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At least 163 records · Page 9

Determination of ionic abundances in the Io torus using the Hopkins Ultraviolet Telescope

Attention is given to a 415-1864-A spectrum of the emissions from the Io torus with about 3-A resolution in first order (830-1864 A) obtained with HUT in December 1990. A list of the 31 strongest features shows that, apart from five features that are totally or partially terrestrial, all are due to O(+), S(+), S(2+), and S(3+). There is no evidence for elements other than oxygen and sulfur. The spectrum shows many additional weaker emission features so that the existence of minor species cannot be ruled out at this time. Because the HUT spectrum contains well-resolved lines for all four of the major species, the mixing ratio (Ni/ne) for each one can be determined without using models of the spectral emissions, or a detailed geometric model of the torus plasma. The relative concentration of O(+) determined from the HUT observation is 38 percent less than that obtained from the Voyager UVS data.

Moos, H. W.↗

Unloading Versus Driven Processes Derived from Auroral Energy Deposition and Polar Cap Size

The intensity of far ultraviolet auroral emissions at all local times during the three substorm phases has been monitored by the Ultraviolet Imager (UVI) on the Polar spacecraft for many substorms. Changes in the energy flux and characteristic energy of the precipitating electrons can be derived from these observations by modeling of the spectral emission processes. The global and local energy deposition is a new parameter that can be used in substorm studies since it provides a measure of energy transfer from the tail to the ionosphere due to precipitating electrons at a time resolution of three minutes. The polar cap area and area of auroral emissions can also be determined at high time resolution during substorms from the UVI images. An example of a substorm that appears to be driven by solar wind dynamic pressure alone will be presented. The polar cap area and other parameters do not indicate a growth phase prior to substorm onset. In another example, the slow growth phase followed by a very rapid increase in energy deposition during the expansion phase will be shown. This substorm was preceded by a southward IMF orientation. In these two examples, the role the solar wind in determining polar cap area is discussed. The time development of the area of auroral emissions is also discussed in relation to substorm phase and energy deposition. If the auroral emissions occur on closed field lines then the area of auroral emissions may provide an indication of changes in the thickness of the plasma sheet during each substorm phase.

Brittnacher, M. J.↗

Spatial-frequency response of the Limb Infrared Monitor of the Stratosphere /LIMS/ radiometer

The Limb Infrared Monitor of the Stratosphere (LIMS), an experiment on the Nimbus-7 satellite, is designed to scan the earth's limb vertically and measure spectral emission profiles of trace atmospheric gases believed to be important in processes controlling the stratospheric ozone distribution. Experiment objectives are reviewed and several analyses and measurements are described which were performed to determine the adequacy of the system for satisfying these objectives. Adequate spatial-frequency response for all the spectral channels is required to provide, through inversion of the measured limb-radiance profiles, important information about the temperature, structure, and composition of the atmosphere. From the LIMS design-model data, the MTF was calculated for the optical system, the detector field mask, the electronics, and the overall system, for each channel. The signal output performance of the instrument was predicted from the system MTF data model input radiance data for each channel. MTF measurements made on the flight sensor confirmed the analytical results. The predictions indicate that the instrument can satisfy the basic measurement objectives of the experiment.

Wilson, R. G.↗

Using contour maps to search for red-shifted 511 keV features in BATSE GRB spectra

Since their discovery twenty years ago, the origin of gamma-ray bursts (GRB's) has remained an intriguing mystery. The quest to understand these objects has given rise to a plethora of competing theories. Several theories suggest that GRB's are galactic in origin while others suggest that GRB's are cosmological. One piece of evidence that might provide scientistis with a key to understanding the origin of GRB's may be whether or not spectral emission and absorption features exist in burst spectra. If the features exist and can be attributed to either cyclotron lines or to red-shifted 511 keV annihilation lines then credence would be given to those theories that support a galactic origin, i.e. near neutron stars. A method of searching for spectral features in burst spectra (BATSE HER data) is outlined.

