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At least 163 records · Page 9

Messengers from the Early Solar System - Comets as Carriers of Cosmic Information

Viewed from a cosmic perspective, Earth is a dry planet yet its oceans are enriched in deuterium by a large factor relative to nebular hydrogen. Can comets have delivered Earth s water? The question of exogenous delivery of water and organics to Earth and other young planets is of critical importance for understanding the origin of Earth s water, and for assessing the possible existence of exo-planets similar to Earth. Strong gradients in temperature and chemistry in the proto-planetary disk, coupled with dynamical models, imply that comets from the Oort Cloud and Kuiper Disk reservoirs should have diverse composition. The primary volatiles in comets (ices native to the nucleus) provide the preferred metric, and taxonomies based on them are now beginning to emerge [1, 2, 3]. The measurement of cosmic parameters such as the nuclear spin temperatures for H2O, NH3, and CH4, and of enrichment factors for isotopologues (D/H in water and hydrogen cyanide, N-14/N-15 in CN and hydrogen cyanide) provide additional important tests for the origin of cometary material.

Mumma, Michael J.↗

Messengers from the Early Solar System - The Similarity and Diversity of Comets

Viewed from a cosmic perspective, Earth is a dry planet yet its oceans are enriched in deuterium by a large factor relative to nebular hydrogen. Can comets have delivered Earth's water? The question of exogenous delivery of water and organics to Earth and other young planets is of critical importance for understanding the origin of Earth's water, and for assessing the possible existence of exo-planets similar to Earth. Strong gradients in temperature and chemistry in the proto-planetary disk, coupled with dynamical models, imply that comets from the Oort Cloud and Kuiper Disk reservoirs should have diverse composition. The primary volatiles in comets (ices native to the nucleus) provide the preferred metric, and taxonomies based on them are now beginning to emerge [1,2,3]. The measurement of cosmic parameters such as the nuclear spin temperatures for H2O, NH3, and CH4, and of enrichment factors for isotopologues (D/H in water and hydrogen cyanide, N-14/N-15 in CN and hydrogen cyanide provide additional important tests for the origin of cometary material. I will provide an overview of these aspects, and their implications for the origin of Earth's water and prebiotic organics.

Mumma, Michael J.↗

Sodium Variable Conductance Heat Pipe for Radioisotope Stirling Systems

In a Stirling radioisotope system, heat must continually be removed from the General Purpose Heat Source (GPHS) modules to maintain the modules and surrounding insulation at acceptable temperatures. Normally, the Stirling convertor provides this cooling. If the converter stops in the current system, the insulation is designed to spoil, preventing damage to the GPHS, and also ending the mission. An alkali-metal Variable Conductance Heat Pipe (VCHP) has been designed to allow multiple stops and restarts of the Stirling convertor in an Advanced Stirling Radioisotope Generator (ASRG). When the Stirling convertor is turned off, the VCHP will activate when the temperatures rises 30 C above the setpoint temperature. A prototype VCHP with sodium as the working fluid was fabricated and tested in both gravity aided and against gravity conditions for a nominal heater head temperature of 790 C. The results show very good agreement with the predictions and validate the model. The gas front was located at the exit of the reservoir when heater head temperature was 790 C while cooling was ON, simulating an operating Advanced Stirling Converter (ASC). When cooling stopped, the temperature increased by 30 C, allowing the gas front to move past the radiator, which transferred the heat to the case. After resuming the cooling flow, the front returned at the initial location turning OFF the VCHP. The against gravity working conditions showed a colder reservoir and faster transients.

Tarau, Calin↗

Evaluating LSM-Based Water Budgets Over a West African Basin Assisted with a River Routing Scheme

Within the framework of the African Monsoon Multidisciplinary Analysis (AMMA) Land Surface Model Intercomparison Project phase 2 (ALMIP-2), this study evaluates the water balance simulated by the Interactions between Soil, Biosphere, and Atmosphere (ISBA) over the upper Oum River basin, in Benin, using a mesoscale river routing scheme (RRS). The RRS is based on the nonlinear Muskingum Cunge method coupled with two linear reservoirs that simulate the time delay of both surface runoff and base flow that are produced by land surface models. On the basis of the evidence of a deep water-table recharge in that region,a reservoir representing the deep-water infiltration (DWI) is introduced. The hydrological processes of the basin are simulated for the 2005-08 AMMA field campaign period during which rainfall and stream flow data were intensively collected over the study area. Optimal RRS parameter sets were determined for three optimization experiments that were performed using daily stream flow at five gauges within the basin. Results demonstrate that the RRS simulates stream flow at all gauges with relative errors varying from -22% to 3% and Nash-Sutcliffe coefficients varying from 0.62 to 0.90. DWI varies from 24% to 67% of the base flow as a function of the sub-basin. The relatively simple reservoir DWI approach is quite robust, and further improvements would likely necessitate more complex solutions (e.g., considering seasonality and soil type in ISBA); thus, such modifications are recommended for future studies. Although the evaluation shows that the simulated stream flows are generally satisfactory, further field investigations are necessary to confirm some of the model assumptions.

