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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Review of NASA progress in thermal barrier coatings for stationary gas turbines

Ceramic thermal barrier coatings for industrial/utility gas turbines were investigated. In burner rig tests of a zirconia yttria/nickel chromium aluminum yttrium ZrO2-12w/0Y2O3/NiCrAlY coating system on air cooled superalloy specimens, ceramic coating life (spallation) was sensitive to Na and V concentration in the fuel. The locations of coating spallation correspond to areas where combustion products were predicted to condense. Three new thermal barrier coating systems were identified. These are based on calcium silicate, ZrO2-8w/0Y2O3, and a MgO-NiCrAlY cermet. The spall resistance can be increased by reducing the ceramic layer thickness from 0.038 to 0.013 cm and by the use of more oxidation/corrosion resistant bond coats.

Hodge, P. E.↗
NASA NTRS1985

Spallogenic origin of nuclei in meteorites

Results obtained from a model built to evaluate the different interactions between cosmic rays and meteorites are presented. The model, computes, fluxes as a function of depth inside the meteorite, taking into account energy losses by ionization and spallation reactions which induce both particle destruction and production. This procedure, in which particle fluxes and cross sections are treated independently from each other, differs significantly from the thick target approach based on the measurement of spallation products generated in accelerator experiments.

Zanda, B.↗
NASA NTRS1985

Thermal barrier coating life prediction model development

A methodology was established to predict thermal barrier coating life in an environment simulative of that experienced by gas turbine airfoils. Specifically, work is being conducted to determine failure modes of thermal barrier coatings in the aircraft engine environment. Analytical studies coupled with appropriate physical and mechanical property determinations are being employed to derive coating life prediction model(s) on the important failure mode(s). An initial review of experimental and flight service components indicates that the predominant mode of TBC failure involves thermomechanical spallation of the ceramic coating layer. This ceramic spallation involves the formation of a dominant crack in the ceramic coating parallel to and closely adjacent to the metal-ceramic interface. Initial results from a laboratory test program designed to study the influence of various driving forces such as temperature, thermal cycle frequency, environment, and coating thickness, on ceramic coating spalling life suggest that bond coat oxidation damage at the metal-ceramic interface contributes significantly to thermomechanical cracking in the ceramic layer. Low cycle rate furnace testing in air and in argon clearly shows a dramatic increase of spalling life in the non-oxidizing environments.

Sheffler, K. D.↗
NASA NTRS1986

Simulation of cosmic irradiation conditions in thick target arrangements

One approach to simulate 2-pi irradiation conditions of planetary surfaces which has been widely applied in the past are bombardments of so called thick targets. A very large thick target was exposed recently to 2.1 GeV protons at the Bevatron-Bevalac in Berkeley. In a 100x100x180 cm steel-surrounded granodiorite target radioactive medium and high energy spallation products of the incident primary and of secondary particles were analyzed along the beam axis down to depths of 140 g/cm(2) in targets such as Cu, Ni, Co, Fe, T, Si, SiO2 and Al. Activities of these nuclides were exclusively determined via instrumental gamma-ray spectroscopy. Relative yields of neutron capture and spallation products induced in Co and Cu targets during the thick target bombardment are shown as a function of depth. The majority of the medium energy products such as Co-58 from Co targets exhibit a maximum at shallow depths of 40-60 g/cm(2) and then decrease exponentially. In a comparable 600 MeV proton bombarded thick target such a slight maximum for medium energy products was not observed. Rather, Co-58 activities in Co decreased steadily with the highest activity at the surface. The activities of the n-capture product Co-60 increase steadily starting at the surface. This indicates the rapidly growing flux of low energy neutrons within the target.

Theis, S.↗
NASA NTRS1986

Thermal barrier coating life prediction model development

A methodology is established to predict thermal barrier coating life in a environment similar to that experienced by gas turbine airfoils. Experiments were conducted to determine failure modes of the thermal barrier coating. Analytical studies were employed to derive a life prediction model. A review of experimental and flight service components as well as laboratory post evaluations indicates that the predominant mode of TBC failure involves thermomechanical spallation of the ceramic coating layer. This ceramic spallation involves the formation of a dominant crack in the ceramic coating parallel to and closely adjacent to the topologically complex metal ceramic interface. This mechanical failure mode clearly is influenced by thermal exposure effects as shown in experiments conducted to study thermal pre-exposure and thermal cycle-rate effects. The preliminary life prediction model developed focuses on the two major damage modes identified in the critical experiments tasks. The first of these involves a mechanical driving force, resulting from cyclic strains and stresses caused by thermally induced and externally imposed mechanical loads. The second is an environmental driving force based on experimental results, and is believed to be related to bond coat oxidation. It is also believed that the growth of this oxide scale influences the intensity of the mechanical driving force.

