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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Creep and stress relaxation modeling of polycrystalline ceramic fibers

A variety of high performance polycrystalline ceramic fibers are currently being considered as reinforcement for high temperature ceramic matrix composites. However, under mechanical loading about 800 C, these fibers display creep related instabilities which can result in detrimental changes in composite dimensions, strength, and internal stress distributions. As a first step toward understanding these effects, this study examines the validity of a mechanism-based empirical model which describes primary stage tensile creep and stress relaxation of polycrystalline ceramic fibers as independent functions of time, temperature, and applied stress or strain. To verify these functional dependencies, a simple bend test is used to measure stress relaxation for four types of commercial ceramic fibers for which direct tensile creep data are available. These fibers include both nonoxide (SCS-6, Nicalon) and oxide (PRD-166, FP) compositions. The results of the Bend Stress Relaxation (BSR) test not only confirm the stress, time, and temperature dependencies predicted by the model, but also allow measurement of model empirical parameters for the four fiber types. In addition, comparison of model tensile creep predictions based on the BSR test results with the literature data show good agreement, supporting both the predictive capability of the model and the use of the BSR text as a simple method for parameter determination for other fibers.

Dicarlo, James A.↗
NASA NTRS2003

High Temperature Permeability of Carbon Cloth Phenolic Composite

The carbon fiber phenolic resin composite material used for the RSRM nozzle insulator occasionally experiences problems during operation from pocketing or spalling-like erosion and lifting of plies into the char layer. This phenomenon can be better understood if the permeability of the material at elevated temperatures is well defined. This paper describes an experimental approach to determining high temperature permeability of the carbon phenolic material used as the RSRM nozzle liner material. Two different approaches were conducted independently using disk and bar type specimens with the designed permeability apparatus. The principle of the apparatus was to subject a test specimen to a high pressure differential and a heat supply and to monitor both the pressure and temperature variations resulting from gas penetration through the permeable wall between the two chambers. The bar types, especially designed to eliminate sealing difficulties at a high temperature environment, were directly exposed to real time temperature elevation from 22 C to 260 C during the test period. The disk types were pre-heat treated up to 300 C for 8 hours and cooled to room temperature before testing. Nonlinear variation of downstream pressure at a certain temperature range implied moisture release and matrix pyrolysis. Permeability was calculated using a semi-numerical model of quasi-steady state. The test results and the numerical model are discussed in the paper.

Park, O. Y.↗
NASA NTRS2003

Soot Nanostructure And Its Impact Upon The O2 Oxidation Rate

Studies of soot oxidation have ranged from in situ flame studies to shock tubes to flow reactors. Each of these systems possesses particular advantages and limitations related to temperature, time and chemical environments. Despite the aforementioned differences, these soot oxidation investigations share three striking features. First and foremost is the wide variation in the rates of oxidation. Reported oxidation rates vary by factors of +6 to - 20 relative to the Nagle Strickland-Constable (NSC) rate for graphite oxidation [3]. Rate variations are not surprising, as the temperatures, residence times, types of oxidants and methods of oxidation differ from study to study. Nevertheless, a valid explanation for rate differences of this magnitude has yet to be presented.

Wal, Randy L. Vander↗
DOE OSTI2024

Biofuel production from palm oil deoxygenation using nickel-molybdenum on zirconia catalyst using glycerol as a hydrogen donor

The growing demand for renewable energy has generated interest in biofuels as alternatives to fossil fuels. Second-generation biofuels, derived from deoxygenating fats and oils, have garnered a higher level of interest from industry and academia due to their potential for direct replacement of diesel and jet fuels. Palm oil, mostly cultivated in Thailand and composed of C16 and C18 fatty acids, is a primary feedstock sought for biofuel production. Palm oil deoxygenation contains several pathways that may or may not require hydrogen gas. This study aimed to produce biofuels in different fuel ranges, such as gasoline, jet fuel, and diesel, through palm oil deoxygenation using glycerol as a hydrogen source. Glycerol, a low-value byproduct, was used as a hydrogen donor, whereas nickel-molybdenum-supported catalysts were chosen for their high efficiency in deoxygenation and cost-effectiveness. The study investigated the impact of reaction time, temperature, and catalyst activation method on palm oil deoxygenation. Catalyst characterization methods, including XRD, SEM, TEM, XPS, FTIR, TGA, and nitrogen-sorption, were employed to understand the role of catalysts’ activity during palm oil upgrading. Findings indicated that alkane hydrocarbons are the major components in liquid products. The presence of excess hydrogen in post reaction gaseous phase proves the hydrogen donation capability of glycerol. Increased reaction time and temperature facilitated the removal of oxygen from palm oil. Nickel-molybdenum on zirconia activated by sulfidation demonstrated higher stability than by reduction activation.

