature may account for the negative Eu anomaly in the source region of some types of primitive, low TiO2 mare basalts. This origin for the negative Eu anomaly does not preclude the possibility of the LMO as many mare basalts still require prior plagioclase crystallization and separation and/or hybridization involving a KREEP component.

Shearer, C. K.↗
NASA NTRS1989

Geochemistry of polymict ureilite EET83309, and a partially-disruptive impact model for ureilite origin

Bulk-compositional data for the EET83309 polymict ureilite were obtained using INAA and radiochemistry procedures and electron probe analysis. It was found that the EET83309 has a bulk composition indistinguishable from ordinary ('monomict') ureilites for all elements except light-middle REEs (which are present in much higher concentrations), suggesting that polymict ureilites are mixtures of ordinary ureilites which were mixed on a very small number of parent bodies. Despite the light-REE enrichments, polymict ureilites are nearly devoid of basaltic (Al-rich) material. It is suggested that the missing basalt may have been blown off the parent body by a partially disruptive collision with a large C-rich projectile. This impact model of ureilite origin reconciles many paradoxical aspects of ureilite composition.

Warren, Paul H.↗
NASA NTRS1991

Comparative xenology of two angrites

Results are presented on Xe analysis during stepwise heating of the angrite meteorite Lewis Cliff 86010 and the Angra dos Reis angrite. It is shown that both the Lewis Cliff and the Angra dos Reis angrites are poor in trapped Xe and are rich in fission Xe from Pu-244 and in spallation Xe produced by cosmic ray irradiation of Ba and the light REE, and that neither meteorite has an excess of Xe-129 derived from I-129. Both meteorites show significant variations in the composition of the spallation Xe attributable to the separation of the Ba and REE components. The Ba-related spallation in Lewis Cliff differs from that in Angra dos Reis primarily in a lower relative yield of the neutron-sensitive Xe-131 isotope, suggesting a lower neutron flux during cosmic ray exposure for the Lewis Cliff meteorite.

Hohenberg, Charles M.↗