Multidisciplinary↗

The Geologic History of Mars: An Astrobiology Perspective

Fourteen SNC meteorites contain information which must be incorporated with recent spaceflight data for developing Mars' geologic history. SNCs have crystallization ages of 4500 to 160 m.y. Tle oldest meteorite ALH84001 contains information on the Noachian period of Mars' history. There are no meteorites from the Hesperian period and the remaining 13 meteorites fall into two age groups within the Amazonian: The nakhlites around 1300 m.y. and the shergottites between 800-160 m.y. Oxygen isotopic analysis of Martian samples shows two distinct O2 reservoirs throughout Martian history indicating late additions of volatiles and a lack of plate tectonics prior to 3.9 Gy. Evidence for percolation of aqueous brines through impact-produced fractures in the rocky surface is contained in the 3.9 Gy-old ALH84001 carbonate deposits. These carbonates precipitated at approx. 100 C. At this time life had already evolved on Earth. Early Mars could have hosted life similar to the bacteria that inhabited early Earth. Potential microorganisms could have been transported into fractures by carbonate-bearing waters and their remains could have become incorporated into the precipitated carbonate. Since Mars had a weak magnetic field at this time, it can be hypothesized that some of the Martian microorganisms may have been similar to terrestrial magnetotactic bacteria. Over geologic time episodic cratering, and tectonic events have occurred on Mars along with the periodic release of subsurface waters which may have produced clays within SNC meteorites. The geochemical data contained within SNC meteorites complements previous observational data and the recent Mars Global Surveyor data to provide a geological and environmental history which spans almost the entire lifespan on Mars. One of the outstanding features of this model is the possible creation of an early (about 4 Gy) volatile reservoir distinct from the outgassed Mars volatiles, and the persistence of this reservoir throughout most, if not all of subsequent Mars' history. Within the framework of this history a potential scenario for a possible record of living organisms is provided by suggestive structures and organic signatures trapped within secondary mineral deposits and alteration features of some SNC meteorites. Tracing the differences in oxygen isotopic compositions within Martian components allows us to gain insight in the history of Mars.

Gibson, Everett K.↗

GC51D-0831: A Study of the Impact of Dams on Sediment Retention in the Mekong River Basin

Dam construction in the Mekong Basin has many cascading effects on the ecology, economy, and hydrology of the surrounding region. The focus of this study is to utilize the Soil Water Assessment Tool (SWAT), developed at Texas A & M, a rainfall-runoff hydrologic model to determine change in sedimentation in the Mekong Basin after the construction of dams. This study uses land cover land use and reservoir datasets created by the NASA SERVIR-Mekong Regional Land Cover Monitoring System and Dam Inundation Mapping Tool as inputs into the model. The study also builds on the capabilities of the SWAT model by using the sediment trapping efficiency (STE) equation from Brune (1953), rewritten by Kummu & Varis (2007), to calculate STE of dams and estimate change in sediment concentration downstream. The outputs from this study can be used to inform dam operation policies, study the correlation between dams and delta subsidence, and study the impact of dams on river fisheries, which are all pressing issues in the Mekong region.

Earth scienc↗

Unprecedented Drought Challenges for Texas Water Resources in a Changing Climate: What Do Researchers and Stakeholders Need to Know?

Long‐range water planning is complicated by factors that are rapidly changing in the 21st century, including climate, population, and water use. Here, we analyze climate factors and drought projections for Texas as an example of a diverse society straddling an aridity gradient to examine how the projections can best serve water stakeholder needs. We find that climate models are robust in projecting drying of summer‐season soil moisture and decreasing reservoir supplies for both the eastern and western portions of Texas during the 21st century. Further, projections indicate drier conditions during the latter half of the 21st century than even the most arid centuries of the last 1,000 years that included megadroughts. To illustrate how accounting for drought non‐stationarity may increase water resiliency, we consider generalized case studies involving four key stakeholder groups: agricultural producers, large surface water suppliers, small groundwater management districts, and regional water planning districts. We also examine an example of customized climate information being used as input to long‐range water planning. We find that while stakeholders value the quantitative capability of climate model outputs, more specific climate‐related information better supports resilience planning across multiple stakeholder groups. New suites of tools could provide necessary capacity for both short and long‐term, stakeholder‐specific adaptive planning.

