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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Synergistic Integration of Chemo-Resistive and SERS Sensing for Label-Free Multiplex Gas Detection

Practical sensing applications such as real-time safety alerts and clinical diagnoses require sensor devices to differentiate between various target molecules with high sensitivity and selectivity, yet conventional devices such as oxide-based chemo-resistive sensors and metal-based surface-enhanced Raman spectroscopy (SERS) sensors usually do not satisfy such requirements. In this report a label-free, chemo-resistive/SERS multimodal sensor based on a systematically assembled 3D cross-point multifunctional nanoarchitecture (3D-CMA), which has unusually strong enhancements in both “chemo-resistive” and “SERS” sensing characteristics is introduced. 3D-CMA combines several sensing mechanisms and sensing elements via 3D integration of semiconducting SnO 2 nanowire frameworks and dual-functioning Au metallic nanoparticles. It is shown that the multimodal sensor can successfully estimate mixed-gas compositions selectively and quantitatively at the sub-100 ppm level, even for mixtures of gaseous aromatic compounds (nitrobenzene and toluene) with very similar molecular structures. This is enabled by combined chemo-resistive and SERS multimodal sensing providing complementary information.

36 MATERIALS SCIENCE↗

Status of the ITER Electron Cyclotron Heating and Current Drive System

We present that the electron cyclotron (EC) heating and current drive (H&CD) system developed for the ITER is made of 12 sets of high-voltage power supplies feeding 24 gyrotrons connected through 24 transmission lines (TL), to five launchers, four located in upper ports and one at the equatorial level. Nearly all procurements are in-kind, following general ITER philosophy, and will come from Europe, India, Japan, Russia and the USA. The full system is designed to couple to the plasma 20 MW among the 24 MW generated power, at the frequency of 170 GHz, for various physics applications such as plasma start-up, central H&CD and magnetohydrodynamic (MHD) activity control. The design takes present day technology and extends toward high-power continuous operation, which represents a large step forward as compared to the present state of the art. The ITER EC system will be a stepping stone to future EC systems for DEMO and beyond.The development of the EC system is facing significant challenges, which includes not only an advanced microwave system but also compliance with stringent requirements associated with nuclear safety as ITER became the first fusion device licensed as basic nuclear installations as of 9 November 2012. Finally, since the conceptual design of the EC system was established in 2007, the EC system has progressed to a preliminary design stage in 2012 and is now moving forward toward a final design.

42 ENGINEERING↗

Progress in the ITER electron cyclotron heating and current drive system design

We present that an electron cyclotron system is one of the four auxiliary plasma heating systems to be installed on the ITER tokamak. The ITER EC system consists of 24 gyrotrons with associated 12 high voltage power supplies, a set of evacuated transmission lines and two types of launchers. The whole system is designed to inject 20 MW of microwave power at 170 GHz into the plasma. The primary functions of the system include plasma start-up, central heating and current drive, and magneto-hydrodynamic instabilities control. The design takes present day technology and extends towards high power CW operation, which represents a large step forward as compared to the present state of the art. The ITER EC system will be a stepping stone to future EC systems for DEMO and beyond.The EC system is faced with significant challenges, which not only includes an advanced microwave system for plasma heating and current drive applications but also has to comply with stringent requirements associated with nuclear safety as ITER became the first fusion device licensed as basic nuclear installations as of 9 November 2012.Since conceptual design of the EC system established in 2007, the EC system has progressed to a preliminary design stage in 2012, and is now moving forward towards a final design. Lastly, the majority of the subsystems have completed the detailed design and now advancing towards the final design completion.

42 ENGINEERING↗

Designing inorganic electrolytes for solid-state Li-ion batteries: A perspective of LGPS and garnet

Solid state Li-ion batteries (SSLBs) are promising technologies for the next generation energy storage devices with higher energy density and enhanced safety. The solid state electrolyte (SSE) is a key component to deliver these desired electrochemical performance characteristics. Here we provide a brief review on the discovery, synthesis, structure, ion-conduction mechanism, and application of LGPS-type and garnet-type lithium ion conductors as two representative SSEs, aiming to extract principles for future design and discovery of favourable solid state Li-ion electrolytes for SSLBs. Recent advances in the strategies to address the challenges with respect to SSLBs are also discussed. Lastly, a perspective on the future research directions of SSLBs is provided.

