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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

The use of gas chromatography – high resolution mass spectrometry for suspect screening and non-targeted analysis of per- and polyfluoroalkyl substances

This study is a workflow development for the analysis, identification, and categorization of per- and polyfluoroalkyl substances (PFAS) using gas chromatography-high resolution mass spectrometry (GC-HRMS) with non-targeted analysis (NTA) and suspect screening techniques. The behavior of various PFAS in a GC-HRMS was studied with regards to retention indices, ionization susceptibility, fragmentation patterns, etc. A custom PFAS database was constructed from 141 diverse PFAS. The database contains mass spectra from electron ionization (EI) mode, as well as MS and MS/MS spectra from positive and negative chemical ionization (PCI and NCI, respectively) modes. Common fragments of PFAS were identified across a diverse set of 141 PFAS analyzed. A workflow for suspect screening of PFAS and partially fluorinated products of incomplete combustion/destruction (PICs/PIDs) was developed which utilized both the custom PFAS database and external databases. PFAS and other fluorinated compounds were identified in both a challenge sample (designed to test the identification workflow) and incineration samples suspected to contain PFAS and fluorinated PICs/PIDs. The challenge sample resulted in a 100% true positive rate (TPR) for PFAS which were present in the custom PFAS database. In conclusion, several fluorinated species were tentatively identified in the incineration samples using the developed workflow.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Brightness Changes in Sun-like Stars

Does the Sun's energy output vary with time? Are observable climatic changes on the earth caused by changes in the Sun? Can we gain greater insight into this relation-ship by studying other stars with properties similar to the Sun's? In recent years, satellite observations have shown that the solar irradiance varies in phase with the 1 l-year sunspot cycle. The Sun is brighter by about O.l% at the peak of the sunspot cycle when solar magnetic activity is at its maximum. Over longer intervals, changes in the cart h's climate and solar magnetic activity seem to be correlated. We are using automatic photoelectric telescopes to measure brightness changes in a sample of 150 Sun-like stars. Lowell Observatory astronomers have also observed about 30 of these same stars with a manual telescope in a program that began 10 years before ours. Since these two data sets were acquired with different instruments and so have significant systematic differences, we developed software to combine them accurately and, therefore, extend our observational time coverage. We show sample results of brightness variations over 14 years in several Sun-like stars with different ages. Longitudinal studies like these, combined with cross-sectional studies of the larger sample of stars, may eventually allow us to infer with confidence the Sun's long-term brightness history and its impact on the earth's climate.

Henry, Stephen M.↗

Crossed hot-wire data acquisition and reduction system

The report describes a system for rapid computerized calibration acquisition, and processing of data from a crossed hot-wire anemometer is described. Advantages of the system are its speed, minimal use of analog electronics, and improved accuracy of the resulting data. Two components of mean velocity and turbulence statistics up to third order are provided by the data reduction. Details of the hardware, calibration procedures, response equations, software, and sample results from measurements in a turbulent plane mixing layer are presented.

Westphal, R. V.↗

Quantifying Uncertainties in the Thermo-Mechanical Properties of Particulate Reinforced Composites

The present paper reports results from a computational simulation of probabilistic particulate reinforced composite behavior. The approach consists use of simplified micromechanics of particulate reinforced composites together with a Fast Probability Integration (FPI) technique. Sample results are presented for a Al/SiC(sub p)(silicon carbide particles in aluminum matrix) composite. The probability density functions for composite moduli, thermal expansion coefficient and thermal conductivities along with their sensitivity factors are computed. The effect of different assumed distributions and the effect of reducing scatter in constituent properties on the thermal expansion coefficient are also evaluated. The variations in the constituent properties that directly effect these composite properties are accounted for by assumed probabilistic distributions. The results show that the present technique provides valuable information about the scatter in composite properties and sensitivity factors, which are useful to test or design engineers.

