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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

“Wine-Dark Sea” in an Organic Flow Battery: Storing Negative Charge in 2,1,3-Benzothiadiazole Radicals Leads to Improved Cyclability

Redox-active organic materials (ROMs) have shown great promise for redox flow battery applications but generally encounter limited cycling efficiency and stability at relevant redox material concentrations in nonaqueous systems. Here we report a new heterocyclic organic anolyte molecule, 2,1,3-benzothiadiazole, that has high solubility, a low redox potential, and fast electrochemical kinetics. Coupling it with a benchmark catholyte ROM, the nonaqueous organic flow battery demonstrated significant improvement in cyclable redox material concentrations and cell efficiencies compared to the state-of-the-art nonaqueous systems. Especially, this system produced exceeding cyclability with relatively stable efficiencies and capacities at high ROM concentrations (>0.5 M), which is ascribed to the highly delocalized charge densities in the radical anions of 2,1,3-benzothiadiazole, leading to good chemical stability. As a result, this material development represents significant progress toward promising next-generation energy storage.

25 ENERGY STORAGE↗
DOE OSTI2014

On the Natural Frequency of Tidal Current Power Systems - A Discussion of Sea Testing

In order to study its wet natural frequency (in water) and dry frequency (in air), we conducted a two-year measurement campaign by deploying a full-scale prototype tidal current turbine system. A theoretical model is validated, and reveals the measured wet natural frequency of the device could be 54.6% of the dry frequency. Among short-term physics, inflow turbulence is important in the excitation of system resonances that can lead to fatigue damage and system failure. Among long-term physics, the wet natural frequency is highly dependent on tidal constituents, the semi-diurnal tides (M2 and S2) and diurnal tides (K1 and O1).

Li, Ye↗