SEARCH · Search NASA

Results for “VAPORIZATION”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 163 records · Page 9

All sources NASA NTRS DOE OSTI

NASA NTRS2015

Thermodynamics and Kinetics of Silicate Vaporization

Silicates are a common class of materials that are often exposed to high temperatures. The behavior of these materials needs to be understood for applications as high temperature coatings in material science as well as the constituents of lava for geological considerations. The vaporization behavior of these materials is an important aspect of their high temperature behavior and it also provides fundamental thermodynamic data. The application of Knudsen effusion mass spectrometry (KEMS) to silicates is discussed. There are several special considerations for silicates. The first is selection of an appropriate cell material, which is either nearly inert or has well-understood interactions with the silicate. The second consideration is proper measurement of the low vapor pressures. This can be circumvented by using a reducing agent to boost the vapor pressure without changing the solid composition or by working at very high temperatures. The third consideration deals with kinetic barriers to vaporization. The measurement of these barriers, as encompassed in a vaporization coefficient, is discussed. Current measured data of rare earth silicates for high temperature coating applications are discussed. In addition, data on magnesium-iron-silicates (olivine) are presented and discussed.

thermodynamics↗

NASA NTRS2021

Near-Global Variability of Stratospheric Water Vapor Observed by SAGE III/ISS

The Stratospheric Aerosol and Gas Experiment III instrument on the International Space Station (SAGE III/ISS) has been making high quality solar occultation measurements of stratospheric water vapor since June 2017. Here we evaluate the large-scale geophysical variability of the SAGE III/ISS water vapor measurements for the first 3 years of observations (2017–2020) as part of data validation for retrieval version 5.1 (v5.1). Detailed comparisons of SAGE III/ISS v5.1 with the Aura Microwave Limb Sounder (MLS) version 5 retrievals show overall excellent agreement in terms of seasonal mean structure and large-scale variability. SAGE III/ISS data capture the well-known seasonal variations in water vapor including the vertically propagating “tape recorder” in the tropics and lower stratospheric maxima linked to the NH summer monsoons. The high vertical resolution (∼2 km) measurements from SAGE III/ISS demonstrate contributions of the monsoons to the wet phase of “tape recorder” during the Northern Hemisphere (NH) summer. Interannual variations over the short data record are also consistent between SAGE III/ISS and MLS in the stratosphere between 16 and 30 km. We furthermore evaluate large-scale variations in relative humidity (RH) derived from the high vertical resolution SAGE III/ISS water vapor measurements, highlighting the detailed seasonal behavior and links to thermal structure near the tropical tropopause. Spatial distributions of RH at the cold point tropopause (CPT) show a close link between high RH and the minimum CPT temperature in both the NH winter and summer, consistent with temperature control of water vapor near the tropopause.

water vapor↗

NASA NTRSDate not supplied

Vapor Growth of ZnSe-based Compound Semiconductors in Low Gravity environment on International Space Station

Six low-gravity experiments of crystal growth of ZnSe-based compound semiconductors by physical vapor transport (PVT) are scheduled to be processed inside Low Gradient Furnace (LGF) on Materials Science Research Rack (MSRR) in Material Science Laboratory (MSL) on International Space Station (ISS) starting from February 27th, 2023. The flight samples consist of three unseeded growths of ZnSe, Cr-doped ZnSe and ZnSeTe as well as growth of ZnSe on top of three single crystal ZnSe seeds with orientation of (100), (110) and (111). The main scientific objective of the flight experiments is to establish the effects of gravity-driven fluid flows on Earth to (i) the non-uniform incorporation of impurities and defects and (ii) the deviation from stoichiometry observed in the grown crystals caused by growth interface fluctuations and evolution as the results of buoyancy-driven convection and irregular fluid-flows. The investigation will also evaluate the effects of gravity on the PVT process by examining (i) the growth kinetics on various seed orientations, (ii) the dopant segregation and distribution in the Cr doped ZnSe, and (iii) the compositional segregation and distribution in the ternary ZnSeTe crystal grown by PVT. Additionally, from X-ray diffraction/topography and by measuring the density and distribution of various crystalline defects it will assess the self-induced strain effects developed during processing at elevated temperatures caused by the weight of the crystals. During the ground-based preparations, the following tasks have been accomplished: • Establish the thermodynamic properties of the ZnSe binary and related ternary systems by measuring the partial pressures of the vapor phase coexisting with the condensed phases and perform phase diagram calculations for comparison. • Evaluate the effects of gravity-driven convection in the growth process by performing experiments under various vapor transport orientations relative to gravity vector, i.e., horizontal, vertically stabilized and destabilized configurations. • Establish a quantitative correlation between growth parameters and the characteristics and properties of the grown crystals by characterizing the crystals using a variety of techniques. • Evaluate the fundamentals of the current theories on vapor transport and crystal growth kinetics by performing in-situ and real-time monitoring techniques during growth. • Develop a one-dimensional diffusion limited theory of mass transport and two- and three-dimensional numerical simulations of both mass transport and heat transfer and thus establish the microgravity requirements for the flight experiments and to predict the characteristics of the grown crystals such as the solid-vapor interface shapes… etc. and establish a fundamental understanding of the crystal growth process from the comparison with experimental results.

