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At least 163 records · Page 9

Hard X-Ray and Wide Focusing Telescopes

Studies are being carried out to compare the performance of several different separation materials used in the replication process. This report presents the results obtained during the second year of a program which consists of replicating smooth, thin substrates, depositing multilayer coatings upon them, and evaluating their performance. Replication and multilayer coatings are both critically important to the development of focussing hard X-ray telescopes that function up to 100 keV. The activities of the current year include extending the comparison between sputtered amorphous carbon and evaporated gold to include sputtered as well as evaporated gold. The figure of merit being the smoothness of the replica which has a direct effect on the specular reflectivity. These results were obtained with epoxy replication, but they should be applicable to electroformed nickel, the process we expect to use for the ultimate replicated optics.

Gorenstein, Paul↗

Detection of Water Ice on Saturn's Satellite Phoebe

The near-infrared reflectance spectrum of Saturn's satellite Phoebe shows a broad absorption band at 2.0 micrometers and absorption at lambda > 2.2 micrometers, both characteristic of H2O ice. We have successfully modeled the surface of Phoebe with an intimate (granular) mix of H2O ice (3% by weight, grain size 500 micrometers) mixed with fine grains of H2O ice (0.25%) with amorphous carbon (grain size 900 micrometers) as the dominant component. This model reproduces the shape of the measured spectrum and the observed albedo of 0.10 for Phoebe, but it is not unique. The presence of ice establishes Phoebe as an original member of the outer Solar System rather than a renegade asteroid.

Owen, T. C.↗

Infrared Emission from Comets

A brief discussion of the infrared observations from 4 to 20 micrometers of seven comets is presented. The observed infrared emission from comets depends primarily on their heliocentric distance. A model based on grain populations composed of a mixture of silicate and amorphous carbon particles in the mass ratio of about 40 to 1, with a power-law size distribution similar to that inferred for comet Halley, is applied to the observations. The model provides a good match to the observed heliocentric variation of both the 10 micrometers feature and the overall thermal emission from comets West and Halley. Matches to the observations of comet IRAS-Araki-Alcock and the antitail of comet Kohoutek require slightly larger grains. While the model does not match the exact profile and position of the 3.4 micrometers feature discovered in comet Halley, it does produce a qualitative fit to the observed variation of the feature's strength as a function of heliocentric distance. The calculations predict that the continuum under the 3.4 micrometers feature is due primarily to thermal emission from the comet dust when the comet is close to the Sun and to scattered solar radiation at large heliocentric distances, as is observed. A brief discussion of the determination of cometary grain temperatures from the observed infrared emission is presented. It is found that the observed shape of the emission curve from about 4 to 8 micrometers provides the best spectral region for estimating the cometary grain temperature distribution.

Swamy, K. S. Krishna↗

Laboratory Studies of Optical Characteristics and Condensation Processes of Cosmic Dust Particles

Information about the optical characteristics and physical processes involving cosmic dust particles is vital for interpretation of astronomical observations and an understanding of the formation and processing of dust in the evolutionary cycle of matter in the interstellar medium. Cosmic dust particles are formed in a variety of astrophysical environments such as in cool stellar outflows and circumstellar envelopes. Definitive knowledge of the nature, composition, and physical processes of cosmic dust grains, however, can only be inferred from astronomical observations through laboratory experiments on the analogs of hypothesized dust particles and with modeling calculations. Laboratory investigations of the nature, composition, and optical characteristics of cosmic dust particles are being, carried out at many institutions with a variety of experimental techniques. Despite a wealth of available data, however, many basic issues remain unresolved. An experimental facility based on suspension of dust particles in electrodynamic balance in a pressure/temperature controlled environment in a cavity has been operational at the NASA Marshall Space Flight Center, and is currently being employed for studies of dust particle charging mechanisms using electron beams and with UV radiation. In this paper, we discuss two general classes of experiments under planning stages that may be simultaneously carried out on this facility for cosmic dust investigations (i) Infrared optical characteristics (extinction coefficients and scattering phase functions) of the analogs of hypothesized of cosmic dust particles, such as natural and synthetic amorphous silicates with varying compositions, amorphous carbon grains, polycyclic aromatic hydrocarbons (PAHs), and icy core-mantle particles etc. The initial spectral range under consideration is 1-25 micrometers, to be extended to the far infrared region in the future (ii) Condensation of volatile gases on nucleus dust particles to be investigated for planetary and astrophysical environments.