25 ENERGY STORAGE↗

High-Sensitivity NO 2 Gas Sensor: Exploiting UV-Enhanced Recovery in a Hexadecafluorinated Iron Phthalocyanine-Reduced Graphene Oxide

Monitoring ultralow nitrogen dioxide (NO 2 ) concentrations is crucial for air quality management and public health. However, the existing NO 2 gas sensors have several defects, like high cost and power consumption, and exhibit poor selectivity. This study addresses these challenges by presenting a novel hexadecafluorinated iron phthalocyanine-reduced graphene oxide (FePcF 16 -rGO) covalent hybrid sensor for NO 2 detection. This innovative approach, which overcomes the limitations of fabrication cost, energy efficiency, and gas selectivity, is a significant step forward in gas sensor technology. The sensor demonstrates exceptional sensitivity toward ultralow NO 2 concentrations (15.14% response for 100 ppb) with a rapid 60 s UV light-induced recovery. Additionally, the sensor exhibits high selectivity for NO 2 , achieving a limit of detection (LOD) of 8.59 ppb. This approach paves the way for developing cost-effective, energy-efficient, and miniature NO 2 monitoring devices for improved environmental monitoring and enhanced safety in workplaces where NO 2 exposure is a concern.

36 MATERIALS SCIENCE↗

Cybersecurity impact of the growth of data in sports

As the sporting industry continues to increase dependence on new and often massive data sets, they also risk exposing themselves, as well as the leagues, teams, venues, players, and fans, to risks posed by not protecting the confidentiality and integrity of this data. The industry, especially true for professional sports, demands an ever increasing supply of new forms of data to achieve their goals of enticing new fans; enhancing experience; expanding the fan experience from venues and television to the internet and mobile devices; measuring and evaluating the performance and safety of players; and increasing revenue. New methods have emerged to collect data about a variety of aspects of sports ranging from players to fans to teams to venues. Data collected during sporting events is combined with historical data to also help teams analyze and predict performance. To synthesize these predictive analytical and historical memories, sports teams and organizations mix a variety of computer technologies. System integration tends to focus on ensuring the availability of the data and reliability of the technologies but might introduce risks to the confidentiality (privacy) and integrity of the data. Recognizing the potential risks requires review and evaluation. Much of the data is collected for publicly providing information to the fans, so threats to confidentiality pose fewer risks. The greatest risk is violating the privacy of players, such a private performance test, or using technology to gain a competitive advantage.

Jenkins, Stephanie↗

Visual Style Elements in Human–System Interface Design for Nuclear Power Operations: Does Style Affect Performance and Preference?

As the world increasingly adopts renewable and sustainable energy systems, transitionary solutions include nuclear power, which currently provides 20% of the United States’ electricity and is the largest single source of carbon-free electricity generation. Advanced reactors are a critical component of a carbon-free mixed energy portfolio that require careful design of first-of-a-kind control rooms. The application of Human Factors Engineering (HFE) is essential for scientific and iterative testing of novel human–system interface (HSI) concepts to ensure effective, efficient, and safe plant operations. Microworlds are simulators that use simplified physics models and control systems to distill nuclear power operations into essential functions. HFE scientists used the Rancor Microworld Simulator to obtain preference and performance metrics for novel and traditional static HSI design styles. Participants comprised advanced reactor company employees and nuclear industry consultants. A mixture of quantitative and qualitative data was captured. There was a preference for the basic graphical style that included high contrast and traditional color scheme elements. No single HSI design outperformed the others, and the participants did not perform better using their preferred HSI style. We report this experiment is the first in a series of HFE testing for HSIs in advanced reactor control room development. Clear user preferences emerged for elements within static displays. The cutting-edge neumorphic style was the least preferred. Future directions include tests of dynamic displays. HFE is used in evaluating and designing HSI devices that will improve the efficiency and safety of advanced nuclear power operations.

