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Nitrogen doping leads to biradicloid character and subsequent UV red shift.
Cu-Exchanged zeolites are promising materials for the selective conversion of methane to methanol. Their activity is attributed to the presence of small Cu-oxo and Cu-hydroxy clusters, but the nature of active centers in various zeolite structures is still under debate. In this contribution, we combine time dependent density functional theory with spin–orbit coupling to predict the optical spectra of various Cu monomers and dimers in SSZ-13. As a result, we furthermore compare theoretical results to experimental measurements and find that the presence of Cu-hydroxy dimers and Cu monomers could potentially explain the experimentally observed UV-vis-NIR spectra.
Intermolecular charge-transfer excitons play a central role in determining the performance of organic solar cells as their voltage-dependent formation, dissociation, and recombination dynamics contribute to photocurrent generation, radiative/nonradiative voltage losses, and photovoltaic fill factor. Here, we explore the properties of brightly-emitting wide energy gap (>2 eV) charge transfer excitons by measuring the voltage-dependent photoluminescence, photocurrent, and ultrafast pump–probe transient absorption spectra of organic solar cells employing five UV-absorbing donor molecules that differ only by the length of the oligophenylene or acene group at their core. We find that organic solar cells with a strong correlation between their voltage-dependent photocurrent and charge-transfer exciton photoluminescence have low photovoltaic fill factors as they require voltage to facilitate efficient charge-transfer exciton dissociation. In contrast, solar cells that are efficient can readily generate charges without an applied field and have a separate population of tightly-bound charge-transfer excitons that are responsible for emission. Furthermore, considering that the sum of all excitation loss rates (i.e., recombination and charge extraction) must be equal to the excitation generation rate in the steady state, these voltage-dependent data allow us to solve for the voltage-dependent fate of all excitations in the solar cells and estimate upper and lower bounds for geminate and non-geminate recombination, respectively.
We perform time-resolved ionization spectroscopy measurements of the excited state dynamics of CH 2 I 2 and CH 2 IBr following photoexcitation in the deep UV. The fragment ions produced by ionization with a vacuum-ultraviolet probe pulse are measured with velocity map imaging, and the momentum resolved yields are compared with trajectory surface hopping calculations of the measurement observable. Together with recent time-resolved photoelectron spectroscopy measurements of the same dynamics, these results provide a detailed picture of the coupled electronic and nuclear dynamics involved. Overall, our measurements highlight the non-adiabatic coupling between electronic states, which leads to notable differences in the dissociation dynamics for the two molecules.
A transmitted-beam diagnostic (P9TBD) was developed as part of a new experimental platform used to study laser–plasma interactions on OMEGA. Located in the opposing port to the wavelength-tunable (350 nm to 353 nm) UV drive beam, the P9TBD characterizes the beam after it propagates through an undersense plasma. The instrument consists of a large-aperture window that allows light to exit the target chamber and project onto a thin sheet of semi-transparent diffuser material. Light transmitted through the diffuser is recorded using a time-integrated camera and a fiber-optically coupled streaked spectrometer, providing measurements of the energy, power, fluence, polarization, and spectrum of the transmitted beam. Here, the diagnostic enables direct observation of a variety of cross-beam energy transfer phenomena, such as wavelength detuning, polarization effects, and gain saturation.