ZnSe↗

NASA NTRS2023

Stratospheric Water Vapor Affecting Atmospheric Circulation

Water vapor plays an important role in many aspects of the climate system, by affecting radiation, cloud formation, atmospheric chemistry and dynamics. Even the low stratospheric water vapor content provides an important climate feedback, but current climate models show a substantial moist bias in the lowermost stratosphere. Here we report crucial sensitivity of the atmospheric circulation in the stratosphere and troposphere to the abundance of water vapor in the lowermost stratosphere. We show from a mechanistic climate model experiment and inter-model variability that lowermost stratospheric water vapor decreases local temperatures, and thereby causes an upward and poleward shift of subtropical jets, a strengthening of the stratospheric circulation, a poleward shift of the tropospheric eddy-driven jet and regional climate impacts. The mechanistic model experiment in combination with atmospheric observations further shows that the prevailing moist bias in current models is likely caused by the transport scheme, and can be alleviated by employing a less diffusive Lagrangian scheme. The related effects on atmospheric circulation are of similar magnitude as climate change effects. Hence, lowermost stratospheric water vapor exerts a first order effect on atmospheric circulation and improving its representation in models offers promising prospects for future research.

stratosphere↗

NASA NTRS2025

Sealing Europa’s Vents By Vapor Deposition: An Order-of-Magnitude Study

Fractures and vents in the ice crust of Europa, exposing the sub-surface ocean or liquid-water inclusions to the vacuum, might be responsible for the generation of planetary-scale water-vapor plumes. During its passage through the ice, the plume vapor is expected to partially condense on the cold ice walls. Together with other effects (water spillage, compression forces, etc.) this mechanism likely contributes to sealing the vent. In this work, we develop a lumped-parameter model to analyze the sealing timescales associated to water-vapor deposition alone. Neglecting all other possible mechanisms, we find shutting-off times roughly compatible with the 7-hour plume observed in 2012 by the Hubble Space Telescope, suggesting that vapor deposition might have played a major role in sealing the vent. A map of sealing times vs. plume density, mass flow rate and aperture areas is given. Plume quantities from the literature are analyzed and compared to our results. For a given plume density/mass flow rate, small apertures would be sealed quickly by vapor deposition and are thus incompatible with observations.

Europa↗

NASA NTRS1971

Potassium Rankine cycle vapor chamber (heat pipe) radiator study

A structurally integrated vapor chamber fin (heat pipe) radiator is defined and evaluated as a potential candidate for rejecting waste heat from the potassium Rankine cycle powerplant. Several vapor chamber fin geometries, using stainless steel construction, are evaluated and an optimum is selected. A comparison is made with an operationally equivalent conduction fin radiator. Both radiators employ NaK-78 in the primary coolant loop. In addition, the Vapor Chamber Fin (VCF) radiator utilizes sodium in the vapor chambers. Preliminary designs are developed for the conduction fin and VCF concepts. Performance tests on a single vapor chamber were conducted to verify the VCF design. A comparison shows the conduction fin radiator easier to fabricate, but heavier in weight, particularly as meteoroid protection requirements become more stringent. While the analysis was performed assuming the potassium Rankine cycle powerplant, the results are equally applicable to any system radiating heat to space in the 900 to 1400 F temperature range.

Gerrels, E. E.↗

NASA NTRS1972

Vaporization characteristics of carbon heat shields under radiative heating.

