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At least 163 records · Page 9

Airborne Doppler lidar wind field measurements

A coherent Doppler lidar has been used in an aircraft to measure the two-dimensional wind field in a number of different atmospheric situations. The lidar, a pulsed CO2 system, was installed in the NASA Convair 990, Galileo II, and flown in a summer field program that included flights in California, in Oklahoma at the National Severe Storms Laboratory, and in Montana at the Cooperative Convective Precipitation Experiment (CCOPE). This paper provides a brief description of the instrumentation and summarizes the research flights. Examples of some of the results are given along with plans for future use of the lidar.

Bilbro, J.↗

Exploring Causal Relationships and Adjustment Timescales of Aerosol-Cloud Interactions in Geostationary Satellite Observations and CAM6 Using Wavelet Phase Coherence Analysis

We present for the first time within the cloud physics context, the application of wavelet phase coherence analysis to disentangle counteracting physical processes associated with the lead-lag phase difference between cloud-proxy liquid water path (LWP) and aerosol-proxy cloud droplet number concentration ( N d ) in an Eulerian framework using satellite-based observations and climate model outputs. This approach allows us to identify the causality and dominant adjustment timescales governing the correlation between LWP and N d . Satellite observations indicate a more prevalent positive correlation between daytime LWP and N d regardless of whether LWP leads or lags N d . The positive cloud water response, associated with precipitation processes, typically occurs within 1 hr, while the negative response resulting from entrainment drying, usually takes 2–4 hr. CAM6 displays excessively rapid negative responses along with overly strong negative cloud water response and insufficient positive response, leading to a more negative correlation between LWP and N d compared to observations.

54 ENVIRONMENTAL SCIENCES↗

A mesoscale gravity wave event observed during CCOPE. III - Wave environment and probable source mechanisms

The multiscale environment of gravity wave events and the probable mechanisms of their origin are examined on the basis of observations taken during the Cooperative Convective Precipitation Experiment in extreme eastern Montana, during the period from 1200 UTC July 11, 1981, to 0500 UTC July 12. During this time, two distinct gravity wave episodes were diagnosed. The results of the analysis of the evolving structures in the subsynoptic-scale and mesoscale environments indicate that the observed mesoscale gravity waves were generated by geostrophic adjustment processes, with additional energy supplied through interaction with the critical level; their coherence was maintained through a ducting mechanism.

Koch, Steven E.↗

Implications of solar p-mode frequency shifts

An expression is derived that relates solar p-mode frequency shifts to changes in the entropy and magnetic field of the sun. The frequency variations result from changes in path length and propagation speed. Path length changes dominate for entropy perturbations, and propagation speed changes dominate for most types of magnetic field peturbations. The p-mode frequencies increased along with solar activity between 1986 and 1989; these frequency shifts exhibited a rapid rise with increasing frequency followed by a precipitous drop. The positive component of the shifts can be accounted for by variations of the mean square magnetic field strength in the vicinity of the photosphere. The magnetic stress perturbation decays above the top of the convection zone on a length scale comparable to the pressure scale height and grows gradually with depth below. The presence of a resonance in the chromospheric cavity means that the transition layer maintains enough coherence to partially reflect acoustic waves even near cycle maximum.

Goldreich, Peter↗

Ab Initio Study of Energetics, Charge Transfer, and Atomic Structures of FCC Fe/NbC Interfaces with and Without N Doping: From Coherent to Semi-coherent Interfaces

Nitrogen is added to stainless steels to improve their toughness and corrosion resistance. However, it is not well understood how nitrogen may impact the precipitate/matrix interfacial properties. In this work, we consider the (FCC) Fe (001)/NbC (001) interface as a model system to study how interfacial structure, energy, and electron charge are affected by nitrogen using DFT calculations. We compare the structures and energetics of coherent and semi-coherent interfaces by including the elastic contribution component. It is found that nitrogen does not have a significant effect on either the interfacial energy or the atomic arrangement near the interface region. A highly intricate bonding feature is revealed near heterophase interfaces between alloy elements, in which metallic and covalent features are present together with charge transfer. Additionally, the work on determining accurate interfacial energies is at the core of all quantitative precipitation modeling efforts (in particular, in the XMAT Program). In turn, nucleation, growth/dissolution, and coarsening of precipitates contribute critically to the material’s ability to withstand creep, creep fatigue, and other detrimental processes reducing its service life. It is for this reason that developing quantitative understanding of interfaces and their energetics in materials is so important for their development and further improvement.