Ultraviolet Raman scattering is a promising diagnostic for temperature measurements relevant to dynamic compression experiments, where improved signal strength and reduced background are critical. In this work, we experimentally validate Raman thermometry at 266 nm using crystalline quartz heated through the α to β phase transition in a tube furnace. Quartz provides a useful benchmark because of its well-characterized transition temperature near 846 K at ambient pressure. Temperatures inferred from the Stokes to anti-Stokes intensity ratio are compared with thermocouple measurements and with the observed phase transition. Single-shot Raman temperatures track the thermocouple closely, with an empirical single-shot scatter of approximately ±15 K under the present conditions. Temporal averaging reduces shot-to-shot scatter and improves agreement between the Raman temperatures and thermocouple readings to within approximately 8 K, while the transition is identified within 5 K of the accepted value. Measurements are performed using the fourth harmonic of a nanosecond pulsed Nd:YAG laser at 266 nm. The shorter excitation wavelength provides enhanced Raman scattering efficiency and reduced visible background relative to conventional visible excitation. Comparison with 532 nm Raman measurements acquired in the same experimental geometry demonstrates substantially improved signal-to-noise ratio for the UV configuration. These results establish 266 nm Raman thermometry as a reliable and accurate temperature diagnostic under controlled heating conditions and provide a quantitative benchmark for future application in dynamic compression and shock physics experiments.
ABSTRACT Risaliti and Lusso have compiled X-ray and UV flux measurements of 1598 quasars (QSOs) in the redshift range 0.036 ≤ z ≤ 5.1003, part of which, z ∼ 2.4 − 5.1, is largely cosmologically unprobed. In this paper we use these QSO measurements, alone and in conjunction with baryon acoustic oscillation (BAO) and Hubble parameter [H(z)] measurements, to constrain cosmological parameters in six different cosmological models, each with two different Hubble constant priors. In most of these models, given the larger uncertainties, the QSO cosmological parameter constraints are mostly consistent with those from the BAO + H(z) data. A somewhat significant exception is the non-relativistic matter density parameter Ωm0 where QSO data favour Ωm0 ∼ 0.5 − 0.6 in most models. As a result, in joint analyses of QSO data with H(z) + BAO data the 1D Ωm0 distributions shift slightly towards larger values. A joint analysis of the QSO + BAO + H(z) data is consistent with the current standard model, spatially-flat ΛCDM, but mildly favours closed spatial hypersurfaces and dynamical dark energy. Since the higher Ωm0 values favoured by QSO data appear to be associated with the z ∼ 2 − 5 part of these data, and conflict somewhat with strong indications for Ωm0 ∼ 0.3 from most z < 2.5 data as well as from the cosmic microwave background anisotropy data at z ∼ 1100, in most models, the larger QSO data Ωm0 is possibly more indicative of an issue with the z ∼ 2 − 5 QSO data than of an inadequacy of the standard flat ΛCDM model.
Here, we present observations of ASASSN-19dj, a nearby tidal disruption event (TDE) discovered in the post-starburst galaxy KUG 0810+227 by the All-Sky Automated Survey for Supernovae (ASAS-SN) at a distance of d ≃ 98 Mpc. We observed ASASSN-19dj from -21 to 392 d relative to peak ultraviolet (UV)/optical emission using high-cadence, multiwavelength spectroscopy and photometry. From the ASAS-SN g-band data, we determine that the TDE began to brighten on 2019 February 6.8 and for the first 16 d the rise was consistent with a flux ∝t 2 power law. ASASSN-19dj peaked in the UV/optical on 2019 March 6.5 (MJD = 58548.5) at a bolometric luminosity of L = (6.2 ± 0.2) × 10 44 erg s -1 . Initially remaining roughly constant in X-rays and slowly fading in the UV/optical, the X-ray flux increased by over an order of magnitude ~225 d after peak, resulting from the expansion of the X-ray emitting region. The late-time X-ray emission is well fitted by a blackbody with an effective radius of ~1 × 10 12 cm and a temperature of ~6 × 10 5 K. The X-ray hardness ratio becomes softer after brightening and then returns to a harder state as the X-rays fade. Analysis of Catalina Real-Time Transient Survey images reveals a nuclear outburst roughly 14.5 yr earlier with a smooth decline and a luminosity of L V ≥ 1.4 × 10 43 erg s -1 , although the nature of the flare is unknown. ASASSN-19dj occurred in the most extreme post-starburst galaxy yet to host a TDE, with Lick Hδ A = 7.67 ± 0.17 Å.