09 BIOMASS FUELS↗
NASA NTRS2011

Remote Observations of Ion Temperatures in the Quiet Time Magnetosphere

Ion temperature analysis of the first energetic neutral atom images of the quiet -time, extended magnetosphere provides evidence of multiple regions of ion heating. This study confirms the existence of a dawn -dusk asymmetry in ion temperature predicted for quiescent magnetospheric conditions by Spence and Kivelson (1993) and demonstrates that it is an inherent magnetospheric feature.

Keesee, A. M.↗
NASA NTRS2001

The Vitrification and Determination of the Crystallization Time Scales of a Zr58.5Nb2.8Cu15.6Ni12.8Al10.3 Bulk Metallic Glass Forming Liquid

Zr58.5Nb2.8Cul5.6Nil2.8All0.3 is the first bulk glass forming liquid that does not contain beryllium to be vitrified by purely radiative cooling in the containerless electrostatic levitation process. The measured critical cooling rate is 1.75 K/s. The sluggish crystallization kinetics enable the determination of the time-temperature-transformation (TTT) diagram between the liquidus and the glass transition temperatures. At the nose of the TTT diagram, the shortest time to reach crystallization in an isothermal experiment is 32 seconds. In contrast to other bulk metallic glasses the scatter in the crystallization onset times are small at both high and low temperatures.

Hays, C. C.↗
NASA NTRS2006

Intra-seasonal Oscillations Inferred from SABER (TIMED) and MLS (UARS) Temperature Measurements

In the zonal mean meridional winds of the upper mesosphere, intra-seasonal oscillations with periods between 1 and 4 months have been inferred from UARS measurements and independently predicted with the Numerical Spectral Model WSM). The wind oscillations tend to be confined to low latitudes and appear to be driven, at least in part, by small-scale gravity waves propagating in the meridional direction. Winds across the equator should generate, due to dynamical heating and cooling, temperature oscillations with opposite phase in the two hemispheres. Investigating this phenomenon, we have analyzed SABER temperatures from TIMED in the altitude range between 55 and 95 km to delineate with an empirical model, the year-long variability of the migrating tides and zonal mean components. The inferred seasonal variations of the diurnal tide, characterized by amplitude maxima near equinox, are in substantial agreement with UARS observations and results from the NSM. For the zonal mean, the dominant seasonal variations in the SABER temperatures, with annual (12 months) and semiannual (6 months) periodicities, agree well with those derived from UARS measurements. The intra-seasonal variations with periods between 2 and 4 months have amplitudes close to 2 K, almost half as large as those for the dominant seasonal variations. Their amplitudes are in qualitative agreement with the corresponding values inferred from UARS during different years. The SABER and UARS temperature variations reveal pronounced hemispherical asymmetries, consistent with meridional wind oscillations across the equator. The phase of the semi-annual temperature oscillations from the NSM agrees with the observations from UARS and SABER. But the amplitudes are systematically smaller, which may indicate that planetary waves are more important than is allowed for in the model. For the shorter-period intra-seasonal variations, which can be generated by gravity wave drag, the model results are generally in better agreement with the observations.

