Search NASA⌕ Search

SEARCH · Search NASA

Results for “Water Electrolysis”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 163 records · Page 9

Oxygen/hydrogen Space Station propulsion system concept definition for IOC

The potential for the reduction in propulsion system life cycle costs through the use of on-board water electrolysis to generate oxygen and hydrogen propellants, as well as the potential advantages of improved system safety and contamination impact, led to a study to evaluate candidate oxygen-/hydrogen-based propulsion systems. In this study a representative set of propulsion system requirements were compiled and candidate oxygen/hydrogen-based propulsion systems synthesized. These candidate concepts were screened and a systems evaluation was performed on the remaining eight candidate concepts. Detailed system schematics were prepared. Operational design conditions were determined and system weight, volume, energy requirements, and costs were calculated. Evaluation results indicated that the oxygen/hydrogen propulsion systems can provide simple, low cost, and viable systems for the IOC Space Station. Based on these data, a relative concept evaluation was conducted using as selection criteria reliability, safety, cost, technical risk, contamination, operational utility, growth potential, and integration potential. Top ranked candidate systems were recommended to NASA/MSFC for consideration for the IOC Space Station.

Shoji, J. M.↗

Environmental control/life support system for Space Station

The functional, operational, and design load requirements for the Environmental Control/Life Support System (ECLSS) are described. The ECLSS is divided into two groups: (1) an atmosphere management group and (2) a water and waste management group. The interaction between the ECLSS and the Space Station Habitability System is examined. The cruciform baseline station design, the delta and big T module configuration, and the reference Space Station configuration are evaluated in terms of ECLSS requirements. The distribution of ECLSS equipment in a reference Space Station configuration is studied as a function of initial operating conditions and growth orbit capabilities. The benefits of water electrolysis as a Space Station utility are considered.

Miller, C. W.↗

Space Station propulsion system test bed

The test bed to study H2/O2 propulsion technology for the Space Station is discussed. The test bed consists of propellant accumulators, valving, instrumentation, and controls configured in a 9-ft cube. A water electrolysis module was added to simulate the baseline propulsion system configuration. The activation of the test bed is described, and results are presented from tests of the system, including verification of the control system, thruster tests, electrolysis system testing, and acceptance test, oxidizer system, and fuel system blowdowns.

Norman, A. M.↗

Power considerations for an early manned Mars mission utilizing the space station

Power requirements and candidate electrical power sources were examined for the supporting space infrastructure for an early (2004) manned Mars mission. This two-year mission (60-day stay time) assumed a single six crew piloted vehicle with a Mars lander for four of the crew. The transportation vehicle was assumed to be a hydrogen/oxygen propulsion design with or without large aerobrakes and assembled and checked out on the LEO Space Station. The long transit time necessitated artificial gravity of the crew by rotating the crew compartments. This rotation complicates power source selection. Candidate power sources were examined for the Lander, Mars Orbiter, supporting Space Station, co-orbiting Propellant Storage Depot, and alternatively, a co-orbiting Propellant Generation (water electrolysis) Depot. Candidates considered were photovoltaics with regenerative fuel cells or batteries, solar dynamics, isotope dynamics, and nuclear power.

Valgora, Martin E.↗

Electrocatalysts for oxygen electrodes in fuel cells and water electrolyzers for space applications

In most instances separate electrocatalysts are needed to promote the reduction of O2 in the fuel cell mode and to generate O2 in the energy storage-water electrolysis mode in aqueous electrochemical systems operating at low and moderate temperatures (T greater than or equal to 200 C). Interesting exceptions are the lead and bismuth ruthenate pyrochlores in alkaline electrolytes. These catalysts on high area carbon supports have high catalytic activity for both O2 reduction and generation (1,2). Rotating ring-disk electrode measurements provide evidence that the O2 reduction proceeds by a parallel four-electron pathway. The ruthenates can also be used as self-supported catalysts to avoid the problems associated with carbon oxidation, but the electrode performance so far achieved in the research at Case Western Reserve University (CWRU) is considerably less. At the potentials involved in the anodic mode the ruthenate pyrochlores have substantial equilibrium solubility in concentrated alkaline electrolyte. This results in the loss of catalyst into the bulk solution and a decline in catalytic activity. Furthermore, the hydrogen generation counter electrode may become contaminated with reduction products from the pyrochlores (lead, ruthenium). A possible approach to this problem is to immobilize the pyrochlore catalyst within an ionic-conducting solid polymer, which would replace the fluid electrolyte within the porous gas diffusion O2 electrode. For bulk alkaline electrolyte, an anion-exchange polymer is needed with a transference number close to unity for the Oh(-) ion. Preliminary short-term measurements with lead ruthenates using a commercially available partially-fluorinated anion-exchange membrane as an overlayer on the porous gas-fed electrode indicate lower anodic polarization and virtually unchanged cathodic polarization.