Varmette, Peter G.↗

Io's heat flow from infrared radiometry: 1983-1993

We report the following results from a decade of infrared radiometry of Io: (1) The average global heat flow is more than approx. 2.5 W/sq.m, (2) large warm (less than or equal to 200 K) volcanic regions dominate the global heat flow, (3) smal high-temperature (greater than or = 300 K) 'hotspots' contribute little to the average heat flow, (4) thermal anomalies on the leading hemisphere contribute about half of the heat flow, (5) a substantial amount of heat is radiated during Io's night, (6) high-temperature (greater than or = 600 K) 'outbursts' occurred during approx. 4% of the nights we observed, (7) 'Loki' is the brightest, persistent, infrared emission feature, and (8) some excess emission is always present at the longitude of Loki, but its intensity and other characteristics change between apparitions. Observations of Io at M(4.8 micrometer), 8.7 micrometer, N(10 micrometer), and Q(20 micrometer) with the Infrared Telescope Facility presented here were collected during nine apparitions between 1983 and 1993. These measurements provide full longitudinal coveraged as well as an eclipse observation and the detection of two outbursts. Reflected sunlight, passive thermal emission, and radiation from thermal anomalies all contribute to the observed flux densities. We find that a new thermophysical model is required to match all the data. Two key elements of this model are (1) a 'thermal reservoir' unit which lowers daytime temperatures, and (2) the 'thermal pedestal effect' which shifts to shorter wavelengths the spectral emission due to the reradiation of solar energy absorbed by the thermal anomalies. The thermal anomalies are modeled with a total of 10 source components at five locations. Io's heat flow is the sum of the power from these components.

Veeder, Glenn J.↗

Multicolor Inks of Black Phosphorus for Midwave‐Infrared Optoelectronics

Abstract Black phosphorus (bP) based ink with a bulk bandgap of 0.33 eV ( λ = 3.7 µm) has recently been shown to be promising for large‐area, high performance mid‐wave infrared (MWIR) optoelectronics. However, the development of multicolor bP inks expanding across the MWIR wavelength range has been challenging. Here a multicolor ink process based on bP with spectral emission tuned from 0.28 eV ( λ = 4.4 µm) to 0.8 eV ( λ = 1.5 µm) is demonstrated. Specifically, through the reduction of bP particle size distribution (i.e., lateral dimension and thickness), the optical bandgap systematically blueshifts, reaching up to 0.8 eV. Conversely, alloying bP with arsenic (bP 1− x As x ) induces a redshift in the bandgap to 0.28 eV. The ink processed films are passivated with an infrared‐transparent epoxy for stable infrared emission in ambient air. Utilizing these multicolor bP‐based inks as an infrared light source, a gas sensing system is demonstrated that selectively detects gases, such as CO 2 and CH 4 whose absorption band varies around 4.3 and 3.3 µm, respectively. The presented ink formulation sets the stage for the advancement of multiplex MWIR optoelectronics, including spectrometers and spectral imaging using a low‐cost material processing platform.

Kim, Jae Ik↗

Responses of the Jovian Atmosphere to Cometary Particles and Photon Impacts

Spectra of soft x-ray and EUV emissions of oxygen ions, precipitating into the Jovian atmosphere, are calculated, taking into account the dynamical character of the energy and charge distributions of the ions as they propagate. Monte-Carlo simulations are performed using experimental and theoretical cross sections of ion collisions with the atmospheric gases. The numbers of x-ray and EUV photons produced per precipitating oxygen ion are calculated as functions of the initial ion energy and charge. The energy and charge distribution functions are used to evaluate the intensities of characteristic x-ray and EUV spectral emission lines of oxygen ions in the Jovian aurora.

Dalgarno, A.↗

Cirrus Parameter Retrieval by Combined Analysis of Spectral Thermal Infrared and Lidar Sensing from Aircraft and Space

The distribution, radiative and microphysical parameters of cirrus clouds are an important factor for cloud effects on the global radiation balance and climate. Multispectral thermal infrared observation are the most significant method used to remote sense cirrus parameter from current and planned passive satellite observations. Passive sensing alone has the limitation that both the cloud radiative temperature, or height, and the spectral emissivity must be derived in the analysis. Factors such as multiple cloud laying, which is very common, are known to introduce ambiguities in results. The addition of lidar cloud height structure measurements significantly improves retrievals. Such active/passive observations have been applied from the NASA ER-2 high altitude remote sensing aircraft since 1983. Applications include the study of the effective effective particle size of cirrus and application toward remote sensing of the ice/water content of cirrus clouds in addition to radiative parameters. Limitations, accuracy and examples of retrievals are presented. In 1997 a space shuttle hitch hiker experiment was flown which included a new technology Infrared Spectral Imaging Radiometer and a laser altimeter for direct cloud height measurements. A 30 orbit data set to test global application of combined spectral infrared and laser height measurements were obtained. Initial results for cirrus analysis from the shuttle experiment will also be presented.

