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At least 163 records · Page 9

Chlorine monoxide radical, ozone, and hydrogen peroxide - Stratospheric measurements by microwave limb sounding

Profiles of stratospheric ozone and chlorine monoxide radical (ClO) have been obtained from balloon measurements of atmospheric limb thermal emission at millimeter wavelengths. The ClO measurements, important for assessing the predicted depletion of stratospheric ozone by chlorine from industrial sources, are in close agreement with present theory. The predicted decrease of ClO at sunset was measured. A tentative value for the stratospheric abundance of hydrogen peroxide was also determined.

Waters, J. W.↗

Stratospheric measurements of continuous absorption near 2400 per cm

Measurements of continuous absorption near 2400 per cm by N2 and CO2 over long path lengths in the lower stratosphere are presented. The continua were measured in a stratospheric solar spectrum obtained during sunset with a balloon-borne Michelson interferometer in the 2380-2500 per cm region, and transmittances were calculated by ratioing the amplitudes to those of a high-sun spectrum in order to eliminate the wavelength dependence of the measured flux. Comparison of the measured transmittances with those calculated for a multilayered atmospheric model using laboratory absorption measurements results in a fair agreement, and reveals the primary component of the absorption throughout most of the range to be N2, with the CO2 contribution equal to that of N2 only at the CO2 band head. In this region, the shape of the continuum is very sensitive to the sub-Lorentzian line shape assumed in the calculations, and so, if the shape of the N2 continuum at low temperatures can be determined through laboratory measurements, may be used to infer air-broadened far-wing CO2 line shape.

Rinsland, C. P.↗

Remote detection of the maximum altitude of equatorial ionospheric plasma bubbles

Nearly 200 post-sunset low-altitude passes of the Alouette 2 and ISIS 1 satellites near the dip equator are studied in order to find the maximum ionospheric plasma bubble altitudes, which are determined by calculating the apex altitude of the magnetic field line passing through the satellite when it is immersed in a bubble. The calculations are made only upon the observation of conjugate hemisphere ionospheric echoes, which result from ducted HF sounder signals that are guided along field-aligned irregularities within the plasma depletion. The maximum bubble altitudes corresponding to the three longitude sectors centered on zero deg, 75 deg W, and 105 deg E, are found to often exceed 1000 km, but seldom 3000 km. The electron density depletions within these field-aligned bubbles, as measured at the point of satellite encounter with the topside ionosphere, are generally less than a factor of two but may exceed a factor of ten.

Benson, R. F.↗

Global distribution of stratospheric aerosols by satellite measurements

A description is given of the first-ever global stratospheric aerosol climatology which is being developed by the earth-orbiting SAM II and SAGE satellite-based sensors. These sensors use the technique of solar occulation; that is, for every spacecraft sunrise and sunset, the modulation of solar intensity caused by the intervening earth-limb is measured. These data are mathematically inverted to yield vertical profiles of aerosol extinction coefficients with 1 km resolution. The data show seasonal variations which are similar in each hemisphere, with strong correlation between aerosol extinction and the corresponding temperature field. Typical values of extinction in the stratosphere are found to be about 0.0001 to 0.0002 per km at 1 micrometer; stratospheric optical depths at this wavelength are about 0.002. The peak extinction in the stratospheric aerosol layer follows the tropopause with altitude, with peak extinction ratios about 10 km above the local tropopause.

Mccormick, M. P.↗

Stratospheric measurements of collision-induced absorption by molecular oxygen

High-resolution stratospheric solar absorption spectra recorded at sunset with a balloon-borne interferometer, from an altitude of 33 km, are used in a study of collision-induced absorption by the fundamental vibration-rotation band of O2, whose continuum has been identified in the 1400-1700/cm region in spectra obtained at tangent altitudes below 22 km. It is found that transmittance measurements in intervals free of atmospheric line absorption agree with values calculated with the O2 absorption coefficients of Timofeyev and Tonkov (1978), and that the measurements indicate a 20% upper limit for the uncertainty of the available O2 absorption coefficients at lower stratospheric temperatures, on the order of 220 K.

Rinsland, C. P.↗

Stratospheric ozone and hydroxyl radical measurements by balloon-borne lidar

An experiment is reported in which a balloon-borne lidar system was used to measure ozone and the hydroxyl radical in the stratosphere by two lidar techniques. Ozone was measured in the 20-37 km altitude range using differential absorption lidar, and the hydroxyl radical was measured in the 34-37 km range using remote laser-induced fluorescence. Ozone concentrations were determined with a vertical resolution of 0.5 km, and in addition, horizontally resolved ozone measurements with 0.15-km resolution were obtained over a 2-km range. The temporal variation of the hydroxyl radical concentration ranged from 40 parts/trillion shortly after noon to about 5 parts/trillion two hours after sunset. Possible modifications to the system are discussed which can yield an improvement in the sensitivity of between one and two orders of magnitude, thus permitting measurements of the hydroxyl radical in the 20-30-km altitude range.