Demasi, J. T.↗
NASA NTRS1987

Cosmic-ray-produced neon and helium in the summit lavas of Maui

The identification of cosmic-ray-produced Ne-21c in addition to He-3c, components attributed to cosmic ray-induced spallation reactions, are reported in gases extracted by fusion of olivines and clinopyroxenes after vacuum-crushing. The observed (He-3/Ne-21)c ratios and the ratio of Ne-21c in olivine to that in clinopyroxene are consistent with an in situ origin of He-3c and Ne-21c by cosmic-ray spallation reactions. These components could be important for interpreting helium isotopic data in terrestrial reservoirs. Geophysical applications could include determinations of erosion rates and exposure histories of terrestrial rocks.

Marti, K.↗
NASA NTRS1987

Evidence in meteorites for an active early sun

High-sensitivity noble gas mass-spectrometric analyses of meteorite grains having solar flare heavy ion tracks show large enrichments of spallation-produced Ne-21 and Ar-38 when compared to nonirradiated grains from the same meteorite. The enhanced spallation effects in the irradiated grains are due to irradiation by energetic protons early in the history of the solar system, before compaction of the host meteorite. They require a proton fluence (E greater than 10 MeV) of 10 to the 16th to 10 to the 18th/cu cm. These results are best explained by solar flare irradiation in the early solar system with a proton flux several orders of magnitude higher than contemporary solar flares. The Ne isotopic structure suggests a harder energy spectrum than is characteristic of contemporary flares. These observations provide direct evidence for an active early (T Tauri) sun.

Caffee, M. W.↗
NASA NTRS1988

Thermal barrier coating life prediction model development

A life prediction model for correlating the spallation life of ceramic thermal barrier coatings is developed which includes both cyclic and time-dependent damage. The cyclic damage is related to the calculated cyclic inelastic strain range, while the time-dependent damage is related to the oxidation kinetics at the bond-ceramic interface. The cyclic inelastic strain range is calculated using a modified form of the Walker viscoplastic material model; calculation of the oxidation kinetics is based on traditional oxidation algorithms using experimentally determined parameters. The correlation between the actual and predicted spallation lives is within a factor of 3.

Cruse, T. A.↗
NASA NTRS1991

Thermal barrier coating life prediction model development

A thermal barrier coated (TBC) turbine component design system, including an accurate TBC life prediction model, is needed to realize the full potential of available TBC engine performance and/or durability benefits. The objective of this work, which was sponsored in part by NASA, was to generate a life prediction model for electron beam - physical vapor deposited (EB-PVD) zirconia TBC. Specific results include EB-PVD zirconia mechanical and physical properties, coating adherence strength measurements, interfacial oxide growth characteristics, quantitative cyclic thermal spallation life data, and a spallation life model.

Meier, Susan M.↗
NASA NTRS1992

Light-element abundances in Population II dwarfs

This paper reviews the abundances of the light elements lithium, beryllium, and boron in main-sequence and subgiant, Population II stars. Li is important to cosmology because it is synthesized in the Big Bang, but is also used to study stellar structure. Beryllium is useful for studying galactic chemical evolution because its formation in the interstellar medium involves different physics to stellar nucleosynthesis, and it thus provides independent data on the evolution of the halo. Some (though not all) inhomogeneous Big Bang nucleosynthesis codes predict a significant primordial component to this element, so its observed abundance may constrain such models. Boron, observations of which became feasible with the operation of the Hubble Space Telescope, provides complementary data to Be, helping check the element ratios predicted by calculations of spallation reactions in the interstellar medium, and will indicate whether the observed Be abundance has an excess over the expected spallation component, indicating a possible primordial component.