Study of the vaporization characteristics of samples of ATJ graphite, a material that has been considered for use on a Jovian probe. These samples were subjected to radiative heating loads of approximately 2 kW/sq cm in argon atmospheres of pressures from 0.00046 to 1 atm. Surface temperatures, mass loss rates, and spatially resolved emission spectral data were recorded. These data are analyzed to determine carbon vapor pressure as a function of temperature and are compared with current models for the vapor pressure of carbon. The effects of finite vaporization (i.e., nonequilibrium) rates are considered and compared with experiment. Estimates of the heat of vaporization from an energy balance are also presented.

Davy, W. C.↗

NASA NTRS1972

Vapor chamber fin radiator study for the potassium Rankine cycle.

Gerrels, E. E.↗

NASA NTRS1976

Vaporization of graphite in the temperature range of 4000 to 4500 K

The vaporization of graphite under intense laser radiation is considered both theoretically and experimentally. Under intense radiation, the mass-loss rate can be high enough to cause the flow in the laser plume to be supersonic. It is shown that under these conditions the vaporization process is coupled to the plume gasdynamics and the mass-loss rate for graphite is 62% of the free vaporization rate. Experimental results are presented for surface temperatures from 3985 to 4555 K and mass-loss rates from 0.56 to 27.0 g per sq cm sec. The results are used to determine the vapor pressure of graphite in a pressure range of 2 to 11 atm, and the values are shown to be in agreement with the JANAF vapor pressure curve.

Lundell, J. H.↗

NASA NTRS1979

Effect of degree of fuel vaporization upon emissions for a premixed prevaporized combustion system

An experimental and analytical study of the combustion of partially vaporized fuelair mixtures was performed to assess the impact of the degree of fuel vaporization upon emissions for a premixing-prevaporizing flametube combustor. Data collected show near linear increases in nitrogen oxide emissions with decreasing vaporization at equivalence ratios of 0.6. For equivalence ratio of 0.72, the degree of vaporization had very little impact on nitrogen oxide emissions. A simple mechanism which accounts for the combustion of liquid droplets in partially vaporized mixtures was found to agree with the measured results with fair accuracy with respect to both trends and magnitudes.

Cooper, L. P.↗

NASA NTRS1978

Global exchange of water vapor on Mars

Observations of the global distribution and seasonal variation of the Martian atmospheric water vapor have been made from the Viking orbiters for a continuous period covering more than half of a Martian year. The seasonal dependence of the latitude distribution of the column abundance of vapor is consistent with a model in which the vapor is in equilibrium with the regolith at polar and middle latitudes. The results indicate the existence of a permanent reservoir of water ice buried at a depth of 10 cm to 1 meter at all latitudes poleward of 40 deg. The behavior of the vapor in the summer hemisphere suggests an annual net transport of the vapor phase from the southern to the northern hemisphere, with deposition of ice of thickness on the order of a few milligrams per sq cm at northern polar latitudes. The hemispheric asymmetry is the result of the propagation of global dust storms originating in the south.

Farmer, C. B.↗

NASA NTRS1979

Effect of degree of fuel vaporization upon emissions for a premixed prevaporized combustion system

An experimental and analytical study of the combustion of partially vaporized fuel/air mixtures was performed to assess the impact of the degree of fuel vaporization upon emissions for a premixing-prevaporizing flametube combustor. Data collected showed near-linear increases in NOx emmissions with decreasing vaporization at equivalence ratios of 0.6. For equivalence ratios of 0.72, the degree of vaporization had very little impact on NOx emissions. A simple mechanism which accounts for the combustion of liquid droplets in partially vaporized mixtures was found to agree with the measured results with fair accuracy with respect to both trends and magnitudes.

Cooper, L. P.↗

NASA NTRS1980

Application of an automatic cloud tracking technique to Meteosat water vapor and infrared observations

The automatic cloud tracking system was applied to METEOSAT 6.7 micrometers water vapor measurements to learn whether the system can track the motions of water vapor patterns. Data for the midlatitudes, subtropics, and tropics were selected from a sequence of METEOSAT pictures for 25 April 1978. Trackable features in the water vapor patterns were identified using a clustering technique and the features were tracked by two different methods. In flat (low contrast) water vapor fields, the automatic motion computations were not reliable, but in areas where the water vapor fields contained small scale structure (such as in the vicinity of active weather phenomena) the computations were successful. Cloud motions were computed using METEOSAT infrared observations (including tropical convective systems and midlatitude jet stream cirrus).