drought↗

A Sublimation Model for the Martian Polar Swiss-Cheese Features. Observational and Modeling Studies of the South Polar Residual Cap

In their pioneering work Leighton and Murray argued that the Mars atmosphere, which is 95 percent CO2 today, is controlled by vapor equilibrium with a much larger polar reservoir of solid CO2. Here we argue that the polar reservoir is small and cannot function as a long-term buffer to the more massive atmosphere. Our work is based on modeling the circular depressions (Swiss-cheese features) in the south polar cap. We argue that a solid CO2 layer approximately 8 meters thick is being etched away to reveal water ice underneath. Preliminary results from the THEMIS (Thermal Emission Imaging System) instrument seem to confirm our model.

Byrne, Shane↗

Diurnal Forcing of Planetary Atmospheres

Much progress has been made on calculations of the Martian seasonal water cycle using the Mars Climate Model developed for this purpose. Two papers, documenting the model and the water transport results obtained with it have been published in the Journal of Geophysical Research - Planets. An additional paper describing results related to the evolution of the seasonal water cycle as a result of orbital changes was published in Advances in Space Research. Since that time, further studies have concentrated on the consequences of the soil adsorption required to match the observed water cycle and its relation to the stability of ground ice and other potential water reservoirs. Earth-related studies have concentrated on incorporating an efficient and realistic microphysical model into the Ames Stratospheric General Circulation Model used to simulate the spread of the ML Pinatubo and other volcanic clouds in the stratosphere. In addition, visualizations of the simulations are being incorporated into a video describing the UARS mission. A paper describing the new stratospheric aerosol microphysics package (and its consequences for volcanic cloud evolution) will be submitted in the near future. The paper will discuss the relative importance of condensation and coagulation to early particle growth and the separation of the cloud by sedimentation of the larger particles. A more general paper which highlights the observation that particle number densities did not increase dramatically after the ML Pinatubo eruption is planned. Simulations of atmospheric transport will be extended to include studies of terrestrial tropospheric tracers using the Fifth-Generation Penn State/NCAR Mesoscale Model.

Houben, Howard C.↗

Thermoelectrically cooled cloud physics expansion chamber

The design and fabrication of a thermoelectric chiller for use in chilling a liquid reservoir is described. Acceptance test results establish the accuracy of the thermal model and predict the unit performance under various conditions required by the overall spacelab program.

Buist, R. J.↗

Laboratory studies on the reactions between chlorine, sulfur dioxide, and oxygen - Implications for the Venus stratosphere

Fourier transform IR spectrophotometry is used to monitor the reactants and products in a Venus stratosphere simulation study involving the photolysis of mixtures of Cl2 and SO2, with and without O2 present in an atmosphere of N2. When several speculative reactions inferred from these experiments are incorporated by the Yung and DeMore (1982) model of Venus stratospheric chemistry, it emerges that SO2Cl2 is a key reservoir species for chlorine, and that the reaction between Cl and SO2 furnishes an important cycle for the destruction of O2 and the conversion of SO2 to H2SO4, thereby providing a possible solution to the photochemistry of the Venus stratosphere.

