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The 1993 solar cell calibration balloon flight was completed on July 29, 1993. All objectives of the flight program were met. Forty modules were carried to an altitude of 120,000 ft (36.6 km). Data telemetered from the modules was corrected to 28 C and to 1 AU. The calibrated cells have been returned to 8 participants and can now be used as reference standards in simulator testing of cells and arrays.
A Computerized Ultrasonic Testing System (CUTS) was developed to measure, in real-time, the rate of deposition and thickness of chromium plated on the inside of thick steel tubes. The measurements are made from the outside of the tubes with the ultrasonic pulse-echo technique. The resolution of the system is 2.5 micron. (0.0001 in.) and the accuracy is better than 10 micron (0.0004 in.). The thickness is measured using six transducers mounted at different locations on the tube. In addition, two transducers are mounted on two reference standards, thereby allowing the system to be continuously calibrated. The tube temperature varies during the process, thus the input from eight thermocouples, located at the measurement sites, is used to calculate and compensate for the change in return time of the ultrasonic echo due to the temperature dependence of the sound velocity. CUTS is applicable to any commercial process where real-time change of thickness of a sample has to be known, with the advantage of facilitating increased efficiency and of improving process control.
An international comparison of Dobson ozone spectrophotometers, organized and partially funded by the World Meteorological Organization (WMO), was held at the Lichtklimatisches Observatorium (LKO) in Arosa, Switzerland, July-August 1990. Countries participating with a total of 18 Dobson instruments were Belgium, Czechoslovakia, Denmark, Germany, Greece, Hungary, Iceland, Norway, Poland, Portugal, Rumania, Spain, Switzerland, the United Kingdom, the United States, and the United Soviet Socialist Republics. The reference standard instrument for the comparison was U.S.A. Secondary Standard Dobson Spectrophotometer 65 maintained by the NOAA Climate and Monitoring and Diagnostics Laboratory, Boulder, Colorado. The mean difference in ozone obtained with the Dobson instruments relative to Dobson instrument 65, calculated from ADDSGQP observations in the air mass range 1.15-3.2, was minus 1.0 plus or minus 1.2 (1 sigma) percent. The WMO Standard Brewer Spectrometer 39 also participated. In the mean, the Brewer instrument measured 0.6 plus or minus 0.2 (1 sigma) percent more ozone than did Dobson instrument 65. Results are presented, also, of ozone vertical profile measurements made with the Dobson instruments, two Brewer spectrometers, a LIDAR, a balloon ozonesonde flown from Hohenpeissenberg, Germany, and balloon ozonesondes flown from Payerne, Switzerland.
The 1994 solar cell calibration balloon flight was completed on August 6, 1994. All objectives of the flight program were met. Thirty-seven modules were carried to an altitude of 119,000 ft (36.6 km). Data telemetered from the modules was corrected to 28 C and to 1 AU. The calibrated cells have been returned to the 6 participants and can now be used as reference standards in simulator testing of cells and arrays.
The Advanced Photovoltaic Experiment was designed to generate laboratory reference standards as well as to explore the durability of a wide variety of space solar cells. In addition to the cells, it was equipped with an absolute cavity radiometer to measure solar intensity, a spectroradiometer to measure the spectral content of this radiation and a sun angle sensor. Data from the solar cells and various sensors was obtained on a daily basis during the first eleven months of the 69 month flight. In this paper pre-flight and post-flight laboratory measurements are compared with on-orbit calibration data. Pre-flight and post-flight calibration data of the cavity radiometer as well as on-orbit data demonstrated the accuracy and durability of the Eppley instrument flown on APEX.
The Advanced Photovoltaic Experiment (APEX) was designed to generate laboratory reference standards as well as to explore the durability of a wide variety of space solar cells. In addition to the cells, it was equipped with an absolute cavity radiometer to measure solar intensity, a spectroradiometer to measure the spectral content of this radiation, and a sun angle sensor. Data from the solar cells and various sensors was obtained on a daily basis during the first eleven months of the 69 month flight. We compare pre-flight and post-flight laboratory measurements with on-orbit calibration data. Pre-flight and post-flight calibration data for the cavity radiometers as well as on-orbit data demonstrated the accuracy and durability of the Eppley Labs instrument flown on APEX.