ABSTRACT We present observations of SN 2020fqv, a Virgo-cluster type II core-collapse supernova (CCSN) with a high temporal resolution light curve from the Transiting Exoplanet Survey Satellite (TESS) covering the time of explosion; ultraviolet (UV) spectroscopy from the Hubble Space Telescope (HST) starting 3.3 d post-explosion; ground-based spectroscopic observations starting 1.1 d post-explosion; along with extensive photometric observations. Massive stars have complicated mass-loss histories leading up to their death as CCSNe, creating circumstellar medium (CSM) with which the SNe interact. Observations during the first few days post-explosion can provide important information about the mass-loss rate during the late stages of stellar evolution. Model fits to the quasi-bolometric light curve of SN 2020fqv reveal 0.23 M⊙ of CSM confined within 1450 R⊙ (1014 cm) from its progenitor star. Early spectra (<4 d post-explosion), both from HST and ground-based observatories, show emission features from high-ionization metal species from the outer, optically thin part of this CSM. We find that the CSM is consistent with an eruption caused by the injection of ∼5 × 1046 erg into the stellar envelope ∼300 d pre-explosion, potentially from a nuclear burning instability at the onset of oxygen burning. Light-curve fitting, nebular spectroscopy, and pre-explosion HST imaging consistently point to a red supergiant (RSG) progenitor with $M_{\rm ZAMS}\approx 13.5\!-\!15 \, \mathrm{M}_{\odot }$, typical for SN II progenitor stars. This finding demonstrates that a typical RSG, like the progenitor of SN 2020fqv, has a complicated mass-loss history immediately before core collapse.
Portal matter (PM), having both Standard Model (SM) and dark sector charges, can induce kinetic mixing between the 𝑈(1) 𝐷 dark photon and the SM gauge fields at the 1-loop level offering an attractive mechanism by which light (≲1 GeV) thermal dark matter (DM) can interact with visible matter and obtain its observed relic density. In doing so, if the DM is fermionic, the CMB and other astrophysical observations inform us that it must be Majorana/pseudo-Dirac in nature to avoid velocity/temperature-independent 𝑠-wave annihilation to SM final states. How does this idea fit into a more UV-complete picture also including the SM interactions? There are some reasons to believe that at least a first step along this path may not lie too far away in energy due to the renormalization group equations running of the dark gauge coupling, which for a significant range of parameters, becomes nonperturbative at/before the ∼10’s of TeV energy range. This implies that 𝑈(1) 𝐷 must become embedded in an asymptotically free, non-Abelian group, 𝐺 𝐷 , before this can occur. The breaking of this larger group then produces the masses for the PM and the additional gauge fields associated with 𝐺 𝐷 then can lead to new interactions between the SM and the dark sector. Following several bottom-up approaches, we have examined a set of distinctive and testable phenomenological features associated with this general setup, based upon a number of simplifying assumptions. Clearly, it behooves us to explore the impact of these specific assumptions on these predictions for the array of possible experimental tests of this class of models. In most past analyses it has been assumed that DM is a vectorlike, complex singlet under the group 𝐺 𝐷 . If this assumption is relaxed, the dark sector must be augmented by additional fermion(s) and the associated scalar fields needed to break the gauge symmetries while generating the needed Majorana-like mass terms for the DM. In this paper, we analyze the simplest extension of this kind wherein the DM lies in a vectorlike doublet of 𝐺 𝐷 , which we take to have the structure 𝑆𝑈(2) 𝐼 ×𝑈(1) 𝑌 𝐼 as in earlier work, leading to new phenomenological implications. We find, for example, that given the current LHC search constraints on the masses of heavy gauge bosons, the production of these new dark states with large rates is unlikely to occur at colliders unless they are produced singly in 𝑔𝑔 fusion or their pair production cross sections are resonantly enhanced. Here, we also find that an additional mechanism arises to generate hierarchal neutrino masses in such a setup.