Heaps, W. S.↗

Equatorial ozone profile comparisons using OSO-8 UVMCS and Nimbus 4 BUV data

A comparison is made of equatorial ozone altitude profiles derived from data taken during near-coincident passes of the French solar occultation experiment on OSO-8 and the BUV instrument on Nimbus 4. The period of observation is August through October 1975. OSO-8 data are confined to sunset and the BUV measures ozone during the day for a range of solar zenith angles. Good agreement is found between ozone concentrations from OSO-8 and Nimbus 4 in the region of near overlap, 0.7 mb (52 km). Data indicate that the diurnal variation in ozone below 55 km is less than 20 percent in agreement with current models. The equatorial ozone profile can be described frequently by a single scale height from 34 to 60 km.

Aikin, A. C.↗

A model study of the diurnal variation of mesospheric O3

Diurnal variation of ozone between 50 to 80 km is studied for both oxygen-only and O-N-H-C atmospheres. The temporal variation of ozone density along the ray path as well as that due to the change in the local zenith angle are included in the model computations. The difference between cases with and without the temporal variation of ozone density, is examined. It is found that the inclusion of this variation reduces the ozone concentration at all altitudes. In addition, the greatest effect on the ozone concentration is during sunrise and sunset.

Wang, P. H.↗

The feasibility of using time-dependent photochemical calculations to infer radical species concentrations from solar occultation absorption measurements

In connection with fast chemical reactions, short-lived stratospheric species experience rapid concentration variations at sunset and sunrise. For solar occultation absorption measurements, these rapid concentration variations may introduce significant errors with respect to the inference of atmospheric abundances for some species due to asymmetrical concentration distributions. Most retrieval algorithms assume that concentration distributions are spherically symmetric. The effect of this assumption on the accuracy of inferred concentrations has been studied by Kerr et al. (1977). The present investigation considers the feasibility of using a time-dependent one-dimensional photochemical model to provide detailed information about the asymmetrical distribution for use in the retrieval procedure. As shown by Boughner et al. (1980), diurnal effects can be represented by an inhomogeneity factor. It is found that the NO retrieval improves considerably with the inclusion of a correction factor containing the asymmetrical variations.

Larsen, J. C.↗

Fabry-Perot interferometer measurements of thermospheric neutral wind gradients and reversals at Arecibo

Direct measurements of the meridional neutral winds in the thermosphere made with the Fabry-Perot interferometer at the Arecibo Observatory show the postmidnight meridional wind reversal that was inferred from previous incoherent scatter radar ion-drift data and airglow intensity maps and observed in-situ with the Atmosphere Explorer-E satellite. Data for three nights between October 29 and December 9, 1981, are presented. For this period, the meridional wind is observed to be northward after sunset and to turn south before midnight; the velocities often exceed 100 m/sec. After midnight, its direction is seen to reverse to northward for one to two hours. The reversal after midnight is recurrent and propagates from the equator, as predicted on the basis of previous meridional airglow intensity measurements.

Friedman, J. F.↗

Stratospheric N2O mixing ratio profile from high-resolution balloon-borne solar absorption spectra and laboratory spectra near 1880/cm

A nonlinear least-squares fitting procedure is used to derive the stratospheric N2O mixing ratio profile from balloon-borne solar absorption spectra and laboratory spectra near 1880/cm. The atmospheric spectra analyzed here were recorded during sunset from a float altitude of 33 km with the University of Denver's 0.02/cm resolution interferometer near Alamogordo, N.M. (33 deg N) on Oct. 10, 1979. The laboratory data are used to determine the N2O line intensities. The measurements suggest an N2O mixing ratio of 264 ppbv near 15 km, decreasing to 155 ppbv near 28 km.

Rinsland, C. P.↗

Ground-based infrared spectroscopic measurements of atmospheric hydrogen cyanide

A number of lines of the nu-3 band of hydrogen cyanide have been detected in solar absorption spectra recorded near sunrise and sunset at Kitt Peak National Observatory (elevation 2095 m) with a 0.01/cm resolution Fourier transform spectrometer. Analysis of two of the strongest and best isolated lines has led to a value of 2.73 x 10 to the 15th molecules/sq cm for the vertical column abundance of HCN above Kitt Peak. The accuracy of this value is estimated as + or - 25%. This result, combined with the stratospheric concentration of HCN derived by Coffey, Mankin, and Cicerone (1981), yields 166 parts per trillion by volume for the average mixing ratio of HCN between 2 and 12 km. This is the first determination of the HCN concentration in the nonurban troposphere.