99 GENERAL AND MISCELLANEOUS↗

Solid electrolytes for solid-state and lithium-sulfur batteries

The stringent demands placed on batteries by emerging vehicle technologies such as plug-in and battery electric vehicles suggest that improvements in the safety and performance of electrochemical energy storage devices, as well as concurrent reductions in their cost, are highly desirable. Current strategies for improving performance have largely focused on Li-ion battery chemistries. In this project went beyond the state of the art by pursuing electrolyte chemistries that will enable the use of Li metal anodes and sulfur cathodes, either concurrently in a solid state Li-S battery, or as a means to achieve a Li metal anode which is stable upon cycling. More specifically, our effort advanced strategies to enable Li metal anodes for myriad beyond Li-ion chemistries . LLZO garnet (Li 7 La 3 Zr 2 O 12 ) is the first bulk-scale ceramic electrolyte to exhibit the combination of superionic conductivity (1mS/cm at 298K), high shear modulus (61 GPa) to suppress Li dendrite penetration, and apparent electrochemical stability (0-6V vs Li/Li + ), thus enabling Li metal anodes. However, to date there are no reports confirming LLZO can tolerate current densities > 1mA/cm 2 , thus demonstrating relevance to PHEV/EV batteries. Our goal was to investigate the mechanisms that govern the Li-LLZO interfacial stability as a function of current density. We determined that defects in polycrystalline LLZO reduce the critical current density (CCD). Primarily contaminants on the LLZO surface and grain boundaries were the primary defects the limited the CCD. Using our experience with synthesis and processing (Sakamoto and Wolfenstine) and sophisticated materials characterization (Nanda), we precisely controlled atomistic and microstructural defects and correlated their effects on controlling the critical current density. These data fed into multi-scale computation models (Siegel and Monroe) to isolate and quantify the roles that each defect played in controlling the critical current density. Bridging this knowledge gap allowed us to demonstrate that LLZO can withstand > 1mA/cm 2 .

25 ENERGY STORAGE↗

Modal Frequency Identification of Vibrational Response Measurements: Simulation/Experiment/Validation

Many critical systems operating in the open seas or in the air employ a variety of subsystems ranging from machinery for propulsion to airfoils for flight or even reactor components as simple as pipes carrying much-need cooling for control purposes. In these subsystems,whether they be aboard a surface ship or submarine or AUV or in-flight aboard a rocket or aircraft—critical components must be monitored in real-time for safety and in some cases survival. Mechanical devices operating in noisy environments create a challenging signal processing problem to estimate their vibrational signatures in real-time. In order to estimate the performance of a particular type of device from noisy vibration data, it is necessary to identify signatures that make it unique. Resonant (modal) frequencies emitted offer a signature characterizing its operation.

42 ENGINEERING↗

CFD Simulation of Bubble Growing Under a Downward Facing Surface

The heat removing of downward facing surface is an important issue in many areas, including nuclear safety, solar storage system and electronic cooling devices. Therefore, the characteristic and heat removal capability of downward facing boiling were investigated by many experiments in recent years. Among these studies, the thickness of bubble is considered as an important parameter. The increasing of bubble thickness will increase the thermal resistance of cooling process and reduce the cooling ability. In order to focus on the dynamics of bubble thickness, Das et al. injected air into sodium dodecyl sulphate (SDS) solution through a nozzle under the horizontal downward facing surface. The bubble will be formed by the air injection and kept under the horizontal plate. The diameter of nozzle, horizontal plate and SDS solution tank are 2 mm, 20 mm and 30 mm, respectively. The growing processing and the stable thickness of the bubble were recorded in the experiment. Basing on the conditions of Das's experiment, the appropriate computational fluid dynamics (CFD) simulation was conducted. The growing process and the stable thickness of bubble under difference contact angle are predicted by CFD in this study.