Ryan, Sean G.↗
NASA NTRS1992

Search for Cm-248 in the early solar system

Possible evidence for the presence of Cm-248 in the early solar system was reported from fission gas studies (Rao and Gopalan, 1973) and recently from studies of very high nuclear track densities (not less than 5 x 10 exp 8/sq cm) in the merrillite of the H4 chondrite Forest Vale (F.V.) (Pellas et al., 1987). We report here an analysis of the isotopic abundances of xenon in F.V. phosphates and results of track studies in phosphate/pyroxene contacts. The fission xenon isotopic signature clearly identifies Pu-244 as the extinct progenitor. We calculate an upper limit Cm-248/Pu-244 to be less than 0.0015 at the beginning of Xe retention in F.V. phosphates. This corresponds to an upper limit of the ratio Cm-248/U-235 of not greater than 5 x 10 exp -5 further constraining the evidence for any late addition of freshly synthesized actinide elements just prior to solar system formation. The fission track density observed after annealing the phosphates at 290C (1 hr, which essentially erases spallation recoil tracks) is also in agreement with the Pu-244 abundance inferred from fission Xe. The spallation recoil tracks produced during the 76 Ma cosmic-ray exposure account for the very high track density in merrillites.

Lavielle, B.↗
NASA NTRS1993

The boron-to-beryllium ratio in halo stars - A signature of cosmic-ray nucleosynthesis in the early Galaxy

We discuss Galactic cosmic-ray (GCR) spallation production of Li, Be, and B in the early Galaxy with particular attention to the uncertainties in the predictions of this model. The observed correlation between the Be abundance and the metallicity in metal-poor Population II stars requires that Be was synthesized in the early Galaxy. We show that the observations and such Population II GCR synthesis of Be are quantitatively consistent with the big bang nucleosynthesis production of Li-7. We find that there is a nearly model independent lower bound to B/Be of about 7 for GCR synthesis. Recent measurements of B/Be about 10 in HD 140283 are in excellent agreement with the predictions of Population II GCR nucleosynthesis. Measurements of the boron abundance in additional metal-poor halo stars is a key diagnostic of the GCR spallation mechanism. We also show that Population II GCR synthesis can produce amounts of Li-6 which may be observed in the hottest halo stars.

Walker, T. P.↗
NASA NTRS1994

Cosmic ray models for early galactic lithium, beryllium, and boron production

To better understand the early galactic production of Li, Be, and B by cosmic ray spallation and fusion reactions, the dependence of these production rates on cosmic ray models and model parameters is examined. The sensitivity of elemental and isotropic production to the cosmic ray pathlength magnitude and energy dependence, source spectrum spallation kinematics, and cross section uncertainties is studied. Changes in these model features, particularly those features related to confinement, are shown to alter the Be- and B-versus-Fe slopes from a naive quadratic relation. The implications of our results for the diffuse gamma-ray background are examined, and the role of chemical evolution and its relation to our results is noted. It is also noted that the unmeasured high energy behavior of alpha + alpha fusion can lead to effects as large as a factor of 2 in the resultant yields. Future data should enable Population II Li, Be, and B abundances to constrain cosmic ray models for the early Galaxy.

Fields, Brian D.↗
NASA NTRS1994

Cosmic-ray models for early Galactic Lithium, Beryllium, and Boron production

To understand better the early Galactic production of Li, Be, and B by comsmic-ray spallation and fusion reactions, the dependence of these production rates on cosmic-ray models and model parameters is examined. The sensitivity of elemental and isotopic production to the cosmic-ray path length magnitude and energy dependence, source spectrum, spallation kinematics, and cross section uncertainties is studied. Changes in these model features, particularly those features related to confinement, are shown to alter the Be- and B- versus-Fe slopes from a naive quadratic relation. The implications of our results for the diffuse gamma-ray background are examined, and the role of chemical evolution and its relation to our results is noted. It is also noted that the unmeasured high-energy behavior of alpha + alpha fusion can lead to effects as large as a factor of 2 in the resultant yields. Future data should enable Population II Li, Be, and B abundances to constrain cosmic-ray models for the early Galaxy.