Prakash, Jai↗

Design, operation, and critical issues of the U.S. Space Station Freedom propulsion system

The U.S. Space Station Freedom Manned Base (SSFMB) propulsion system is a gaseous hydrogen/oxygen-based system for primary reboost, attitude control, and station contingencies using electrolyzed water as a propellant. A secondary propulsion reboost system employs multipropellant resistojets which utilize the various waste gases generated during normal station operations. The hydrogen/oxygen propulsion system is comprised of several modules which contain thrusters, propellant storage tanks, regulation subsystems, water electrolysis units, electronic controls, and fluid plumbing. The resistojet system is comprised of one module containing the resistojets, regulators, electronic controls, and fluid plumbing. The waste gas propellant storage takes place in the Fluid Management System.

Morano, Joseph S.↗

Space Station Technology Summary

The completion of the Space Station Propulsion Advanced Technology Programs established an in-depth data base for the baseline gaseous oxygen/gaseous hydrogen thruster, the waste gas resistojet, and the associated system operations. These efforts included testing of a full end-to-end system at National Aeronautics and Space Administration (NASA)-Marshall Space Flight Center (MSFC) in which oxygen and hydrogen were generated from water by electrolysis at 6.89 MPa (1,000 psia), stored and fired through the prototype thruster. Recent end-to-end system tests which generate the oxygen/hydrogen propellants by electrolysis of water at 20.67 MPa (3,000 psia) were completed on the Integrated Propulsion Test Article (IPTA) at NASA-Johnson Space Center (JSC). Resistojet testing has included 10,000 hours of life testing, plume characterization, and electromagnetic interference (EMI) testing. Extensive 25-lbf thruster testing was performed defining operating performance characteristics across the required mixture ratio and thrust level ranges. Life testing has accumulated 27 hours of operation on the prototype thruster. A total of seven injectors and five thrust chambers were fabricated to the same basic design. Five injectors and three thrust chambers designed to incorporate improved life, performance, and producibility characteristics are ready for testing. Five resistojets were fabricated and tested, with modifications made to improve producibility. The lessons learned in the area of producibility for both the O2/H2 thrusters and for the resistojet have resolved critical fabrication issues. The test results indicate that all major technology issues for long life and reliability for space station application were resolved.

Iacabucci, R.↗

Electrocatalysis for oxygen electrodes in fuel cells and water electrolyzers for space applications

In most instances separate electrocatalysts are needed to promote the reduction of O2 in the fuel cell mode and to generate O2 in the energy storage-water electrolysis mode in aqueous electrochemical systems operating at low and moderate temperatures (T greater than or equal to 200 C). Interesting exceptions are the lead and bismuth ruthenate pyrochlores in alkaline electrolytes. These catalysts on high area carbon supports have high catalytic activity for both O2 reduction and generation. Rotating ring-disk electrode measurements provide evidence that the O2 reduction proceeds by a parallel four-electron pathway. The ruthenates can also be used as self-supported catalysts to avoid the problems associated with carbon oxidation, but the electrode performance so far achieved in the research at Case Western Reserve University (CWRU) is considerably less. At the potentials involved in the anodic mode the ruthenate pyrochlores have substantial equilibrium solubility in concentrated alkaline electrolyte. This results in the loss of catalyst into the bulk solution and a decline in catalytic activity. Furthermore, the hydrogen generation counter electrode may become contaminated with reduction products from the pyrochlores (lead, ruthenium).

Prakash, Jai↗

Power considerations for an early manned Mars mission utilizing the Space Station

Power requirements and candidate electrical power sources were examined for the supporting space infrastructure for an early (2004) manned Mars mission. This two-year mission (60-day stay time) assumed a single six crew piloted vehicle with a Mars lander for four of the crew. The transportation vehicle was assumed to be a hydrogen/oxygen propulsion design with or without large aerobrakes and assembled and checked out on the LEO Space Station. The long transit time necessitated artificial gravity of the crew by rotating the crew compartments. This rotation complicates power source selection. Candidate power sources were examined for the Lander, Mars Orbiter, supporting Space Station, co-orbiting Propellant Storage Depot, and, alternatively, a co-orbiting Propellant Generation (water electrolysis) Depot. Candidates considered were photovoltaics with regenerative fuel cells or batteries, solar dynamics, isotope dynamics, and nuclear power.