An apparatus is provided for use in determining surface conductivity of a flat or shaped conductive material at microwave frequencies. A plate has an electrically conductive surface with first and second holes passing through the plate. An electrically conductive material under test (MUT) is maintained in a spaced apart relationship with the electrically conductive surface of the plate by one or more nonconductive spacers. A first coupling loop is electrically shielded within the first hole while a second coupling loop is electrically shielded within the second hole. A dielectric resonator element is positioned between the first and second coupling loops, while also being positioned closer to the MUT than the electrically conductive surface of the plate. Microwave energy at an operating frequency f is supplied from a signal source to the first coupling loop while microwave energy received at the second coupling loop is measured. The apparatus is capable of measuring the Q-factor of the dielectric resonator situated in the 'cavity' existing between the electrically conductive surface of the plate and the MUT. Surface conductivity of the electrically conductive surface can be determined via interpolation using: 1 ) the measured Q-factor with the electrically conductive surface in place, and 2) the measured Q-factor when the MUT is replaced with reference standards having known surface conductivities.
Rate constants of 15 OH reactions with halogen-substituted alkanes, C1 to C3, were studied using a relative rate technique in the temperature range 283-403 K. Compounds studied were CHF2Cl (22), CHF2Br (22B), CH3F (41), CH2F2 (32), CHF3 (23), CHClFCCl2F (122a), CHCl2CF3 (123), CHClFCF3 (124), CH3CF3 (143a), CH3CH2F (161), CF3CHFCF3 (227ea), CF3CH2CF3 (236fa), CF3CHFCHF2 (236ea), and CHF2CF2CH2F (245ca). Using CH4, CH3CCl3, CF3CF2H, and C2H6 as primary reference standards (JPL 92-20 rate constants), absolute rate constants are derived. Results are in good agreement with previous experimental results for six of the compounds studied, including CHF2Cl, CHF2Br, CH2F2, CH3CF3, CHFClCFCl2, and CF3CHFCF3. For the remainder the relative rate constants are lower than those derived from experiments in which OH loss was used to measure the reaction rate. Comparisons of the derived Arrhenius A factors with previous literature transition-state calculations show order of magnitude agreement in most cases. However, the experimental A factors show a much closer proportionality to the number of H atoms in the molecule than is evident from the transition state calculations. For most of the compounds studied, an A factor of (8 +/- 3)E-13 cm(exp 3)/(molecule s) per C-H bond is observed. A new measurement of the ratio k(CH3CCl3)/k(CH4) is reported that is in good agreement with previous data.
The 1996 solar cell calibration balloon flight campaign was completed with the first flight on June 30, 1996 and a second flight on August 8, 1996. All objectives of the flight program were met. Sixty-four modules were carried to an altitude of 120,000 ft (36.6 km). Full 1-5 curves were measured on 22 of these modules, and output at a fixed load was measured on 42 modules. This data was corrected to 28 C and to 1 AU (1.496 x 10(exp 8) km). The calibrated cells have been returned to the participants and can now be used as reference standards in simulator testing of cells and arrays.