Fields, Brian D.↗
NASA NTRS1994

Large ejecta fragments from asteroids

The asteroid 4 Vesta, with its unique basaltic crust, remains a key mystery of planetary evolution. A localized olivine feature suggests excavation of subcrustal material in a crater or impact basin comparable in size to the planetary radius (R(sub vesta) is approximately = 280 km). Furthermore, a 'clan' of small asteroids associated with Vesta (by spectral and orbital similarities) may be ejecta from this impact 151 and direct parents of the basaltic achondrites. To escape, these smaller (about 4-7 km) asteroids had to be ejected at speeds greater than the escape velocity, v(sub esc) is approximately = 350 m/s. This evidence that large fragments were ejected at high speed from Vesta has not been reconciled with the present understanding of impact physics. Analytical spallation models predict that an impactor capable of ejecting these 'chips off Vesta' would be almost the size of Vesta! Such an impact would lead to the catastrophic disruption of both bodies. A simpler analysis is outlined, based on comparison with cratering on Mars, and it is shown that Vesta could survive an impact capable of ejecting kilometer-scale fragments at sufficient speed. To what extent does Vesta survive the formation of such a large crater? This is best addressed using a hydrocode such as SALE 2D with centroidal gravity to predict velocities subsequent to impact. The fragmentation outcome and velocity subsequent to the impact described to demonstrate that Vesta survives without large-scale disassembly or overturning of the crust. Vesta and its clan represent a valuable dataset for testing fragmentation hydrocodes such as SALE 2D and SPH 3D at planetary scales. Resolution required to directly model spallation 'chips' on a body 100 times as large is now marginally possible on modern workstations. These boundaries are important in near-surface ejection processes and in large-scale disruption leading to asteroid families and stripped cores.

Asphaug, E.↗
NASA NTRS1997

Sulfur Impurities and the Microstructure of Alumina Scales

The relationship between the microstructure of alumina scales, adhesion, and sulfur content was examined through a series of nickel alloys oxidized in 1100 to 1200 deg. C cyclic or isothermal exposures in air. In cyclic tests of undoped NiCrAl, adhesion was produced when the sulfur content was reduced, without any change in scale microstructure. Although interfacial voids were not observed in cyclic tests of NiCrAl, they were promoted by long-term isothermal exposures, by sulfur doping, and in most exposures of NiAl. Two single crystal superalloys, PWA 1480 and Rene' N5, were also tested, either in the as-received condition or after the sulfur content had been reduced to less than 1 ppmw by hydrogen annealing. The unannealed alloys always exhibited spalling to bare metal, but interfacial voids were not observed consistently. Desulfurized PWA 1480 and Rene' N5 exhibited remarkable adhesion and no voidage for either isothermal or cyclic exposures. The most consistent microstructural feature was that, for the cases where voids did form, the scale undersides exhibited corresponding areas with ridged oxide grain boundaries. Voids were not required for spallation nor were other microstructural features essential for adhesion. These observations are consistent with the model whereby scale spallation is controlled primarily by interfacial sulfur segregation and the consequent degradation of oxide-metal bonding.

Smialek, James L.↗
NASA NTRS1999

Chemical Vapor Deposition of Turbine Thermal Barrier Coatings

Ceramic thermal barrier coatings extend the operating temperature range of actively cooled gas turbine components, therefore increasing thermal efficiency. Performance and lifetime of existing ceram ic coatings are limited by spallation during heating and cooling cycles. Spallation of the ceramic is a function of its microstructure, which is determined by the deposition method. This research is investigating metalorganic chemical vapor deposition (MOCVD) of yttria stabilized zirconia to improve performance and reduce costs relative to electron beam physical vapor deposition. Coatings are deposited in an induction-heated, low-pressure reactor at 10 microns per hour. The coating's composition, structure, and response to the turbine environment will be characterized.

Haven, Victor E.↗
NASA NTRS2000

Cyclic Oxidation Testing and Modelling: A NASA Lewis Perspective

The Materials Division of the NASA Lewis Research Center has been heavily involved in the cyclic oxidation of high temperature materials for 30 years. Cyclic furnace and burner rig apparati have been developed, refined, and replicated to provide a large scale facility capable of evaluating many materials by a standard technique. Material behavior is characterized by weight change data obtained throughout the test, which has been modelled in a step-wise process of scale growth and spallation. This model and a coupled diffusion model have successfully described cyclic behavior for a number of systems and have provided insights regarding life prediction and variations in the spalling process. Performance ranking and mechanistic studies are discussed primarily for superalloys and coating alloys. Similar cyclic oxidation studies have been performed on steels, intermetallic compounds, thermal barrier coatings, ceramics, and ceramic composites. The most common oxidation test was performed in air at temperatures ranging from 800 deg. to 1600 C, for times up to 10000 h, and for cycle durations of 0.1 to 1000 h. Less controlled, but important, test parameters are the cooling temperature and humidity level. Heating and cooling rates are not likely to affect scale spallation. Broad experience has usually allowed for considerable focus and simplification of these test parameters, while still revealing the principal aspects of material behavior and performance. Extensive testing has been performed to statistically model the compositional effects of experimental alloys and to construct a comprehensive database of complex commercial alloys.

Smialek, J. L.↗