Spann, J. F., Jr.↗

Decoding the Domino: The Dark Side of Iapetus

We present new spectra of the leading and trailing hemispheres of Iapetus from 2.4 to 3.8 micron. We have combined the leading hemisphere spectra with previous observations by others to construct a composite spectrum of the dark side (leading) hemisphere from 0.3 to 3.8 gm. We review attempts to deduce the composition of the dark material from previously available spectrophotometry. None of them (numbering more than 20 million!) leads to a synthetic spectrum that matches the new data. An intimate mixture of water ice, amorphous carbon and a nitrogen-rich organic compound (modeled here as Triton tholin) can fit the entire composite dark side spectrum. Observations in this spectral region have not revealed this mix of material on any other object observed thus far. We propose that this dark material may have originated on Titan, where atmospheric photochemistry has been producing nitrogen-rich organic compounds for 4.5 GY.

Owen, Tobias C.↗

Physical Properties of Centaur Objects

Centaurs are objects in unstable orbits that cross the orbits of the giant planets. They are presumed to be recent additions to the planetary zone of the Solar System, having been dynamically perturbed from the Kulper Disk by the gravitational action of Neptune. Telescopic observations of Centaurs are important because they give us a view of the composition (and in some cases cometary activity) of large bodies that are normally to far from the Sun to be studied in detail. This paper reports on physical observations, primarily through spectroscopy, of the compositions of a small number of Centaurs that have been studied to date. In particular, the composition of 5145 Pholus is reviewed, following the published work of Crulkshank et al., in which compositional models that fit the spectrum well included H2O ice, the organic solid Titan tholin, a light hydrocarbon ice (e.g., CH3OH), the silicate mineral olivine, and amorphous carbon. The Centaur 1997 CU(26) shows evidence for H2O ice, but nothing else is yet identified.

Cruikshank, Dale P.↗

Low Temperature Growth of Nanostructured Diamond Films on Metals

The field of nanocrystalline diamond and tetrahedral amorphous carbon films has been the focus of intense experimental activity in the last few years for applications in field emission display devices, optical windows, and tribological coatings, The choice of substrate used in most studies has typically been silicon. For metals, however, the thermal expansion mismatch between the diamond film and substrate gives rise to thermal stress that often results in delamination of the film. To avoid this problem in conventional CVD deposition low substrate temperatures (less than 700 C) have been used, often with the incorporation of oxygen or carbon monoxide to the feedgas mixture. Conventionally grown CVD diamond films are also rough and would require post-deposition polishing for most applications. Therefore, there is an obvious need to develop techniques for deposition of well-adhered, smooth nano-structured diamond films on metals for various tribological applications. In our work, nanostructured diamond films are grown on a titanium alloy substrate using a two-step deposition process. The first step is performed at elevated temperature (820 C) for 30 minutes using a H2/CH4/N2 gas mixture in order to grow a thin (approx. 600 nm) nanostructured diamond layer and improve film adhesion. The remainder of the deposition involves growth at low temperature (less than 600 C) in a H2/CH4/O2 gas mixture. Laser reflectance Interferometry (LRI) pattern during growth of a nanostructured diamond film on Ti-6Al-4V alloy. The first 30 minutes are at a high temperature of 820 C and the rest of the film is grown at a low temperature of 580 T. The fringe pattern is observed till the very end due to extremely low surface roughness of 40 nm. The continuation of the smooth nanostructured diamond film growth during low temperature deposition is confirmed by in-situ laser reflectance interferometry and by post-deposition micro-Raman spectroscopy and surface profilometry. Similar experiments performed without the starting nanostructured diamond layer resulted in poorly adhered films with a more crystalline appearance and a higher surface roughness. This low temperature deposition of nanostructured diamond films on metals offers advantages in cases where high residual thermal stress leads to delamination at high temperatures.

Baker, Paul A.↗

The Origins of Polycyclic Aromatic Hydrocarbons: Are They Everywhere?