Endlich, R. M.↗

NASA NTRS1982

The effect of water vapor on fatigue crack Growth in 7475-t651 aluminum alloy plate

The effects of water vapor on fatigue crack growth in 7475-T651 aluminum alloy plate at frequencies of 1 Hz and 10 Hz were investigated. Twenty-five mm thick compact specimens were subjected to constant amplitude fatigue testing at a load ratio of 0.2. Fatigue crack growth rates were calculated from effective crack lengths determined using a compliance method. Tests were conducted in hard vacuum and at water vapor partial pressures ranging from 94 Pa to 3.8 kPa. Fatigue crack growth rates were frequency insensitive under all environment conditions tested. For constant stress intensity factor ranges crack growth rate transitions occurred at low and high water vapor pressures. Crack growth rates at intermediate pressures were relatively constant and showed reasonable agreement with published data for two Al-Cu-Mg alloys. The existence of two crack growth rate transitions suggests either a change in rate controlling kinetics or a change in corrosion fatigue mechanism as a function of water vapor pressure. Reduced residual deformation and transverse cracking specimens tested in water vapor versus vacuum may be evidence of embrittlement within the plastic zone due to environmental interaction.

Dicus, D. L.↗

NASA NTRS1983

Techniques for avoiding discrimination errors in the dynamic sampling of condensable vapors

In the mass spectrometric sampling of dynamic systems, measurements of the relative concentrations of condensable and noncondensable vapors can be significantly distorted if some subtle, but important, instrumental factors are overlooked. Even with in situ measurements, the condensables are readily lost to the container walls, and the noncondensables can persist within the vacuum chamber and yield a disproportionately high output signal. Where single pulses of vapor are sampled this source of error is avoided by gating either the mass spectrometer ""on'' or the data acquisition instrumentation ""on'' only during the very brief time-window when the initial vapor cloud emanating directly from the vapor source passes through the ionizer. Instrumentation for these techniques is detailed and its effectiveness is demonstrated by comparing gated and nongated spectra obtained from the pulsed-laser vaporization of several materials.

Lincoln, K. A.↗

NASA NTRS1984

Another Look at the Optimum Frequencies for a Water Vapor Radiometer

A water vapor radiometer is used to estimate the columnar content of atmospheric water vapor or equivalently the line-of-sight path delay due to water vapor. Two measurement channels are used in order to separate the effects of the liquid and vapor phases of water. The efficiency of the path delay or columnar vapor estimate is dependent on the choice of on-line frequency channel. Previous analysis of this problem has suggested frequencies from 20.3 to 21 GHz. The frequency that yields the minimum error in the inversion algorithm is shown here to be both site and season dependent. Hence, the concept of an optimum frequency must represent an averaging process over the entire range of meteorological conditions that is expected. For a range of sites and condition representing a cross section of the continental United States the optimum on-line frequency seems to be 20.6 GHz.

Resch, G. M.↗

NASA NTRS1984

Effect of water vapor on fatigue crack growth in 7475-T651 aluminum alloy plate

Dicus, D. L.↗

NASA NTRS1985

Water vapor content in the polar atmosphere measured by Lyman-alpha/OH fluorescence method

The water vapor of the polar stratosphere possibly plays an important role in various aeronomical processes; for example, OH radical formation through photodissociation of H2O, formation of water cluster ions, radiative energy transfer in the lower stratosphere, condensation onto particulate matter, and so on. In addition to these, it has been speculated, from the viewpoint of global transport and/or budget of water vapor, that the polar stratosphere functions as an active sink. STANFORD (1973) emphasized the existence of the stratospheric Cist cloud in the polar stratosphere which brought a large loss rate of stratospheric water vapor through a so-called freeze-out of cloud particles from the stratosphere into the troposphere. However, these geophysically interesting problems unfortunately remain to be solved, owing to the lack of measurements on water vapor distribution and its temporal variation in the polar stratosphere. The water vapor content measured at Syowa Station (69.00 deg S, 39.35 deg E), Antarctica using a balloon-borne hygrometer (Lyman - alpha/OH fluorescence type) is discussed.

Iwasaka, Y.↗