Valgora, Martin E.↗

SPE propulsion electrolyzer for NASA's integrated propulsion test article

Hamilton Standard has delivered a 3000 PSI SPE Propulsion Electrolyzer Stack and Special Test Fixture to the NASA Lyndon B. Johnson Space Center (JSC) Integrated Propulsion Test Article (IPTA) program in June 1990, per contract NAS9-18030. This prototype unit demonstrates the feasibility of SPE-high pressure water electrolysis for future space applications such as Space Station propulsion and Lunar/Mars energy storage. The SPE-Propulsion Electrolyzer has met or exceeded all IPTA program goals. It continues to function as the primary hydrogen and oxygen source for the IPTA test bed at the NASA/JSC Propulsion and Power Division Thermochemical Test Branch.

Source record↗

Integrated oxygen recovery system

Life Systems has conceptualized an innovative Integrated Oxygen Recovery System (IORS) applicable to advanced mission air revitalization. The IORS provides the capability to electrochemically generate metabolic oxygen (O2) and recover O2 from the space habitat atmosphere via a carbon dioxide (CO2) reduction process within a single assembly. To achieve this capability, the IORS utilizes a Solid Metal Cathode (SMC) water electrolysis unit that simultaneously serves as the Sabatier CO2 reduction reactor. The IORS enables two major life support systems currently baselined in closed loop air revitalization systems to be combined into one smaller, less complex system. This concept reduces fluidic and electrical interface requirements and eliminates a hydrogen (H2) interface. Life Systems is performing an evaluation of the IORS process directed at demonstrating performance and quantifying key physical characteristics including power, weight, and volume. Technical progress achieved during the first two months of the program is summarized.

Lee, M. Gene↗

Integrated oxygen recovery system

Life Systems has conceptualized an innovative Integrated Oxygen Recovery System (IORS) applicable to advanced mission air revitalization. The IORS provides the capability to electrochemically generate metabolic oxygen (O2) and recover O2 from the space habitat atmosphere via a carbon dioxide (CO2) reduction process within a single assembly. To achieve this capability, the IORS utilizes a Solid Metal Cathode (SMC) water electrolysis unit that simultaneously serves as the Sabatier CO2 reduction reactor. The IORS enables two major life support systems currently baselined in closed loop air revitalization systems to be combined into one smaller, less complex system. This concept reduces fluidic and electrical interface requirements and eliminates a hydrogen (H2) interface. Life Systems is performing an evaluation of the IORS process directed at demonstrating performance and quantifying key physical characteristics including power, weight, and volume. The results of the checkout, shakedown, and initial parametric tests are summarized.

Lee, M. Gene↗

Propulsion technology discipline

Viewgraphs on propulsion technology discipline for Space Station Freedom are presented. Topics covered include: water electrolysis O2/H2 system; hydrazine system advancements; common technology; fluids disposal; and storable bipropellant system.

Jones, Lee W.↗

Propellant production and useful materials: Hardware data from components and the systems

Research activities at the University of Arizona/NASA Space Engineering Research Center are described; the primary emphasis is on hardware development and operation. The research activities are all aimed toward introducing significant cost reductions through the utilization of resources locally available at extraterrestrial sites. The four logical aspects include lunar, Martian, support, and common technologies. These are described in turn. The hardware realizations are based upon sound scientific principles which are used to screen a host of interesting and novel concepts. Small scale feasibility studies are used as the screen to allow only the most promising concepts to proceed. Specific examples include: kg/day-class oxygen plant that uses CO2 as the feed stock, spent stream utilization to produce methane and 'higher' compounds (using hydrogen from a water electrolysis plant), separation of CO from the CO2, reduction of any iron bearing silicate (lunar soils), production of structural components, smart sensors and autonomous controls, and quantitative computer simulation of extraterrestrial plants. The most important feature of all this research continues to be the training of high-quality students for our future in space.

Ramohalli, Kumar↗

Primary and secondary electrical space power based on advanced PEM systems

For new space ventures, power continues to be a pacing function for mission planning and experiment endurance. Although electrochemical power is a well demonstrated space power technology, current hardware limitations impact future mission viability. In order to document and augment electrochemical technology, a series of experiments for the National Aeronautics and Space Administration Lewis Research Center (NASA LeRC) are underway at the Los Alamos National Laboratory that define operational parameters on contemporary proton exchange membrane (PEM) hardware operating with hydrogen and oxygen reactants. Because of the high efficiency possible for water electrolysis, this hardware is also thought part of a secondary battery design built around stored reactants - the so-called regenerative fuel cell. An overview of stack testing at Los Alamos and of analyses related to regenerative fuel cell systems are provided in this paper. Finally, this paper describes work looking at innovative concepts that remove complexity from stack hardware with the specific intent of higher system reliability. This new concept offers the potential for unprecedented electrochemical power system energy densities.