Huang, F. T.↗
NASA NTRS1985

Mobile trace element contents in Jilin chondrite

A determination is conducted of ppm-ppt levels of Co, Se, Ga, Rb, Cs, Te, Bi, Ag, In, Tl, Zn and Cd (arranged empirically in order of increasing mobility at 1000 C) by radiochemical neutron activation analysis in eight Jilin samples of known Ar-40 content and a large vein from one of these. The trace element contents of the vein do not differ markedly from those of Jilin whole-rock samples. Only Rb correlates with Ar-40, possibly due to chance. All elements but Cd are present at levels similar to thdse in H4-6 chondrites with long K/Ar age (i.e., presumably mildly shocked). These levels are low relative to those in analogous L4-6 chondrites suggesting that H chondrites formed and/or evolved under higher pre-shock temperatures than did mildly shocked L chondrites. Time-temperature conditions during shock-loading of Jilin parent material were mild relative to those in strongly shocked L chondrites, being sufficient at most only to mobilize Cd.

Sakuragi, Y.↗
NASA NTRS1985

Defects in silicon effect on device performance and relationship to crystal growth conditions

A relationship between material defects in silicon and the performance of electronic devices will be described. A role which oxygen and carbon in silicon play during the defects generation process will be discussed. The electronic properties of silicon are a strong function of the oxygen state in the silicon. This state controls mechanical properties of silicon efficiency for internal gettering and formation of defects in the device's active area. In addition, to temperature, time, ambience, and the cooling/heating rates of high temperature treatments, the oxygen state is a function of the crystal growth process. The incorporation of carbon and oxygen into silicon crystal is controlled by geometry and rotation rates applied to crystal and crucible during crystal growths. Also, formation of nucleation centers for oxygen precipitation is influenced by the growth process, although there is still a controversy which parameters play a major role. All these factors will be reviewed with special emphasis on areas which are still ambiguous and controversial.

Jastrzebski, L.↗
NASA NTRS2005

Semiautomated, Reproducible Batch Processing of Soy

A computer-controlled apparatus processes batches of soybeans into one or more of a variety of food products, under conditions that can be chosen by the user and reproduced from batch to batch. Examples of products include soy milk, tofu, okara (an insoluble protein and fiber byproduct of soy milk), and whey. Most processing steps take place without intervention by the user. This apparatus was developed for use in research on processing of soy. It is also a prototype of other soy-processing apparatuses for research, industrial, and home use. Prior soy-processing equipment includes household devices that automatically produce soy milk but do not automatically produce tofu. The designs of prior soy-processing equipment require users to manually transfer intermediate solid soy products and to press them manually and, hence, under conditions that are not consistent from batch to batch. Prior designs do not afford choices of processing conditions: Users cannot use previously developed soy-processing equipment to investigate the effects of variations of techniques used to produce soy milk (e.g., cold grinding, hot grinding, and pre-cook blanching) and of such process parameters as cooking times and temperatures, grinding times, soaking times and temperatures, rinsing conditions, and sizes of particles generated by grinding. In contrast, the present apparatus is amenable to such investigations. The apparatus (see figure) includes a processing tank and a jacketed holding or coagulation tank. The processing tank can be capped by either of two different heads and can contain either of two different insertable mesh baskets. The first head includes a grinding blade and heating elements. The second head includes an automated press piston. One mesh basket, designated the okara basket, has oblong holes with a size equivalent to about 40 mesh [40 openings per inch (.16 openings per centimeter)]. The second mesh basket, designated the tofu basket, has holes of 70 mesh [70 openings per inch (.28 openings per centimeter)] and is used in conjunction with the press-piston head. Supporting equipment includes a soy-milk heat exchanger for maintaining selected coagulation temperatures, a filter system for separating okara from other particulate matter and from soy milk, two pumps, and various thermocouples, flowmeters, level indicators, pressure sensors, valves, tubes, and sample ports

Thoerne, Mary↗
NASA NTRS1993

Stress-rupture behavior of small diameter polycrystalline alumina fibers

Continuous length polycrystalline alumina fibers are candidates as reinforcement in high temperature composite materials. Interest therefore exists in characterizing the thermomechanical behavior of these materials, obtaining possible insights into underlying mechanisms, and understanding fiber performance under long term use. Results are reported on the time-temperature dependent strength behavior of Nextel 610 and Fiber FP alumina fibers with grain sizes of 100 and 300 nm, respectively. Below 1000 C and 100 hours, Nextel 610 with the smaller grain size had a greater fast fracture and rupture strength than Fiber FP. The time exponents for stress-rupture of these fibers were found to decrease from approximately 13 at 900 C to below 3 near 1050 C, suggesting a transition from slow crack growth to creep rupture as the controlling fracture mechanism. For both fiber types, an effective activation energy of 690 kJ/mol was measured for rupture. This allowed stress-rupture predictions to be made for extended times at use temperatures below 1000 C.

