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At least 163 records · Page 9

Materials processing in space

Processing-refining of raw materials from extraterrestrial sources is detailed for a space materials handling facility. The discussion is constrained to those steps necessary to separate desired components from raw or altered input ores, semi-purified feedstocks, or process scrap and convert the material into elements, alloys, and consumables. The materials are regarded as originating from dead satellites and boosters, lunar materials, and asteroids. Strong attention will be given to recycling reagent substances to avoid the necessity of transporting replacements. It is assumed that since no aqueous processes exist on the moon, the distribution of minerals will be homogeneous. The processing-refining scenario will include hydrochemical, pyrochemical, electrochemical, and physical techniques selected for the output mass rate/unit plant mass ratio. Flow charts of the various materials processing operations which could be performed with lunar materials are provided, noting the necessity of delivering several alloying elements from the earth due to scarcities on the moon.

Waldron, R. D.↗

A Coordinated Focused Ion Beam/Ultramicrotomy Technique for Serial Sectioning of Hayabusa Particles and Other Returned Samples

Recent sample return missions, such as NASA's Stardust mission to comet 81P/Wild 2 and JAXA's Hayabusa mission to asteroid 25143 Itokawa, have returned particulate samples (typically ~5-50 μm) that pose tremendous challenges to coordinated analysis using a variety of nano- and micro-beam techniques. The ability to glean maximal information from individual particles has become increasingly important and depends critically on how the samples are prepared for analysis. This also holds true for other extraterrestrial materials, including interplanetary dust particles, micrometeorites and lunar regolith grains. Traditionally, particulate samples have been prepared using microtomy techniques (e.g., [1]). However, for hard mineral particles ≳20 μm, microtome thin sections are compromised by severe chatter and sample loss. For these difficult samples, we have developed a hybrid technique that combines traditional ultramicrotomy with focused ion beam (FIB) techniques, allowing for the in situ investigation of grain surfaces and interiors. Using this method, we have increased the number of FIB-SEM prepared sections that can be recovered from a particle with dimensions on the order of tens of μms. These sections can be subsequently analyzed using a variety of electron beam techniques. Here, we demonstrate this sample preparation technique on individual lunar regolith grains in order to study their space-weathered surfaces. We plan to extend these efforts to analyses of individual Hayabusa samples.

Berger, E. L.↗

Orbit Transfers for Dawn's Ceres Operations: Navigation and Mission Design Experience at a Dwarf Planet

Dawn, a mission belonging to NASA’s Discovery Program, was launched on September 27, 2007 to explore two objects in the main asteroid belt in order to yield insights into important questions about the formation and evolution of the solar system. Successfully completing all mission objectives at Vesta, Dawn arrived at dwarf planet Ceres in March 2015 and continued its journey to a series of four near circular polar science orbits. Dawn became the first mission to orbit around two extraterrestrial targets; such a mission would have been impossible without the low thrust ion propulsion system (IPS). Maneuvering a spacecraft using only the IPS for the transfers between the mapping orbits posed many technical challenges to Dawn’s flight team at NASA’s Jet Propulsion Laboratory. Failure of the second reaction wheel assembly, shortly before leaving Vesta, added another challenge for Dawn’s flight team. This paper discusses the mission design and navigational experience and challenges during Dawn’s Ceres operations.

Han, Dongsuk↗

Modeling, simulation, and control of an extraterrestrial oxygen production plant

The immediate objective is the development of a new methodology for simulation of process plants used to produce oxygen and/or other useful materials from local planetary resources. Computer communication, artificial intelligence, smart sensors, and distributed control algorithms are being developed and implemented so that the simulation or an actual plant can be controlled from a remote location. The ultimate result of this research will provide the capability for teleoperation of such process plants which may be located on Mars, Luna, an asteroid, or other objects in space. A very useful near-term result will be the creation of an interactive design tool, which can be used to create and optimize the process/plant design and the control strategy. This will also provide a vivid, graphic demonstration mechanism to convey the results of other researchers to the sponsor.