42 ENGINEERING↗

Extra-light gamma-ray imager for safeguards and homeland security

Gamma-ray imaging is the most important way to identify unknown gamma-ray emitting objects in decommissioning, security, overcoming accidents. Over the past two decades a system for producing of gamma images in these conditions became more or less portable devices. But in recent years these systems have become the hand-held devices. This is very important, especially in emergency situations, and measurements for safety reasons. We describe the first integrated hand-held instrument for emergency and security applications. The device is based on the coded aperture image formation, position sensitive gamma-ray (X-ray) detector Medipix2 (detectors produces by X-ray Imaging Europe) and tablet computer. The development was aimed at creating a very low weight system with high angular resolution. We present some sample gamma-ray images by camera. Main estimated parameters of the system are the following. The field of view video channel ∼ 490 deg. The field of view gamma channel ∼ 300 deg. The sensitivity of the system with a hexagonal mask for the source of Cs-137 (Eg = 662 keV), is in units of dose D ∼ 100 mR. This option is less then order of magnitude worse than for the heavy, non-hand-held systems (e.g., gamma-camera Cartogam, by Canberra.) The angular resolution of the gamma channel for the sources of Cs-137 (Eg = 662 keV) is about 1.20 deg. (authors)

42 ENGINEERING↗

PV backsheets survey protocol: A framework for geo-spatial field surveys for bulk material characterization and reliability analysis applied across 41 PV systems

As widespread adoption of photovoltaic (PV) technologies continues, understanding the lifetime of modules is paramount to the viability of the industry as an environmentally conscious alternative to traditional energy generation. Although power degradation can affect the total energy production of a module over its lifetime, module safety failures necessitate the removal of a module leading to a loss of not only the particular asset, but the earning potential of the device. Therefore, it is critical to ensure that the components that provide essential safety functions for PV module operate for their entire rated lifetime. PV backsheets provide necessary electrical insulation to the completed device and failure of this component is cause for a immediate removal of the module. Degradation of the PV module backsheet has led to module safety failures in large-scale installations, costing millions of dollars in damages and lost potential revenue. The spatio-temporal degradation of fielded PV modules is important to study in order to identify which modules within installations are experiencing the greatest exposure conditions and in turn have the highest chance of failure. This paper describes a comprehensive field survey protocol developed for monitoring PV module backsheet performance using solely non-destructive methods in commercial PV fields. The protocol establishes a field naming convention, sampling method, data handling requirements, and measurement procedures. By ensuring consistent data collection practices, the field survey protocol enables research groups to obtain data of uniform quality on backsheet performance over multiple years and locations. In this study, the developed protocol was implemented at forty-one PV sites. Eight different types of airside layer backsheet materials including poly(vinylidene fluoride) (PVDF), acrylic PVDF, poly(tetrafluoroethylene-co-hexafluoropropylene-co-vinylidene fluoride) (THV), poly(vinyl fluoride) (PVF), poly(ethylene terephthalate) (PET), fluoroethylene vinyl ether (FEVE), polyethylene naphthalate (PEN), and glass were identified using attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy. The field survey results show that the spatial distribution of degradation indicators are non-uniform within a particular module, individual site, and across site locations. The degradation of PV modules increased in severity for modules mounted at the edge of rows (across a field) and near the junction box (within a module). This study demonstrates the sensitivity of material performance to exposure length across different materials and climates.

14 SOLAR ENERGY↗

Development and validation of a mathematical model of heart rate response to fluid perturbation