During the past 15 years considerable progress in observational techniques has been achieved in the middle-infrared region (5000-500 per centimeter, 2-20 micron), the region where most diagnostic molecular vibrations occur. Spectra of many different astronomical infrared sources, some deeply embedded in dark molecular clouds and others at their edges, are now available. These spectra provide a powerful probe, not only for the identification of interstellar molecules in both the gas and solid phases, but also of the physical and chemical conditions which prevail in these two very different domains. The two lectures will focus on the evidence that polycyclic aromatic hydrocarbons (PAHs) are an important, ubiquitous and abundant interstellar species. PAHs are. extremely stable species which can range in size from a few angstroms across to several hundred angstroms (PAHs are also the building blocks of amorphous carbon particles). This identification rests on the suggestive agreement between the laboratory spectra of PAHs with a set of IR emission bands which emanate from many different sources where ultraviolet starlight impinges on a "dusty" region. The picture is that individual PAHs are first pumped into highly vibrationally excited states and relax by fluorescence at their fundamental vibrational frequencies. That PAHs are a ubiquitous interstellar component has serious ramifications in other spectral regions as well, including the strong extinction in the ultraviolet, and the classic visible diffuse interstellar bands discovered more than 50 years ago (but unexplained to this day) The first part of the course will focus on the interpretation of astronomical spectra. The second lecture will start by showing how recent laboratory data on PAHs taken under realistic interstellar conditions has con borated the PAH hypothesis and led to great insight into the conditions in the PAH containing regions. This lecture will end by reviewing the ever-increasing evidence for interstellar PAHs in meteorites and interplanetary dust particles. This in conjunction with the recent suggestion that PAHs are abundant in Jupiter's atmosphere will make the point that "PAHs are Everywhere".

Allamandola, L. J.↗

The 5-8 Micron Infrared Spectrum of the Galactic Center and the Composition of Interstellar Dust

Interstellar dust is an important component of the interstellar medium which dominates the opacity and, hence, regulates radiative transfer, molecule formation, and thermal balance of the ISM. Much of our knowledge on the composition of interstellar dust results from infrared spect,oscopy. The extinction along the line of sight towards the galactic center is believed to be dominated by dust in the diffuse ISM. Because of the high extinction and high IR flux, IR spectra of galactic center sources have been a prime sampling ground for the characteristics of interstellar dust. We have obtained 5-8 micrometer spectra of the galactic center using the KAO. These spectra show absorption features at 5.5, 5.8, 6.1, and 6.8 micrometers. Together with features in the 3 micrometer region previously observed by us using the IRTF, these features are compared to laboratory spectra of candidate materials. We conclude that the 3.0 and 6.1 micrometer feature are carried by H2O, likely in the form of water of hydration in interstellar silicates. The 3.4, 5.5, 5.8, and 6.8 micrometer features are due to CH2, CH3 and C=O stretching and deformation modes in a hydrocarbon grain component. Comparing derived dust abundances, we conclude that silicates dominate the interstellar dust volume. Hydrocarbon and (small) graphite grains contribute each about 0.1. The remainder of the interstellar dust volume does not show strong IR absorption features and is likely in the form of large graphite, amorphous, carbon, or diamond grains.

Tielens, A. G. G. M.↗

Mineralogical Characterization of Vigarano Matrix: HRTEM and EFTEM Observations

HRTEM and EFTEM have been used to study Vigarano matrix. Fine-grained rim olivines commonly contain inclusions of amorphous carbon and a Ca-Al-rich phase, whereas olivines in the clastic matrix contain rare inclusions of poorly graphitized carbon. Additional information is contained in the original extended abstract.