36 MATERIALS SCIENCE↗

Coherent lidar airborne windshear sensor - Performance evaluation

As part of the NASA/FAA National Integrated Windshear Program, a measurable windshear hazard index has been defined that can be remotely sensed from an aircraft, to give the pilot information about the wind conditions along the flight path. A technology analysis and end-to-end performance simulation measuring signal-to-noise ratios and resulting wind velocity errors for competing coherent laser radar (lidar) systems have been carried out. The results show that a Ho:YAG lidar at a wavelength of 2.1 microns and a CO2 lidar at 10.6 microns can give the pilot information about the line-of-sight component of a windshear threat from his present position to a region extending 2-4 km in front of the aircraft. This constitutes a warning time of 20-40 s, even in conditions of moderately heavy precipitation.

Targ, Russell↗

Active populations and growth of soil microorganisms are framed by mean annual precipitation in three California annual grasslands

Climate influences soil microbial composition and function, but the relative importance of a site's historic climate versus its more immediate environmental conditions is unclear. Using quantitative stable isotope probing (qSIP), we characterized actively growing soil microbial communities and soil properties in three California annual grasslands that span a rainfall gradient and have developed on similar parent material. The soils were assayed in the wet winter season, when environmental conditions are most similar across sites. Since growing populations might be expected to be most responsive to contemporary environmental conditions, we hypothesized that the structure of growing microbial communities would be more similar across the gradient than that of total communities (i.e., including non-growing populations). In addition, we hypothesized that population growth rates would be slowest in the driest site, reflecting a legacy effect of low soil moisture on microbial growth. Soils along the rainfall gradient differed in pH, texture, and cation exchange capacity, but not in total C, C:N or dominant minerals. The radiocarbon (14C) age of soil C (reflecting turnover time) increased with mean annual precipitation but soil respiration was uniformly modern, reflecting microbial reliance on recent C inputs across the sites. The structure of both total and growing microbial communities differed across sites. Across major microbial phyla, including the Actinobacteria, Acidobacteria, Bacteroidetes, Gemmatimonadetes and Proteobacteria, bacterial growth rates were consistently lower in the site with the lowest mean annual precipitation. Taxa that were growing at the dry site alone grew more slowly than taxa that grew at multiple sites. These results reflect the influence of climate history and point to the role of environmental filtering at the driest site in shaping its slower growing microbial community, possibly reflecting adaptation to repeated exposure to water stress. Lastly, across taxa, the growth rate of a taxon at one site was correlated with its growth rate in the other sites. Furthermore, this growth rate coherence is likely a consequence of genetically determined physiological traits and is consistent with the idea that evolutionary history constrains growth rate.

Environmental filtering↗

Dual heterogeneous structures lead to ultrahigh strength and uniform ductility in a Co-Cr-Ni medium-entropy alloy

Alloys with ultra-high strength and sufficient ductility are highly desired for modern engineering applications but difficult to develop. Here we report that, by a careful controlling alloy composition, thermomechanical process, and microstructural feature, a Co-Cr-Ni-based medium-entropy alloy (MEA) with a dual heterogeneous structure of both matrix and precipitates can be designed to provide an ultra-high tensile strength of 2.2 GPa and uniform elongation of 13% at ambient temperature, properties that are much improved over their counterparts without the heterogeneous structure. Electron microscopy characterizations reveal that the dual heterogeneous structures are composed of a heterogeneous matrix with both coarse grains (10~30 μm) and ultra-fine grains (0.5~2 μm), together with heterogeneous L1 2 -structured nanoprecipitates ranging from several to hundreds of nanometers. The heterogeneous L1 2 nanoprecipitates are fully coherent with the matrix, minimizing the elastic misfit strain of interfaces, relieving the stress concentration during deformation, and playing an active role in enhanced ductility.

36 MATERIALS SCIENCE↗

Coherent HF radar backscatter from small-scale irregularities in the dusk sector of the subauroral ionosphere

This paper describes the characteristics of backscatter from decameter-scale ionospheric plasma density irregualarities, observed with an impressive regularity by the Goose Bay (Labrador) high-frequency (HF) radar in the dusk sector of the winter ionosphere, and discusses the relation of the scatter to the midlatitude trough. It is shown that this dusk scatter can be readily distinguished from other types of late afternoon/early evening scatter by the extreme equatorward position of its source region and by the low values of its associated radar Doppler velocities (not above 200 m/s) and spectral widths (not more than 200 m/s). A comparison of the radar observations with nearly simultaneous particle precipitation data obtained with the DMSP F6 satellite demonstrated that the source region of the backscatter lies within the subauroral ionosphere. It is shown that the characteristics of dusk scatter are compatible with the Spiro et al. (1978) model of the electrodynamics of the midlatitude trough.