Physiological closed-loop controlled (PCLC) medical devices monitor and automatically adjust the patient’s condition by using physiological variables as feedback, ideally with minimal human intervention to achieve the target levels set by a clinician. PCLC devices present a challenge when it comes to evaluating their performance, where conducting large clinical trials can be expensive. Virtual physiological patients simulated by validated mathematical models can be utilized to obtain preclinical evidence of safety and assess the performance of the PCLC medical device during normal and worst-case conditions that are unlikely to happen in a limited clinical trial. A physiological variable that plays a major role during fluid resuscitation is heart rate (HR). For in silico assessment of PCLC medical devices regarding fluid perturbation, there is currently no mathematical model of HR validated in terms of its predictive capability performance. This paper develops and validates a mathematical model of HR response using data collected from sheep subjects undergoing hemorrhage and fluid infusion. The model proved to be accurate in estimating the HR response to fluid perturbation, where averaged between 21 calibration datasets, the fitting performance showed a normalized root mean square error (NRMSE) of 7.41 ± 2.8%. The model was also evaluated in terms of model predictive capability performance via a leave-one-out procedure (21 subjects) and an independent validation dataset (6 subjects). Two different virtual cohort generation tools were used in each validation analysis. The generated envelope of virtual subjects robustly met the defined acceptance criteria, in which 95% of the testing datasets presented simulated HR patterns that were within a deviation of 50% from the observed data. In addition, out of 16000 and 18522 simulated subjects for the leave one-out and independent datasets, the model was able to generate at least one virtual subject that was close to the real subject within an error margin of 9.56 ± 3.15% and 11.1 ± 1.22% NRMSE, respectively. In conclusion, the model can generate valid virtual HR physiological responses to fluid perturbation and be incorporated into future non-clinical simulated testing setups for assessing PCLC devices intended for fluid resuscitation.

59 BASIC BIOLOGICAL SCIENCES↗

TH-C-18C-01: MRI Safety

Clinical diagnostic medical physicists may be responsible for implementing and maintaining a comprehensive MR safety program. Accrediting bodies including the ACR, IAC, Radsite and The Joint Commission each include aspects of MR Safety into their imaging accreditation programs; MIPPA regulations further raise the significance of non-compliance. In addition, The Joint Commission recently announced New and Revised Diagnostic Imaging Standards for accredited health care organizations which include aspects of MR Safety. Hospitals and clinics look to the physicist to understand guidelines, regulations and accreditation requirements related to MR safety. The clinical medical physicist plays a significant role in a clinical practice by understanding the physical basis for the risks and acting as a facilitator to successfully implement a safety program that provides well-planned siting, allows for the safe scanning of certain implanted devices, and helps radiologists manage specific patient exams. The MRI scanning of specific devices will be discussed including cardiac pacemakers and neurostimulators such as deep brain stimulators. Furthermore for sites involved in MR guided interventional procedures, the MR physicist plays an essential role to establish safe practices. Creating a framework for a safe MRI practice includes the review of actual safety incidents or close calls to determine methods for prevention in the future. Learning Objectives: Understand the requirements and recommendations related to MR safety from accrediting bodies and federal regulations. Understand the Medical Physicist's roles to ensure MR Safety. Identify best practices for dealing with implanted devices, including pacemakers and deep brain stimulators. Review aspects of MR safety involved in an MR guided interventional environment. Understand the important MR safety aspects in actual safety incidents or near misses.

60 APPLIED LIFE SCIENCES↗

The strain capacitor: A novel energy storage device

A novel electromechanical energy storage device is reported that has the potential to have high energy densities. It can efficiently store both mechanical strain energy and electrical energy in the form of an electric field between the electrodes of a strain-mismatched bilayer capacitor. When the charged device is discharged, both the electrical and mechanical energy are extracted in an electrical form. The charge-voltage profile of the device is suitable for energy storage applications since a larger portion of the stored energy can be extracted at higher voltage levels compared to a normal capacitor. Its unique features include the potential for long lifetime, safety, portability, wide operating temperature range, and environment friendliness. The device can be designed to operate over varied operating voltage ranges by selecting appropriate materials and by changing the dimensions of the device. In this paper a finite element model of the device is developed to verify and demonstrate the potential of the device as an energy storage element. This device has the potential to replace conventional energy storage devices.