Mital, Subodh K.↗

Gamma-Ray Burst Intensity Distributions

We use the lag-luminosity relation to calculate self-consistently the redshifts, apparent peak bolometric luminosities L(sub B1), and isotropic energies E(sub iso) for a large sample of BATSE bursts. We consider two different forms of the lag-luminosity relation; for both forms the median redshift, for our burst database is 1.6. We model the resulting sample of burst energies with power law and Gaussian dis- tributions, both of which are reasonable models. The power law model has an index of a = 1.76 plus or minus 0.05 (95% confidence) as opposed to the index of a = 2 predicted by the simple universal jet profile model; however, reasonable refinements to this model permit much greater flexibility in reconciling predicted and observed energy distributions.

Band, David L.↗

Experimental reproduction of space weathering of C-type asteroids by He exposure: irradiation-energy and physical-property dependence

Visible and near-infrared observations of C-type asteroid 162173 Ryugu suggest that the surface color variation seems to have resulted from a surface-correlated process which changed the color from blue to red, but the mechanism for the change is not yet identified. Space weathering is one possible mechanism responsible for the color variation, but the spectral changes of C-type asteroids from space weathering are not yet fully understood. We have carried out He exposure experiments on hydrous carbonaceous chondrites in order to understand the irradiation-energy and the physical-property dependence of space weathering of C-type asteroids. He exposure to different porosities of the same meteorite samples results in different behavior of spectral changes. In addition, the meteorite samples with the same porosity and the same surface roughness show different spectral changes when the samples are exposed to He ions with different energies. Therefore, our experiments indicate that spectral changes by space weathering of C-type asteroids depend not only on the asteroid types but also on the physical properties of the regolith surface and the solar-wind He energy.

Michael E Zolensky↗

From Apollo to Artemis: How Processing ANGSA Core Samples 73001/2 Can Help to Prepare for Future Sample Return Missions to the Moon and Beyond.

Introduction: Apollo Sample 73001/2 is a ~71cm long double drive tube consisting of an upper part (73002) and a lower part (73001) that contains regolith collected near Lara Crater at the Apollo 17 site, Station 3. The double drive tube is believed to have penetrated a lunar landslide deposit that was transported from the slope of the South Massif into the Taurus-Littrow Valley [1]. As part of the ANGSA (Apollo Next Generation Sample Analyses) initiative, preparing a preliminary examination (PE) catalog of 73001/2 is a crucial first step for the early identification of material types such as rock fragments and potential stratigraphy within the core. Many new curation and scientific tools such as X-ray computed tomography (XCT) [3], multi-spectral imaging [4], and gas extraction manifold with piercing tool [5-7], have been applied to the ANGSA core to benefit curation strategy, PE efforts, sample allocation to the planetary science community, and ultimately help to prepare for future sample return missions like Artemis. 73001/2 Preliminary Examination and Processing: Sample 73002 was successfully opened and extruded in Nov. 2019 and fully dissected at the end of 2021. Sample 73001 (Fig. 1) was successfully extruded in March 2022 after careful planning before opening the Core Sample Vacuum Container (CSVC) that was holding the drive tube of 73001. XCT, as part of PE, was used to scan the bottom and top part of the 73001 core tube within the CSVC prior to opening it to 1) facilitate non-destructive, rapid detection of any contamination potentials due to piercing of the CSVC during gas extraction [7]; and 2) to aid in the Artemis sample tool development and provide data on the knife edge seal of the CSVC. This knowledge will help us connect the mechanics of the implemented design (i.e., XCT data) to the performance of the seal (i.e., data on the gas samples will tell us how well the seal preserved the volatile record of lunar samples). Both type of information will feed forward into Artemis tool and storage strategies for future samples. Results and Lessons learned: The XCT data of the CSVC and core tube within showed that the bottom Teflon cap was not pierced during gas extraction (Fig. 1c) and thus, the sample integrity remained guaranteed during piercing and subsequent gas extraction. However, the XCT scan of the top of the core (Fig. 1b) revealed that the drive tube was overfilled with lunar soil and the tool that keeps the soil constrained within the drive tube was not fully deployed. These preliminary data allowed us to implement the necessary steps to prevent loss of sample integrity, including any potential stratigraphy shifts during extrusion. Processing Apollo core 73001/2, creating an informative PE catalog, and applying new and refined tools and technologies for sample analyses are invaluable activities that will assist in circumventing any potential pitfalls, aid in the characterization of samples, and help in the assessment of how well any lunar material has been collected and preserved in the past. This will aid in designing future sample collections and curation procedures and help to prepare for future human exploration and sampling missions such as Artemis. References: [1] Schmitt H. (2017) Icarus 298, 2-33. [3] Zeigler et al. (2021) LPSC 52nd, #2632; [4] Sun et al. (2021), LPSC 52nd, #1789; [5] Parai et al. (2021), LPSC 52nd #2665; [6] Schild et al. (2021) LPSC 52nd #1888; [7] McDonald (2022) ESL 2022.