Ruohoniemi, J. M.↗

Comparison of Vertical Surface Deformation Estimates Derived From Space-Based Gravimetry, Ground-Based GPS, and Model-Based Hydrologic Loading Over Snow-Dominated Watersheds in the United States

Spatiotemporal variability in Earth's terrestrial water storage (TWS) causes changes in surface deformation. The potential for using ground-based Global Positioning System (GPS) vertical displacement observations for estimating TWS is explored through a comparison of vertical displacements derived from space-based gravimetric retrievals, ground-based GPS, and model-based hydrologic estimates. The study presented here focuses on two snow-dominated basins in the Western United States for the years 2003–2016. Seasonal variations are observed in the vertical displacements derived from all three data sets, and the variation is coherent with the changes in hydrologic loading. Good consistency is observed between any two of the three data sets with gravimetric retrievals and hydrologic model estimates providing the highest level of agreement (i.e., all examined stations with correlation coefficient R > 0.70). Vertical displacements derived from gravimetric retrievals and ground-based GPS yielded R > 0.70 for more than 89% of the stations. In addition, it is found that both GPS-derived and space-based, gravimetry-derived vertical displacements clearly reflected the impact of climate variation (i.e., heavy precipitation during 2010–2011 winter followed by prolonged drought). Vertical displacements derived from the hydrologic model highlighted the relatively large precipitation convergence phase during late 2010 to early 2011 at some stations but not the prolonged drought that followed. The results indicate that ground-based GPS observations of vertical displacement have the capability to capture variations in TWS changes, which can be systematically merged in conjunction with Gravity Recovery and Climate Experiment (GRACE) into a land surface model to improve TWS estimates in a follow-up study.

Gaohong Yin↗

Calibrating radar wind profiler reflectivity factor using surface disdrometer observations

Abstract. This study uses surface disdrometer reflectivity factor estimates to calibrate the vertical and off-vertical pointing radar beams produced by an ultra high frequency (UHF) band radar wind profiler (RWP) deployed at the US Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) program Southern Great Plains (SGP) Central Facility in northern Oklahoma from April 2011 through July 2019. The methodology consists of five steps. First, the recorded Doppler velocity power spectra are adjusted to account for Nyquist velocity aliasing and coherent integration filtering effects. Second, the spectrum moments are calculated. The third step increases the signal-to-noise ratio (SNR) due to inflated noise power estimates during convective rain events that cause SNR to be biased low. The fourth step determines the RWP calibration constant for one radar beam (called the “reference” beam) by comparing uncalibrated RWP reflectivity factors at 500 m above the ground to 1 min resolution surface disdrometer reflectivity factors. The last step uses the calibrated reference beam reflectivity factor to calibrate the other radar beams during precipitation. There are two key findings. The RWP sensitivity decreased by approximately 3 to 4 dB yr−1 as the hardware aged. This drift was slow enough that the reference calibration constant can be estimated over 3-month intervals using episodic rain events. The calibrated moments are available on the DOE ARM data archive, and the Python processing code is available on public repositories.

54 ENVIRONMENTAL SCIENCES↗

Electrostatic waves stimulated by coherent VLF signals propagating in and near the inner radiation belt

The excitation of electrostatic waves by whistler-mode VLF signals propagating along magnetic-field lines in and near the earth's inner radiation belt is examined on the basis of ISEE-1 observations obtained during July-December 1983. The data are presented in extensive graphs and characterized in detail. The effect is seen in about 60 percent of the ISEE-1 orbits penetrating the belt and for signals originating in both hemispheres, with an electrostatic-wave effective bandwidth roughly proportional to the local magnetic-field strength. These results are interpreted in terms of a theoretical model in which scattering of the VLF waves off magnetic-field-aligned plasma density irregularities is followed by particle pitch-angle scattering and precipitation in the radiation belt; the latter effect could then produce new irregularities via a feedback mechanism.

Bell, T. F.↗

Pulsed laser Doppler measurements of wind shear

There is a need for a sensor at the airport that can remotely detect, identify, and track wind shears near the airport in order to assure aircraft safety. To determine the viability of a laser wind-shear system, the NASA pulsed coherent Doppler CO2 lidar (Jelalian et al., 1972) was installed in a semitrailer van with a rooftop-mounted hemispherical scanner and was used to monitor thunderstorm gust fronts. Wind shears associated with the gust fronts at the Kennedy Space Center (KSC) between 5 July and 4 August 1978 were measured and tracked. The most significant data collected at KSC are discussed. The wind shears were clearly visible in both real-time velocity vs. azimuth plots and in postprocessing displays of velocities vs. position. The results indicate that a lidar system cannot be used effectively when moderate precipitation exists between the sensor and the region of interest.