Schooley, L.↗

X-Ray Absorption near Edge Structure Spectroscopic Study of Hayabusa Category 3 Carbonaceous Particles

Analyses with a scanning transmission x-ray microscope (STXM) using x-ray absorption near edge structure (XANES) spectroscopy were applied for the molecular characterization of two kinds of carbonaceous particles of unknown origin, termed category 3, which were collected from the Hayabusa spacecraft sample catcher. Carbon-XANES spectra of the category 3 particles displayed typical spectral patterns of heterogeneous organic macromolecules; peaks corresponding to aromatic/olefinic carbon, heterocyclic nitrogen and/or nitrile, and carboxyl carbon were all detected. Nitrogen-XANES spectra of the particles showed the presence of N-functional groups such as imine, nitrile, aromatic nitrogen, amide, pyrrole, and amine. An oxygen-XANES spectrum of one of the particles showed a ketone group. Differences in carbon- and nitrogen-XANES spectra of the category 3 particles before and after transmission electron microscopic (TEM) observations were observed, which demonstrates that the carbonaceous materials are electron beam sensitive. Calcium-XANES spectroscopy and elemental contrast mapping identified a calcium carbonate grain from one of the category 3 particles. No fluorine-containing molecular species were detected in fluorine-XANES spectra of the particles. The organic macromolecular features of the category 3 particles were distinct from commercial and/or biological ‘fresh (non-degraded)’ polymers, but the category 3 molecular features could possibly reflect degradation of contaminant polymer materials or polymer materials used on the Hayabusa spacecraft. However, an extraterrestrial origin for these materials cannot currently be ruled out.

Asteroides↗

Report of the Terrestrial Bodies Science Working Group. Volume 1: Executive summary

Current knowledge of Mercury, Venus, Mars, the Moon, asteroids, comets, and the Galilean satellites were reviewed along with related NASA programs and available mission concepts. Exploration plans for the 1980 to 1990 period are outlined and recommendations made. Topics discussed include: scientific objectives and goals, exploration strategy and recommended mission plans, supporting research and technology, Earth-based and Earth-orbital investigations, data analysis and synthesis, analysis of extraterrestrial materials, broadening the science support base, and international cooperation.

Source record↗

Neutron Activation Analysis of Single Grains Recovered by the Hayabusa Spacecraft

The Hayabusa spacecraft was launched on May 9, 2003 and reached an asteroid Itokawa (25143 Itokawa) in September 2005. After accomplishing several scientific observations, the spacecraft tried to collect the surface material of Itokawa by touching down to the asteroid in November. The spacecraft was then navigated for the earth. In encountering several difficulties, Hayabusa finally returned to the earth on June 12, 2010 and the entry capsule was successfully recovered. Initially, a g-scale of solid material was aimed to be captured into the entry capsule. Although the sample collection was not perfectly performed, it was hoped that some extraterrestrial material was stored into the capsule. After careful and extensive examination, more than 1500 particles were recognized visibly by microscopes, most of which were eventually judged to be extraterrestrial, highly probably originated from Itokawa [1]. Several years before the launching of the Hayabusa spacecraft, the initial analysis team was officially formed under the selection panel at ISAS. As a member of this team, we have been preparing for the initial inspection of the returned material from many scientific viewpoints [2]. Once the recovered material had been confirmed to be much less than 1 g, a scheme for the initial analysis was updated accordingly [3]. In this study, we aim to analyze tiny single grains by instrumental neutron activation analysis (INAA). As the initial analysis is to be started in mid-January, 2011, some progress for the initial analysis using INAA is described here. Analytical procedure

Ebihara, M.↗

Lunar and Meteorite Thin Sections for Undergraduate and Graduate Studies

The Johnson Space Center (JSC) has the unique responsibility to curate NASA's extraterrestrial samples from past and future missions. Curation includes documentation, preservation, preparation, and distribution of samples for research, education, and public outreach. Between 1969 and 1972 six Apollo missions brought back 382 kilograms of lunar rocks, core samples, pebbles, sand and dust from the lunar surface. JSC also curates meteorites collected on US expeditions to Antarctica including rocks from Moon, Mars, and many asteroids including Vesta. Studies of rock and soil samples from the Moon and meteorites continue to yield useful information about the early history of the Moon, the Earth, and the inner solar system.

Allen, J.↗

What Can Interplanetary Dust Particles Tell Us About Interstellar Dust?

Dust is injected into the interplanetary medium by both comets and asteroids and there is reason to believe that particles from both of these types of sources are represented in the population of interplanetary dust collected in the stratosphere. The presence of isotopic anomalies and of adjacent mineral and carbonaceous phases that are chemically unequilibrated indicates that these particles contain primitive materials that have avoided many of the alteration processes that have affected most other extraterrestrial materials since their aggregation in the Solar nebula. This suggests that many of the subcomponents of the collected dust may have a chemical and isotopic 'memory' that extends back through the formation of the Solar System and therefore reflects the properties of interstellar dust populations. Indeed, it is possible that some of the subcomponents of the collected dust could have been true interstellar dust grains prior to the formation of the Solar nebula. The implications of this possibility will be discussed in light of our present knowledge of interplanetary dust.