ANGSA↗

Advanced Intelligent System Application to Load Forecasting and Control for Hybrid Electric Bus

The primary motivation for this research emanates from providing a decision support system to the electric bus operators in the municipal and urban localities which will guide the operators to maintain an optimal compromise among the noise level, pollution level, fuel usage etc. This study is backed up by our previous studies on study of battery characteristics, permanent magnet DC motor studies and electric traction motor size studies completed in the first year. The operator of the Hybrid Electric Car must determine optimal power management schedule to meet a given load demand for different weather and road conditions. The decision support system for the bus operator comprises three sub-tasks viz. forecast of the electrical load for the route to be traversed divided into specified time periods (few minutes); deriving an optimal 'plan' or 'preschedule' based on the load forecast for the entire time-horizon (i.e., for all time periods) ahead of time; and finally employing corrective control action to monitor and modify the optimal plan in real-time. A fully connected artificial neural network (ANN) model is developed for forecasting the kW requirement for hybrid electric bus based on inputs like climatic conditions, passenger load, road inclination, etc. The ANN model is trained using back-propagation algorithm employing improved optimization techniques like projected Lagrangian technique. The pre-scheduler is based on a Goal-Programming (GP) optimization model with noise, pollution and fuel usage as the three objectives. GP has the capability of analyzing the trade-off among the conflicting objectives and arriving at the optimal activity levels, e.g., throttle settings. The corrective control action or the third sub-task is formulated as an optimal control model with inputs from the real-time data base as well as the GP model to minimize the error (or deviation) from the optimal plan. These three activities linked with the ANN forecaster proving the output to the GP model which in turn produces the pre-schedule of the optimal control model. Some preliminary results based on a hypothetical test case will be presented for the load forecasting module. The computer codes for the three modules will be made available fe adoption by bus operating agencies. Sample results will be provided using these models. The software will be a useful tool for supporting the control systems for the Electric Bus project of NASA.

Momoh, James↗

Large Scale Study of Ligand–Protein Relative Binding Free Energy Calculations: Actionable Predictions from Statistically Robust Protocols

The accurate and reliable prediction of protein–ligand binding affinities can play a central role in the drug discovery process as well as in personalized medicine. Of considerable importance during lead optimization are the alchemical free energy methods that furnish an estimation of relative binding free energies (RBFE) of similar molecules. Recent advances in these methods have increased their speed, accuracy, and precision. This is evident from the increasing number of retrospective as well as prospective studies employing them. However, such methods still have limited applicability in real-world scenarios due to a number of important yet unresolved issues. Here, we report the findings from a large data set comprising over 500 ligand transformations spanning over 300 ligands binding to a diverse set of 14 different protein targets which furnish statistically robust results on the accuracy, precision, and reproducibility of RBFE calculations. We use ensemble-based methods which are the only way to provide reliable uncertainty quantification given that the underlying molecular dynamics is chaotic. These are implemented using TIES (Thermodynamic Integration with Enhanced Sampling). Results achieve chemical accuracy in all cases. Ensemble simulations also furnish information on the statistical distributions of the free energy calculations which exhibit non-normal behavior. We find that the “enhanced sampling” method known as replica exchange with solute tempering degrades RBFE predictions. We also report definitively on numerous associated alchemical factors including the choice of ligand charge method, flexibility in ligand structure, and the size of the alchemical region including the number of atoms involved in transforming one ligand into another. Our findings provide a key set of recommendations that should be adopted for the reliable application of RBFE methods.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The kinematic properties of Milky Way stellar halo populations