There are many photovoltaic (PV) applications where lighter weight and/or bendable PV power would be beneficial. This includes the curved surfaces of buildings, buildings with weight limitations, boats, automobiles, or other portable applications. In many of these cases, the bending will be only a single occurrence at installation or the amount of bending, even if repeated, is not dramatic. This allows for crystalline silicon modules to be used. For flexible applications, the dominant material for the frontsheet is polyethylene tetrafluoroethylene (PETFE). As a fluoropolymer it resists soiling, is UV stable, and PETFE is a more mechanically durable fluoropolymer. However, in the interests of keeping costs down, less expensive alternative polymers are desirable. In this study, highly accelerated ultraviolet light and heat stresses are applied to candidate materials and the degradation kinetics are determined to provide information to evaluate their suitability for use in a PV application.
Fast, non-destructive, outdoor-compatible methods for photovoltaic module characterization are essential for monitoring module quality without disrupting energy production. UV-fluorescence (UVF) imaging of the encapsulant layer can be used for crack detection in the field. We show that UVF patterns vary widely between modules and types of applied stress. We propose that combining accelerated stress testing (e.g. thermal cycling and damp heat) with field investigations can help build understanding of different types of UVF, which are formed and subsequently quenched at varying rates. Ultimately, such understanding could enable estimating when cracks were formed.
The effects of a pulsed, focused, deep-UV (4.66 eV) laser on wide and ultra-wide bandgap semiconductors were investigated with photoluminescence (PL) and Raman spectroscopy. Three semiconductor single crystals were studied: silicon carbide (6H-SiC), gallium nitride (GaN), and gallium oxide (β-Ga 2 O 3 ). Atomic emission lines from neutral Ga or Si were observed during the laser-damage process. For all three semiconductors, PL mapping (3.49 eV laser excitation) of the damaged material revealed visible emission bands in the 2.6–2.8 eV range, attributed to point defects. Raman spectra (2.33 eV excitation) showed a reduction in the Raman peak intensities in the damaged region, along with weak PL bands around 1.9–2.1 eV.
We present high-resolution dual-comb spectroscopy across two broad UV spectral regions spanning 372–410 nm and 325–342 nm. This is achieved by generating sixth and seventh harmonics, respectively, from a low-noise 2.35 µm Cr:ZnS dual-comb laser system. The sixth harmonic band contains approximately 1,000,000 spectrally resolved comb lines, while the seventh harmonic band—around 550,000 comb lines. With the line spacing of 80 MHz, this corresponds to a resolving power of up to 10 million, offering remarkable spectral resolution.
The UV photodissociation dynamics of 2-iodothiophene are monitored by an XUV probe pulse that promotes iodine 4d core-to-valence transitions. Absorption changes from molecular iodine species conclusively show that dissociation requires up to ~1 picosecond.
This report analyzes the independently tested performance of eight germicidal ultraviolet (GUV) upper-room luminaires marketed for use in occupied spaces and purchased between March and June 2023. Three of the luminaires used UV-emitting LEDs, and the remaining five luminaires used low-pressure mercury (LPM) lamps. Product testing covered radiometric and electrical performance for each luminaire. Initial performance was measured for all eight products, and four were additionally measured after 100 h and 500 h of operation. Measured performance was compared against manufacturer or vendor claims. Specifiers and buyers of GUV products need accurate performance claims and data to deploy GUV technology safely and effectively. As with the CALiPER GUV Round 1 report, this CALiPER GUV Round 2 report demonstrates that manufacturers and vendors need significant education and training to accurately test and report the performance of their GUV products. Further development of industry consensus standards and guidelines may address testing limitations and improve test methods, product performance, and the accuracy of performance claims.
Chemical and thermal characterization (FTIR-ATR, Soxhlet extraction, DSC) of polymeric encapsulants (EVA, POE, EPE) aged under thermal accelerated aging, without the presence of a UV source
Chemical and thermal characterization (FTIR-ATR, Soxhlet extraction, DSC) of polymeric encapsulants (EVA, POE, EPE) aged under accelerated aging conditions containing an UV source.