Abreu, N. M.↗

Characteristics of Interstellar and Circumstellar Dust

This paper will review our current knowledge of circumstellar and interstellar dust from an astronomical point of view. About half of the interstellar dust volume consists of amorphous silicates. The remainder has to be made up of an carbonaceous component such as graphite, amorphous carbon (i.e., soot), Polycyclic Aromatic Hydrocarbon molecules (PAHs), and/or organic grain mantles (i.e., mixed polymers). The observational evidence for these components will be reviewed and their relative importance assessed. The emphasis will be on recent observations using the Infrared Space Observatory. Most of these dust components are formed in the outflows from stars in the late stages of their evolution (i.e., red giants, planetary nebulae, novae, supergiants, Wolf Rayet stars, and supernovae). Indeed, observation of such objects indicate an even richer spectrum of stardust components, including also SiC, MgS, and aluminates and crystalline silicates. These observations will be briefly discussed. The stardust budget of the galaxy will be reviewed and the relative importance of the various birth sites assessed. Finally, in recent years, isotopic composition studies have shown that some circumstellar and interstellar dust grains have been incorporated into solar system bodies such as planetary dust particles and meteorites without totally losing their identity. Among the components identified are SiC, graphite, diamonds, PAHs, aluminum oxides, as well as various trace element carbides. Studies of this kind have opened up a new window on the composition and structure of interstellar dust. These different sources of information on interstellar and circumstellar dust will be briefly contrasted.

Tielens, A. G. G. M.↗

Titania and Oberon: Surface Composition from New Near-Infrared Observations and Reflectance Models

Here we report the combination of new near-ir spectra (1.45-2.48 micrometers), of Titania and Oberon obtained in September 1995 at a resolving power of approx. 800, with older near-ir observations (0.5- 1.44 micrometers), and recent UV (0.22-0.48 micrometers) observations obtained with HST. Previous interpretations suggest these surfaces are chiefly composed of water ice and varying amounts of spectrally neutral material. The new near-ir data provide the opportunity to search for absorption bands that could be attributable to surface materials other than water ice and because the combined spectra include such a broad wavelength region, to undertake improved models of water and neutral components on the surface. The calculated near-ir geometric albedos clearly exhibit three broad spectral features. Two (1.52- & 2.05 micrometer) have previously been used to demonstrate the presence of water ice on these satellites. The third (approx. 1.65 micrometer), suggests the presence of hexagonal water ice at low temperatures, and may provide a mechanism of estimating the surface temperature. There is no spectral evidence for ices of CO2, CO, NH3 or CH4. At UV wavelengths there is a broad absorption near 0.27-0.28 micrometer previously attributed to OH formed by magnetospheric-surface interactions and retained at the low surface temperatures of these satellites. Surface components used in a Hapke scattering models include values for a combination of irradiated water ice in the UV and hexagonal water ice at 100k in the near-ir (IR), amorphous carbon (AC), and tholins (T) (produced from gas and solid). Results of these models suggest the surfaces of Titania/Oberon are composed of IW (-77/52%) with AC the next most abundant component (approx. 19/52%) and finally T (approx. 4/7%).

Roush, Ted L.↗

The Zodiacal Emission Spectrum as Determined by COBE and its Implications

We combine observations from the DIRBE and FIRAS instruments on the COBE satellite to derive an annually-averaged spectrum of the zodiacal cloud in the 10 to 1000 micron wavelength region. The spectrum exhibits a break at approx. 150 microns which indicates a sharp break in the dust size distribution at a radius of about 30 microns The spectrum can be fit with a single blackbody with a lambda(exp -2) emissivity law beyond 150 microns and a temperature of 240 K. We also used a more realistic characterization of the cloud to fit the spectrum, including a distribution of dust temperatures, representing different dust compositions and distances from the sun, as well as a realistic representation of the spatial distribution of the dust. We show that amorphous carbon and silicate dust with respective temperatures of 280 and 274 K at 1 AU, and size distributions with a break at grain radii of 14 and 32 microns, can provide a good fit to the average zodiacal dust spectrum. The total mass of the zodiacal cloud is 2 to 11 Eg (Eg=10(exp 18) g), depending on the grain composition. The lifetime of the cloud, against particle loss by Poynting- Robertson drag and the effects of solar wind, is about 10(exp 5) yr. The required replenishment rate is approx. 10(exp 14) g/yr. If this is provided by asteroid belt alone, the asteroids lifetime would be approx. 3 x 10(exp 10) yr. But comets and Kuiper belt objects may also contribute to the zodiacal cloud.