36 MATERIALS SCIENCE↗

Demonstrating compliance with moderator content limits in uranium dioxide powder upon leaving a furnace environment

A challenge was posed to the criticality safety consultant to consider whether instrumentation identified by Plant Management in an existing facility could be claimed as appropriate safety measures to ensure compliance with moderator content limits in uranium dioxide (UO{sub 2}) powder. During processing of low enriched UO{sub 2}, trays of powder are heated in a steam and hydrogen environment in order to reduce fluoride levels. Whilst in the furnace environment criticality safety is ensured by the geometry of the furnace trays used to convey the powder; however, upon leaving the furnace the UO{sub 2} is bulked to a 210 litre drum subject to limited moderation control. Under fault conditions there is a potential that the powder may become wetted due to an imbalance in furnace gas flows resulting in steam condensing in the cooling section of the furnace. Therefore, the safety case methodology followed suggests that two independent and diverse safety measures are provided to terminate the progression of the fault(s) to criticality. The existing criticality safety case credits an infra-red moisture meter as one of two safety measures; however, the calibration procedure required to ensure this device remains suitable is a considerable challenge from a plant operability perspective. As an initial review failed to identify any suitable like-for-like replacement, the National Nuclear Laboratory (NNL) Nuclear Safety Section were requested by the customer to consider the existing criticality safety case and investigate whether any existing instrumentation could be used as an alternative method of detecting conditions in which excess moisture could be present within the furnace trays. A number of solutions were proposed and the benefits and challenges around each are discussed in this paper, concluding with the approach adopted by the project. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Architecture of the personnel protection systems for Spallation Neutron Source Second Target Station

The Oak Ridge National Laboratory (ORNL) is implementing a major upgrade to the Spallation Neutron Source (SNS) facility, encompassing the addition of the Second Target Station (STS). Preliminary design reviews have been conducted on several STS Personnel Protection Systems (PPS). The reviews focused primarily on the integration with the existing SNS PPS, the new proton transport tunnel, and the target areas. Development of the PPS is ongoing, to ensure a coherent safety system with the mission of protecting users and workers from prompt radiation hazards while providing high beam availability to operations. The STS PPS element in the Integrated Control System (ICS) is a facility-wide system composed of multiple safety subsystems, including the Ring to Second Target (RTST) beam transport tunnel, Target, Bunker and Instruments. Personnel working in all these geographic areas are protected by modular reliable PPS solutions. The safety system enforces access controls, radiation monitoring, beam destination control, and application of critical device inhibit upon detection of abnormal condition. It uses well-documented processes, Common Industrial Protocol (CIP) safety, pulsed test, and redundancy to achieve the desired Safety Integrity Level (SIL). This paper gives an architectural overview of the STS PPS and a detailed safety plan for the SNS facility, addressing safety solutions and human factors.

Michaelides, Tommy [ORNL] (ORCID:0000000190499869)↗

MR Imaging of Patients with Cardiac Implantable Electronic Devices (CIEDs): Implementing a Program and Optimizing CMR

Purpose of review: How to implement a program for MRI in patients with conditional and non-conditional (“legacy”) CIED. How to optimize safety and image quality in CMR? What the radiologists need to know: device programming, pre- and post-MRI CIED parameters. Recent findings: New Center for Medicare and Medicaid Services (CMS) guidelines have opened MRI to many patients with nonconditional devices. Newer pulse sequences for cardiac MRI (CMR) in device patients, including modified cine, late gadolinium enhancement and T1 mapping sequences, have resulted in improved image quality in device patients. We present several cases of CMR in device patients, including imaging of leadless pacemakers subcutaneous ICDs. Imaging pitfalls/artifacts in CMR interpretation are also presented. Summary: An organized institutional workflow with an established protocol involving proper patient screening, device programming, scan monitoring, and pre- and post-ICD interrogation minimizes risk in patients with conditional and non-conditional CIEDs. Although rare, significant changes in lead performance, power-on/reset, inappropriate pacing or ICD discharges and battery voltage depletion should be documented. High-quality scans with accurate scar characterization in CIED patients require the use of wideband sequences. CMS has recently acknowledged MRI as a reasonable test necessary for the diagnosis and treatment of beneficiaries with implanted CIEDs, improving the financial prospects and encouraging future developments.

62 RADIOLOGY AND NUCLEAR MEDICINE↗