ABSTRACT In the Gaia era, stellar kinematics are extensively used to study Galactic halo stellar populations, to search for halo structures, and to characterize the interface between the halo and hot disc populations. We use distribution function-based models of modern data sets with 6D phase space data to qualitatively describe a variety of kinematic spaces commonly used in the study of the Galactic halo. Furthermore, we quantitatively assess how well each kinematic space can separate radially anisotropic from isotropic halo populations. We find that scaled action space (the ‘action diamond’) is superior to other commonly used kinematic spaces at this task. We present a new, easy to implement selection criterion for members of the radially anisotropic Gaia–Enceladus merger remnant. Assuming a 1:1 ratio of Gaia–Enceladus stars to more isotropic halo, we find our selection achieves a sample purity of 86 per cent in our models with respect to contamination from the more isotropic halo. We compare this criterion to literature criteria, finding that it produces the highest purity in the resulting samples, at the expense of a modest reduction in completeness. We also show that selection biases that underlie nearly all contemporary spectroscopic data sets can noticeably impact the E−Lz distribution of samples in a manner that may be confused for real substructure. We conclude by providing recommendations for how authors should use stellar kinematics in the future to study the Galactic stellar halo.

79 ASTRONOMY AND ASTROPHYSICS↗

Turbulence Measurements on a Wing-Fuselage Junction Model for CFD Validation

Current turbulence models, such as those employed in Reynolds-averaged Navier-Stokes CFD, are unable to reliably predict the onset and extent of the three-dimensional separated flow that typically occurs in wing fuselage junctions. To critically assess, as well as to improve upon, existing turbulence models, experimental validation-quality flow field data in the junction region is needed. To that end, NASA has developed a CFD validation experiment for a generic full-span wing-fuselage junction model at subsonic conditions. In this paper, we present and discuss sample results from this effort, with a focus on turbulence measurements in the separated corner flow of the wing-fuselage junction that were obtained with an internally mounted laser Doppler velocimetry (LDV) system. In addition, sample comparisons between the flow field measurements and representative CFD of our test case are presented and here, we highlight some of the key discrepancies.

Kegerise, Michael↗

Techniques for Automated Single-Star Photometry

Tennessee State University operates several automatic photoelectric telescopes (APTs) located at Fairborn Observatory in the Patagonia Mountains of southern Arizona. The APTs are dedicated to photometric monitoring programs that would be expensive and difficult to accomplish without the advantages of automation. I review the operation of two of the telescopes (a 0.75- and 0.80-meter (m) APT) and the quality-control techniques that result in the routine acquisition of single-star differential photometry with a precision of 0.001 mag for single observations and 0.0001 - 0.0002 mag for seasonal means. I also illustrate the capabilities of the APTS with sample results from a program to measure luminosity cycles in sun-like stars and a related program to search for the signatures of extrasolar planets around these stars.