Yun, Hee Mann↗
NASA NTRS2000

Constituent-Based Life Models Being Developed for SiC/SiC Composites

For the successful utilization of ceramic matrix composites (CMC) as hot-section components in advanced aeropropulsion engines, the CMC constituents will need to be tailored and optimized to meet all the critical property demands of each component. Under the High-Speed Research (HSR) and Advanced High-Temperature Engine Materials Technology (HITEMP) Programs, the NASA Glenn Research Center at Lewis Field initiated research to develop mechanistic models for key CMC thermostructural properties. These models would describe the effects of different constituent factors (composition, geometry, and volume fraction) and of potential application conditions (stress, time, temperature, and environment) on these properties. Particular focus was placed on both analytical and numerical modeling of state-of-the-art SiC/SiC composites where the primary load-bearing constituents are stoichiometric SiC fibers in a complex multiphase SiC matrix produced by chemical vapor infiltration and melt infiltration. Recent studies have resulted in computer-based numerical models for the elastic modulus, thermal expansion, and thermal conductivity properties of the SiC/SiC system. Additional studies have generated analytical and empirical models for the time dependence of composite rupture strength at temperatures above 2200 F (1200 C), where CMC's have an important thermostructural advantage over current nickel-based superalloys. These life models utilize thermal activation theory and fiber stress-rupture results measured at Glenn to generate Larson-Miller (L M) plots of fiber rupture strength versus q, a single time- and temperature-dependent parameter. Assuming a worse case in which the SiC matrix is cracked, rupture is then controlled by the time-dependent fracture characteristics of the fiber bundles bridging the matrix cracks. With this as the controlling mechanism, one can then use simple composite theory and the fiber L M plots to predict CMC rupture strength versus the q parameter. The dashed line shows the predicted rupture strength of a SiC/SiC composite that is reinforced by a state-of-the-art stoichiometric SiC fiber. For the q parameter, time is in hours and temperature in degrees kelvin. To generate these predictions, a two-dimensional 0 /90 composite with approximately 16 percent fiber in the applied stress direction and an air test environment were assumed. As such, it is possible to compare the model predictions against limited stress-rupture data for this CMC as shown by the data points. The good agreement confirms the rupture model at least for the selected CMC and test conditions. Thus for this particular SiC/SiC composite, one can estimate a 1000-hr rupture strength of approximately 12 ksi at 2400 F (T = 1588 K and q = 39 700 K). At lower CMC application stresses, the SiC matrix is typically uncracked, so both the fiber and matrix constituents share the composite load. In this case, CMC rupture is controlled by the constituent with the longest rupture time based on the creep rate of the composite. Measured Monkman-Grant plots of rupture time versus creep rate for the two SiC constituents have been used to develop CMC life models for this important application condition. NASA and DOD are currently using this information to establish application and material goals for more advanced CMC's that can be used at even higher temperatures.

DiCarlo, James A.↗
NASA NTRS1983

A non-linear viscoelastic characterisation method for matrix resin composites

Lifetime prediction of matrix resin composites is an important problem because of their viscoelastic character. If the Time-Temperature-Stress-Superposition principle is valid, results from short time tests at high stress levels can give the necessary information for the prediction of long time behavior. At such stress levels the viscoelastic response is nonlinear. In this contribution the basis of a computer routine is presented starting from a thermodynamical formulation given by Schapery. This method gives in an accurate way the different material parameters in that nonlinear constitutive equation for different stresses and temperatures.

Hiel, C. C.↗
NASA NTRS1975

Characterization of BCL strain gages for use to 1366 K (2000 F)

Strain gage behavior under static and transient heating conditions at various strain rates and high temperatures (1366 K(2000 F) was studied. Optimum time-temperature parameters were developed for preconditioning (prestabilizing) the gages. A limited study was carried out to determine the extent of spalling of platinum cladding during fabrication of platinum-clad wire strain gages. Further verification was also carried out on the convergence and repeatability of the apparent strain characteristics of the gage under heating and cooling cycles. The significance of these characteristics from the standpoint of enhancing measurement accuracy is also discussed. It was concluded that the gage should perform satisfactorily to temperatures approaching 1366 K (2000 F).