Demore, W. B.↗

Comet C2012 S1 (ISON)s Carbon-rich and Micron-size-dominated Coma Dust

Comet C/2012 S1 (ISON) was unique in that it was a dynamically new comet derived from the Nearly Isotropic Oort cloud reservoir of comets with a sun-grazing orbit. We present thermal models for comet ISON (rh approx.1.15 AU, 2013-Oct-25 11:30 UT) that reveal comet ISON's dust was carbon-rich and dominated by a narrow size distribution dominated by approx. micron-sized grains. We constrained the models by our SOFIA FORCAST photometry at 11.1, 19.7 and 31.5 microns and by a silicate feature strength of approx.1.1 and an 8-13microns continuum greybody color temperature of approx. 275-280 K (using Tbb ∝ r−0.5 h and Tbb approx. 260-265 K from Subaru COMICS, 2013-Oct-19 UT)[1,2]. N-band spectra of comet ISON with the BASS instrument on the NASA IRTF (2013-Nov-11-12 UT) show a silicate feature strength of approx. 1.1 and an 11.2microns forsterite peak.[3] Our thermal models yield constraints the dust composition as well as grain size distribution parameters: slope, peak grain size, porosity. Specifically, ISON's dust has a low silicate-to- amorphous carbon ratio (approx. 1:9), and the coma size distribution has a steep slope (N4.5) such that the coma is dominated by micron-sized, moderately porous, carbon-rich dust grains. The N-band continuum color temperature implies submicronto micron-size grains and the steep fall off of the SOFIA far-IR photometry requires the size distribution to have fewer relative numbers of larger and cooler grains compared to smaller and hotter grains. A proxy for the dust production rate is fρ approx.1500 cm, akin to Afρ. ISON has a moderate-to-low dust-to-gas ratio. Comet ISON's dust grain size distribution does not appear similar to the few well-studied long-period Nearly Isotropic Comets (NICs), namely C/1995 O1 (Hale-Bopp) and C/2001 Q4 (NEAT) that had smaller and/or more highly porous grains and larger sizes, or C/2007 N4 (Lulin) and C/2006 P1 (McNaught) that had large and/or compact grains. Radial transport to comet-forming disk distances (≥ 20 AU) is easier for smaller grains (≤1 micron) than for larger grains (approx. 20 microns like Stardust terminal particles). The presence of predominantly micron-sized and smaller grains suggests comet ISON may have formed either earlier in disk evolution whereby larger grains did not have the time to be transported to distances beyond Neptune, or the comet formed so far out in the disk that larger grains did not traverse such large radial distances. The high carbon-content of ISON's refractory dust appears to be complimented by the presence of limitedlifetime organic (CHON-like) grain materials: preliminary analyses of near-IR and high-resolution optical spectra indicate that gas-phase daughter molecules C2, CN, and CH were more abundant than their parent molecules (C2H2, C2H6, measured in the near- IR). Dust composition as well as grain size distribution parameters (slope, peak grain size, and porosity) give clues to comet origins.

NASA/DLR Stratospheric Observatory↗

Fluorescence Excitation Models of Ammonia and Amidogen Radical (NH2) in Comets: Application to Comet C/2004 Q2 (Machholz)

Ammonia is a major reservoir of nitrogen atoms in cometary materials. However, detections of ammonia in comets are rare, with several achieved at radio wavelengths. A few more detections were obtained through near-infrared observations (around the 3 m wavelength region), but moderate relative velocity shifts are required to separate emission lines of cometary ammonia from telluric absorption lines in the 3 micron wavelength region. On the other hand, the amidogen radical (NH2 -- a photodissociation product of ammonia in the coma) also shows rovibrational emission lines in the 3 micron wavelength region. Thus, gas production rates for ammonia can be determined from the rovibrational emission lines of ammonia (directly) and amidogen radical (indirectly) simultaneously in the near-infrared. In this article, we present new fluorescence excitation models for cometary ammonia and amidogen radical in the near-infrared, and we apply these models to the near-infrared high-dispersion spectra of comet C/2004 Q2 (Machholz) to determine the mixing ratio of ammonia to water in the comet. Based on direct detection of NH3 lines, the mixing ratio of NH3/H2O is 0.46% +/- 0.03% in C/2004 Q2 (Machholz), in agreement with other results. The mixing ratio of ammonia determined from the NH2 observations (0.31% -- 0.79%) is consistent but has relatively larger error, owing to uncertainty in the photodissociation rates of ammonia. At the present level of accuracy, we confirm that NH3 could be the sole parent of NH2 in this comet.

Kawakita, Hideyo↗

Mars atmospheric D/H - Consistent with polar volatile theory?

Current theories on the Martian water history are discussed on the basis of data for the D/H ratio in the Martian atmosphere (which was found to be enhanced by a factor of 6 + or - relative to the value on earth). In particular, the calculations of Yung et al. (1988), on the basis of their photochemical model, are found to be inconsistent with current theories for the evolution of the polar deposits on Mars. While the photochemical model predicts that about 95 percent of the Martian water has escaped over geologic time and the nonatmospheric reservoir is now only 02 m thick, the polar volatile theory suggest that polar deposits contain the equivalent of tens of meters of water, requiring a more rapid escape of H and D to space than predicted by the photochemical model to match the observed D/H ratio. The paper examines the behavior of the polar caps and the atmospheric water vapor over geologic time and the loss of H and D to space. It is concluded that, at present, it is premature to accept a specific history for water on Mars.