Sandford, Scott A.↗

Cryogenic Curation: Isolated Technology and Mission Operational Requirements for Sample Return

Future lunar, Mars, asteroid, and comet sample return missions may collect samples that have been preserved at sub-freezing or even cryogenic temperatures. For such samples, the study of volatiles and temperature-sensitive minerals will have high priority. Valuable geochemical and mineralogical information will be lost if such samples are allowed to reach ambient temperatures on Earth. The ability to store, document, subdivide, and transport extraterrestrial geologic samples while maintaining sub-freezing or cryogenic temperatures, possibly as low as 40 K, is required for the complete scientific study of samples from cold environments.

Calaway, Michael J.↗

Technology Development for Human Exploration Beyond LEO in the New Millennium IAA-13-3 Strategies and Plans for Human Mars Missions

As we look forward into the new millennium, the extension of human presence beyond Low-Earth Orbit (LEO) looms large in the plans of NASA. The Agency's Strategic Plan specifically calls out the need to identify and develop technologies for 100 and 1000-day class missions beyond LEO. To meet the challenge of these extended duration missions, it is important that we learn how to utilize the indigenous resources available to us on extraterrestrial bodies. This concept, known as In-Situ Resource Utilization (ISRU) can greatly reduce the launch mass & cost of human missions while reducing the risk. These technologies may also pave the way for the commercial development of space. While no specific target beyond LEO is identified in NASA's Strategic Plan, mission architecture studies have been on-going for the Moon, Mars, Near-Earth Asteroids and Earth/Moon & Earth/Sun Libration Points. As a result of these studies, the NASA Office of Space Flight (Code M) through the Johnson and Kennedy Space Centers, is leading the effort to develop ISRU technologies and systems to meet the current and future needs of human missions beyond LEO and on to Mars. This effort also receives support from the NASA Office of Biological and Physical Research (Code U), the Office of Space Science (Code S), and the Office of Aerospace Technology (Code R). This paper will present unique developments in the area of fuel and oxidizer production, breathing air production, water production, C02 collection, separation of atmospheric gases, and gas liquefaction and storage. A technology overview will be provided for each topic along with the results achieved to date, future development plans, and the mission architectures that these technologies support.

Larson, William E.↗

Amino Acid Chemistry as a Link Between Small Solar System Bodies and Carbonaceous Chondrites

Establishing chemical links between meteorites and small solar system bodies, such as comets and asteroids, provides a tool for investigating the processes that occurred during the formation of the solar system. Carbonaceous meteorites are of particular interest, since they may have seeded the early Earth with a variety of prebiotic organic compounds including amino acids, purines and pyrimidines, which are thought to be necessary for the origin of life. Here we report the results of high-performance liquid chromatography (HPLC) based amino acid analyses of the acid-hydrolyzed hot water extracts from pristine interior pieces of the CI carbonaceous chondrites Orgueil and Ivuna and the CM meteorites Murchison and Murray. We found that the CI meteorites Orgueil and Ivuna contained high abundances of beta-alanine and glycine, while only traces of other amino acids like alanine, alpha-amino-n-butryic acid (ABA) and alpha-aminoisobutyric acid (AIB) were detected in these meteorites. Carbon isotopic measurements of beta-alanine and glycine in Orgueil by gas chromatography combustion-isotope ratio mass spectrometry clearly indicate an extraterrestrial origin of these amino acids. The amino acid composition of Orgueil and Ivuna was strikingly different from the CM chondrites Murchison and Murray. The most notable difference was the high relative abundance of B-alanine in Orgueil and Ivuna compared to Murchison and Murray. Furthermore, AIB, which is one of the most abundant amino acids found in Murchison and Murray, was present in only trace amounts in Orgueil and Ivuna. Our amino acid data strongly suggest that the CI meteorites Orgueil and Ivuna came from a different type of parent body than the CM meteorites Murchison and Murray, possibly from an extinct comet. It is generally thought that carbonaceous meteorites are fragments of larger asteroidal bodies delivered via near Earth objects (NEO). Orbital and dynamic studies suggest that both fragments of main belt asteroids and comets replenish the NEO population, therefore extinct comets may contribute up to half of all NEO's. A comparison of an amino acid analysis of a returned NEO sample to CI and CM carbonaceous chondrites would help establish a link between small solar system bodies and meteorites. Based on our amino acid measurements of CI and CM chondrites, amino acid chemistry can be included as an additional set of criteria to constrain the nature of meteorite parent bodies.