Dimarzio, C.↗

Molecular Dynamics Simulations of Microstructural Effects on Austenite-Martensite Interfaces in NiTi

Formation and migration of austenite-martensite interfaces plays the key role in reversible martensitic transformations of shape memory alloys (SMAs). How these interfaces interact with the SMA microstructure is a primary determining factor in important functional properties such as hysteresis and transformation span. As such, successful microstructural engineering of SMAs requires in-depth knowledge of interface behavior. The rapid nature of martensitic transformations makes experimental observations of moving austenite-martensite interfaces challenging. Molecular dynamics (MD) simulation is a unique tool which can probe the atomic-scale details of austenite-martensite interfaces as they migrate through different microstructures. However, in focusing on the entire transformation process, including the nucleation of new phases, MD studies are usually performed so far from equilibrium that their relevance to experiment is questionable. Here, we demonstrate new MD techniques to generate energetically preferred austenite-martensite interfaces in NiTi under near-equilibrium conditions. The interfaces are semi-coherent, exhibiting a series of structural disconnections, and they can migrate rapidly through single crystals under only small thermodynamic driving forces. In contrast, when interfaces migrate in polycrystals, their motion is impeded by thermoelastic effects as well as changes in orientation relationships at grain boundaries. Microstructures which accumulate large amounts of elastic energy tend to release some fraction through irreversible, hysteresis-inducing mechanisms. We demonstrate that engineering microstructures with less constraints is a viable strategy to produce SMAs with reduced hysteresis and transformation span. Similar thermoelastic and hysteresis-inducing mechanisms also arise when austenite-martensite interfaces encounter precipitates and can be controlled by tuning characteristics of the precipitate distribution.

Gabriel Plummer↗

Molecular Dynamics Simulations of Microstructural Effects on Austenite-Martensite Interfaces in NiTi

The formation and migration of austenite-martensite interfaces plays the key role in reversible martensitic transformations of shape memory alloys (SMAs). How these interfaces interact with the SMA microstructure is a primary determining factor in important functional properties such as hysteresis and transformation span. As such, successful microstructural engineering of SMAs requires in-depth knowledge of interface behavior. The rapid nature of martensitic transformations makes experimental observations of moving austenite-martensite interfaces challenging. Molecular dynamics (MD) simulation is a unique tool which can probe the atomic-scale details of austenite-martensite interfaces as they migrate through different microstructures. However, in focusing on the entire transformation process, including the nucleation of new phases, MD studies are usually performed so far from equilibrium that their relevance to experiment is questionable. Here, we demonstrate new MD techniques to generate energetically preferred austenite-martensite interfaces in NiTi under near-equilibrium conditions. The interfaces are semi-coherent, exhibiting a series of structural disconnections, and they can migrate rapidly through single crystals under only small thermodynamic driving forces. In contrast, when interfaces migrate in polycrystals, their motion is impeded by thermoelastic effects as well as changes in orientation relationships at grain boundaries. Microstructures which accumulate large amounts of elastic energy tend to release some fraction through irreversible, hysteresis-inducing mechanisms. We demonstrate that engineering microstructures with less constraints is a viable strategy to produce SMAs with reduced hysteresis and transformation span. Similar thermoelastic and hysteresis-inducing mechanisms also arise when austenite-martensite interfaces encounter precipitates and can be controlled by tuning characteristics of the precipitate distribution.

Gabriel Plummer↗

Molecular Dynamics Simulations of Microstructural Effects on Austenite-Martensite Interfaces in NiTi