The cumulative all-sky survey by the Compton Gamma Ray Observatory (CGRO), composed of data acquired during the first three years of the mission, included a number of regions of very limited exposure. The most glaring deficiency in coverage was toward the region of the South Galactic Pole (SGP), which received significantly less exposure than other directions- by a factor of at least 2 to 3. Furthermore, nearly all of the SGP exposure was accumulated during the first year of the mission. Since blazars are known to be time-variable, and of unknown duty cycle, a pointing of the CCRO in that direction was considered highly desirable, and long overdue. In addition, data gathered from a pointing toward the SGP and its comparison with comprehensive data available for the North Galactic Pole would be extremely valuable to investigators studying the extragalactic diffuse emission. The reasons outlined above prompted our initiation of a Cycle 4 campaign to systematically search with EGRET and COMPTEL for gamma-ray emission from sources near the South Galactic Pole. The Cycle 4 SGP campaign consisted of tnvo 14-day observations separated in in time by approximately 10 months. The temporal separation of the observations was requested to allow a test for possible variations in the detected sources. Our primary targets were 38 FSRQs which lie within 30 degrees of the SGP, and which satisfy the basic criteria for candidate gamma-ray AGNs,flat-spectrum radio sources, many of which exhibit blazar-type properties). These targets were selected from the standard references, and from the available on-line databases (e.g., the NASA Extragalactic Database, NED), as the most promising AGN targets in the vicinity of the SGP. A 30 radius from the SGP was chosen as the boundary of our survey, since the selected targets would then fall within the most sensitive portion of the fields of view of EGRET and COMPTEL (i.e., within a 30 zenith angle), for a CGRO pointing directed exactly at the SGP. Our South Galactic Pole Survey yielded a number of exciting results. The EGRET data were analyzed using the maximum likelihood techniques to estimate the intensity, spectrum, and position of gamma-ray sources in the field of view. Our analysis revealed four sources at energies greater than 100 MeV with likelihood ratios corresponding to greater than 30 detections (Vestrand et al. 1996). One of the sources is associated with the well known gamma-ray blazar PKS 0208-512, but the other three were previously unknown. Among the new detections was PKS 2155-304 which is often considered a prototype of the x-ray selected BL Lacs. PKS 2155-304, which was also detected at hard x-ray energies by CGRO/OSSE, is one of the brightest BL Lac objects in the sky at optical through x-ray energies and has a history of rapid, strong multiwavelength variability. As such, it has been the subject of intensive, contemporaneous, multiwavelength monitoring covering radio frequencies to x-ray energies.
The 1997 solar cell calibration balloon flight campaign consisted of three flights, the first flight on June 11, 1997, the second flight on August 2, 1997, and the third flight on August 24, 1997. One flight, flown on August 14, 1997, was terminated early because of a telemetry transmitter failure, and its payload was reflown on the August 24 flight. All objectives of the flight program were met. Ninety-eight modules were carried to an altitude of approximately 120,000 ft (36.6 km). Full I-V curves were measured on 32 of these modules, and output at a fixed load was measured on 66 modules. This data was corrected to 28 C and to 1 AU (1.496 x 10(exp 8) km). The calibrated cells have been returned to the participants and can now be used as reference standards in simulator testing of cells and arrays.
The 1998 solar cell calibration balloon flight campaign consisted of one flight, which occurred on August 15, 1998. All objectives of the flight program were met. Thirty-one modules were carried to an altitude of = 120,000 ft (36.6 km). Full I-V curves were measured on 4 of these modules, and output at a fixed load was measured on 27 modules. This data was corrected to 28 C and to 1 AU (1.496 x 10(exp 8) km). The calibrated cells have been returned to the participants and can now be used as reference standards in simulator testing of cells and arrays.
Chilled-mirror humidity sensor technology recently was adapted for use with the VIZ radiosonde. The principle of the chilled-mirror operation is to lower its temperature until dew forms on the mirror, at that point the dew point temperature is noted and the mirror is then heated to evaporate the moisture. The cycle is repeated. Research conducted from NASA's Wallops Flight Facility has provided comparisons between the chilled-mirror sensor and the carbon hygristor of VIZ, and the capacitive sensors of AIR Inc. and Vaisala Co. We believe the chilled-mirror sensor is accurate and would serve as a reference standard for evaluating operational radiosonde relative humidity sensors. Thus, differences seen in the comparisons are beginning to furnish insight into developing better humidity sensors. We discuss these comparison results as well as reproducibility results from a dual chilled-mirror measurement.