Lemcoe, M. M.↗
NASA NTRS1975

The thermal system for an environmental chamber

The design of a cooling and heating system for obtaining temperatures in the range of -60 C to +120 C on a thermal shroud is described. The proposed temperature control uses mechanical refrigeration with Freon-22 as the primary refrigerant, methanol as the secondary coolant for low temperatures, and electrically heated ethylene glycol for high temperatures. The system is designed to give the following time-temperature characteristics: lowering the temperature from +30 C to -60 C in 1.5 hours; maintaining the temperature at -60 C for a period of 6 hours; heating from -60 C to +120 C in 3 hours; maintaining the temperature at +120 C for a period of 6 hours; and cooling from +120 C in 1.5 hours. A description of the system and its operation are given.

Srinivasan, K.↗
NASA NTRS1982

Preliminary Analysis of STS-3 Entry Heat-Transfer Data for the Orbiter Windward Centerline

A preliminary analysis of heat transfer data on the space shuttle orbiter windward centerline for the STS-3 mission entry is presented. Temperature-time history plots for each measurement location and tabulated wall temperature and convective heating rate data at 21 selected trajectory points are included. The STS-3 flight data are also compared with predictions by two approximation methods for computing convective heat transfer rates in equilibrium air.

Throckmorton, D. A.↗
NASA NTRS1990

Ignition characteristics of the nickel-based alloy UNS N07001 in pressurized oxygen

The development of ignition and combustion in pressurized oxygen atmospheres was studied for the nickel-based alloy UNS N07001. Ignition of the alloy was achieved by heating the top surface of a cylindrical specimen with a continuous-wave CO2 laser. Two heating procedures were used. In the first, laser power was adjusted to maintain an approximately linear increase in surface temperature. In the second, laser power was periodically increased until autoheating (self-heating) was established. It was found that the alloy would autoheat to combustion from temperatures below the solidus temperature. In addition, the alloy had a tendency to develop combustion zones (hot spots) at high oxygen pressures when the incremental (step) heating test mode was used. Unique points on the temperature-time curves that describe certain events are defined and the temperatures at which these events occur are given for the oxygen pressure range of 1.72 to 13.8 MPa (250 to 2000 psia).

Bransford, J. W.↗
NASA NTRS2007

Infrared Camera Characterization of Bi-Propellant Reaction Control Engines during Auxiliary Propulsion Systems Tests at NASA's White Sands Test Facility in Las Cruces, New Mexico

This paper describes the application of a FUR Systems A40M infrared (IR) digital camera for thermal monitoring of a Liquid Oxygen (LOX) and Ethanol bi-propellant Reaction Control Engine (RCE) during Auxiliary Propulsion System (APS) testing at the National Aeronautics & Space Administration's (NASA) White Sands Test Facility (WSTF) near Las Cruces, New Mexico. Typically, NASA has relied mostly on the use of ThermoCouples (TC) for this type of thermal monitoring due to the variability of constraints required to accurately map rapidly changing temperatures from ambient to glowing hot chamber material. Obtaining accurate real-time temperatures in the JR spectrum is made even more elusive by the changing emissivity of the chamber material as it begins to glow. The parameters evaluated prior to APS testing included: (1) remote operation of the A40M camera using fiber optic Firewire signal sender and receiver units; (2) operation of the camera inside a Pelco explosion proof enclosure with a germanium window; (3) remote analog signal display for real-time monitoring; (4) remote digital data acquisition of the A40M's sensor information using FUR's ThermaCAM Researcher Pro 2.8 software; and (5) overall reliability of the system. An initial characterization report was prepared after the A40M characterization tests at Marshall Space Flight Center (MSFC) to document controlled heat source comparisons to calibrated TCs. Summary IR digital data recorded from WSTF's APS testing is included within this document along with findings, lessons learned, and recommendations for further usage as a monitoring tool for the development of rocket engines.

Holleman, Elizabeth↗