Spinhirne, James D.↗

Infrared emission spectrophotometric study of the changes produced by TiN coating of metal surfaces in an operating EHD contact

Infrared emission spectra and related measurements were obtained from an operating ball/plate elastohydrodynamic (EHD) sliding contact under a variety of operating conditions. In order to be able to compare the effect of the ball surface, some of the balls were coated with a thin layer of titanium nitride (TiN) by vapor deposition. Polyphenyl ether (5P4E) was used as lubricant and 1 percent of 1,1,2-trichloroethane (TCE) as a surface-probing additive. TiN is chemically inert and its thermal conductivity is lower than that of steel. Therefore, the overall temperatures with TiN coated balls were higher. Nevertheless, no scuffing was observed with the coated balls under conditions giving rise to scuffing with the uncoated balls. Tractions were lower with the TiN coated balls and always when TCE was added to the 5P4E. These findings were found to be inversely related to the degree of polarization of the spectral emission bands. The intensity and the dichrosim of these bands were related to shear rates and inlet conditions of the EHD contact.

Keller, L. E.↗

Infrared emission spectrophotometric study of the changes produced by TiN coating of metal surfaces in an operating EHD contact

Infrared emission spectra and related measurements were obtained from an operating ball/plate EHD sliding contact under a variety of operating conditions. In order to be able to compare the effect of the ball surface, some of the steel balls were coated with a thin layer of titanium nitride (TiN) by vapor deposition. Polyphenyl ether (5P4E) was used as the lubricant and 1 percent of 1,1,2-trichloroethane TCE) as an additive with a high affinity for steel but a low affinity for TiN. TiN is chemically inert, but its thermal conductivity is lower than that of steel. Therefore, the overall temperatures with TiN-coated balls were higher. Nevertheless, no scuffng was observed with the coated balls under conditions giving rise to scuffing with the uncoated balls. Tractions were lower with the TiN-coated balls and with the steel balls when TCE was added to the 5P4E. These findings were found to be inversely related to the degree of polarization of the spectral emission bands. The intensity and the dichroism of these bands were related to shear rates and inlet conditions of the EHD contact.

Keller, L. E.↗

Strategy for Ultranarrow Light Down-Conversion for Displays Based on Bicolor-Emitting 2D Colloidal Heterostructures

The demand for ultranarrow spectral emission below 10 nm is critical for next-generation displays. Although current colloidal nanocrystals are successful in light down-conversion applications, they fall short in matching the stringent color purity requirements set by standards like Rec. 2020. Achieving such narrow linewidths through material engineering alone remains elusive, necessitating innovative light management strategies that avoid optical losses and maintain device efficiency. Here, in this work, we present a novel 2D colloidal heterostructure design, combining a CdSe core nanoplatelet, a CdS crown, and a CdZnS shell, to achieve bright bicolor emission in the solid state (green/red) emission with tunable intensity ratios controlled by excitation power (either optical or electrical). Integration of these nanoplatelets into a dielectric cavity further narrows the emission linewidth to sub-2 nm while enhancing the photoluminescence intensity by up to 200 times, meeting the Rec. 2020 color purity targets. This approach paves the way for a strategy avoiding complex laser-based solutions.

2D nanocrystals↗

Detection and quantification of trace technetium in the presence of molybdenum using laser-induced breakdown spectroscopy

Technetium (Tc) is a very important element that is encountered in many aspects, from its presence in radioactive waste and its potential environmental impact to its use as a medical radioisotope. Its detection and quantification in liquid samples is traditionally cumbersome, involving detailed sample preparation and analysis by mass spectrometry or scintillation. This article demonstrates the first comprehensive emission spectral analysis of Tc from a liquid sample by immobilization in a polymer and analysis by laser-induced breakdown spectroscopy (LIBS). A survey of LIBS spectra was completed to identify the strongest analytical lines for quantification of trace Tc in the presence of Mo. The quantification of Tc in a Mo-containing matrix was selected because Tc radioisotopes are the daughter products of Mo isotope decay. The first reported calibration curves by LIBS are provided with limits of detection and quantification down to 0.710 µg mL −1 and 1.39 µg mL −1 , respectively. Ultimately, this study demonstrated the feasibility of trace Tc quantification using LIBS and will serve as a reference for future research related to monitoring this radioactive species.

Andrews, Hunter B. [Oak Ridge National Laboratory ↗