Formation and migration of austenite-martensite interfaces plays the key role in reversible martensitic transformations of shape memory alloys (SMAs). How these interfaces interact with the SMA microstructure is a primary determining factor in important functional properties such as hysteresis and transformation span. As such, successful microstructural engineering of SMAs requires in-depth knowledge of interface behavior. The rapid nature of martensitic transformations makes experimental observations of moving austenite-martensite interfaces challenging. Molecular dynamics (MD) simulation is a unique tool which can probe the atomic-scale details of austenite-martensite interfaces as they migrate through different microstructures. However, in focusing on the entire transformation process, including the nucleation of new phases, MD studies are usually performed so far from equilibrium that their relevance to experiment is questionable. Here, we demonstrate new MD techniques to generate energetically preferred austenite-martensite interfaces in NiTi under near-equilibrium conditions. The interfaces are semi-coherent, exhibiting a series of structural disconnections, and they can migrate rapidly through single crystals under only small thermodynamic driving forces. In contrast, when interfaces migrate in polycrystals, their motion is impeded by thermoelastic effects as well as changes in orientation relationships at grain boundaries. Microstructures which accumulate large amounts of elastic energy tend to release some fraction through irreversible, hysteresis-inducing mechanisms. We demonstrate that engineering microstructures with less constraints is a viable strategy to produce SMAs with reduced hysteresis and transformation span. Similar thermoelastic and hysteresis-inducing mechanisms also arise when austenite-martensite interfaces encounter precipitates and can be controlled by tuning characteristics of the precipitate distribution.

Gabriel Plummer↗

Selection of a Representative Subset of Global Climate Models that Captures the Profile of Regional Changes for Integrated Climate Impacts Assessment

We present the Representative Temperature and Precipitation (T&P) GCM Subsetting Approach developed within the Agricultural Model Intercomparison and Improvement Project (AgMIP) to select a practical subset of global climate models (GCMs) for regional integrated assessment of climate impacts when resource limitations do not permit the full ensemble of GCMs to be evaluated given the need to also focus on impacts sector and economics models. Subsetting inherently leads to a loss of information but can free up resources to explore important uncertainties in the integrated assessment that would otherwise be prohibitive. The Representative T&P GCM Subsetting Approach identifies five individual GCMs that capture a profile of the full ensemble of temperature and precipitation change within the growing season while maintaining information about the probability that basic classes of climate changes (relatively cool/wet, cool/dry, middle, hot/wet, and hot/dry) are projected in the full GCM ensemble. We demonstrate the selection methodology for maize impacts in Ames, Iowa, and discuss limitations and situations when additional information may be required to select representative GCMs. We then classify 29 GCMs over all land areas to identify regions and seasons with characteristic diagonal skewness related to surface moisture as well as extreme skewness connected to snow-albedo feedbacks and GCM uncertainty. Finally, we employ this basic approach to recognize that GCM projections demonstrate coherence across space, time, and greenhouse gas concentration pathway. The Representative T&P GCM Subsetting Approach provides a quantitative basis for the determination of useful GCM subsets, provides a practical and coherent approach where previous assessments selected solely on availability of scenarios, and may be extended for application to a range of scales and sectoral impacts.

Climate Change; GCMs; Climate Model Subset; Repres↗

Observation of [VCu1–Ini2+VCu1–] Defect Triplets in Cu-Deficient CuInS2

Copper indium disulfide (CuInS2) is a semiconductor with a direct energy band gap of 1.53 eV, an optimal value for highly efficient thin-film solar cells. But it has reached only ~ 11 % power conversion efficiency, far less than the theoretically achievable value of ~ 30 %. The cause of this low performance is not understood. A single crystal grown from 1 mol% Cu-deficient melt was studied, using atomic resolution high-angle annular dark-field (HAADF) scanning transmission electron microscopy (STEM) and electron dispersive spectroscopy (EDS). While the bulk crystal is exactly stoichiometric CuInS2, it contains nanometer-thick, structurally coherent, Cu-deficient interphases that form along rotational twin boundaries in the {112} plane. Transition zones from bulk crystal to interphase are observed, where In is seen to move from its normal site InIn in the chalcopyrite structure to a tetrahedral interstitial site Ini, while Cu remains in its normal CuCu position. Two InIn rows of the bulk crystal merge into one row of Ini, causing excess Ini in the interphase. The concentrations of CuCu and Ini reflect a ratio of Cu vacancies, VCu, to excess Ini of ~ 2. Their relative lattice positions, and the high electrical resistivity of the crystal, suggests that VCu and excess Ini ‘precipitate’ as self-compensating, electrically neutral, [VCu1- Ini2+ VCu1-] defect triplets. This is the first atomic-level observation of the ordered defect that has been invoked as the basic structural modifier in chalcopyrite compound homologs. The interphases introduce an optical gap of 1.47 eV. Electron trapping in band tail states, evident from a photoconductivity exponent of 0.54, is the likely cause of an unusually low electron mobility of 0.1 cm2V-1s-1. The overall result is that making CuInS2 slightly copper-poor inserts nanometer-thick layers of the interphase into the bulk crystal. This study shows that apparently conflicting results of the effect of Cu deficiency on CuInS2 thin-film solar cells may be resolved by analyzing structure and composition at nanometer spatial resolution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