Henry, Gregory W.↗

CO2 Flux Estimation Errors Associated with Moist Atmospheric Processes

Vertical transport by moist sub-grid scale processes such as deep convection is a well-known source of uncertainty in CO2 source/sink inversion. However, a dynamical link between vertical transport, satellite based retrievals of column mole fractions of CO2, and source/sink inversion has not yet been established. By using the same offline transport model with meteorological fields from slightly different data assimilation systems, we examine sensitivity of frontal CO2 transport and retrieved fluxes to different parameterizations of sub-grid vertical transport. We find that frontal transport feeds off background vertical CO2 gradients, which are modulated by sub-grid vertical transport. The implication for source/sink estimation is two-fold. First, CO2 variations contained in moist poleward moving air masses are systematically different from variations in dry equatorward moving air. Moist poleward transport is hidden from orbital sensors on satellites, causing a sampling bias, which leads directly to small but systematic flux retrieval errors in northern mid-latitudes. Second, differences in the representation of moist sub-grid vertical transport in GEOS-4 and GEOS-5 meteorological fields cause differences in vertical gradients of CO2, which leads to systematic differences in moist poleward and dry equatorward CO2 transport and therefore the fraction of CO2 variations hidden in moist air from satellites. As a result, sampling biases are amplified and regional scale flux errors enhanced, most notably in Europe (0.43+/-0.35 PgC /yr). These results, cast from the perspective of moist frontal transport processes, support previous arguments that the vertical gradient of CO2 is a major source of uncertainty in source/sink inversion.

moist atmospheric processes↗

Algorithmic Enhancements for the VULCAN Navier-Stokes Solver

Work performed over the last three years has resulted in the addition of several new algorithms to the VULCAN code, NASA's standard for Navier-Stokes calculations in high-speed aeropropulsion devices. This final report describes the new techniques in brief and presents sample results from their use.

Edwards, Jack R.↗

Algorithmic Enhancements for the VULCAN Navier-Stokes Solver

Work performed over the last three years has resulted in the addition of several new algorithms to the VULCAN code, NASA's standard for Navier-Stokes calculations in high-speed aeropropulsion devices. This final report describes the new techniques in brief and presents sample results from their use.

Edwards, Jack R.↗

Developing a Tool to Collect Microbiological Samples in Space

We developed and tested a tool to collect aseptic samples during extravehicular activity or space walks. This tool can withstand the extreme temperature (-92 – 90 ˚C) and pressure variations without compromising the sterility of the collection device or the integrity of the sample. Results from ground testing the tool demonstrate that external surfaces of space suits are not sterile and that a wide variety of human associated bacteria and some fungi can survive at least seven hours of exposure to vacuum. These bacteria include non-spore forming organisms like Staphylococcus that are not normally considered extremophiles We plan to use this tool to characterize the exterior of the International Space Station. We expect the results of this work to guide the planetary protection requirements and contamination control strategy for crewed missions to Mars. This tool could also be used to monitor contamination associated with the Artemis missions to the moon or collect aseptic samples robotically in environments that are not suitable for human exploration.

A B Regberg↗

Nevada National Security Site - E-Tunnel Wastewater Disposal System: Fourth Quarter 2019

This report includes the results of monthly inspections and monitoring for October, November, and December 2019. Monthly inspections and monitoring were conducted on October 15, November 26, and December 18, 2019. Inspections include a visual assessment of the berms, ponding, water levels relative to the overflow pipes, tunneling or burrowing into the berms, soil conditions on and around the berms, erosion or sloughing of the slopes of the berms, seeps at the toe of the berms, deep-rooting botanicals on the berms, and fencing. Monthly monitoring includes measurements of the instantaneous flow rate, hydrogen ion activity (pH), and specific conductance of the E-Tunnel Wastewater Disposal System (ETDS) discharge. Annual sample results of the effluent water from the ETDS are also included in this report. The effluent sample was collected on September 11, 2019, and analyzed for the parameters listed in Table 1-B of Permit NEV 96021. In addition, Permit NEV 96021 requires the collection and analysis of representative groundwater samples from Well ER 12-1 every 24 months. This summary report provides the information pertaining to the sampling and analysis of groundwater samples collected on April 10, 2019.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