Glavin, Daniel P.↗

Were Ocean Impacts an Important Mechanism to Deliver Meteoritic Organic Matter to the Early Earth? Some Inferences from Eltanin

Several workers have addressed the potential for extraterrestrial delivery of volatles, including water and complex organic compounds, to the early Earth. For example, Chyba and Sagan (1992) argued that since impacts would destroy organic matter, most extraterrestrial organics must be delivered in the fine-fractions of interplanetary dust. More recent computer simulations (Pierazzo and Chyba, 1999), however, have shown that substantial amounts of amino acids may survive the impacts of large (km-sized) comets and that this may exceed the amounts derived from IDPs or Miller-Urey synthesis in the atmosphere. Once an ocean developed on the early Earth, impacts of small ,asteroids and comets into deep-ocean basins were potentially common and may have been the most likely events to deliver large amounts of organics. The deposits of the late Pliocene impact of the Eltanin asteroid into the Bellingshausen Sea provide the only record of a deep-ocean (approx. 5 km) impact that can be used to constrain models of these events. This impact was first discovered in 1981 as an Ir anomaly in sediment cores collected by the USNS Eltanin in 1965 (Kyte et al., 1981). In 1995, Polarstem expedition ANT XII/4 made the first geological survey of the suspected impact region. Three sediment cores sampled around the San Martin seamounts (approx. 57.5S, 91 W) contained well-preserved impact deposits that include disturbed ocean sediments and meteoritic impact ejecta (Gersonde et al., 1997). The latter is composed of shock- melted asteroidal materials and unmelted meteorites. In 2001, the FS Polarstem returned to the impact area during expedition ANT XVIII/5a. At least 16 cores were recovered that contain ejecta deposits. These cores and geophysical data from the expedition can be used to map the effects of the impact over a large region of the ocean floor.

Kyte, Frank T.↗

Curating NASA's Past, Present, and Future Astromaterial Sample Collections

The Astromaterials Acquisition and Curation Office at NASA Johnson Space Center (hereafter JSC curation) is responsible for curating all of NASA's extraterrestrial samples. JSC presently curates 9 different astromaterials collections in seven different clean-room suites: (1) Apollo Samples (ISO (International Standards Organization) class 6 + 7); (2) Antarctic Meteorites (ISO 6 + 7); (3) Cosmic Dust Particles (ISO 5); (4) Microparticle Impact Collection (ISO 7; formerly called Space-Exposed Hardware); (5) Genesis Solar Wind Atoms (ISO 4); (6) Stardust Comet Particles (ISO 5); (7) Stardust Interstellar Particles (ISO 5); (8) Hayabusa Asteroid Particles (ISO 5); (9) OSIRIS-REx Spacecraft Coupons and Witness Plates (ISO 7). Additional cleanrooms are currently being planned to house samples from two new collections, Hayabusa 2 (2021) and OSIRIS-REx (2023). In addition to the labs that house the samples, we maintain a wide variety of infra-structure facilities required to support the clean rooms: HEPA-filtered air-handling systems, ultrapure dry gaseous nitrogen systems, an ultrapure water system, and cleaning facilities to provide clean tools and equipment for the labs. We also have sample preparation facilities for making thin sections, microtome sections, and even focused ion-beam sections. We routinely monitor the cleanliness of our clean rooms and infrastructure systems, including measurements of inorganic or organic contamination, weekly airborne particle counts, compositional and isotopic monitoring of liquid N2 deliveries, and daily UPW system monitoring. In addition to the physical maintenance of the samples, we track within our databases the current and ever changing characteristics (weight, location, etc.) of more than 250,000 individually numbered samples across our various collections, as well as more than 100,000 images, and countless "analog" records that record the sample processing records of each individual sample. JSC Curation is co-located with JSC's Astromaterials Research Office, which houses a world-class suite of analytical instrumentation and scientists. We leverage these labs and personnel to better curate the samples. Part of the cu-ration process is planning for the future, and we refer to these planning efforts as "advanced curation". Advanced Curation is tasked with developing procedures, technology, and data sets necessary for curating new types of collections as envi-sioned by NASA exploration goals. We are (and have been) planning for future cu-ration, including cold curation, extended curation of ices and volatiles, curation of samples with special chemical considerations such as perchlorate-rich samples, and curation of organically- and biologically-sensitive samples.

