Thermodynamic properties of interstitial elements in the refractory metals Semiannual report, 1 Dec. 1966 - 31 May 1967
Partial molar free energies, enthalpies, and entropies of carbon dissolved in solid molybdenum, tungsten, niobium, and tantalum
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Partial molar free energies, enthalpies, and entropies of carbon dissolved in solid molybdenum, tungsten, niobium, and tantalum
The Group VIA-Re binary systems are characterized by the presence of several intermediate phases. The u phase is present in all of the systems, but the a-Mn phases occur in only the Mo-Re and W-Re systems. The occurrence of these intermediate phases appears to be governed largely by electronic factors and is predictable on the basis of electron/atom ratio. The thermionic work functions of the intermediate phase materials were experimentally determined. function and the screening of the outermost electrons in the Group VIA metals was found. A correlation between the work As might be expected for purely metallic substances, the work functions were relatively high, in the range 4. 5 to 5. 0 eV, and in each case were bracketed by the work functions of the pure constituents. A discontinuous change in the average work function with composition is proposed, based on a thermodynamical treatment of the electron vapor.
Investigating interdiffusion of W-Ta, W-Mo, and W-Nb systems in refractory temperature range
The application of low-amplitude, high-frequency fatigue vibrations during creep testing of two strain-aging refractory alloys (molybdenum-base TZC and tantalum-base T-111) significantly reduced the creep strength of these materials. This strength reduction caused dramatic increases in both the first-stage creep strain and the second-stage creep rate. The magnitude of the creep rate acceleration varied directly with both frequency and A ratio (ratio of alternating to mean stress), and also varied with temperature, being greatest in the range where the strain-aging phenomenon was most prominent. It was concluded that the creep rate acceleration resulted from a negative strain rate sensitivity which is associated with the strain-aging phenomenon in these materials. (A negative rate sensitivity causes flow stress to decrease with increasing strain rate, instead of increasing as in normal materials.)
As NASA continues to expand its horizon, exploration and discovery creates the need of advancement in technology. The Jupiter Icy Moon Orbiter's (JIMO) mission to explore and document the outer surfaces, rate the possibility of holding potential life forms, etc. within the three moons (Callisto, Ganymede, and Europa) proves to be challenging. The orbiter itself consists of many sections including: the nuclear reactor and the power conversion system, the radiator panels, and the thrusters and antenna. The nuclear reactor serves as a power source, and if successfully developed, can operate for extended periods. During the duration of my tenure at NASA Glenn Research Center's (NASA GRC) Advanced Metallics Branch, I was assigned to assist Frank J. Ritzert on analyzing the feasibility of the Electron Beam Welded Hastelloy X (HX), a nickel-based superalloy, to Niobium- 1 %Zirconium (Nb-1 Zr) and other refractory metals/alloys including Tantalum, Molybdenum, Tungsten, and Rhenium alloys. This welding technique is going to be used for the nuclear reactor within JIMO.
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A combination gravity and manually powered rapid billet loader reduces the time required for transferring hot metal billets from a heating furnace to an extrusion press. Positioned between the furnace and extrusion press, this loader is a simple slide-delivery device.
Electron emission test of uranium carbide compatibility with tungsten alloys for nuclear fuel elements
Appropriate brazing metals and temperatures facilitate the welding or brazing of base metals with tungsten inert gas equipment. The highest quality bond is obtained when TIG welding is performed in an inert atmosphere.
Iridium as high temperature protective coating for unalloyed niobium and tantalum
Effects of hydrostatic pressure on mechanical properties of tungsten, tungsten-thorium alloys, and iron-carbon alloys
Electric resistivity measurements to determine solubility and diffusion of oxygen in tantalum, columbium, and alloys
Corrosion resistance of Nb and Ta tubing alloys to boiling K
Pressure dependence of tensile stress-strain behavior of recrystallized powder metallurgy tungsten at environmental pressures of 11 kilobars
Physical and mechanical properties of rhenium, technetium, hafnium, noble metals, and related alloys reviewed in terms of availability and costs