Vanderborgh, N. E.↗

The TMI regenerable solid oxide fuel cell

Energy storage and production in space requires rugged, reliable hardware which minimizes weight, volume, and maintenance while maximizing power output and usable energy storage. These systems generally consist of photovoltaic solar arrays which operate during sunlight cycles to provide system power and regenerate fuel (hydrogen) via water electrolysis; during dark cycles, hydrogen is converted by the fuel cell into system. The currently preferred configuration uses two separate systems (fuel cell and electrolyzer) in conjunction with photovoltaic cells. Fuel cell/electrolyzer system simplicity, reliability, and power-to-weight and power-to-volume ratios could be greatly improved if both power production (fuel cell) and power storage (electrolysis) functions can be integrated into a single unit. The Technology Management, Inc. (TMI), solid oxide fuel cell-based system offers the opportunity to both integrate fuel cell and electrolyzer functions into one unit and potentially simplify system requirements. Based an the TMI solid oxide fuel cell (SOPC) technology, the TMI integrated fuel cell/electrolyzer utilizes innovative gas storage and operational concepts and operates like a rechargeable 'hydrogen-oxygen battery'. Preliminary research has been completed on improved H2/H2O electrode (SOFC anode/electrolyzer cathode) materials for solid oxide, regenerative fuel cells. Improved H2/H2O electrode materials showed improved cell performance in both fuel cell and electrolysis modes in reversible cell tests. ln reversible fuel cell/electrolyzer mode, regenerative fuel cell efficiencies (ratio of power out (fuel cell mode) to power in (electrolyzer model)) improved from 50 percent (using conventional electrode materials) to over 80 percent. The new materials will allow the TMI SOFC system to operate as both the electrolyzer and fuel cell in a single unit. Preliminary system designs have also been developed which indicate the technical feasibility of using the TMI SOFC technology for space applications with high energy storage efficiencies and high specific energy. Development of small space systems would also have potential dual-use, terrestrial applications.

Cable, Thomas L.↗

The TMI Regenerative Solid Oxide Fuel Cell

Energy storage and production in space requires rugged, reliable hardware which minimizes weight, volume, and maintenance while maximizing power output and usable energy storage. Systems generally consist of photovoltaic solar arrays which operate (during sunlight cycles) to provide system power and regenerate fuel (hydrogen) via water electrolysis and (during dark cycles) fuel cells convert hydrogen into electricity. Common configurations use two separate systems (fuel cell and electrolyzer) in conjunction with photovoltaic cells. Reliability, power to weight and power to volume ratios could be greatly improved if both power production (fuel cells) and power storage (electrolysis) functions can be integrated into a single unit. The solid oxide fuel cell (SOFC) based design integrates fuel cell and electrolyzer functions and potentially simplifies system requirements. The integrated fuel cell/electrolyzer design also utilizes innovative gas storage concepts and operates like a rechargeable 'hydrogen-oxygen battery'. Preliminary research has been completed on improved H2/H20 electrode (SOFC anode/electrolyzer cathode) materials for regenerative fuel cells. Tests have shown improved cell performance in both fuel and electrolysis modes in reversible fuel cell tests. Regenerative fuel cell efficiencies, ratio of power out (fuel cell mode) to power in (electrolyzer mode), improved from 50 percent using conventional electrode materials to over 80 percent. The new materials will allow a single SOFC system to operate as both the electolyzer and fuel cell. Preliminary system designs have also been developed to show the technical feasibility of using the design for space applications requiring high energy storage efficiencies and high specific energy. Small space systems also have potential for dual-use, terrestrial applications.

Cable, Thomas L.↗

In-Situ Propellant Production on Mars: A Sabatier/Electrolysis Demonstration Plant

An efficient, reliable propellant production plant has been developed for use on Mars. Using a Sabatier reactor in conjunction with a water electrolysis system, a complete demonstration plant has produced methane and liquid oxygen from simulated Martian atmosphere. The production plant has demonstrated high efficiency, extended duration production and autonomous operations. This paper presents the results and conclusions relating to eventual use in a Mars sample return mission. This work was funded by the Jet Propulsion Laboratory (JPL). The production plant was built and tested at the Propulsion Center of Lockheed Martin at the Denver Colorado facility.

Clark, David L.↗