Zeigler, R. A.↗

Aqueous Alteration Mineralogy in CM Carbonaceous Chondrites

Iron-nickel sulfides are found in most or all solar system environments, and are probably the only minerals found in all extraterrestrial materials on hand. Despite the ubiquity, they have not received the attention they deserve. The most common Fe-Ni sulfides in chondrites are troilite (FeS), pyrrhotite (Fe1- XS) and pentlandite (Fe,Ni)9S8. Troilite is believed to have resulted from sulfidation of metal (Fe-Ni) grains in an H2Scontaining environment. Pyrrhotite is produced when friable troilite grains, which are exfoliated from the metal nucleus, are submitted to continued sulfidation [1]. Some asteroids are known to have experienced aqueous alteration, forming products including new generations of sulfides (pyrrhotite and pentlandite). Pentlandite in particular is known to form during such alteration [1]. However, experimental work by Lauretta has indicated that pentlandite may also have been formed during the initial sulfidation process [2], due to the faster diffusion rate of nickel into the forming sulfide, as compared to iron. Finally, there is considerable evidence [1,3&4] for a family of phases intermediate between pyrrhotite and pentlandite, following the trend of the high temperature monosulfide solid solution [5], something not encountered in terrestrial rocks.

Chokai, J.↗

Solar System Samples for Research, Education, and Public Outreach

In the next two years, during the NASA Year of the Solar System, spacecraft from NASA and our international partners will; encounter a comet, orbit asteroid 4 Vesta, continue to explore Mars with rovers, and launch robotic explorers to the Moon and Mars. We have pieces of all these worlds in our laboratories, and their continued study provides incredibly valuable "ground truth" to complement space exploration missions. Extensive information about these unique materials, as well as actual lunar samples and meteorites, are available for display and education. The Johnson Space Center (JSC) has the unique responsibility to curate NASA's extraterrestrial samples from past and future missions. Curation includes documentation, preservation, preparation, and distribution of samples for research, education, and public outreach.

Allen, J.↗

Organic Contamination Baseline Study in NASA Johnson Space Center Astromaterials Curation Laboratories

Future robotic and human spaceflight missions to the Moon, Mars, asteroids, and comets will require curating astromaterial samples with minimal inorganic and organic contamination to preserve the scientific integrity of each sample. 21st century sample return missions will focus on strict protocols for reducing organic contamination that have not been seen since the Apollo manned lunar landing program. To properly curate these materials, the Astromaterials Acquisition and Curation Office under the Astromaterial Research and Exploration Science Directorate at NASA Johnson Space Center houses and protects all extraterrestrial materials brought back to Earth that are controlled by the United States government. During fiscal year 2012, we conducted a year-long project to compile historical documentation and laboratory tests involving organic investigations at these facilities. In addition, we developed a plan to determine the current state of organic cleanliness in curation laboratories housing astromaterials. This was accomplished by focusing on current procedures and protocols for cleaning, sample handling, and storage. While the intention of this report is to give a comprehensive overview of the current state of organic cleanliness in JSC curation laboratories, it also provides a baseline for determining whether our cleaning procedures and sample handling protocols need to be adapted and/or augmented to meet the new requirements for future human spaceflight and robotic sample return missions.

Calaway, Michael J.↗

Iron-Nickel Sulfide Compositional Ranges in CM Chondrites: No Simple Plan

Iron-nickel sulfides are found in most or all solar system environments, and are probably the only minerals found in all extraterrestrial materials on hand. Despite this ubiquity, they have only just begun the attention they deserve. The most common Fe-Ni sulfides in chondrites are troilite (FeS), pyrrhotite (Fe(1-x)S) and pentlandite (Fe,Ni)9S8. Troilite is believed to have resulted from sulfidation of metal (Fe-Ni) grains in an H2S-containing environment. Pyrrhotite is produced when friable troilite grains, which are exfoliated from the metal nucleus, are submitted to continued sulfidation. Some asteroids are known to have experienced aqueous alteration, forming products including new generations of sulfides (pyrrhotite and pentlandite). Pentlandite in particular is known to form during such alteration. However, experimental work by Lauretta has indicated that pentlandite may also have been formed during the initial sulfidation process, due to the faster diffusion rate of nickel into the forming sulfide, as compared to iron. Finally, there is considerable evidence for a family of phases intermediate between pyrrhotite and pentlandite, following the trend of the high temperature monosulfide solid solution, something not encountered in terrestrial rocks. Each sulfide has its own particular stability conditions, which have been determined for most phases. The long-term objective of our research is to characterize sulfides in chondritic materials in order to better establish the conditions under which they formed, and the subsequent processes they experienced. Ultimately, it will be possible to infer whether the sulfides in the chondrites were formed in the solar nebula or on asteroids, and if formed on the asteroids, deduce how much alteration has occurred there. Here we explore the relationships between the finest grain size portions of carbonaceous chondrites, these being matrix and chondrule rims; fine-grained materials are the most sensitive to their environment. This abstract is one of a series reporting results for chondrites, earlier work reported results for a much more limited set of CMs, as well as for CVs and CIs.

Zolensky, Michael↗