Rinsland, C. P.↗

Influence of the E region dynamo on equatorial spread F

The integrated E region Pedersen conductivity can be an important parameter in determining whether the bottomside of the equatorial F layer will be stable against the Rayleigh-Taylor gravitational instability. The F layer is observed to become unstable when it rises to great heights after sunset. One effect of this height rise is to decrease the stabilizing influence of ion-neutral collisions at F region heights. It is shown here that the same eastward electric field that raises the F layer also decreases the Pedersen conductivity of the E region, which further destabilizes convective overturning. Because the conductivity of magnetic tubes that penetrate the main F layer is large compared to the E layer contribution, these effects are important only for the bottomside of the equatorial F layer.

Hanson, W. B.↗

Space observations of aerosols and ozone; Proceedings of the Topical Meeting, Ottawa, Canada, May 16-June 2, 1982

The measurement of aerosols from space is discussed, taking into account the role of aerosols in climate, instrumentation and further measurement systems, retrieval procedures, measurements and observations, ground truth measurements, and effects on remote sensing and on climate. Aspects of ozone variability in the middle atmosphere are explored, giving attention to the quasi-biennial oscillation in equatorial stratospheric temperatures and total ozone, global pictures on the ozone field from high altitudes from DE-1, measurements of atmospheric ozone from aircraft and from balloons, a mesospheric ozone profile at sunset, periodic and aperiodic ozone variations in the middle and upper stratosphere, solar eclipse induced variations in mesospheric ozone concentrations, and solar UV and ozone balloon measurements. The determination of aerosol optical depth is considered along with a method for estimating cross radiance.

Mccormick, M. P.↗

Balloon borne LIDAR measurements of stratospheric hydroxyl radical

A balloon-borne laser radar (LIDAR) system for determining the stratospheric hydroxyl radical concentration constructed and flown by the Goddard Space Flight Center is discussed. The system measured hydroxyl in the altitude range of 34-37 km during an afternoon and early evening, producing the first post-sunset hydroxyl determination ever obtained. Daytime values (approximately 5 x 10 to the 6th/cu cm) are somewhat lower than previous measurements using in situ resonance fluorescence. Nighttime values (approximately 7 x 10 to the 5th/cu cm at 2100 CDT) are found to be higher than predicted by current one-dimensional models. Possible sources of these discrepancies, together with improvements possible in future systems, are outlined.

Heaps, W. S.↗

Estimating unbiased horizontal velocity components from ST/MST radar measurements: A case study

In this paper a self-editing quick look procedure is presented for use at the Sunset radar. It is used for determining relatively unbiased hourly estimates of the u and v components of the wind. The technique presented here should be applicable to all height ranges, though only ST results are presented here. The vertical wind component, w, may be measured directly by pointing the radar beam straight up. The east and west components of the wind, u and v, however, must be estimated by projecting to the horizontal plane the radial velocity, vr, actually observed by pointing the radar suitably off zenith.

Clark, W. L.↗

LEC System Development

The Lajet Energy Company (LEC) 460 is described. A parabolic dish which incorporates a microprocessor to automatically point it toward the Sun from sunrise to sunset is used. The dish is composed of a set of mirrors (made of reflective polymeric film) which focus and concentrate the Sun's energy on a receiver, producing intense but controlled amounts of heat. The LEC 460 employs a design concept that permits the use of common and low cost materials. All major structural components are fabricated from low carbon, low alloy steel using methods adaptable to mass production. The mirrors are supported on a steel tubing frame. This frame is attached near its center of gravity to a cantilevered support structure. The mirrors and frame are counterbalanced by the weight of the receiver, thus reducing the energy needed to move the collector (parasitic load) and allowing movement on two axes. Each LEC 460 solar concentrator contains a reflective array consisting of twenty four 60 inch diameter mirrors.

Halbert, D. D.↗

Stratospheric temperature profile from balloon-borne measurements of the 10.4-micron band of CO2

The technique of nonlinear least squares spectral curve fitting has been used to derive the stratospheric vertical temperature profile from balloon-borne measurements of the 10.4 micron band of CO2. The spectral data were obtained at sunset with the approximately 0.02 per cm resolution University of Denver interferometer system from a float altitude of 33.5 km near Alamogordo, New Mexico, on 23 March 1981. The r.m.s. deviation between the retrieved temperature profile and correlative radiosonde measurements is 2.2 K.

Rinsland, C. P.↗