Jakosky, Bruce M.↗

On the effects of the ocean on atmospheric CFC-11 lifetimes and emissions

The ocean is a reservoir for CFC-11, a major ozone-depleting chemical. Anthropogenic production of CFC-11 dramatically decreased in the 1990s under the Montreal Protocol, which stipulated a global phase out of production by 2010. However, studies raise questions about current overall emission levels and indicate unexpected increases of CFC-11 emissions of about 10 Gg/yr after 2013 (based upon measured atmospheric concentrations and an assumed atmospheric lifetime). These findings heighten the need to understand processes that could affect the CFC-11 lifetime, including ocean fluxes. We evaluate how ocean uptake and release through 2300 affects CFC-11 lifetimes, emission estimates, and the long-term return of CFC-11 from the ocean reservoir. We show that ocean uptake yields a shorter total lifetime and larger inferred emission of atmospheric CFC-11 from 1930 to 2075 compared to estimates using only atmospheric processes. Ocean flux changes over time result in small but not completely negligible effects on the calculated unexpected emissions change (decreasing it by 0.4 ± 0.3 Gg/yr). Moreover, it is expected that the ocean will eventually become a source of CFC-11, increasing its total lifetime thereafter. Ocean outgassing should produce detectable increases in global atmospheric CFC-11 abundances by the mid-2100s, with emission of around 0.5 Gg/yr; this should not be confused with illicit production at that time. An illustrative model projection suggests that climate change is expected to make the ocean a weaker reservoir for CFC-11, advancing the detectable change in the global atmospheric mixing ratio by about 5 yr.

Anthropogenic production of CFC-11↗

Differential Muon Tomography to Continuously Monitor Changes in the Composition of Subsurface Fluids

Muon tomography has been used to seek hidden chambers in Egyptian pyramids and image subsurface features in volcanoes. It seemed likely that it could be used to image injected, supercritical carbon dioxide as it is emplaced in porous geological structures being used for carbon sequestration, and also to check on subsequent leakage. It should work equally well in any other application where there are two fluids of different densities, such as water and oil, or carbon dioxide and heavy oil in oil reservoirs. Continuous monitoring of movement of oil and/or flood fluid during enhanced oil recovery activities for managing injection is important for economic reasons. Checking on leakage for geological carbon storage is essential both for safety and for economic purposes. Current technology (for example, repeat 3D seismic surveys) is expensive and episodic. Muons are generated by high- energy cosmic rays resulting from supernova explosions, and interact with gas molecules in the atmosphere. This innovation has produced a theoretical model of muon attenuation in the thickness of rock above and within a typical sandstone reservoir at a depth of between 1.00 and 1.25 km. Because this first simulation was focused on carbon sequestration, the innovators chose depths sufficient for the pressure there to ensure that the carbon dioxide would be supercritical. This innovation demonstrates for the first time the feasibility of using the natural cosmic-ray muon flux to generate continuous tomographic images of carbon dioxide in a storage site. The muon flux is attenuated to an extent dependent on, amongst other things, the density of the materials through which it passes. The density of supercritical carbon dioxide is only three quarters that of the brine in the reservoir that it displaces. The first realistic simulations indicate that changes as small as 0.4% in the storage site bulk density could be detected (equivalent to 7% of the porosity, in this specific case). The initial muon flux is effectively constant at the surface of the Earth. Sensitivity of the method would be decreased with increasing depth. However, sensitivity can be improved by emplacing a greater array of particle detectors at the base of the reservoir.

Coleman, Max↗

Simulation of the transport of halogen species from the equatorial and mid-latitude stratosphere to the polar stratosphere in a two-dimensional model

The bulk of O sub 3 destruction in the Antarctic stratosphere takes place in the lower stratosphere between 15 and 25 km. Both O sub 3 and the halogen reservoir species have their origins in the higher altitude region (20 to 30 km) in the equatorial and mid-latitude stratosphere. Using the Caltech-JPL two-dimensional residual circulation model, researchers investigate the growth of stratospheric halogen due to the increase of CFCl sub 3 and CF sub 2 Cl sub 2.

Yung, Yuk L.↗

Lunar volcanic glasses and their constraints on mare petrogenesis

The compositional properties of volcanic glasses from the Apollo 11, 14, 15 and 16 landing sites are examined and implications of the results for mare basalt petrogenesis and deep lunar structures are discussed. Major-element and nickel analyses were performed on the glasses using electron probe techniques, and R-mode principal component analysis was performed on the 19 different compositions of glass distinguished. The glasses are found to form two distinct chemical arrays based on the major elements and Ni. The presence of two chemically isolated cumulate systems in the mantle at different depths is thus inferred, and a model is developed for mare petrogenesis in which each system was itself composed of two lithologic components that underwent hybridization, assimilation or mixing to generate the large compositional range of magmas represented by the lunar volcanic glasses. The surface-correlated elements associated with the volcanic glasses are attributed to another reservoir in the deep interior which may be responsible for gas emissions causing lunar transient phenomena. The model developed allows predictions to be made concerning the liquidus phase relations, trace and radiogenic element distributions, nonradiogenic isotope compositions and sample ages.

Delano, J. W.↗