The Advanced Photovoltaic Experiment was designed to generate laboratory reference standards as well as to explore the durability of a wide variety of space solar cells. In addition to the cells, it was equipped with an absolute cavity radiometer to measure solar intensity, a spectroradiometer to measure the spectral content of this radiation and a sun angle sensor. Data from the solar cells and various sensors was obtained on a daily basis during the first eleven months of the 69 month flight. In this paper we compare pre-flight and post-flight laboratory measurements with on-orbit calibration data. Pre-flight and post-flight calibration data of the cavity radiometer as well as on-orbit data demonstrated the accuracy and durability of the Eppley Labs. instrument flown on APEX.
While it is recognized that no single snow algorithm is capable of producing accurate global estimates of snow depth, for research purposes it is useful to test an algorithm's performance in different climatic areas in order to see how it responds to a variety of snow conditions. This study is one of the first to develop separate passive microwave snow algorithms for North America and Eurasia by including parameters that consider the effects of variations in forest cover and crystal size on microwave brightness temperature. A new algorithm (GSFC 1996) is compared to a prototype algorithm (Chang et al., 1987) and to a snow depth climatology (SDC), which for this study is considered to be a standard reference or baseline. It is shown that the GSFC 1996 algorithm compares much more favorably to the SDC than does the Chang et al. (1987) algorithm. For example, in North America in February there is a 15% difference between the GSFC 198-96 Algorithm and the SDC, but with the Chang et al. (1987) algorithm the difference is greater than 50%. In Eurasia, also in February, there is only a 1.3% difference between the GSFC 1996 algorithm and the SDC, whereas with the Chang et al. (1987) algorithm the difference is about 20%. As expected, differences tend to be less when the snow cover extent is greater, particularly for Eurasia. The GSFC 1996 algorithm performs better in North America in each month than dose the Chang et al. (1987) algorithm. This is also the case in Eurasia, except in April and May when the Chang et al.(1987) algorithms is in closer accord to the SDC than is GSFC 1996 algorithm.
The 1999 solar cell calibration balloon flight campaign consisted of two flights, which occurred on June 14, 1999, and July 6, 1999. All objectives of the flight program were met. Fifty-seven modules were carried to an altitude of approximately equal to 120,000 ft (36.6 km). Full I-V curves were measured on five of these modules, and output at a fixed load was measured on forty-three modules (forty-five cells), with some modules repeated on the second flight. This data was corrected to 28 C and to 1 AU (1.496 x 10 (exp 8) km). The calibrated cells have been returned to their owners and can now be used as reference standards in simulator testing of cells and arrays.
In the past few years, the National Institute for Standards and Technology (NIST) has been promoting the idea of quantitatively determining the additives in smokeless gunpowder using micellar capillary electrophoresis as a means of investigating the criminal use of hand guns and pipe bombs. As a part of this effort, we have evaluated both supercritical fluid and ultrasonic solvent extractions for the quantitative recovery of nitroglycerin (NG), diphenylamine (DPA), N-nitrosodiphenylamine (NnDPA), and ethyl centralite (EC) from gunpowder. Recoveries were evaluated by repeat extraction and matrix spiking experiments. The final extraction protocol provides greater than 95 percent recoveries. To help other researches validate their own analytical method for additive determinations, NIST is exploring the development of a standard reference material, Additives in Smokeless Gunpowder. The evaluated method is being applied to two double-base (NG-containing) powders, one stabilized with diphenylamine and the other with ethyl centralite. As part of this reference material development effort, we are conducting an interlaboratory comparison exercise among the forensic and military gunpowder measurement community.
The 2000 solar cell calibration balloon flight campaign consisted of two flights, which occurred on June 27, 2000, and July 5, 2000. All objectives of the flight program were met. Sixty-two modules were carried to an altitude of approximately 120,000 ft (36.6 km). Full I-V curves were measured on sixteen of these modules, and output at a fixed load was measured on thirty-seven modules (forty-six cells), with some modules repeated on the second flight. Nine modules were flown for temperature measurement only. This data was corrected to 28 C and to 1 AU (1.496x10(exp 8) km). The calibrated cells have been returned to their owners and can now be used as reference standards in simulator testing of cells and arrays.