Fixsen, D. J.↗

Disappearance of 19P/Borrelly's Silicate Feature in 2001 Apparition Is Attributed to Increase in Grain Size

We report on observations and analysis of HIFOGS 10 microns spectrophotometry of short period comet 19P/Borrelly on 2003 October 13, 15 UT at the NASA IRTF. 19P/Borrelly is one of two short period comets, comet 4PIFaye being the other, to have a silicate feature detected. During Borrelly s perihelion passage in 1994 December, a silicate feature was present with a flux-to-continuum ratio of 0.25. Two apparitions later in 2003 October, the silicate feature is absent. Thermal emission modeling using amorphous olivine and amorphous carbon shows that a slight increase in grain size accounts for the disappearance of the silicate feature. Analysis of 19P/Borrelly suggests grain size, and not the absence of olivine minerals, may be responsible for the absence of silicate features in most short period comets. 19P/Borrelly is one of the more active short period comets. However, short period comets as a family are less active than long period comets. Short period comets probably originated in the Kuiper Belt and suffered collisions while in residence in the outer solar system. Upon evolution into orbits that take them through the inner solar system, the surfaces of short period comets are exposed to sunlight through their many perihelion passages. This is in contrast to long period comets which probably originated near Jupiter and were expelled to the Oort cloud where they have existed and been exposed to cosmic ray processing. By studying the grain properties in short period comets and comparing to long period comets, we compare the effects on the grain populations of different parent body evolution histories. Upcoming opportunities to study short and long period comets will be advertised.

Wooden, D. H.↗

The infrared spectrum of the Galactic center and the composition of interstellar dust

We have obtained 5-8 micrometers spectra of the Galactic center from the Kuiper Airborne Observatory at resolving powers of approximately 50, approximately 150, and approximately 300. These spectra show absorption features at 5.5, 5.8, 6.1, and 6.8 micrometers. Together with previously observed features in the 3 micrometers region, these features are compared with laboratory spectra of candidate materials. The 3.0 and 6.1 micrometers features are due to the OH stretching and bending variations of H2O and are well fitted by water of hydration in silicates (e.g., talc). The 3.0 micrometer band is equally well fitted by ice mixtures containing 30% H2O, but such mixtures do not provide a good fit to the observed 6.1 micrometer band. The 3.4 and 6.8 micrometers features are identified with the CH stretching and deformation modes in CH2 and CH3 groups in saturated aliphatic hydrocarbons. The 6.1 micrometer band shows a short wavelength shoulder centered on 5.8 micrometer, attributed to carbonyl (C double bond O) groups in this interstellar hydrocarbon dust component. Finally, the narrow 5.5 micrometer feature is also attributed to carbonyl groups, but in the form of metal carbonyls [e.g., Fe(CO)4]. We have derived column densities and abundances along the line of sight toward the Galactic center for the various identified dust components. This analysis shows that hydrocarbon grains contain only 0.08 of the elemental abundance of C and contribute only a relatively minor fraction (0.1) of the total dust volume. Most of the interstellar dust volume is made up of silicates (approximately 0.6). Small graphite grains, responsible for the 2200 angstroms bump, account for 0.07 of the total dust volume. The remaining one-quarter of the interstellar dust volume consists of a material(s) without strong IR absorption features. Likely candidates include large graphite grains, diamonds, or amorphous carbon grains, which all have weak or no IR active modes. Finally, various models for the origin of the hydrocarbon dust component of the interstellar dust are discussed. All of them face some problems in explaining the observations, in particular, the absence of the spectroscopic signature of hydrocrbon grains in sources associated with molecular clouds.

NASA Discipline Exobiology↗

On the Formation of Massive Stars

We calculate numerically the collapse of slowly rotating, nonmagnetic, massive molecular clumps of masses 30,60, and 120 Stellar Mass, which conceivably could lead to the formation of massive stars. Because radiative acceleration on dust grains plays a critical role in the clump's dynamical evolution, we have improved the module for continuum radiation transfer in an existing two-dimensional (axial symmetry assumed) radiation hydrodynamic code. In particular, rather than using "gray" dust opacities and "gray" radiation transfer, we calculate the dust's wavelength-dependent absorption and emission simultaneously with the radiation density at each wavelength and the equilibrium temperatures of three grain components: amorphous carbon particles. silicates, and " dirty ice " -coated silicates. Because our simulations cannot spatially resolve the innermost regions of the molecular clump, however, we cannot distinguish between the formation of a dense central cluster or a single massive object. Furthermore, we cannot exclude significant mass loss from the central object(s) that may interact with the inflow into the central grid cell. Thus, with our basic assumption that all material in the innermost grid cell accretes onto a single object. we are able to provide only an upper limit to the mass of stars that could possibly be formed. We introduce a semianalytical scheme for augmenting existing evolutionary tracks of pre-main-sequence protostars by including the effects of accretion. By considering an open outermost boundary, an arbitrary amount of material could, in principal, be accreted onto this central star. However, for the three cases considered (30, 60, and 120 Stellar Mass originally within the computation grid), radiation acceleration limited the final masses to 3 1.6, 33.6, and 42.9 Stellar Mass, respectively, for wavelength-dependent radiation transfer and to 19.1, 20.1, and 22.9 Stellar Mass. for the corresponding simulations with gray radiation transfer. Our calculations demonstrate that massive stars can in principle be formed via accretion through a disk. The accretion rate onto the central source increases rapidly after one initial free-fall time and decreases monotonically afterward. By enhancing the nonisotropic character of the radiation field, the accretion disk reduces the effects of radiative acceleration in the radial direction - a process we call the "flashlight effect." The flashlight effect is further amplified in our case by including the effects of frequency-dependent radiation transfer. We conclude with the warning that a careful treatment of radiation transfer is a mandatory requirement for realistic simulations of the formation of massive stars.

Yorke, Harold W.↗

Decoding IR Spectra of Cosmic Ices and Organics in the Laboratory

Tremendous strides have been made in our understanding of interstellar material over the past twenty-five years thanks to significant developments in observational IR astronomy and dedicated laboratory experiments. Twenty-five years ago the composition of interstellar dust was largely guessed at. Today the composition of interstellar dust is reasonably well understood. In the diffuse interstellar medium (ISM) the dust population is mainly comprised of small grains of silicates and amorphous carbon. In dark molecular clouds, the birthplace of stars and planets, these cold refractory dust particles are coated with mixed molecular ices whose composition is reasonably well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by early interstellar chemistry standards, is widespread throughout the Universe. This extraordinary progress has been made possible by the close collaboration of laboratory experimentalists and theoreticians with IR astronomers using groundbased, air-borne, and orbiting telescopes.

Allamandola, Louis J.↗

Measurement of Damage Profiles from Solar Wind Implantation

NASA's Genesis Mission launched from Cape Canaveral in August of 2001 with the goal of collecting solar wind in ultra-pure materials. The samples were returned to Earth more than three years later for subsequent analysis. Although the solar wind is comprised primarily of protons, it also contains ionized species representing the entire periodic table. The Genesis mission took advantage of the natural momentum of these ionized species to implant themselves in specialized collectors including single crystal Si and SiC. The collectors trapped the solar wind species of interest and sustained significant damage to the surface crystal structure as a result of the ion bombardment. In this work, spectroscopic ellipsometry has been used to evaluate the extent of this damage in Si and SiC samples. These results and models are compared for artificially implanted samples and pristine non-flight material. In addition, the flown samples had accumulated a thin film of molecular contamination as a result of outgassing in flight, and we demonstrate that this layer can be differentiated from the material damage. In addition to collecting bulk solar wind samples (continuous exposure), the Genesis mission actually returned silicon exposed to four different solar wind regimes: bulk, high speed, low speed, and coronal mass ejections. Each of these solar wind regimes varies in energy, but may vary in composition as well. While determining the composition is a primary goal of the mission, we are also interested in the variation in depth and extent of the damage layer as a function of solar wind regime. Here, we examine flight Si from the bulk solar wind regime and compare the results to both pristine and artificially implanted Si. Finally, there were four samples which were mounted in an electrostatic "concentrator" designed to reject a large fraction (>85%) of incoming protons while enhancing the concentration of ions mass 4-28 amu by a factor of at least 20. Two of these samples were single crystal 6H silicon carbide. (The others were polycrystalline CVD diamond and amorphous carbon that were not examined in the work.) The ion damaged SiC samples from the concentrator were studied in comparison to the flight Si from the bulk array to understand differences in the extent of the damage.

McNamara, K. M.↗